Solid state nuclear magnetic resonance最新文献_第4页

Development of in situ high resolution NMR: Proof-of-principle for a new (spinning) cylindrical mini-pellet approach applied to a Lithium ion battery 原位高分辨率核磁共振的开发：应用于锂离子电池的新型（旋转）圆柱形微型颗粒方法的原理验证

IF 3.2 3区化学

Solid state nuclear magnetic resonance Pub Date : 2023-12-18 DOI: 10.1016/j.ssnmr.2023.101914

Irshad Mohammad , Musa Ali Cambaz , Ago Samoson , Maximilian Fichtner , Raiker Witter

{"title":"Development of in situ high resolution NMR: Proof-of-principle for a new (spinning) cylindrical mini-pellet approach applied to a Lithium ion battery","authors":"Irshad Mohammad , Musa Ali Cambaz , Ago Samoson , Maximilian Fichtner , Raiker Witter","doi":"10.1016/j.ssnmr.2023.101914","DOIUrl":"10.1016/j.ssnmr.2023.101914","url":null,"abstract":"<div>Solid-state nuclear magnetic resonance (ssNMR) spectroscopy is a powerful technique for characterizing the local structure and dynamics of battery and other materials. It has been widely used to investigate bulk electrode compounds, electrolytes, and interfaces. Beside common ex situ investigations, in situ and operando techniques have gained considerable importance for understanding the reaction mechanisms and cell degradation of electrochemical cells.Herein, we present the recent development of in situ magic angle spinning (MAS) NMR methodologies to study batteries with high spectral resolution, setting into context possible advances on this topic. A mini cylindrical cell type insert for 4 mm MAS rotors is introduced here, being demonstrated on a Li/VO2F electrochemical system, allowing the acquisition of high-resolution 7Li MAS NMR spectra, spinning the electrochemical cell up to 15 kHz.</div>","PeriodicalId":21937,"journal":{"name":"Solid state nuclear magnetic resonance","volume":"129 ","pages":"Article 101914"},"PeriodicalIF":3.2,"publicationDate":"2023-12-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"138740138","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

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Field-stepwise-swept solid-state 127I NMR of 1,4-diiodobenzene 1,4-二碘苯的场逐步扫描固态127I核磁共振。

IF 3.2 3区化学

Solid state nuclear magnetic resonance Pub Date : 2023-12-01 DOI: 10.1016/j.ssnmr.2023.101905

Kazuhiko Yamada , Tatsuo Kaiho

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Kinetics of 1H →31P NMR cross-polarization and dynamics in a layered crystalline α-Sn(IV) phosphate α-Sn(IV)磷酸层状晶体的1H→31P核磁共振交叉极化动力学及动力学

IF 3.2 3区化学

Solid state nuclear magnetic resonance Pub Date : 2023-10-01 DOI: 10.1016/j.ssnmr.2023.101898

Vladimir I. Bakhmutov, Douglas W. Elliott, Hong-Cai Zhou

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Solid-state NMR of organic molecules: Characterising solid-state form 有机分子的固态核磁共振:表征固态形式

IF 3.2 3区化学

Solid state nuclear magnetic resonance Pub Date : 2023-08-01 DOI: 10.1016/j.ssnmr.2023.101876

Steven P. Brown, Yongchao Su

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High resolution solid-state NMR on the desktop 高分辨率固态核磁共振在桌面上

IF 3.2 3区化学

Solid state nuclear magnetic resonance Pub Date : 2023-08-01 DOI: 10.1016/j.ssnmr.2023.101884

Ke Xu , Fettah Aldudak , Oliver Pecher , Marco Braun , Andreas Neuberger , Holger Foysi , Jörn Schmedt auf der Günne

{"title":"High resolution solid-state NMR on the desktop","authors":"Ke Xu , Fettah Aldudak , Oliver Pecher , Marco Braun , Andreas Neuberger , Holger Foysi , Jörn Schmedt auf der Günne","doi":"10.1016/j.ssnmr.2023.101884","DOIUrl":"10.1016/j.ssnmr.2023.101884","url":null,"abstract":"<div>High-resolution low-field nuclear magnetic resonance (NMR) spectroscopy has found wide application for characterization of liquid compounds because of the low maintenance cost of modern permanent magnets. Solid-state NMR so far is limited to low-resolution measurements of static powders, because of the limited space available in this type of magnet. Magic-angle sample spinning and low-magnetic fields are an attractive combination to achieve high spectral resolution especially for paramagnetic solids. Here we show that magic angle spinning modules can be miniaturized using 3D printing techniques so that high-resolution solid-state NMR in permanent magnets becomes possible. The suggested conical rotor design was developed using finite element calculations and provides sample spinning frequencies higher than 20 kHz. The setup was tested on various diamagnetic and paramagnetic compounds including paramagnetic battery materials. The only comparable experiments in low-cost magnets known so far, had been done in the early times of magic angle spinning using electromagnets at much lower sample spinning frequency. Our results demonstrate that high-resolution low-field magic-angle-spinning NMR does not require expensive superconducting magnets and that high-resolution solid-state NMR spectra of paramagnetic compounds are feasible. Generally, this could introduce low-field solid-state NMR for abundant nuclei standard as a routine analytical tool.</div>","PeriodicalId":21937,"journal":{"name":"Solid state nuclear magnetic resonance","volume":"126 ","pages":"Article 101884"},"PeriodicalIF":3.2,"publicationDate":"2023-08-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"9982675","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

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Remembering Shimon Vega: Special issue on solid-state and DNP NMR 纪念Shimon Vega：固态和DNP NMR特刊

