两种新型层状铟-1,4-苯二羧酸盐配合物的离子热合成、晶体结构和发光性质

Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry Pub Date : 2016-05-03 DOI:10.1080/15533174.2014.989574

Saying Li, L. Du, Zhi-Hong Liu

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引用次数: 1

摘要

在离子热条件下合成了两种新型有机无机杂化铟配合物[C6H11N2]2[In2(BDC)3Br2](1)和[C7H13N2]2[In2(BDC) 3Br2] (2) (BDC2 - = 1,4-苯二羧酸盐)，并用元素分析、FT-IR和TG对其进行了表征。单x射线衍射研究表明化合物1和2是同构的。两者均在空间群P21/c的单斜晶系中结晶。它们的结构特点是由InO5Br多面体和1,4-苯二甲酸酯有机连接体构成的具有较大环的新型石墨状层状结构。所使用的离子离子[C6H11N2]+位于层间，补偿了框架的负电荷。此外，还研究了它们的发光特性。

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Ionothermal Synthesis, Crystal Structure, and Luminescent Properties of Two Novel Layered Indium-1,4-Benzenedicarboxylate Complexes

Two novel organic-inorganic hybrid indium complexes, [C6H11N2]2[In2(BDC)3Br2] (1) and [C7H13N2]2[In2(BDC) 3Br2] (2) (BDC2– = 1,4-benzenedicarboxylate), have been synthesized under ionothermal conditions and characterized by elemental analysis, FT-IR, and TG. Single X-ray diffraction studies revealed that compounds 1 and 2 are isostructural. Both crystallize in the monoclinic system with space group P21/c. Their structures are characterized as novel graphite-like layered structure with larger rings constructed by InO5Br polyhedra and the 1,4-benzendicarboxylate organic linkers. The used ILs cations [C6H11N2]+ are located between the layers and compensate for the negative charges of framework. Furthermore, their luminescent properties have also been studied.

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来源期刊

Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry 工程技术-纳米科技

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审稿时长

5 months