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Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry最新文献

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Synthesis, Crystal Structure, and Antimicrobial Activity of Manganese(III) and Iron(III) Complexes Derived from Similar bis-Schiff Bases 相似双希夫碱衍生的锰(III)和铁(III)配合物的合成、晶体结构和抗菌活性
Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry Pub Date : 2016-05-16 DOI: 10.1080/15533174.2015.1137068
Zihong Pan, G. Zhao, L. Xue, Wei-chun Yang
{"title":"Synthesis, Crystal Structure, and Antimicrobial Activity of Manganese(III) and Iron(III) Complexes Derived from Similar bis-Schiff Bases","authors":"Zihong Pan, G. Zhao, L. Xue, Wei-chun Yang","doi":"10.1080/15533174.2015.1137068","DOIUrl":"https://doi.org/10.1080/15533174.2015.1137068","url":null,"abstract":"A new manganese(III) complex, [Mn(L1)(CH3OH)(dca)] 1, and a new iron(III) complex, [Fe(L2)(CH3OH)(NCS)] 2, for which dca is dicyanoamide anion, and L1 and L2 are the dianionic form of N,N′-3,4-methylphenylenebis(5-methylsalicylaldimine) and N,N′-bis(5-methylsalicylidene)-o-phenylenediamine, respectively, have been prepared and characterized by elemental analyses, IR, and single-crystal X-ray crystallographic determination. The crystal of complex 1 is orthorhombic: space group Pna21, a = 14.6557(6), b = 10.8906(5), c = 15.0536(7) Å, V = 2402.7(2) Å3, Z = 4, R1 = 0.0321, wR2 = 0.0715. The crystal of complex 2 is monoclinic: space group C2/c, a = 14.6798(9), b = 11.1306(7), c = 27.831(1) Å, β = 93.782(2)°, V = 4537.6(5) Å3, Z = 8, R1 = 0.0423, wR2 = 0.1027. The bis-Schiff base ligands coordinate to the metal center through phenolate O and imine N atoms. Both the Mn and Fe atoms in the complexes are in octahedral coordination, with the equatorial donor atoms come from the Schiff base ligands, and with the axial donor atoms come from a methanol O atom and a pseudohalide N atom. The effects of the complexes on the antimicrobial activity against Staphylococcus aureus, Escherichia coli, and Candida albicans were studied.","PeriodicalId":22118,"journal":{"name":"Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2016-05-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"89443496","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 3
Synthesis and Characterization of Mg(OH)2 and MgO Nanostructures Via Simple Hydrothermal Method 简单水热法合成氧化镁纳米结构及表征
Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry Pub Date : 2016-05-03 DOI: 10.1080/15533174.2014.988826
M. Sabet, M. Salavati‐Niasari, Zahra Asgari Fard
{"title":"Synthesis and Characterization of Mg(OH)2 and MgO Nanostructures Via Simple Hydrothermal Method","authors":"M. Sabet, M. Salavati‐Niasari, Zahra Asgari Fard","doi":"10.1080/15533174.2014.988826","DOIUrl":"https://doi.org/10.1080/15533174.2014.988826","url":null,"abstract":"Mg(OH)2 and MgO nanostructures were synthesized via simple hydrothermal method by MgSO4, ethylenediamine, and hydrazine as reagents. The products were characterized with X-ray diffraction, scanning electron microscopy, transmission electron microscopy, and energy-dispersive X-ray spectroscopy. Different parameter's effect on product size and morphology was investigated.","PeriodicalId":22118,"journal":{"name":"Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2016-05-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"77727200","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 2
NiO/ZnO Core-Shell Nanoparticles In Situ Synthesis Via Microemulsion Method 微乳液法原位合成NiO/ZnO核壳纳米颗粒
Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry Pub Date : 2016-05-03 DOI: 10.1080/15533174.2014.989595
D. Han, C. Wang, D. Li, Z. Cao
