Surfaces and Interfaces最新文献

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Magneto-electric properties of (1-x)LaFeO3 - (x)MnFe2O4 based hybrid nanocomposites for advanced technological applications 用于先进技术应用的(1-x)LaFeO3 - (x)MnFe2O4基杂化纳米复合材料的磁电性能
IF 5.7 2区 材料科学
Surfaces and Interfaces Pub Date : 2025-06-28 DOI: 10.1016/j.surfin.2025.107070
Sehrish Inam , Muhammad Khalid , Zaheer Uddin , Muhammad Younas , Imed Boukhris , M.G.B. Ashiq
{"title":"Magneto-electric properties of (1-x)LaFeO3 - (x)MnFe2O4 based hybrid nanocomposites for advanced technological applications","authors":"Sehrish Inam ,&nbsp;Muhammad Khalid ,&nbsp;Zaheer Uddin ,&nbsp;Muhammad Younas ,&nbsp;Imed Boukhris ,&nbsp;M.G.B. Ashiq","doi":"10.1016/j.surfin.2025.107070","DOIUrl":"10.1016/j.surfin.2025.107070","url":null,"abstract":"<div><div>In this research paper, a series of (1-x)LaFeO<sub>3</sub> - (x)MnFe<sub>2</sub>O<sub>4</sub> (LFO/MFO) nanocomposites with concentrations (<em>x</em> = 0.1, 0.2, 0.3, 0.4, and 0.5) were synthesized through sol-gel auto combustion method. The x-ray diffraction analysis revealed pure FCC spinel phase and perovskite structure for MFO added in LFO respectively. FTIR analysis showed ʋ<sub>1</sub> and ʋ<sub>2</sub> absorption bands with wavenumbers 500 and 400 cm<sup>-1</sup>. The frequency dependent dielectric parameters were investigated across abroad spectrum of AC frequencies, starting from 1 MHz to 3 GHz. Dielectric behaviors were found in well agreement with Maxwell – Wagner model followed by Koop’s theory, and hopping model at high frequency region. The Cole-Cole plot elaborated the conduction phenomenon. The nanocomposites demonstrate a stable and consistent dielectric constant (ε′) and dielectric loss (ε″) at moderate frequencies, making them highly suitable for applications in microwave devices, such as resonators, filters, and antennas where stable dielectric properties are crucial for efficient performance. The magnetic behavior was found at room temperature (RT) by applying magnetic field from -22 to +22 k Oe. Magnetic squareness for all prepared samples found &lt;0.5 reported multi-domain structures that can be utilized in many technological areas like electronics, automotive, telecommunications, and magnetic storage devices.</div></div>","PeriodicalId":22081,"journal":{"name":"Surfaces and Interfaces","volume":"72 ","pages":"Article 107070"},"PeriodicalIF":5.7,"publicationDate":"2025-06-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144518882","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
In-situ NbC reinforced In625 claddings by ultrasonic vibration-assisted laser cladding: Mechanical properties and high-temperature oxidation resistance analysis 超声振动辅助激光熔覆原位NbC增强In625熔覆层的力学性能和高温抗氧化性分析
IF 5.7 2区 材料科学
Surfaces and Interfaces Pub Date : 2025-06-27 DOI: 10.1016/j.surfin.2025.107066
Yingying Zhang , Jiayu Sun , Liaoyuan Chen , Zhengyu Sun , Yanchong Gao , Yiqi Wang , Tianbiao Yu
{"title":"In-situ NbC reinforced In625 claddings by ultrasonic vibration-assisted laser cladding: Mechanical properties and high-temperature oxidation resistance analysis","authors":"Yingying Zhang ,&nbsp;Jiayu Sun ,&nbsp;Liaoyuan Chen ,&nbsp;Zhengyu Sun ,&nbsp;Yanchong Gao ,&nbsp;Yiqi Wang ,&nbsp;Tianbiao Yu","doi":"10.1016/j.surfin.2025.107066","DOIUrl":"10.1016/j.surfin.2025.107066","url":null,"abstract":"<div><div>This study explores how ultrasonic vibration integrated with laser cladding influences the formation and performance of in-situ NbC reinforced In625 claddings, focusing on microstructural characteristics, mechanical properties, and resistance to high-temperature oxidation under varying ultrasonic powers (0–440 W). Ultrasonic vibration notably enhances NbC formation, refines grain size, and improves particle distribution uniformity. Optimal