Science and Technology of Advanced Materials最新文献

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Multicrystalline informatics: a methodology to advance materials science by unraveling complex phenomena 多晶信息学:通过揭示复杂现象推动材料科学发展的方法学
IF 5.5 3区 材料科学
Science and Technology of Advanced Materials Pub Date : 2024-12-31 DOI: 10.1080/14686996.2024.2396272
Noritaka Usami, Kentaro Kutsukake, Takuto Kojima, Hiroaki Kudo, Tatsuya Yokoi, Yutaka Ohno
{"title":"Multicrystalline informatics: a methodology to advance materials science by unraveling complex phenomena","authors":"Noritaka Usami, Kentaro Kutsukake, Takuto Kojima, Hiroaki Kudo, Tatsuya Yokoi, Yutaka Ohno","doi":"10.1080/14686996.2024.2396272","DOIUrl":"https://doi.org/10.1080/14686996.2024.2396272","url":null,"abstract":"Multicrystalline materials play a crucial role in our society. However, their microstructure is complicated, and there is no universal approach to achieving high performance. Therefore, a methodology is necessary to answer the fundamental question of how we should design and create microstructures. ‘Multicrystalline informatics’ is an innovative approach that combines experimental, theoretical, computational, and data sciences. This approach helps us understand complex phenomena in multicrystalline materials and improve their performance. The paper covers various original research bases of multicrystalline informatics, such as the three-dimensional visualization of crystal defects in multicrystalline materials, the machine learning model for predicting crystal orientation distribution, network analysis of multicrystalline structures, computational methods using artificial neural network interatomic potentials, and so on. The integration of these research bases proves to be useful in understanding unexplained phenomena in complex multicrystalline materials. The paper also presents examples of efficient optimization of the growth process of high-quality materials with the aid of informatics, as well as prospects for extending the methodology to other materials.","PeriodicalId":21588,"journal":{"name":"Science and Technology of Advanced Materials","volume":null,"pages":null},"PeriodicalIF":5.5,"publicationDate":"2024-12-31","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142257226","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Tracking the evolution of the morphology and stress distribution of SIS thermoplastic elastomers under tension using atomic force microscopy 利用原子力显微镜跟踪 SIS 热塑性弹性体在拉力作用下的形态和应力分布演变情况
IF 5.5 3区 材料科学
Science and Technology of Advanced Materials Pub Date : 2024-12-31 DOI: 10.1080/14686996.2024.2402685
Ling Gao, Haonan Liu, Xiaobin Liang, Makiko Ito, Ken Nakajima
{"title":"Tracking the evolution of the morphology and stress distribution of SIS thermoplastic elastomers under tension using atomic force microscopy","authors":"Ling Gao, Haonan Liu, Xiaobin Liang, Makiko Ito, Ken Nakajima","doi":"10.1080/14686996.2024.2402685","DOIUrl":"https://doi.org/10.1080/14686996.2024.2402685","url":null,"abstract":"Styrene-based ABA-type triblock copolymers and their blends are widely investigated thermoplastic elastomers (TPEs). The design of tough TPE materials with high strength and resilience requires further clarification of the relationship between microstructure and macroscopic properties of stretched samples. Here, we applied atomic force microscopy (AFM)-based quantitative nanomechanical mapping to study the deformation behavior of poly(styrene-<i>b</i>-isoprene-<i>b</i>-styrene) blends under tension. The results indicated that the glassy polystyrene (PS) domains deformed and inhomogeneous stress distributions developed in the initial stretching stage. At 200% strain, the glassy PS domains started to crack. The change in the peak value in the JKR Young’s modulus diagram during stretching was consistent with the stress – strain curve. Analysis of the particles before and after stretching suggested that the glassy domains separated and reorganized during stretching.","PeriodicalId":21588,"journal":{"name":"Science and Technology of Advanced Materials","volume":null,"pages":null},"PeriodicalIF":5.5,"publicationDate":"2024-12-31","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142257224","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Robust and orange-yellow-emitting Sr-rich polytypoid α-SiAlON (Sr3Si24Al6N40:Eu2+) phosphor for white LEDs 用于白光 LED 的稳定且可发出橙黄色光的富硒多晶体 α-SiAlON (Sr3Si24Al6N40:Eu2+) 荧光粉