{"title":"NiO/ZnO Core-Shell Nanoparticles In Situ Synthesis Via Microemulsion Method","authors":"D. Han, C. Wang, D. Li, Z. Cao","doi":"10.1080/15533174.2014.989595","DOIUrl":"https://doi.org/10.1080/15533174.2014.989595","url":null,"abstract":"Nanoparticles of NiO(core)/ZnO(shell) core-shell and nanoparticles were successfully prepared in Triton X-100/n-hexanol/cyclohexane/water W/O microemulsion system. Basic synthesis conditions were determined. Ni(OH)2/Zn(OH)2 nanoparticles were first synthesized at room temperature then calcined at 500°C to form NiO/ZnO nanoparticles. The calcined products were studied by means of TEM, and XRD analyzers. The mechanism of the core shell NiO/ZnO nanoparticles formation is explained.","PeriodicalId":22118,"journal":{"name":"Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2016-05-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"87646780","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 10
Synthesis of Magnetic MWNTs/ZnS/Fe3O4 Nanocomposites and Their Enhanced Photocatalytic Activity 磁性MWNTs/ZnS/Fe3O4纳米复合材料的合成及其增强光催化活性
Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry Pub Date : 2016-05-03 DOI: 10.1080/15533174.2015.1031047
Xiao-jie Song, Fan-Ming Yang, Qun Fang, Hanmei Hu, Fei Xu
{"title":"Synthesis of Magnetic MWNTs/ZnS/Fe3O4 Nanocomposites and Their Enhanced Photocatalytic Activity","authors":"Xiao-jie Song, Fan-Ming Yang, Qun Fang, Hanmei Hu, Fei Xu","doi":"10.1080/15533174.2015.1031047","DOIUrl":"https://doi.org/10.1080/15533174.2015.1031047","url":null,"abstract":"Magnetic multiwalled carbon nanotubes (MWNTs)/ZnS/Fe3O4 nanocomposites were prepared using Fe3O4 and ZnS nanoparticles via in situ chemical precipitation method onto the surface of MWNTs. The nanocomposites were characterized by X-ray diffraction, transmission electron microscopy, high-resolution transmission electron microscopy, and energy-dispersive X-ray spectroscopy. The results revealed that the photocatalytic activity of MWNTs/ZnS/Fe3O4 nanocomposites for methylene blue solution increased obviously compared with pure ZnS NPs. Moreover, as a magnetic material, MWNTs/ZnS/Fe3O4 nanocomposites could be easily collected from aqueous solution by an external magnet, and used repeatedly.","PeriodicalId":22118,"journal":{"name":"Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2016-05-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"74481125","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 3
Synthesis, Crystal Structure, and Theoretical Calculation of the Cu(II) Complex With 1,2-Benzisothiazolin-3-one 1,2-苯并异噻唑啉-3-酮配合物Cu(II)的合成、晶体结构及理论计算
Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry Pub Date : 2016-05-03 DOI: 10.1080/15533174.2014.988236
Xia Li, Guanhua Zhu, Lei Dong, Chunhua Ni, Xingchen Yan, Liangmin Yu
{"title":"Synthesis, Crystal Structure, and Theoretical Calculation of the Cu(II) Complex With 1,2-Benzisothiazolin-3-one","authors":"Xia Li, Guanhua Zhu, Lei Dong, Chunhua Ni, Xingchen Yan, Liangmin Yu","doi":"10.1080/15533174.2014.988236","DOIUrl":"https://doi.org/10.1080/15533174.2014.988236","url":null,"abstract":"A novel copper(II) complex [Cu2(BIT)4(DMF)2]•2DMF (BIT = 1,2-benzisothiazolin-3-one, DMF = N,N-dimethylformamide) was synthesized via standing diffusion method. The structure of crystal was characterized by elemental analysis, IR spectroscopy and single-crystal X-ray diffraction. The complex crystallizes in monoclinic C2/c space group and a = 30.850 (3) Å, b = 8.5534 (8) Å, c = 21.6491 (18) Å, β= 128.487 (2)°, V = 4.4716 (7) nm3, Z = 4. The fluorescent properties of the complex was studied. Theoretical study of the complex was carried out by density functional theory B3LYP method using Gaussian 03 program. CCDC: 911350.","PeriodicalId":22118,"journal":{"name":"Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2016-05-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"88684387","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 8
Ionothermal Synthesis, Crystal Structure, and Luminescent Properties of Two Novel Layered Indium-1,4-Benzenedicarboxylate Complexes 两种新型层状铟-1,4-苯二羧酸盐配合物的离子热合成、晶体结构和发光性质
Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry Pub Date : 2016-05-03 DOI: 10.1080/15533174.2014.989574
Saying Li, L. Du, Zhi-Hong Liu
{"title":"Ionothermal Synthesis, Crystal Structure, and Luminescent Properties of Two Novel Layered Indium-1,4-Benzenedicarboxylate Complexes","authors":"Saying Li, L. Du, Zhi-Hong Liu","doi":"10.1080/15533174.2014.989574","DOIUrl":"https://doi.org/10.1080/15533174.2014.989574","url":null,"abstract":"Two novel organic-inorganic hybrid indium complexes, [C6H11N2]2[In2(BDC)3Br2] (1) and [C7H13N2]2[In2(BDC) 3Br2] (2) (BDC2– = 1,4-benzenedicarboxylate), have been synthesized under ionothermal conditions and characterized by elemental analysis, FT-IR, and TG. Single X-ray diffraction studies revealed that compounds 1 and 2 are isostructural. Both crystallize in the monoclinic system with space group P21/c. Their structures are characterized as novel graphite-like layered structure with larger rings constructed by InO5Br polyhedra and the 1,4-benzendicarboxylate organic linkers. The used ILs cations [C6H11N2]+ are located between the layers and compensate for the negative charges of framework. Furthermore, their luminescent properties have also been studied.","PeriodicalId":22118,"journal":{"name":"Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2016-05-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"86214418","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 1
Ag-ZnO Incorporated Silica Based Bio-Nanocomposite Prepared by Low Cost Method for Photocatalytic Dye Degradation 低成本制备Ag-ZnO硅基生物纳米复合材料光催化降解染料
Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry Pub Date : 2016-05-03 DOI: 10.1080/15533174.2014.989581
Tan Hong, T. Radhika, R. J. Ramalingam, Farook Adam
{"title":"Ag-ZnO Incorporated Silica Based Bio-Nanocomposite Prepared by Low Cost Method for Photocatalytic Dye Degradation","authors":"Tan Hong, T. Radhika, R. J. Ramalingam, Farook Adam","doi":"10.1080/15533174.2014.989581","DOIUrl":"https://doi.org/10.1080/15533174.2014.989581","url":null,"abstract":"Zinc-silver incorporated rice husk silica catalysts were prepared by a simple sol-gel precipitation. The FT-IR and thermal analyses are confirms the complete removal of the template after calcination at 773 K. From the XRD pattern, it could observed that zinc and silver which incorporated into rice husk silica with its characteristic crystalline form. Methylene blue (MB) was used to evaluate the photocatalytic activity of the prepared samples. During photodegradation, concentration of methylene blue was decreased within 1 h under the studied reaction condition. The incorporation of silver ions on rice husk silica improves the crystalinity and activity.","PeriodicalId":22118,"journal":{"name":"Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2016-05-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"80797326","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 3
Syntheses and Structures of Two Organic–Inorganic Composite Vanadoborates Na2(Hen)4[B18V12O60]·16H2O and (H2en)6[B18V12O60]2·2tepa·11H2O 两种有机-无机复合钒酸盐Na2(Hen)4[B18V12O60]·16H2O和(H2en)6[B18V12O60]2·2tepa·11H2O的合成与结构
Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry Pub Date : 2016-05-03 DOI: 10.1080/15533174.2014.989577
Hailou Li, Yamin Cheng, Jie Luo, P. Ma, Junwei Zhao, Lijuan Chen