mechanical properties were observed at 330 W, with a 20.2 HV increase in microhardness and a 22.8 % reduction in wear volume, alongside a transition in wear mechanism from adhesive to fatigue wear. High-temperature oxidation tests at 800 °C for 60 h revealed the formation of Cr<sub>2</sub>O<sub>3</sub>, Nb<sub>2</sub>O<sub>5</sub>, NiO, and NiCr<sub>2</sub>O<sub>4</sub> oxides, with the 330 W setting demonstrating superior oxidation resistance—2.67 mg/cm<sup>2</sup> wt gain and a 3.65 μm oxide layer, significantly lower than non-ultrasonic samples. However, as the ultrasonic power was further increased to 440 W, the cladding exhibited reduced microhardness, diminished wear resistance, and a decline in its ability to withstand high-temperature oxidation. This indicates that ultrasonic power should not exceed a certain limit, as excessive power can adversely affect the performance of the cladding. These findings underscore the efficacy of ultrasonic vibration in enhancing the performance of NbC reinforced In625 claddings, offering valuable insights for improving high-temperature oxidation resistance.</div></div>","PeriodicalId":22081,"journal":{"name":"Surfaces and Interfaces","volume":"72 ","pages":"Article 107066"},"PeriodicalIF":5.7,"publicationDate":"2025-06-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144514173","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Janus functionalized molybdenene monolayers Janus功能化钼单分子层
IF 5.7 2区 材料科学
Surfaces and Interfaces Pub Date : 2025-06-27 DOI: 10.1016/j.surfin.2025.107069
Longyuzhi Xu , Arslan Zulfiqar , Muhammad Saqib Arslan , Zhijing Huang , Shuming Zeng , Zonglin Gu
{"title":"Janus functionalized molybdenene monolayers","authors":"Longyuzhi Xu ,&nbsp;Arslan Zulfiqar ,&nbsp;Muhammad Saqib Arslan ,&nbsp;Zhijing Huang ,&nbsp;Shuming Zeng ,&nbsp;Zonglin Gu","doi":"10.1016/j.surfin.2025.107069","DOIUrl":"10.1016/j.surfin.2025.107069","url":null,"abstract":"<div><div>Molybdenene, having been experimentally synthesized [Sahu et al., Nat. Nanotechnol<em>.</em> <strong>18</strong>, 1430 (2023)], is the only Dirac material which concurrently possesses metallic characteristics. This innovative material has a variety of unique and outstanding properties, indicating significant potential applications across several fields. However, the instability of the free-standing molybdenene structure imposes considerable constraints on its possible use. To solve this problem, we designed 105 Janus monolayer structures by dual functionalization with X and Y atoms (X/<em>Y</em> = <em>H</em>, Li, Be, B, C, N, O, F, Na, Mg, Al, Si, P, S, Cl; X ≠ Y) on both basal planes of free-standing molybdenene (defined as Mo₂XY), aiming to achieve stable molybdenene monolayer derivatives. Using density functional theory (DFT) calculations and <em>ab</em> initio molecular dynamics (AIMD) simulations, we systematically investigated the energetic, mechanical, dynamical, and thermodynamical stability of these 105 Mo₂XY structures. Remarkably, our calculations revealed two completely stable Janus molybdenene monolayer derivatives, <em>i.e</em>., Mo<sub>2</sub>HF and Mo<sub>2</sub>OMg. We also investigated the mechanical and electronic properties of these two Janus monolayers. Our study not only stabilizes the free-standing molybdenene via chemical functionalization at both two surfaces, but also introduces two novel stable Janus molybdenene monolayer derivatives, providing a critical theoretical foundation for their future applications.</div></div>","PeriodicalId":22081,"journal":{"name":"Surfaces and Interfaces","volume":"72 ","pages":"Article 107069"},"PeriodicalIF":5.7,"publicationDate":"2025-06-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144518657","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
