Fu-Sheng Zhang , Jia-Bin Liu , Zi-Ye Li , Kai-Lang Liu , Yu-Han Yang , Ru-Qian Lian , Xing-Qiang Shi , Jiang-Long Wang , Peng-Lai Gong
{"title":"Band offsets rules between inorganic molecular crystal α-Sb₂O₃ and two-dimensional semiconductor materials for nanoelectronic applications","authors":"Fu-Sheng Zhang , Jia-Bin Liu , Zi-Ye Li , Kai-Lang Liu , Yu-Han Yang , Ru-Qian Lian , Xing-Qiang Shi , Jiang-Long Wang , Peng-Lai Gong","doi":"10.1016/j.surfin.2025.107752","DOIUrl":"10.1016/j.surfin.2025.107752","url":null,"abstract":"<div><div>The pursuit of high-performance, miniaturized electronics has spurred the exploration of two-dimensional semiconductor materials (2DSMs) for various device applications. While inorganic molecular crystal α-Sb₂O₃ shows promise as a van der Waals (vdW) dielectric or insulating substrate to enhance 2DSMs-based device performance, its moderate bandgap limits its broader use. To address this limitation, we perform a comprehensive first-principles study on the interfacial interaction and its impact on the band alignment between α-Sb₂O₃ and common 2DSMs, establishing selection rules of band offsets (BOs) for optimal device performance. Our key findings show that moderate band offsets (m-BOs), with both conduction band offset (CBO) and valence band offset (VBO) exceeding 0.5 eV, are crucial for preserving the intrinsic electronic properties of 2DSMs by significantly reducing interfacial interactions between α-Sb₂O₃ and 2DSMs. Furthermore, we establish the other layer-dependent selection rule of BOs, enabling the identification of 18, 57, and 81 2DSMs as 2D channels allowing three, four, and five α-Sb₂O₃ layers to function as outstanding vdW dielectrics. Our work offers valuable insights for designing and optimizing advanced nanoelectronic devices based on few-layer α-Sb₂O₃ and its suiTable 2DSM counterparts.</div></div>","PeriodicalId":22081,"journal":{"name":"Surfaces and Interfaces","volume":"75 ","pages":"Article 107752"},"PeriodicalIF":6.3,"publicationDate":"2025-09-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145223305","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Sina Hatami-Kakesh, Sedigheh Zeinali, Mohammad Mahdi Zerafat
{"title":"Enhanced supercapacitor performance via synergistic integration of MOFs and polyaniline: Structural and electrochemical investigations","authors":"Sina Hatami-Kakesh, Sedigheh Zeinali, Mohammad Mahdi Zerafat","doi":"10.1016/j.surfin.2025.107757","DOIUrl":"10.1016/j.surfin.2025.107757","url":null,"abstract":"<div><div>The escalating worldwide energy demand and the pressing need to address environmental challenges have catalyzed the advancement of novel, sustainable energy storage solutions. Supercapacitors, characterized by elevated power density and extended cycle life, are emerging as a viable choice in this field. This study develops a MIL-53(Fe)/UiO-66/PANI (MUPA) composite for use as an enhanced supercapacitor electrode. MIL-53(Fe) and UiO-66 were synthesized via solvothermal routes, while polyaniline (PANI) was produced through oxidative polymerization; the components were integrated by wet impregnation and ultrasonic dispersion to ensure uniform mixing. A comprehensive suite of characterization techniques was employed to elucidate structural and chemical properties. By adjusting the component ratio, the optimized composite (MUPA212) achieved a specific capacitance of 608 F g⁻¹ in three-electrode testing, nearly doubling the capacitance of the initial MUPA formulation. In a hybrid device paired with activated carbon, it delivered an energy density of 13.77 Wh kg⁻¹ at a power density of 800 W kg⁻¹ and sustaining 10.6 Wh kg⁻¹ at a high power density of 6400 W kg⁻¹. within a 1.6 V window and maintained 93.2 % capacitance over 10,000 cycles. These outcomes underscore the promise of the MUPA composite as a scalable, efficient platform for durable energy storage.</div></div>","PeriodicalId":22081,"journal":{"name":"Surfaces and Interfaces","volume":"75 ","pages":"Article 107757"},"PeriodicalIF":6.3,"publicationDate":"2025-09-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145269987","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Muhammad Sanaullah Shah, Zhang Zhenyu, Sohail Ahmad, Wang Shuiying, Hou Hongying, Zuo Xiaoqing, Muhammad Zia Ullah Shah