{"title":"Syntheses and Structures of Two Organic–Inorganic Composite Vanadoborates Na2(Hen)4[B18V12O60]·16H2O and (H2en)6[B18V12O60]2·2tepa·11H2O","authors":"Hailou Li, Yamin Cheng, Jie Luo, P. Ma, Junwei Zhao, Lijuan Chen","doi":"10.1080/15533174.2014.989577","DOIUrl":"https://doi.org/10.1080/15533174.2014.989577","url":null,"abstract":"Two organic–inorganic composite vanadoborates Na2(Hen)4[B18V12O60]·16H2O (1) (en = ethylenediamine) and (H2en)6[B18V12O60]2·2tepa·11H2O (2) (tepa = tetraethylenepentamine) have been hydrothermally synthesized and characterized by elemental analyses, inductively coupled plasma atomic emission spectrometry (ICP-AES) analyses, IR spectra, and X-ray crystallography. Single-crystal structural analyses show that 1 exhibits a 2-D polyoxovanadium borate sheet architecture with a four-connected topology established by [B18V12O60]6− units via Na+ bridges whereas the molecular unit of 2 consists of two discrete [B18V12O60]6− clusters, six diprotonated [H2en]2+ cations, two tepa molecules, and 11 lattice water molecules.","PeriodicalId":22118,"journal":{"name":"Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2016-05-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"75693195","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 3
Design of ZnCdS Quantum Dots Loaded on Mesoporous Silica as a UV-Light-Sensitive Photocatalyst 介孔二氧化硅负载ZnCdS量子点作为紫外光敏感光催化剂的设计
Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry Pub Date : 2016-05-03 DOI: 10.1080/15533174.2014.989578
A. Pourahmad, M. Deljoopour
{"title":"Design of ZnCdS Quantum Dots Loaded on Mesoporous Silica as a UV-Light-Sensitive Photocatalyst","authors":"A. Pourahmad, M. Deljoopour","doi":"10.1080/15533174.2014.989578","DOIUrl":"https://doi.org/10.1080/15533174.2014.989578","url":null,"abstract":"The synthesis of ZnCdS nanomaterial in MCM-41 matrix has been realized by chemical synthesis among MCM-41, ZnCl2, and CdCl2 via an ion exchange method in aqueous solution. X-ray diffraction analysis (XRD), diffuse reflectance spectroscopy (DRS), transmission electron microscopy (TEM), and Fourier transform infrared spectroscopy (FT-IR) were used to characterize the products. Several parameters were examined, catalyst amount (0.1–6 g L−1), pH (3–12), and initial concentration of MB (0.16–3.2 ppm). The extent of degradation was estimated from the residual concentration by spectrophotometrically. The average size of ZnCdCl2 in MCM-41 nanostructure was obtained about 3 nm by TEM.","PeriodicalId":22118,"journal":{"name":"Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2016-05-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"72973496","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 4
Synthesis and Evaluation of Neutral Gd(III), Mn(II) Complexes From DTPA-Bisamide Derivative as Potential MRI Contrast Agents dtpa -双酰胺衍生物中性Gd(III)， Mn(II)配合物的合成与评价
Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry Pub Date : 2016-05-03 DOI: 10.1080/15533174.2014.988820
Zhen-Chuan Liao, Chao-rui Li, Zheng-yin Yang
{"title":"Synthesis and Evaluation of Neutral Gd(III), Mn(II) Complexes From DTPA-Bisamide Derivative as Potential MRI Contrast Agents","authors":"Zhen-Chuan Liao, Chao-rui Li, Zheng-yin Yang","doi":"10.1080/15533174.2014.988820","DOIUrl":"https://doi.org/10.1080/15533174.2014.988820","url":null,"abstract":"A strong chelating ligand was synthesized through the modification of DTPA by bioactive 5-fluorouracil derivatives and characterized by means of mass spectra, Fourier transform infrared spectra, elemental analysis, and nuclear magnetic resonance spectroscopy. Its complexes of Gd(III) and Mn(II) were designed as potential MRI contrast agents. Thermodynamic stability constant of the complexes indicated that they were stable enough to prevent the metal ions from releasing. Relaxivity studies showed that the two complexes provided higher T1-weighted relaxivity than that of commercial contrast agent Gd-DTPA and the Mn(II) complex owned much higher T2-weighted relaxation property. Both the Gd(III) and Mn(II) complexes had the advantage of becoming promising T1-weighted MRI contrast agents.","PeriodicalId":22118,"journal":{"name":"Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2016-05-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"77348773","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 1
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