SiC/Hf2CO2 vdWs heterojunction: Type-II narrow-bandgap heterojunction with excellent carrier mobility and photogalvanic effect SiC/Hf2CO2 vdWs异质结:ii型窄带隙异质结,具有优异的载流子迁移率和光电效应
IF 5.7 2区 材料科学
Surfaces and Interfaces Pub Date : 2025-06-26 DOI: 10.1016/j.surfin.2025.107055
Meng Guo , Zhen Cui , Taifei Zhao
{"title":"SiC/Hf2CO2 vdWs heterojunction: Type-II narrow-bandgap heterojunction with excellent carrier mobility and photogalvanic effect","authors":"Meng Guo ,&nbsp;Zhen Cui ,&nbsp;Taifei Zhao","doi":"10.1016/j.surfin.2025.107055","DOIUrl":"10.1016/j.surfin.2025.107055","url":null,"abstract":"<div><div>In this work, the first-principles calculations were employed to systematically examine the structure, electronic and optical properties of the SiC/Hf<sub>2</sub>CO<sub>2</sub> van der Waals heterojunction. Our calculations demonstrate that the heterojunction forms a type-II S-scheme structure with a direct bandgap of 1.25 eV, exhibiting strong redox capability. Carrier mobility calculations exhibit strong conductivity along the armchair direction, with the electron mobility of 2.57 × 10<sup>4</sup> cm²/Vs. The heterojunction enhances ultraviolet absorption and extends absorption into the visible range, overcoming the spectral limitations of 2D SiC. The maximum photocurrent was calculated at the photon energy of 3.0 eV, confirming its visible light detection capability. These results indicate that SiC/Hf<sub>2</sub>CO<sub>2</sub> heterojunction exhibits significant potential in self-powered photodetector.</div></div>","PeriodicalId":22081,"journal":{"name":"Surfaces and Interfaces","volume":"72 ","pages":"Article 107055"},"PeriodicalIF":5.7,"publicationDate":"2025-06-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144514175","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Low temperature synthesis of yellow-green emission carbon dots with excellent antibacterial activity for Escherichia coli and Methicillin-resistant Staphylococcus aureus 低温合成对大肠杆菌和耐甲氧西林金黄色葡萄球菌具有良好抑菌活性的黄绿色发射碳点
IF 5.7 2区 材料科学
Surfaces and Interfaces Pub Date : 2025-06-26 DOI: 10.1016/j.surfin.2025.107056
Beibei Wang, Ping Yang, Gang Zhou, Qingshan Shi, Xiaobao Xie
{"title":"Low temperature synthesis of yellow-green emission carbon dots with excellent antibacterial activity for Escherichia coli and Methicillin-resistant Staphylococcus aureus","authors":"Beibei Wang,&nbsp;Ping Yang,&nbsp;Gang Zhou,&nbsp;Qingshan Shi,&nbsp;Xiaobao Xie","doi":"10.1016/j.surfin.2025.107056","DOIUrl":"10.1016/j.surfin.2025.107056","url":null,"abstract":"<div><div>Human life is seriously threatened by the development of antibiotic-resistant microorganisms. The most promising antibacterial agents for dormant pathogenic among the range of nanomaterials are carbon dots. This work proposes a fast and environmentally friendly method for preparing yellow-emission carbon dots (YCDs), which could be completed within 30 min at 80 °C by using ascorbic acid and cetylpyridinium chloride monohydrate as precursors. Crucially, the obtained YCDs could be easily internalized by bacteria and emit bright yellow-green light inside the cells due to the small size (3.9 ± 0.6 nm) and large stokes shift (161 nm). Additionally, the YCDs display excellent effectiveness against pathogenic bacteria, especially for Gram-negative and resistant Gram-positive bacteria. The minimum inhibitory concentration for methicillin-resistant <em>Staphylococcus aureus</em> (MRSA) and <em>Escherichia coli</em> are 1.25 and 5 μg mL<sup>−1</sup>, respectively. Furthermore, results demonstrate that the excellent antibacterial ability of YCDs is attributed to a combination of the hydrophobic of alkyl chain, oxidative damage and electrostatic interaction. Overall, our work provides an environmentally friendly and low-cost method to prepare the yellow-green emission carbon dots with strong antibacterial activity against resistant bacteria.</div></div>","PeriodicalId":22081,"journal":{"name":"Surfaces and Interfaces","volume":"72 ","pages":"Article 107056"},"PeriodicalIF":5.7,"publicationDate":"2025-06-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144518881","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Fabrication of porous β−cyclodextrin polymer mixed matrix membranes for benzotriazole removal from aqueous solution 多孔β -环糊精聚合物混合基质膜的制备及其去除苯并三唑的研究