IF 5.5 3区 材料科学
Science and Technology of Advanced Materials Pub Date : 2024-12-31 DOI: 10.1080/14686996.2024.2396276
Mehdi Estili, Rong-Jun Xie, Kohsei Takahashi, Shiro Funahashi, Tohru S. Suzuki, Naoto Hirosaki
{"title":"Robust and orange-yellow-emitting Sr-rich polytypoid α-SiAlON (Sr3Si24Al6N40:Eu2+) phosphor for white LEDs","authors":"Mehdi Estili, Rong-Jun Xie, Kohsei Takahashi, Shiro Funahashi, Tohru S. Suzuki, Naoto Hirosaki","doi":"10.1080/14686996.2024.2396276","DOIUrl":"https://doi.org/10.1080/14686996.2024.2396276","url":null,"abstract":"Nitrides and oxynitrides isostructural to α-Si<sub>3</sub>N<sub>4</sub> (<i>M</i>-α-SiAlON, <i>M</i> = Sr, Ca, Li) possess superb thermally stable photoluminescence (PL) properties, making them reliable phosphors for high-power solid-state lighting. However, the synthesis of phase-pure Sr-α-SiAlON still remains a great challenge and has only been reported for Sr below 1.35 at.% as the large size of Sr<sup>2+</sup> ions tends to destabilize the α-SiAlON structure. Here, we succeeded to synthesize the single-phase powders of a unique ‘Sr-rich’ polytypoid α-SiAlON (Sr<sub>3</sub>Si<sub>24</sub>Al<sub>6</sub>N<sub>40</sub>:Eu<sup>2+</sup>) phosphor with three distinctive Sr/Eu luminescence sites using a solid-state remixing-reannealing process. The Sr content of this polytypoid structure exceeds those of a few previously reported structures by over 200%. The phase purity, composition, structure, and PL properties of this phosphor were investigated. A single phase can be obtained by firing the stoichiometric mixtures of all-nitride precursors at 2050°C under a 0.92 MPa N<sub>2</sub> atmosphere. The Sr<sub>3</sub>Si<sub>24</sub>Al<sub>6</sub>N<sub>40</sub>:Eu<sup>2+</sup> shows an intense orange-yellow emission, with the emission maximum of 590 nm and internal/external quantum efficiency of 66%/52% under 400 nm excitation. It also has a quite small thermal quenching, maintaining 93% emission intensity at 150°C. In comparison to Ca-α-SiAlON:Eu<sup>2+</sup>, this Sr counterpart shows superior quantum efficiency and thermal stability, enabling it to be an interesting orange-yellow down-conversion luminescent material for white LEDs. The experimental confirmation of the existence of such ‘Sr-rich’ SiAlON systems, in a single-phase powder form, paves the way for the design and synthesis of novel ‘Sr-rich’ SiAlON-based phosphor powders with unparalleled properties.","PeriodicalId":21588,"journal":{"name":"Science and Technology of Advanced Materials","volume":null,"pages":null},"PeriodicalIF":5.5,"publicationDate":"2024-12-31","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142257225","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
A comprehensive data network for data-driven study of battery materials 用于电池材料数据驱动研究的综合数据网络
IF 5.5 3区 材料科学
Science and Technology of Advanced Materials Pub Date : 2024-12-31 DOI: 10.1080/14686996.2024.2403328
Yibin Xu, Yen-Ju Wu, Huiping Li, Lei Fang, Shigenobu Hayashi, Ayako Oishi, Natsuko Shimizu, Riccarda Caputo, Pierre Villars
{"title":"A comprehensive data network for data-driven study of battery materials","authors":"Yibin Xu, Yen-Ju Wu, Huiping Li, Lei Fang, Shigenobu Hayashi, Ayako Oishi, Natsuko Shimizu, Riccarda Caputo, Pierre Villars","doi":"10.1080/14686996.2024.2403328","DOIUrl":"https://doi.org/10.1080/14686996.2024.2403328","url":null,"abstract":"Data-driven material research for property prediction and material design using machine learning methods requires a large quantity, wide variety, and high-quality materials data. For battery materials, which are commonly polycrystalline, ceramics, and composites, multiscale data on