Solar RRL最新文献

筛选
英文 中文
Synergistic Enhancement of Efficiency and Stability in Triple-Cation Perovskite Solar Cells via Optimal Cadmium Sulfide Quantum Dots Incorporation 三阳离子钙钛矿太阳能电池效率和稳定性的协同增强
IF 4.8 3区 工程技术
Solar RRL Pub Date : 2026-07-30 DOI: 10.1002/solr.70444
Shervin Daneshvar e Asl, Hamaneh Zarenezhad, Sarp Kaya
{"title":"Synergistic Enhancement of Efficiency and Stability in Triple-Cation Perovskite Solar Cells via Optimal Cadmium Sulfide Quantum Dots Incorporation","authors":"Shervin Daneshvar e Asl,&nbsp;Hamaneh Zarenezhad,&nbsp;Sarp Kaya","doi":"10.1002/solr.70444","DOIUrl":"https://doi.org/10.1002/solr.70444","url":null,"abstract":"<p>In this study, we investigate the incorporation of cadmium sulfide (CdS) quantum dots (QDs) into the active layer of triple-cation perovskite solar cells (PSCs) to simultaneously enhance device efficiency and operational stability. A systematic optimization revealed that 0.75 wt.% CdS QDs significantly improve perovskite film crystallinity, morphology, and light absorption and effectively passivate trap states, facilitate charge extraction, and enhance carrier dynamics. Devices with 0.75 wt.% CdS QDs achieved a peak power conversion efficiency (PCE), reduced hysteresis, improved external quantum efficiency, and excellent long-term stability, retaining ~86% of their initial PCE after 21 days of storage. Our findings underscore the potential of CdS QDs as a multifunctional additive for advancing the performance and durability of next-generation PSCs.</p>","PeriodicalId":230,"journal":{"name":"Solar RRL","volume":"10 15","pages":""},"PeriodicalIF":4.8,"publicationDate":"2026-07-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"148616918","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Beyond Exact Current Matching: Fabrication-Tolerant Design of All-Perovskite Tandem Solar Cells via Surrogate Modeling and Diode-Based J–V Reconstruction 超越精确电流匹配:通过替代建模和基于二极管的J-V重建的全钙钛矿串联太阳能电池的制造容忍设计
IF 4.8 3区 工程技术
Solar RRL Pub Date : 2026-07-30 DOI: 10.1002/solr.70434
Mohammadreza Ghobadzadeh, Hamzeh Kashi Yarandi, Maryam Shahrostami, Ali Akbar Haji Zeynali Biyoki, Javad Maleki
{"title":"Beyond Exact Current Matching: Fabrication-Tolerant Design of All-Perovskite Tandem Solar Cells via Surrogate Modeling and Diode-Based J–V Reconstruction","authors":"Mohammadreza Ghobadzadeh,&nbsp;Hamzeh Kashi Yarandi,&nbsp;Maryam Shahrostami,&nbsp;Ali Akbar Haji Zeynali Biyoki,&nbsp;Javad Maleki","doi":"10.1002/solr.70434","DOIUrl":"https://doi.org/10.1002/solr.70434","url":null,"abstract":"<p>All-perovskite tandem solar cells (TSCs) offer a promising route toward efficient photovoltaics, but their performance is affected by current mismatch and thickness variations. Here, we develop an explainable and robust optimization framework for a two-terminal CsPbBr<sub>3</sub>/CsPbI<sub>3</sub>/MASnI<sub>3</sub> TSC. A coupled optical–electrical finite element method (FEM) generates an absorber-thickness dataset to train a multioutput multilayer perceptron surrogate for predicting subcell <i>J</i><sub>SC</sub>, <i>V</i><sub>OC</sub>, fill factor (FF), and power conversion efficiency (PCE). The surrogate is integrated with nominal and Monte Carlo-based robust optimization to identify thickness configurations that balance subcell currents while maintaining a high limiting current under ±10 nm variations. The nominal design achieves near-perfect current matching of 0.009 mA/cm<sup>2</sup> in the prediction and 0.08 mA/cm<sup>2</sup> in the FEM validation, but its mismatch exceeds 2 mA/cm<sup>2</sup> under thickness variation. In contrast, the robust design accepts a finite mismatch of 0.516 mA/cm<sup>2</sup> in the prediction and 0.54 mA/cm<sup>2</sup> in the FEM validation, but occupies a flatter region of the design space. SHapley Additive exPlanations (SHAP) analysis interprets the learned relationship between thickness and current mismatch, showing that mismatch sensitivity arises from coupled spectral redistribution among subcells rather than independent absorber-thickness contributions. Diode-based reconstruction yields a PCE of 29.61% for the robust design versus 28.86% for the nominal case. These findings establish robust design as a reliable paradigm than strict current matching for high-performance perovskite TSCs.