IF 5.7 2区 材料科学
Surfaces and Interfaces Pub Date : 2025-06-25 DOI: 10.1016/j.surfin.2025.107051
Haiyan Li , Zhihao Liu , Jiayue Han , Yujie Sun , Mingchen Gao , Yanhong Ji , Chaohong Tan , Meipeng Jian
{"title":"Fabrication of porous β−cyclodextrin polymer mixed matrix membranes for benzotriazole removal from aqueous solution","authors":"Haiyan Li ,&nbsp;Zhihao Liu ,&nbsp;Jiayue Han ,&nbsp;Yujie Sun ,&nbsp;Mingchen Gao ,&nbsp;Yanhong Ji ,&nbsp;Chaohong Tan ,&nbsp;Meipeng Jian","doi":"10.1016/j.surfin.2025.107051","DOIUrl":"10.1016/j.surfin.2025.107051","url":null,"abstract":"<div><div>Preparation of powdered materials into membrane is one of the effective means to address the susceptibility of nanopowder adsorbent materials to loss. In this study, we first explored the potential of porous <em>β</em>−cyclodetrin polymer (P−CDP) powders in the removal of benzotraizole (BTA), and found that P−CDP powders have high efficiency in removing BTA, and the mechanism of BTA removal on P−CDP powders was investigated, in which the ionic C−F bonding of P−CDP powders and N−H bonding of BTA chemical combination and create a new covalent N−F bonding. Furthermore, the π-π interactions and hydrogen bonds also played an important role on BTA molecules. In order to solve the problems that powdered materials are not easy to recycle and easy to cause secondary pollution of water bodies, a innovative adsorptive mixed matrix membranes were prepared <em>via</em> integration P−CDP powders into polyacrylonitrile (PAN) membranes. The P−CDP/PAN mixed matrix membranes were fabricated by a simple phase inversion strategy. The physicochemical properties of the obtained membranes were characterized and the different loading rates of P−CDP powders were compared. Experimental results showed that the optimal P−CDP/PAN membranes had the fastest saturation time for BTA adsorption (10 min) and the highest BTA adsorption capacity of 337 mg·g<sup>−1</sup>. Meanwhile, the P−CDP/PAN membranes exhibited the hydrophilic nature with a high water permeance of 83 L·m<sup>−2</sup>·h<sup>−1</sup>·bar<sup>−1</sup>. In addition, the optimal P−CDP/PAN membranes displayed promising application in dynamic system for removing BTA. Moreover, the P−CDP/PAN membranes demonstrated outstanding regeneration efficiency and reusability over multiple cycles, coupled with simplified post-treatment procedures for phase separation compared to conventional powdered adsorbents. This study provides a novel strategy in fabricating adsorptive membranes for emerging organic contaminants removal.</div></div>","PeriodicalId":22081,"journal":{"name":"Surfaces and Interfaces","volume":"72 ","pages":"Article 107051"},"PeriodicalIF":5.7,"publicationDate":"2025-06-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144502128","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Exploring AlFe3N and GaFe3N as nitrogen carriers for chemical looping ammonia synthesis via density functional theory 利用密度泛函理论探索AlFe3N和gfe3n作为化学环氨合成的氮载体
IF 5.7 2区 材料科学
Surfaces and Interfaces Pub Date : 2025-06-25 DOI: 10.1016/j.surfin.2025.107054
Ilyas Bouziani , Chaimae Elkadiri , Ghulam Abbas , Mohamed Naji , Abdessamad Faik