{"title":"Fabrication of binary NiSe2–ZnS nanocomposites for high-performance supercapacitors with enhanced energy storage","authors":"Muhammad Sanaullah Shah, Zhang Zhenyu, Sohail Ahmad, Wang Shuiying, Hou Hongying, Zuo Xiaoqing, Muhammad Zia Ullah Shah","doi":"10.1016/j.surfin.2025.107750","DOIUrl":"10.1016/j.surfin.2025.107750","url":null,"abstract":"<div><div>The development of supercapacitor technology has advanced significantly because of the high need for efficient and sustainable energy storage solutions. This study investigates the synthesis and electrochemical performance of NiSe<sub>2</sub>-ZnS nanocomposites as promising electrode materials for high-performance supercapacitor. The NiSe<sub>2</sub>-ZnS nanocomposites were synthesized via simple chemical method, and characterized. The results showed that the NiSe<sub>2</sub>-ZnS composite have outstanding electrochemical behaviors, combining the superior chemical stability and thermal durability of NiSe<sub>2</sub> with the remarkable electrical conductivity of ZnS. The NiSe<sub>2</sub>-ZnS hybrid electrode demonstrated remarkable electrochemical behavior, delivering a specific capacitance of 810 F g<sup>-1</sup> in a three-electrode system and 87.3 F g<sup>-1</sup> when evaluated in a two-electrode configuration. It also demonstrated a notable energy density (ED) of 27.2 Wh/kg and a high power density (PD) of 3744.7 W/kg. Notably, the electrode retained 96.7% of its original capacitance even after 5000 continuous charge-discharge cycles conducted under a current load of 15 A g<sup>-1</sup>, demonstrating excellent cycling durability. This research shows that NiSe<sub>2</sub>-ZnS nanocomposites is a good-performance, low-cost, and sustainable material for next-generation supercapacitors.</div></div>","PeriodicalId":22081,"journal":{"name":"Surfaces and Interfaces","volume":"75 ","pages":"Article 107750"},"PeriodicalIF":6.3,"publicationDate":"2025-09-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145269988","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Fangjun Shi , Wanshan Jiang , Li Zhang , Jing Hong
{"title":"Surface uniformity enhancement in artificial joint polishing via halbach array-assisted magnetic liquid metal abrasive flow","authors":"Fangjun Shi , Wanshan Jiang , Li Zhang , Jing Hong","doi":"10.1016/j.surfin.2025.107735","DOIUrl":"10.1016/j.surfin.2025.107735","url":null,"abstract":"<div><div>To overcome surface non-uniformity issues in abrasive flow polishing of complex-curvature artificial joints, a Halbach array-assisted magnetic liquid metal abrasive flow polishing method is proposed. Magnetic nanoparticles are introduced into a liquid metal carrier to form a magnetically responsive medium, which enables precise control over abrasive particle migration in weak-flow regions through the single-sided enhanced magnetic field generated by the Halbach array. Numerical simulations indicate that at a flow velocity of 3 m/s, the average velocity in weak-flow regions increases from 1.29 to 1.51 m/s, while the average surface pressure rises from 9288 Pa to 14,308 Pa. Turbulent kinetic energy and pressure–velocity (PV) values increase by 150% and 83.3%, respectively. Erosion analysis demonstrates a 145% improvement in material removal efficiency in weak-flow regions, effectively reducing polishing blind regions by enhancing particle dynamics and energy transfer. Experimental validation corroborates these numerical findings. Surface roughness in weak-flow regions decreases from 121 nm to 72 nm, corresponding to a 40.5% reduction. The maximum surface roughness variation between different regions decreases from 52.2 nm to 13.6 nm, indicating a 73.9% improvement in polishing uniformity. These results highlight the significant advantages of this method in enhancing both polishing efficiency and uniformity for complex biomedical surfaces.