</p>","PeriodicalId":230,"journal":{"name":"Solar RRL","volume":"10 15","pages":""},"PeriodicalIF":4.8,"publicationDate":"2026-07-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"148616968","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Boosting Carrier Transport in Carbon-Based Hole-Transport-Layer-Free Perovskite Solar Cells via 2D/3D Interfacial Structural Configuration 通过二维/三维界面结构配置促进碳基无空穴-输运层钙钛矿太阳能电池中的载流子输运
IF 4.8 3区 工程技术
Solar RRL Pub Date : 2026-07-30 DOI: 10.1002/solr.70447
Shiqi You, Liangping Zhu, Wenyan Zhao, Xixi Han, Jiayi Wang, Yumin Liu, Yanna Xu, Shaojian Fu, Chuanjin Tian, Chang-an Wang, Zhipeng Xie
{"title":"Boosting Carrier Transport in Carbon-Based Hole-Transport-Layer-Free Perovskite Solar Cells via 2D/3D Interfacial Structural Configuration","authors":"Shiqi You,&nbsp;Liangping Zhu,&nbsp;Wenyan Zhao,&nbsp;Xixi Han,&nbsp;Jiayi Wang,&nbsp;Yumin Liu,&nbsp;Yanna Xu,&nbsp;Shaojian Fu,&nbsp;Chuanjin Tian,&nbsp;Chang-an Wang,&nbsp;Zhipeng Xie","doi":"10.1002/solr.70447","DOIUrl":"https://doi.org/10.1002/solr.70447","url":null,"abstract":"<p>Interfacial nonradiative recombination and operational instability remain major barriers to the commercialization of perovskite solar cells (PSCs). Hole-transport-layer-free carbon-based PSCs (C-PSCs) provide a promising low-cost and scalable device configuration, yet their efficiency is strongly limited by defective and energetically mismatched perovskite/carbon interfaces. Here, a phenethylammonium chloride (PEACl)-induced interfacial reconstruction strategy is developed to form in situ a Ruddlesden–Popper (RP) two-dimensional (2D) capping layer on three-dimensional (3D) perovskite absorbers. Analyses via low-angle X-ray diffraction (XRD), photoluminescence (PL), and X-ray photoelectron spectroscopy (XPS) demonstrate that a 2D RP phase capping layer is formed. This layer passivates defects associated with undercoordinated lead, improves interfacial energy states, and enhances surface moisture resistance. Consequently, interfacial recombination is substantially suppressed, while hole extraction toward the carbon electrode is promoted and electron back-transfer is inhibited. The optimized C-PSCs deliver a power conversion efficiency (PCE) of 17.75% with a fill factor of 69.02%, together with enhanced open-circuit voltage. Moreover, the unencapsulated device retains over 93% of its initial efficiency after 550<sup> </sup>h of exposure to humid air, evidencing markedly improved stability. This work establishes 2D RP phase-mediated interfacial reconstruction as an effective route toward efficient, stable, and low-cost carbon-based perovskite photovoltaics.</p>","PeriodicalId":230,"journal":{"name":"Solar RRL","volume":"10 15","pages":""},"PeriodicalIF":4.8,"publicationDate":"2026-07-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"148616967","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Recent Advances of Quasi-Two-Dimensional Perovskite Solar Cells 准二维钙钛矿太阳能电池的研究进展
IF 4.8 3区 工程技术
Solar RRL Pub Date : 2026-07-28 DOI: 10.1002/solr.70427
Yekai Li, Xiangxi Chen, Chunli Xiang, Minhan Liu, Xing Zhou, Jin Zhao, Qiang Zhou, Xiang Li, Hongquan Zhao, Xingzhu Wang, Weichuan Zhang