substances, materials, and batteries are required. In this work, we develop a data network composed of three interlinked databases, from which we can obtain comprehensive data on substances such as crystal structures and electronic structures, data on materials such as chemical composition, structure, and properties, and data on batteries such as battery composition, operation conditions, and capacity. The data are extracted from research papers on solid electrolytes and cathode materials, selected by screening more than 330 thousand papers using natural language processing tools. Data extraction and curation are carried out by editors specialized in material science and trained in data standardization.","PeriodicalId":21588,"journal":{"name":"Science and Technology of Advanced Materials","volume":null,"pages":null},"PeriodicalIF":5.5,"publicationDate":"2024-12-31","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142269850","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Correction. 更正。
IF 7.4 3区 材料科学
Science and Technology of Advanced Materials Pub Date : 2024-10-02 eCollection Date: 2024-01-01 DOI: 10.1080/14686996.2024.2408081
{"title":"Correction.","authors":"","doi":"10.1080/14686996.2024.2408081","DOIUrl":"https://doi.org/10.1080/14686996.2024.2408081","url":null,"abstract":"<p><p>[This corrects the article DOI: 10.1080/14686996.2024.2378684.].</p>","PeriodicalId":21588,"journal":{"name":"Science and Technology of Advanced Materials","volume":null,"pages":null},"PeriodicalIF":7.4,"publicationDate":"2024-10-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.ncbi.nlm.nih.gov/pmc/articles/PMC11448319/pdf/","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142372770","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Novel temperature responsive polymer based sealant for embolization. 用于栓塞的新型温度响应聚合物密封剂。
IF 7.4 3区 材料科学
Science and Technology of Advanced Materials Pub Date : 2024-09-25 eCollection Date: 2024-01-01 DOI: 10.1080/14686996.2024.2409059
Ali E Dabiri, Ravin Narain, Yi-Yang Peng, Wenda Wang, Max Itkins, Ghassan S Kassab
{"title":"Novel temperature responsive polymer based sealant for embolization.","authors":"Ali E Dabiri, Ravin Narain, Yi-Yang Peng, Wenda Wang, Max Itkins, Ghassan S Kassab","doi":"10.1080/14686996.2024.2409059","DOIUrl":"10.1080/14686996.2024.2409059","url":null,"abstract":"<p><p>A sealant has been developed that improves upon current catheter-based treatments in the following ways: 1) Efficient delivery system, 2) No in situ polymerization, 3) No harmful byproducts, and 4) Cost-effective formulation. During the development process, particular attention was given to materials that were tunable, safe, and effective sealant agents. The thermo-responsive properties of poly(N-isopropylacrylamide) (PNIPAM) provides an ideal foundation to develop an optimized solution. Through a combination of model-based and material testing, a hydrogel was developed that balances conformational factors to achieve a customized transition temperature, radiopacity suitable for visualization, mechanical properties suitable for delivery via 3Fr catheter, sufficient cohesion once applied to resist migration under physiological pressures and an improved safety profile. Two applications, embolization of lymphatic leakage and exclusions of the left atrial appendage (LAA), to eliminate LAA dead space to reduce the risk of thromboembolic events, were considered. The material and benchtop results for this product demonstrate the suitability of this new material not only for these applications but also for other potential healthcare applications.</p>","PeriodicalId":21588,"journal":{"name":"Science and Technology of Advanced Materials","volume":null,"pages":null},"PeriodicalIF":7.4,"publicationDate":"2024-09-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.ncbi.nlm.nih.gov/pmc/articles/PMC11451279/pdf/","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142381615","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Effects of the matrix-bounded nanovesicles of high-hydrostatic pressure decellularized tissues on neural regeneration 高静水压脱细胞组织的基质纳米颗粒对神经再生的影响