</div></div>","PeriodicalId":22081,"journal":{"name":"Surfaces and Interfaces","volume":"75 ","pages":"Article 107735"},"PeriodicalIF":6.3,"publicationDate":"2025-09-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145223541","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Design and development of carbon nanotube-integrated cobalt phosphate (CoP2O6/CNT) composite via a solid-state strategy for enhanced bi-functional electrocatalytic performance in oxygen and urea oxidation reactions","authors":"Bodicherla Naresh , T.V.M. Sreekanth , Chandra Reddy Neeragatti Suma , Kummara Sunil Kumar , Kisoo Yoo , Jonghoon Kim","doi":"10.1016/j.surfin.2025.107723","DOIUrl":"10.1016/j.surfin.2025.107723","url":null,"abstract":"<div><div>Cobalt phosphate (CoP<sub>2</sub>O<sub>6</sub>) and its carbon nanotube-based composite (CoP<sub>2</sub>O<sub>6</sub>/CNT) were synthesized via a solid-state approach and thoroughly investigated for their bi-functional electrocatalytic performance toward the oxygen evolution reaction (OER) and urea oxidation reaction (UOR). The integration of CNTs significantly improved the electrical conductivity and facilitated charge transport, leading to enhanced catalytic activity. The CoP<sub>2</sub>O<sub>6</sub>/CNT composite exhibited a low overpotential of 370 mV at 25 mA cm⁻² for OER with a Tafel slope of 158 mV dec⁻¹, outperforming the pristine CoP<sub>2</sub>O<sub>6</sub>. For UOR, the composite demonstrated a notably reduced overpotential of 170 mV at 25 mA cm⁻² and a Tafel slope of 133 mV dec⁻¹, indicating efficient urea electro-oxidation kinetics. The superior bi-functional activity is attributed to the synergistic interplay between the active phosphate phase and the conductive CNT network, which enhances electron mobility and exposes more electroactive sites. These results position CoP<sub>2</sub>O<sub>6</sub>/CNT as a promising bi-functional electrocatalyst for sustainable energy applications.</div></div>","PeriodicalId":22081,"journal":{"name":"Surfaces and Interfaces","volume":"75 ","pages":"Article 107723"},"PeriodicalIF":6.3,"publicationDate":"2025-09-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145223520","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Boyu Gao, Yumeng Lu, Liang Chen, Yuehao Gu, Wenjing Gao, Renhong Chen, Anmin Liu
{"title":"Theoretical screening and mechanistic insights into alcohol and sugar additives for aqueous zinc-ion batteries","authors":"Boyu Gao, Yumeng Lu, Liang Chen, Yuehao Gu, Wenjing Gao, Renhong Chen, Anmin Liu","doi":"10.1016/j.surfin.2025.107746","DOIUrl":"10.1016/j.surfin.2025.107746","url":null,"abstract":"<div><div>Through theoretical screening of various alcohol and sugar molecules, this study has discovered that the performance of aqueous zinc-ion batteries (AZIBs) can be enhanced by adding xylitol and sucrose as electrolyte additives. Specifically, this work employs an integrated theoretical screening framework (frontier orbitals, electrostatic potential, Fukui functions, and adsorption energy mapping), which represents a novel methodological approach. It was found that xylitol and sucrose molecules can undergo adsorption behavior on the zinc anode surface, forming a molecular adsorption layer that reduces the occurrence of side reactions and dendrite growth. By performing in-depth theoretical calculations, different modification mechanisms exhibited by xylitol and sucrose were determined. For the first time, this study mechanistically distinguishes xylitol (modulating short-range structure) and sucrose (modulating long-range structure), revealing two distinct yet effective molecular pathways. Xylitol primarily influences the short-range coordination structure of Zn²⁺. At certain concentrations, xylitol molecules enter the first solvation shell of Zn²⁺, forming [Zn (H<sub>2</sub>O)<sub>5</sub>(C<sub>5</sub>H<sub>12</sub>O<sub>5</sub>)]<sup>2+</sup> complexes. In contrast, sucrose molecules mainly affect the long-range coordination structure of Zn²⁺. This study provides theoretical guidance for the design and development of electrolyte additives for AZIBs.</div></div>","PeriodicalId":22081,"journal":{"name":"Surfaces and Interfaces","volume":"75 ","pages":"Article 107746"},"PeriodicalIF":6.3,"publicationDate":"2025-09-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145223539","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Iron nanoparticles-chitosan/reduced graphene oxide (mCS@rGO) beads as a multifunctional material for the adsorption and degradation of phenol from aqueous media","authors":"Marina Barbosa de Farias , Patrícia Prediger , Melissa Gurgel Adeodato Vieira","doi":"10.1016/j.surfin.2025.107744","DOIUrl":"10.1016/j.surfin.2025.107744","url":null,"abstract":"<div><div>A magnetic multifunctional material (mCS@rGO) was developed and used to remove phenol from water through adsorption and Fenton-based