{"title":"Recent Advances of Quasi-Two-Dimensional Perovskite Solar Cells","authors":"Yekai Li,&nbsp;Xiangxi Chen,&nbsp;Chunli Xiang,&nbsp;Minhan Liu,&nbsp;Xing Zhou,&nbsp;Jin Zhao,&nbsp;Qiang Zhou,&nbsp;Xiang Li,&nbsp;Hongquan Zhao,&nbsp;Xingzhu Wang,&nbsp;Weichuan Zhang","doi":"10.1002/solr.70427","DOIUrl":"https://doi.org/10.1002/solr.70427","url":null,"abstract":"<p>Quasi-two-dimensional (quasi-2D) perovskites are promising materials for next-generation photovoltaics, offering significantly improved moisture and thermal stability over conventional three-dimensional (3D) perovskites. However, their intrinsic multiple-quantum-well structure and the inclusion of bulky insulating organic cations severely hinder charge-carrier transport, interlayer charge transfer, and phase purity, resulting in power conversion efficiencies that still lag substantially behind those of 3D counterparts. This review systematically analyzes the structural and optoelectronic properties of key quasi-2D perovskite systems, including the Ruddlesden–Popper, Dion–Jacobson, and alternating-cation-in-the-interlayer phases. It then outlines the persistent challenges in realizing high-performance devices, focusing particularly on crystallographic orientation control and phase distribution regulation. Recent advances in performance optimization are comprehensively reviewed, encompassing compositional engineering, intermediate-phase manipulation, solvent and additive strategies, interfacial modification, and advanced deposition techniques, with corresponding mechanistic insights provided. Finally, current limitations are critically evaluated, and future research directions toward rational molecular design and scalable manufacturing are proposed to advance the practical deployment of efficient and stable quasi-2D perovskite solar cells.</p>","PeriodicalId":230,"journal":{"name":"Solar RRL","volume":"10 14","pages":""},"PeriodicalIF":4.8,"publicationDate":"2026-07-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"148616154","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Quantifying Perovskite Solar Cell Degradation via Machine Learning From Spatially Resolved Multimodal Luminescence Time Series 通过机器学习从空间分辨多模态发光时间序列量化钙钛矿太阳能电池退化
IF 4.8 3区 工程技术
Solar RRL Pub Date : 2026-07-28 DOI: 10.1002/solr.70433
Giulio Barletta, Simon Ternes, Saif Ali, Zohair Abbas, Chiara Ostendi, Marialucia D’Addio, Erica Magliano, Pietro Asinari, Eliodoro Chiavazzo, Aldo Di Carlo
{"title":"Quantifying Perovskite Solar Cell Degradation via Machine Learning From Spatially Resolved Multimodal Luminescence Time Series","authors":"Giulio Barletta,&nbsp;Simon Ternes,&nbsp;Saif Ali,&nbsp;Zohair Abbas,&nbsp;Chiara Ostendi,&nbsp;Marialucia D’Addio,&nbsp;Erica Magliano,&nbsp;Pietro Asinari,&nbsp;Eliodoro Chiavazzo,&nbsp;Aldo Di Carlo","doi":"10.1002/solr.70433","DOIUrl":"https://doi.org/10.1002/solr.70433","url":null,"abstract":"<p>Perovskite solar cells achieve remarkable power conversion efficiencies, yet operational stability remains a major barrier to large-scale deployment. Reliable and rapid assessment of device state of health is therefore essential. Conventional electrical diagnostics, such as illuminated current–voltage (J–V) sweeps, provide accurate performance metrics but are time-consuming and do not resolve spatially localized degradation, motivating non-invasive imaging-based alternatives. Here, a deep-learning framework is introduced to estimate PSC efficiency retention, <i>R</i><sub>PCE</sub> = PCE<sub><i>t</i></sub>/PCE<sub>0</sub>, directly from multimodal luminescence imaging acquired during device aging. Each sample combines electroluminescence (EL), open-circuit photoluminescence (PL<sub>oc</sub>), and short-circuit photoluminescence (PL<sub>sc</sub>) at an aged state with device-specific reference images at <i>t </i>= 0, enabling learning of degradation-relevant spatial changes. LumPerNet, a compact convolutional neural network, is benchmarked against a spatially homogenized control in which each luminescence channel is replaced by its spatial average while retaining the same learning framework and leakage-aware protocol. The comparison indicates that global luminescence evolution contains most of the predictive signal, while spatial information provides a secondary contribution to robustness. These results establish spatially resolved luminescence imaging as a practical route for accelerated stability testing and non-invasive degradation monitoring in perovskite photovoltaics.