{"title":"Design of ZnCdS Quantum Dots Loaded on Mesoporous Silica as a UV-Light-Sensitive Photocatalyst","authors":"A. Pourahmad, M. Deljoopour","doi":"10.1080/15533174.2014.989578","DOIUrl":null,"url":null,"abstract":"The synthesis of ZnCdS nanomaterial in MCM-41 matrix has been realized by chemical synthesis among MCM-41, ZnCl2, and CdCl2 via an ion exchange method in aqueous solution. X-ray diffraction analysis (XRD), diffuse reflectance spectroscopy (DRS), transmission electron microscopy (TEM), and Fourier transform infrared spectroscopy (FT-IR) were used to characterize the products. Several parameters were examined, catalyst amount (0.1–6 g L−1), pH (3–12), and initial concentration of MB (0.16–3.2 ppm). The extent of degradation was estimated from the residual concentration by spectrophotometrically. The average size of ZnCdCl2 in MCM-41 nanostructure was obtained about 3 nm by TEM.","PeriodicalId":22118,"journal":{"name":"Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry","volume":null,"pages":null},"PeriodicalIF":0.0000,"publicationDate":"2016-05-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"4","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1080/15533174.2014.989578","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
引用次数: 4
Abstract
The synthesis of ZnCdS nanomaterial in MCM-41 matrix has been realized by chemical synthesis among MCM-41, ZnCl2, and CdCl2 via an ion exchange method in aqueous solution. X-ray diffraction analysis (XRD), diffuse reflectance spectroscopy (DRS), transmission electron microscopy (TEM), and Fourier transform infrared spectroscopy (FT-IR) were used to characterize the products. Several parameters were examined, catalyst amount (0.1–6 g L−1), pH (3–12), and initial concentration of MB (0.16–3.2 ppm). The extent of degradation was estimated from the residual concentration by spectrophotometrically. The average size of ZnCdCl2 in MCM-41 nanostructure was obtained about 3 nm by TEM.
以MCM-41为基体,采用离子交换法在水溶液中以MCM-41、ZnCl2和CdCl2为原料进行化学合成,实现了纳米材料ZnCdS的合成。采用x射线衍射分析(XRD)、漫反射光谱(DRS)、透射电子显微镜(TEM)和傅里叶变换红外光谱(FT-IR)对产物进行表征。考察了催化剂用量(0.1-6 g L−1)、pH(3-12)和MB初始浓度(0.16-3.2 ppm)等参数。用分光光度法测定残留浓度,估计降解程度。透射电镜观察到MCM-41纳米结构中ZnCdCl2的平均尺寸约为3 nm。