degradation processes. The adsorption performance of the mCS@rGO beads towards phenol was evaluated through kinetic, equilibrium, and thermodynamic analyses. An adsorption capacity of 50.1 mg/g and a removal rate of 55 % were obtained. The kinetic data showed that multiple adsorption mechanisms and rate-limiting steps may be involved. The equilibrium data were most accurately described by the Sips isothermal model. Thermodynamic parameters indicated that the process is spontaneous and endothermic. The beads were also used as catalysts in Fenton-type processes. The influence of process variables on degradation performance was assessed through a factorial design, which revealed that the optimal conditions were an H<sub>2</sub>O<sub>2</sub>:phenol molar ratio of 25:1, a catalyst dosage of 1.5 g/L, and a solution pH of 4.95. Then, a heterogeneous Fenton-type process, a heterogeneous sono-Fenton-type process, and a combination of adsorption and oxidation processes were evaluated, yielding removals of 63 %, 83 %, and 91 %, respectively. The best performance, observed for the adsorption/heterogeneous sono-Fenton-type system, confirmed the synergistic effect of the combined techniques. Characterization analyses revealed no significant changes in the composition of mCS@rGO after the processes. Phenol removal was suggested to occur in two sequential stages: adsorption onto the beads via hydrogen bonding and π–π interactions, followed by oxidative reactions.</div></div>","PeriodicalId":22081,"journal":{"name":"Surfaces and Interfaces","volume":"74 ","pages":"Article 107744"},"PeriodicalIF":6.3,"publicationDate":"2025-09-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145159368","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Scalable fabrication of multifunctional NiCr plasma coatings for environmental remediation via oil-water separation and electrocatalytic dye degradation","authors":"Bharani Narayanan , Vijay Dhanabal M․ H․ , Shanmugavelayutham Gurusamy , Kumaresan Lakshmanan","doi":"10.1016/j.surfin.2025.107743","DOIUrl":"10.1016/j.surfin.2025.107743","url":null,"abstract":"<div><div>The pressing need for efficient and sustainable oil-water separation systems arises from the widespread environmental and industrial challenges of oil spills, wastewater contamination, and petrochemical processing. Traditional separation methods often struggle to achieve effective separation under varying environmental conditions, especially in extreme pH, temperature, or complex mixtures. To address this, a superhydrophobic NiCr coating on stainless steel mesh was developed using the scalable plasma spray method, designed specifically for selective oil-water separation. The NiCr-coated mesh demonstrated a significant increase in hydrophobicity, achieving a water contact angle of 153.4° compared to the bare mesh’s 98.1°, which enabled efficient separation by selectively allowing only oil to permeate. Different kinds of oil/water mixtures of petrol, toluene, chloroform, hexane and silicone oil are efficiently separated. Thermal stability and durability tests confirmed the mesh's ability to maintain hydrophobicity across a range of temperatures, pH levels, and under mechanical stresses such as high-speed water jets. In addition to separation, the same NiCr coating was employed as an anode for the electrocatalytic degradation of Rhodamine B, demonstrating its multifunctionality. The multifunctional NiCr coating showcases strong potential for environmental remediation, serving as a scalable solution for both oil-water separation and electrocatalytic dye degradation under ambient conditions.</div></div>","PeriodicalId":22081,"journal":{"name":"Surfaces and Interfaces","volume":"75 ","pages":"Article 107743"},"PeriodicalIF":6.3,"publicationDate":"2025-09-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145223515","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Microscopic analysis on high corrosion-resistant metallic nitride-coated metallic bipolar plate for PEM fuel cell application","authors":"Sundararajan Ramakrishnan , Natarajan Rajalakshmi , Krishna Valleti , Shobit Omar , K. Ramya","doi":"10.1016/j.surfin.2025.107736","DOIUrl":"10.1016/j.surfin.2025.107736","url":null,"abstract":"<div><div>To extend the durability of stainless-steel bipolar plates in proton exchange membrane fuel cells (PEMFCs), a high corrosion resistance titanium nitride (TiN) coating was deposited using cathodic arc-physical vapour deposition (CA-PVD). Optimized pre-processing conditions and deposition parameters enabled the synthesis of multi-layered TiN in a single-step process, eliminating the need for adhesion or additional layers. The incorporation of secondary elements such as oxygen and the creation of nitrogen-rich sites within the coating matrix significantly enhance the corrosion resistance. Long-term studies reveal that the coating retains its structural integrity even after 3000 h of immersion in a simulated PEMFC electrolyte under periodic potential application. Atom probe tomography (APT) analyses microstructural changes at the atomic level to investigate the role of secondary element incorporation in the corrosion resistance of the TiN coating. APT analysis reveals the presence of secondary interfaces, which promote the formation of disordered columnar structures, effectively hindering electrolyte penetration to ensure prolonged corrosion resistance throughout the testing period. This study demonstrates the effectiveness of multi-layered TiN coatings in enhancing the longevity and reliability of bipolar plates for PEMFC applications.</div></div>","PeriodicalId":22081,"journal":{"name":"Surfaces and Interfaces","volume":"74 ","pages":"Article 107736"},"PeriodicalIF":6.3,"publicationDate":"2025-09-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145159932","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Xing Huang , Kai Huang , Huan Xiang , Yao Tan , Huawei Yin , Chengli Tang , Tingzhen Li , Chuanbo Hu
{"title":"Electrochemical behavior and corrosion resistance of the electropolymerized poly(o-toluidine-co-dopamine) film on stainless steel substrates","authors":"Xing Huang , Kai Huang , Huan Xiang , Yao Tan , Huawei Yin , Chengli Tang , Tingzhen Li , Chuanbo Hu","doi":"10.1016/j.surfin.2025.107739","DOIUrl":"10.1016/j.surfin.2025.107739","url":null,"abstract":"<div><div>This study successfully electrodeposited a copolymer of poly(o-toluidine) and poly(dopamine) (POT-co-PDA) onto 304 stainless steel substrates using cyclic voltammetry in a sulfuric acid medium, employing o-toluidine and dopamine hydrochloride as comonomers. Characterization results from ultraviolet-visible (UV–vis) absorption spectroscopy and Fourier transform infrared (FTIR) spectroscopy confirmed the successful synthesis of the copolymer. Scanning electron microscopy (SEM) analysis revealed that the POT-co-PDA copolymer film exhibited a denser and more continuous surface morphology compared to the porous structure of the homopolymer, indicating that the incorporation of dopamine effectively refined the film's microstructure. The electrochemical corrosion performance of the coatings was evaluated through accelerated immersion tests in a 3.5 % NaCl solution. Initially, Tafel polarization curve measurements demonstrated that both POT and POT-co-PDA coatings significantly enhanced the corrosion resistance of the stainless steel substrate. Notably, the POT-co-PDA coating exhibited superior protective performance, achieving a corrosion rate as low as 0.009 mm/year and a protection efficiency of 92.64 % for the substrate. Furthermore, electrochemical impedance spectroscopy (EIS) results revealed that the charge transfer resistance (<em>R</em><sub>ct</sub>) value of the POT-co-PDA coating was 3.5 times and 6.8 times higher than that of the POT homopolymer coating and the bare steel substrate, respectively. This further confirms its significantly enhanced long-term barrier protection capability. The markedly improved corrosion protection performance of the POT-co-PDA coating primarily stems from the multifunctional role of the dopamine units within the copolymer. These units synergistically enhance the coating's physical barrier properties and electrochemical passivation capabilities. Key mechanisms include enhanced interfacial adhesion, increased film compactness, and the passivation effect facilitated by the catechol groups in PDA.</div></div>","PeriodicalId":22081,"journal":{"name":"Surfaces and Interfaces","volume":"74 ","pages":"Article 107739"},"PeriodicalIF":6.3,"publicationDate":"2025-09-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145159934","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}