IF 3.2 3区化学

Solid state nuclear magnetic resonance Pub Date : 2023-08-01 DOI: 10.1016/j.ssnmr.2023.101885

G. Goobes, P.K. Madhu, A. Goldbourt

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Spin diffusion in the Phosphorus-31 NMR relaxation in a layered crystalline α-Sn(IV) phosphate contaminated by paramagnetic impurities 顺磁杂质污染层状α-Sn(IV)磷酸盐中磷-31核磁共振弛豫的自旋扩散

IF 3.2 3区化学

Solid state nuclear magnetic resonance Pub Date : 2023-08-01 DOI: 10.1016/j.ssnmr.2023.101875

Vladimir I. Bakhmutov , Douglas W. Elliott , Nattamai Bhuvanesh , Hong-Cai Zhou

引用次数: 1

Corrigendum to “Implanted-ion β NMR: A new probe for nanoscience” [Solid State Nucl. Magn. Reson. 68-69 (2015) 1–12] “植入离子βNMR：纳米科学的新探针”勘误表[Solid State Nucl.Magn.Reson.68-69（2015）1-12]

IF 3.2 3区化学

Solid state nuclear magnetic resonance Pub Date : 2023-08-01 DOI: 10.1016/j.ssnmr.2023.101886

W.A. MacFarlane

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Investigating particle size effects on NMR spectra of ions diffusing in porous carbons through a mesoscopic model 通过介观模型研究离子在多孔碳中扩散的粒度对核磁共振谱的影响

IF 3.2 3区化学

Solid state nuclear magnetic resonance Pub Date : 2023-08-01 DOI: 10.1016/j.ssnmr.2023.101883

Anagha Sasikumar , Céline Merlet

{"title":"Investigating particle size effects on NMR spectra of ions diffusing in porous carbons through a mesoscopic model","authors":"Anagha Sasikumar , Céline Merlet","doi":"10.1016/j.ssnmr.2023.101883","DOIUrl":"10.1016/j.ssnmr.2023.101883","url":null,"abstract":"<div>Characterizing ion adsorption and diffusion in porous carbons is essential to understand the performance of such materials in a range of key technologies such as energy storage and capacitive deionisation. Nuclear Magnetic Resonance (NMR) spectroscopy is a powerful technique to get insights in these systems thanks to its ability to distinguish between bulk and adsorbed species and to its sensitivity to dynamic phenomena. Nevertheless, a clear interpretation of the experimental results is sometimes rendered difficult by the various factors affecting NMR spectra. A mesoscopic model to predict NMR spectra of ions diffusing in carbon particles is adapted to include dynamic exchange between the intra-particle space and the bulk electrolyte surrounding the particle. A systematic study of the particle size effect on the NMR spectra for different distributions of magnetic environments in the porous carbons is conducted. The model demonstrates the importance of considering a range of magnetic environments, instead of a single chemical shift value corresponding to adsorbed species, and of including a range of exchange rates (between in and out of the particle), instead of a single timescale, to predict realistic NMR spectra. Depending on the pore size distribution of the carbon particle and the ratio between bulk and adsorbed species, both the NMR linewidth and peak positions can be largely influenced by the particle size.</div>","PeriodicalId":21937,"journal":{"name":"Solid state nuclear magnetic resonance","volume":"126 ","pages":"Article 101883"},"PeriodicalIF":3.2,"publicationDate":"2023-08-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"9984738","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

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Determination of the mutual orientation between proton CSA tensors mediated through band-selective 1H–1H recoupling under fast MAS 快速MAS下带选择性1H-1H重耦合介导的质子CSA张量相互取向的测定

IF 3.2 3区化学

Solid state nuclear magnetic resonance Pub Date : 2023-06-01 DOI: 10.1016/j.ssnmr.2023.101874

Takeshi Kobayashi , Yusuke Nishiyama , Manoj Kumar Pandey

{"title":"Determination of the mutual orientation between proton CSA tensors mediated through band-selective 1H–1H recoupling under fast MAS","authors":"Takeshi Kobayashi , Yusuke Nishiyama , Manoj Kumar Pandey","doi":"10.1016/j.ssnmr.2023.101874","DOIUrl":"https://doi.org/10.1016/j.ssnmr.2023.101874","url":null,"abstract":"<div>The mutual orientation of nuclear spin interaction tensors provides critical information on the conformation and arrangement of molecules in chemicals, materials, and biological systems at an atomic level. Proton is a ubiquitous and important element in a variety of substances, and its NMR is highly sensitive due to their virtually 100% natural abundance and large gyromagnetic ratio. Nevertheless, the measurement of mutual orientation between the 1H CSA tensors has remained largely untouched in the past due to strong 1H–1H homonuclear interactions in a dense network of protons. In this study, we have developed a proton-detected 3D 1H CSA/1H CSA/1H CS correlation method that utilizes three techniques to manage homonuclear interactions, namely fast magic-angle spinning, windowless C-symmetry-based CSA recoupling (windowless-ROCSA), and a band-selective 1H–1H polarization transfer. The asymmetric 1H CSA/1H CSA correlated powder patterns produced by the C-symmetry-based methods are highly sensitive to the sign and asymmetry parameter of the 1H CSA, and the Euler angle β as compared to the symmetric pattern obtained by the existing γ-encoded R-symmetry-based CSA/CSA correlation methods and allows a larger spectral area for data fitting. These features are beneficial for determining the mutual orientation between the nuclear spin interaction tensors with improved accuracy.</div>","PeriodicalId":21937,"journal":{"name":"Solid state nuclear magnetic resonance","volume":"125 ","pages":"Article 101874"},"PeriodicalIF":3.2,"publicationDate":"2023-06-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"49866177","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

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