{"title":"Exploring AlFe3N and GaFe3N as nitrogen carriers for chemical looping ammonia synthesis via density functional theory","authors":"Ilyas Bouziani ,&nbsp;Chaimae Elkadiri ,&nbsp;Ghulam Abbas ,&nbsp;Mohamed Naji ,&nbsp;Abdessamad Faik","doi":"10.1016/j.surfin.2025.107054","DOIUrl":"10.1016/j.surfin.2025.107054","url":null,"abstract":"<div><div>The urgent demand for sustainable ammonia production has motivated the exploration of alternatives to the energy-intensive Haber–Bosch process. In this study, density functional theory (DFT) calculations were employed to evaluate the catalytic performance of iron-based antiperovskite nitrides, AlFe<sub>3</sub>N and GaFe<sub>3</sub>N, for green ammonia synthesis via chemical looping. Stability analyses, including phonon dispersion, AIMD simulations, and elastic constants, confirm the dynamic, thermal, and mechanical robustness of both materials. Electronic structure results reveal metallic and ferromagnetic behavior, with a weaker Fe–N bond in GaFe<sub>3</sub>N due to the higher electronegativity of Ga, which enhances charge transfer and surface reactivity. Thermodynamic calculations show that both hydrogenation and (nitridation) are spontaneous at low temperatures, with negative Gibbs free energy values up to 248 K for AlFe<sub>3</sub>N and 415 K for GaFe<sub>3</sub>N. Surface analysis identifies the (111) facet as the most reactive, where Ga-based nitride demonstrates stronger H<sub>2</sub> adsorption (-3.828 eV) and a more exothermic nitrogen vacancy formation energy (-2.429 eV) than Al-based nitride, while the latter shows slightly stronger N<sub>2</sub> adsorption (-1.405 eV). The associative Mars–van Krevelen mechanism is energetically more favorable for GaFe<sub>3</sub>N, confirming its enhanced catalytic performance. These findings highlight the critical role of material composition in tuning catalytic behavior and establish AlFe<sub>3</sub>N and GaFe<sub>3</sub>N as promising catalysts for low-temperature, sustainable ammonia synthesis. Looking ahead, the integration of high-throughput screening with machine learning is expected to accelerate the discovery of efficient nitride-based catalysts for green ammonia production.</div></div>","PeriodicalId":22081,"journal":{"name":"Surfaces and Interfaces","volume":"72 ","pages":"Article 107054"},"PeriodicalIF":5.7,"publicationDate":"2025-06-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144518656","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Enhanced photocatalytic hydrogen evolution through the construction of CdWO4/Mn0.5Cd0.5S interfacial heterojunction 通过构建CdWO4/Mn0.5Cd0.5S界面异质结增强光催化析氢
IF 5.7 2区 材料科学
Surfaces and Interfaces Pub Date : 2025-06-24 DOI: 10.1016/j.surfin.2025.107035
Wenting Xiao , Haohuan Yuan , Jiao Bao , Xin Zhang , Bo Huang , Guannan He
{"title":"Enhanced photocatalytic hydrogen evolution through the construction of CdWO4/Mn0.5Cd0.5S interfacial heterojunction","authors":"Wenting Xiao ,&nbsp;Haohuan Yuan ,&nbsp;Jiao Bao ,&nbsp;Xin Zhang ,&nbsp;Bo Huang ,&nbsp;Guannan He","doi":"10.1016/j.surfin.2025.107035","DOIUrl":"10.1016/j.surfin.2025.107035","url":null,"abstract":"<div><div>Mn<sub>x</sub>Cd<sub>1-x</sub>S is an emerging semiconductor photocatalyst due to the tunable band gap and high visible light response. Nevertheless, high charge recombination rate and severe photo-corrosion are two main drawbacks inhibit its further application. In this paper, CdWO<sub>4</sub>/Mn<sub>0.5</sub>Cd<sub>0.5</sub>S interfacial heterojunctions were formed by the hydrothermal process. The homogeneous distribution of CdWO<sub>4</sub> nanorods and Mn<sub>0.5</sub>Cd<sub>0.5</sub>S nanopolyhedra ensure large contact areas, facilitating more heterojunctions formed at the interfaces. By adjusting the CdWO<sub>4</sub> loading, the optimized binary composite, 9CdWO<sub>4</sub>/Mn<sub>0.5</sub>Cd<sub>0.5</sub>S, reached the hydrogen precipitation rate of 8417.1 μmol‧g<sup>-1</sup>‧h<sup>-1</sup>, surpassing both Mn<sub>0.5</sub>Cd<sub>0.5</sub>S and CdWO<sub>4</sub> monomer. The composite also showed brilliant stability, and an Apparent Quantum Yield (AQY) of 14.13 % at 420 nm. The carrier transfer and photocatalytic hydrogen production mechanisms of the materials were analyzed through various characterizations. This work offered valuable ideas for the application of CdWO<sub>4</sub>-based wide-bandgap semiconductors towards photocatalytic hydrogen production.