</p>","PeriodicalId":230,"journal":{"name":"Solar RRL","volume":"10 15","pages":""},"PeriodicalIF":4.8,"publicationDate":"2026-07-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/solr.70433","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"148616432","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Discrete Aluminum Oxide Surface Passivation Enables High Efficient Cadmium Telluride Solar Cells 离散氧化铝表面钝化实现高效碲化镉太阳能电池
IF 4.8 3区 工程技术
Solar RRL Pub Date : 2026-07-28 DOI: 10.1002/solr.70440
Qianqian Gao, Jiabin Dong, Wenyu Qiu, Ming Li, Yunfeng Wang, Tianyu Xing, Yi Zhang
{"title":"Discrete Aluminum Oxide Surface Passivation Enables High Efficient Cadmium Telluride Solar Cells","authors":"Qianqian Gao,&nbsp;Jiabin Dong,&nbsp;Wenyu Qiu,&nbsp;Ming Li,&nbsp;Yunfeng Wang,&nbsp;Tianyu Xing,&nbsp;Yi Zhang","doi":"10.1002/solr.70440","DOIUrl":"https://doi.org/10.1002/solr.70440","url":null,"abstract":"<p>Cadmium telluride (CdTe) thin film has attracted significant attention in photovoltaic applications due to its high optical absorption coefficient and long-term stable performance. However, the undesired back contact still worsens the charge carrier transport and thus hinders the power conversion efficiency (PCE) of CdTe solar cells. In this study, discrete aluminum oxide (Al<sub>2</sub>O<sub>3</sub>) nanoparticles are developed as a passivation layer to modify the back interface between the CdTe absorber and the Au electrode. The results demonstrate that the poorly coated Al<sub>2</sub>O<sub>3</sub> nanoparticles do not lead to an increase in resistance. In addition, the carrier lifetime improves after Al<sub>2</sub>O<sub>3</sub> nanoparticles are involved, which allows more efficient charge carrier transport at the back contact interface. Finally, the CdTe solar cell exhibits significantly improved fill factor and open-circuit voltage (<i>V</i><sub>OC</sub>) of 74.81% and 848 mV, with a PCE of 17.45%. These results disclose new insights into addressing key challenges that hinder the development of CdTe solar cells.</p>","PeriodicalId":230,"journal":{"name":"Solar RRL","volume":"10 15","pages":""},"PeriodicalIF":4.8,"publicationDate":"2026-07-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"148616236","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Synergistic Molecular Engineering of Novel Self-Assembled Monolayer for Perovskite Solar Cells 钙钛矿太阳能电池新型自组装单层膜的协同分子工程研究
IF 4.8 3区 工程技术
Solar RRL Pub Date : 2026-07-28 DOI: 10.1002/solr.70423
Xuepeng Liu, Jie Liu, Botong Li, Mingyuan Han, Zhipeng Shao, Ziqiang Su, Zedong Lin, Wenyong Feng, Changqing Lin, Yong Ding
{"title":"Synergistic Molecular Engineering of Novel Self-Assembled Monolayer for Perovskite Solar Cells","authors":"Xuepeng Liu,&nbsp;Jie Liu,&nbsp;Botong Li,&nbsp;Mingyuan Han,&nbsp;Zhipeng Shao,&nbsp;Ziqiang Su,&nbsp;Zedong Lin,&nbsp;Wenyong Feng,&nbsp;Changqing Lin,&nbsp;Yong Ding","doi":"10.1002/solr.70423","DOIUrl":"https://doi.org/10.1002/solr.70423","url":null,"abstract":"<p>The commonly used self-assembled hole transport monolayer (SAM) in perovskite solar cells always suffer aggregation, energy level mismatch, and weak interaction with perovskite. Design and develop of novel SAM have been proven to be an important approach to enhance device efficiency and stability. Herein, a novel SAM incorporates methoxynaphthalene as terminal group was successfully developed, named MeONa-4PACz. Compared with commercial MeO-4PACz, MeONa-4PACz exhibits more uniform distribution on the substrate due to the distorted molecular configuration. The