IF 5.5 3区 材料科学
Science and Technology of Advanced Materials Pub Date : 2024-09-19 DOI: 10.1080/14686996.2024.2404380
Mako Kobayashi, Jun Negishi, Naoki Ishida, Yoshihide Hashimoto, Yoshihiro Sasaki, Kazunari Akiyoshi, Tsuyoshi Kimura, Akio Kishida
{"title":"Effects of the matrix-bounded nanovesicles of high-hydrostatic pressure decellularized tissues on neural regeneration","authors":"Mako Kobayashi, Jun Negishi, Naoki Ishida, Yoshihide Hashimoto, Yoshihiro Sasaki, Kazunari Akiyoshi, Tsuyoshi Kimura, Akio Kishida","doi":"10.1080/14686996.2024.2404380","DOIUrl":"https://doi.org/10.1080/14686996.2024.2404380","url":null,"abstract":"Decellularized tissues have been used as implantable materials for tissue regeneration because of their high biofunctionality. We have reported that high hydrostatic pressured (HHP) decellularized ...","PeriodicalId":21588,"journal":{"name":"Science and Technology of Advanced Materials","volume":null,"pages":null},"PeriodicalIF":5.5,"publicationDate":"2024-09-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142269613","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Hybrid biofabricated blood vessel for medical devices testing. 用于医疗器械测试的混合生物制造血管。
IF 7.4 3区 材料科学
Science and Technology of Advanced Materials Pub Date : 2024-09-18 eCollection Date: 2024-01-01 DOI: 10.1080/14686996.2024.2404382
Alberto Portone, Francesco Ganzerli, Tiziana Petrachi, Elisa Resca, Valentina Bergamini, Luca Accorsi, Alberto Ferrari, Simona Sbardelatti, Luigi Rovati, Giorgio Mari, Massimo Dominici, Elena Veronesi
{"title":"Hybrid biofabricated blood vessel for medical devices testing.","authors":"Alberto Portone, Francesco Ganzerli, Tiziana Petrachi, Elisa Resca, Valentina Bergamini, Luca Accorsi, Alberto Ferrari, Simona Sbardelatti, Luigi Rovati, Giorgio Mari, Massimo Dominici, Elena Veronesi","doi":"10.1080/14686996.2024.2404382","DOIUrl":"https://doi.org/10.1080/14686996.2024.2404382","url":null,"abstract":"<p><p>Current <i>in vitro</i> and <i>in vivo</i> tests applied to assess the safety of medical devices retain several limitations, such as an incomplete ability to faithfully recapitulate human features, and to predict the response of human tissues together with non-trivial ethical aspects. We here challenged a new hybrid biofabrication technique that combines bioprinting and Fast Diffusion-induced Gelation strategy to generate a vessel-like structure with the attempt to spatially organize fibroblasts, smooth-muscle cells, and endothelial cells. The introduction of Fast Diffusion-induced Gelation minimizes the endothelial cell mortality during biofabrication and produce a thin endothelial layer with tunable thickness. Cell viability, Von Willebrand factor, and CD31 expression were evaluated on biofabricated tissues, showing how bioprinting and Fast Diffusion-induced Gelation can replicate human vessels architecture and complexity. We then applied biofabricated tissue to study the cytotoxicity of a carbothane catheter under static condition, and to better recapitulate the effect of blood flow, a novel bioreactor named CuBiBox (Customized Biological Box) was developed and introduced in a dynamic modality. Collectively, we propose a novel bioprinted platform for human <i>in vitro</i> biocompatibility testing, predicting the impact of medical devices and their materials on vascular systems, reducing animal experimentation and, ultimately, accelerating time to market.</p>","PeriodicalId":21588,"journal":{"name":"Science and Technology of Advanced Materials","volume":null,"pages":null},"PeriodicalIF":7.4,"publicationDate":"2024-09-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.ncbi.nlm.nih.gov/pmc/articles/PMC11425690/pdf/","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142353127","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
First-principles calculations on dislocations in MgO. 氧化镁中位错的第一性原理计算。
IF 7.4 3区 材料科学
Science and Technology of Advanced Materials Pub Date : 2024-08-19 eCollection Date: 2024-01-01 DOI: 10.1080/14686996.2024.2393567