</div></div>","PeriodicalId":22081,"journal":{"name":"Surfaces and Interfaces","volume":"72 ","pages":"Article 107035"},"PeriodicalIF":5.7,"publicationDate":"2025-06-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144514262","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Chain-length-dependent nanostructure evolution in InOx/PAM composite films: Interface engineering for electrical performance modulation 链长度依赖的纳米结构演变在InOx/PAM复合薄膜:界面工程的电性能调制
IF 5.7 2区 材料科学
Surfaces and Interfaces Pub Date : 2025-06-24 DOI: 10.1016/j.surfin.2025.107039
Zhennan Zhu , Wei Lv , Hongcheng Wang , Xiaojiao Kang , Qiwen Pan , Rihui Yao , Honglong Ning
{"title":"Chain-length-dependent nanostructure evolution in InOx/PAM composite films: Interface engineering for electrical performance modulation","authors":"Zhennan Zhu ,&nbsp;Wei Lv ,&nbsp;Hongcheng Wang ,&nbsp;Xiaojiao Kang ,&nbsp;Qiwen Pan ,&nbsp;Rihui Yao ,&nbsp;Honglong Ning","doi":"10.1016/j.surfin.2025.107039","DOIUrl":"10.1016/j.surfin.2025.107039","url":null,"abstract":"<div><div>The advancement of flexible electronics demands composite semiconductors that harmonize mechanical adaptability and electrical performance. This study elucidates how polyacrylamide (PAM) molecular weight governs nanocrystal evolution in InO<sub>x</sub>/PAM composite films through interfacial coordination dynamics and steric hindrance effects. Increasing PAM molecular weight drives nanocrystal morphology transitions from isotropic spherical clusters (short-chain) to anisotropic strip-like domains (medium-chain), and ultimately to highly dispersed isolated states (long-chain). Simultaneously, PAM modulates the connectivity of metal-oxygen-metal (M-O-M) networks while introducing defect states, establishing a dynamic equilibrium between carrier transport enhancement and defect-mediated scattering. Optimization of molecular weight (150000) and polymer doping concentration (1 wt %) enabled synergistic regulation of nanocrystal interconnectivity and defect generation, achieving 90 % mobility retention of pure InO<sub>x</sub>-TFTs (1.43 cm<sup>2</sup>/V.s) in InO<sub>x</sub>/PAM-TFTs (1.38 cm<sup>2</sup>/V.s). Notably, chain-length-dependent nanocrystal morphology governs carrier transport pathways: strip-like domains facilitate directional percolation, whereas dispersed nanocrystals exacerbate interfacial scattering. This work establishes a chain-length-engineered interface strategy for solution-processed composites, providing universal design principles for balancing crystallinity control and defect generation in next-generation flexible electronics.</div></div>","PeriodicalId":22081,"journal":{"name":"Surfaces and Interfaces","volume":"72 ","pages":"Article 107039"},"PeriodicalIF":5.7,"publicationDate":"2025-06-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144514261","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Bimetallic oxide CrBiO4-integrated energy harvesting device: A step toward self-powered proximity sensors 双金属氧化物crbio4集成能量收集装置:向自供电接近传感器迈进了一步
IF 5.7 2区 材料科学
Surfaces and Interfaces Pub Date : 2025-06-24 DOI: 10.1016/j.surfin.2025.107040
Rumana Farheen S. M. , Sebghatullah Amini , Pruthvi M. P. , Sangamesha M. A. , Manjunatha H. C. , Manjunatha S. , Krishnaveni S.
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