MeONa-4PACz-based substrates display improved wettability for perovskite precursor, leading to enhanced perovskite crystallization. The introduction of naphthalene decreases the size of the π-conjugated system and lowers HOMO level, which achieves better alignment with the valence band of the perovskite layer. Moreover, the superior interaction between MeONa-4PACz with perovskite effectively suppress non-radiative recombination. Consequently, the device employing MeONa-4PACz achieved a high power conversion efficiency of 26.07%. Additionally, devices based on MeONa-4PACz demonstrate exceptional stability compared to MeO-4PACz.</p>","PeriodicalId":230,"journal":{"name":"Solar RRL","volume":"10 15","pages":""},"PeriodicalIF":4.8,"publicationDate":"2026-07-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"148616431","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Flexible Monolithic 2-Terminal Kesterite Cu2ZnSnSe4/Perovskite Tandem Solar Cells 柔性单片2端Kesterite Cu2ZnSnSe4/钙钛矿串联太阳能电池
IF 4.8 3区 工程技术
Solar RRL Pub Date : 2026-07-28 DOI: 10.1002/solr.70432
Muhammad Rehan, Hung Van Tran, Inyoung Jeong, Awet Mana Amare, Ara Cho, S. F. A. Shah, Afia Owusuah Akyaw, Sejin Ahn, Sungjun Hong, JunHo Kim, Jae Ho Yun, Joo Hyung Park, Kihwan Kim, Jihye Gwak, Donghyeop Shin
{"title":"Flexible Monolithic 2-Terminal Kesterite Cu2ZnSnSe4/Perovskite Tandem Solar Cells","authors":"Muhammad Rehan,&nbsp;Hung Van Tran,&nbsp;Inyoung Jeong,&nbsp;Awet Mana Amare,&nbsp;Ara Cho,&nbsp;S. F. A. Shah,&nbsp;Afia Owusuah Akyaw,&nbsp;Sejin Ahn,&nbsp;Sungjun Hong,&nbsp;JunHo Kim,&nbsp;Jae Ho Yun,&nbsp;Joo Hyung Park,&nbsp;Kihwan Kim,&nbsp;Jihye Gwak,&nbsp;Donghyeop Shin","doi":"10.1002/solr.70432","DOIUrl":"https://doi.org/10.1002/solr.70432","url":null,"abstract":"<p>Growing demand for flexible photovoltaics has intensified interest in high-efficiency tandem solar cells. This study demonstrates flexible monolithic kesterite/perovskite tandems by addressing the poor morphology and limited long-wavelength response of low-bandgap kesterite bottom cells. To enable flexible and tandem device applications, high-quality Cu<sub>2</sub>ZnSnSe<sub>4</sub> (CZTSe) films were grown at 480 °C using a low-temperature, single-step coevaporation process compatible with flexible polyimide (PI) substrates. The incorporation of Ag further enhances crystallization and enables the defect passivation in the CZTSe absorber layer. Admittance spectroscopy reveals that Ag incorporation reduces the defect density of states from 1.4 × 10<sup>18</sup> to 8.7 × 10<sup>17</sup> cm<sup>−3</sup> eV<sup>−1</sup>. Consequently, the single-junction efficiency improves from 5.6% to 8.7% on glass and reaches 7.3% on flexible PI substrates. Integration with a perovskite top cell yields a tandem efficiency of 16.4% on glass and a record 11.35% on flexible PI. Furthermore, the flexible device retains ~70% of its initial efficiency after 1000 bending cycles. These results highlight the potential of Ag-doped CZTSe fabricated via low-temperature coevaporation for high-performance, earth-abundant, and flexible tandem photovoltaics.</p>","PeriodicalId":230,"journal":{"name":"Solar RRL","volume":"10 15","pages":""},"PeriodicalIF":4.8,"publicationDate":"2026-07-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"148616430","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Interface Passivation and Morphology Regulation of Fullerene-Based Perovskite Solar Cells for Enhancing Device Performance by phenethylammonium iodide 苯乙基碘化铵增强富勒烯基钙钛矿太阳能电池性能的界面钝化和形态调控
IF 4.8 3区 工程技术
Solar RRL Pub Date : 2026-07-27 DOI: 10.1002/solr.70437
Ye Wang, Hengji Li, Qianwen Cao, Qixu Hu, Lifang Wu, Xiaojie Liu, Ronghui Deng, Tenglong Xu, Chang Xue, Yitian Du, Tianhao Wu, Ihsan Ullah, Selcuk Yerci, Shenghao Wang
