14N NMR of magnetically oriented microcrystals

IF 1.8 3区化学 Q4 CHEMISTRY, PHYSICAL

Solid state nuclear magnetic resonance Pub Date : 2024-03-26 DOI:10.1016/j.ssnmr.2024.101924

Tomoya Kamide, Yasuto Noda, Kazuyuki Takeda

引用次数: 0

Abstract

¹⁴N NMR of magnetically oriented microcrystals is reported. With a home-built ¹H–¹³C–¹⁴N probe capable of modulating the rotation of the sample around the axis normal to the magnetic field, magnetically oriented microcrystal suspension (MOMS) of l-alanine is made. ¹⁴N NMR spectra acquired with various timings during intermittent rotation lead to a rotation pattern of the MOMS similar to that of a single crystal. The effect of orientational distribution of the microcrystals to broadening of the resonance line is discussed.

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磁定向微晶的 14N NMR

报告了磁定向微晶的 14N NMR。利用自制的 1H-13C-14N 探针（该探针能够调节样品绕磁场法线轴的旋转），制备了 l-alanine 的磁定向微晶悬浮液（MOMS）。在间歇旋转过程中，以不同的时间采集 14N NMR 光谱，结果发现 MOMS 的旋转模式与单晶类似。讨论了微晶的取向分布对共振线增宽的影响。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

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来源期刊

Solid state nuclear magnetic resonance 物理-光谱学

CiteScore

5.30

自引率

9.40%

发文量

审稿时长

72 days

期刊介绍： The journal Solid State Nuclear Magnetic Resonance publishes original manuscripts of high scientific quality dealing with all experimental and theoretical aspects of solid state NMR. This includes advances in instrumentation, development of new experimental techniques and methodology, new theoretical insights, new data processing and simulation methods, and original applications of established or novel methods to scientific problems.