Shin Kiyohara, Tomohito Tsuru, Yu Kumagai
{"title":"First-principles calculations on dislocations in MgO.","authors":"Shin Kiyohara, Tomohito Tsuru, Yu Kumagai","doi":"10.1080/14686996.2024.2393567","DOIUrl":"10.1080/14686996.2024.2393567","url":null,"abstract":"<p><p>While ceramic materials are widely used in our society, their understanding of the plasticity is not fully understood. MgO is one of the prototypical ceramics, extensively investigated experimentally and theoretically. However, there is still controversy over whether edge or screw dislocations glide more easily. In this study, we directly model the atomic structures of the dislocation cores in MgO based on the first-principles calculations and estimate the Peierls stresses. Our results reveal that the screw dislocation on the primary slip system exhibits a smaller Peierls stress than the edge dislocation. The tendency is not consistent with metals, but rather with TiN, suggesting a characteristic inherent to rock-salt type materials.</p>","PeriodicalId":21588,"journal":{"name":"Science and Technology of Advanced Materials","volume":null,"pages":null},"PeriodicalIF":7.4,"publicationDate":"2024-08-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.ncbi.nlm.nih.gov/pmc/articles/PMC11370692/pdf/","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142126592","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
From cane to nano: advanced nanomaterials derived from sugarcane products with insights into their synthesis and applications. 从甘蔗到纳米:从甘蔗产品中提取的先进纳米材料及其合成和应用见解。
IF 7.4 3区 材料科学
Science and Technology of Advanced Materials Pub Date : 2024-08-19 eCollection Date: 2024-01-01 DOI: 10.1080/14686996.2024.2393568
Bhavya Mod, Arun V Baskar, Rohan Bahadur, Ehsan Tavakkoli, Lukas Van Zwieten, Gurwinder Singh, Ajayan Vinu
{"title":"From cane to nano: advanced nanomaterials derived from sugarcane products with insights into their synthesis and applications.","authors":"Bhavya Mod, Arun V Baskar, Rohan Bahadur, Ehsan Tavakkoli, Lukas Van Zwieten, Gurwinder Singh, Ajayan Vinu","doi":"10.1080/14686996.2024.2393568","DOIUrl":"10.1080/14686996.2024.2393568","url":null,"abstract":"<p><p>Sugarcane-based products are inherently rich in elements such as silicon, carbon and nitrogen. As such, these become ideal precursors for utilization in a wide array of application fields. One of the appealing areas is to transform them into nanomaterials of high interest that can be employed in several prominent applications. Among nanomaterials, sugarcane products based on silica nanoparticles (SNPs), carbon dots (CDs), metal/metal oxide-based NPs, nanocellulose, cellulose nanofibers (CNFs), and nano biochar are becoming increasingly reported. Through manipulation of the experimental conditions and choosing suitable starting precursors and elements, it is possible to devise these nanomaterials with highly desired properties suited for specific applications. The current review presents the findings from the recent literature wherein an effort has been made to convey new development in the field of sugarcane-based products for the synthesis of the above-mentioned nanomaterials. Various nanomaterials were systematically discussed in terms of their synthesis and application perspectives. Wherever possible, a comparative analysis was carried out to highlight the potential of sugarcane products for the intended purpose as compared to other biomass-based materials. This review is expected to stand out in delivering an up-to-date survey of the literature and provide readers with necessary directions for future research.</p>","PeriodicalId":21588,"journal":{"name":"Science and Technology of Advanced Materials","volume":null,"pages":null},"PeriodicalIF":7.4,"publicationDate":"2024-08-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.ncbi.nlm.nih.gov/pmc/articles/PMC11376298/pdf/","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142140962","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
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