{"title":"Interface Passivation and Morphology Regulation of Fullerene-Based Perovskite Solar Cells for Enhancing Device Performance by phenethylammonium iodide","authors":"Ye Wang,&nbsp;Hengji Li,&nbsp;Qianwen Cao,&nbsp;Qixu Hu,&nbsp;Lifang Wu,&nbsp;Xiaojie Liu,&nbsp;Ronghui Deng,&nbsp;Tenglong Xu,&nbsp;Chang Xue,&nbsp;Yitian Du,&nbsp;Tianhao Wu,&nbsp;Ihsan Ullah,&nbsp;Selcuk Yerci,&nbsp;Shenghao Wang","doi":"10.1002/solr.70437","DOIUrl":"https://doi.org/10.1002/solr.70437","url":null,"abstract":"<p>While [6,6]-phenyl-C<sub>61</sub>-butyric acid methyl ester (PCBM)/bathocuproine (BCP) is widely used as an electron transport stack in inverted perovskite solar cells (PSCs), its interfacial properties remain insufficiently studied. To clarify whether this interface can be optimized to enhance device performance, this work implements a targeted interfacial passivation strategy utilizing a phenethylammonium iodide (PEAI) interlayer to optimize the PCBM/BCP contact and energy alignment. Density functional theory (DFT) calculations reveal that the adsorption configuration of PEAI on PCBM is dominated by hydrogen bonding between the ammonium group of PEAI and the carbonyl group of PCBM, with an adsorption energy of −1.501 eV. This interfacial modification effectively regulates the PCBM surface morphology, homogenizes interfacial potential distribution, and improves energy level alignment. Mechanistic investigations further indicate that PEAI suppresses trap-assisted recombination while promoting interfacial charge extraction. This optimized strategy yields a power conversion efficiency (PCE) of 22.92% for PSCs based on a 1.62 eV triple-cation mixed-halide perovskite absorber, with open-circuit voltage and fill factor reaching 1.18 V and 84.78%, respectively. Furthermore, PEAI-passivated devices retain 94.1% of their initial PCE after 150 h of continuous illumination. This work establishes a feasible and efficient interface engineering strategy for high-performance and short-to-medium-term stable inverted PSCs.</p>","PeriodicalId":230,"journal":{"name":"Solar RRL","volume":"10 14","pages":""},"PeriodicalIF":4.8,"publicationDate":"2026-07-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"148615995","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Correction to “Enhancing Intra-Hour Solar Irradiance Forecasting for Solar Applications: A Blended Model of Satellite, Sky Imager, and Persistence” 更正“增强太阳应用的小时内太阳辐照度预报:卫星、天空成像仪和持久性混合模型”
IF 4.8 3区 工程技术
Solar RRL Pub Date : 2026-07-27 DOI: 10.1002/solr.70429
Bijan Nouri, Jorge Lezaca, Yann Fabel, Annette Hammer, Niklas Blum, Stefan Wilbert
{"title":"Correction to “Enhancing Intra-Hour Solar Irradiance Forecasting for Solar Applications: A Blended Model of Satellite, Sky Imager, and Persistence”","authors":"Bijan Nouri,&nbsp;Jorge Lezaca,&nbsp;Yann Fabel,&nbsp;Annette Hammer,&nbsp;Niklas Blum,&nbsp;Stefan Wilbert","doi":"10.1002/solr.70429","DOIUrl":"https://doi.org/10.1002/solr.70429","url":null,"abstract":"<p>During the production process, an error occurred in the numbering of references. Following a correction to the reference list, several in-text citation numbers were not updated accordingly. As a result, multiple citations throughout the article were linked to incorrect references.</p><p>The reference citations have now been corrected throughout the article.</p><p>We apologize for this error.</p>","PeriodicalId":230,"journal":{"name":"Solar RRL","volume":"10 14","pages":""},"PeriodicalIF":4.8,"publicationDate":"2026-07-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/solr.70429","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"148615996","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
0
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
确定
请完成安全验证×
相关产品
×
本文献相关产品
联系我们:info@booksci.cn Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。 Copyright © 2023 布克学术 All rights reserved.
京ICP备2023020795号-1
ghs 京公网安备 11010802042870号
Book学术文献互助
Book学术文献互助群
群 号:604180095
Book学术官方微信
小红书