Laser ablation process of CsPbBr3 heterostructures for light-emitting diode applications.

We investigated a vacuum thin-film process using laser ablation to fabricate heterostructures of halide perovskite CsPbBr₃ for light-emitting diode (LED) applications. A CsPbBr₃ single crystal synthesized via inverse temperature crystallization was used as the target material for pulsed laser deposition. CsPbBr₃ films were deposited at 150°C, 200°C and 250°C. Structural and optical analysis has revealed that the optimum temperature is 200°C, which display the highest crystallinity and photoluminescence emission efficiency. Time-resolved microwave photoconductivity characterization revealed that the CsPbBr₃ film exhibited a high effective mobility of 2.47 cm²/Vs and long photocarrier lifetime of 16.5 μs. The lifetime is comparable to that of bulk CsPbBr₃ single crystals. This indicates that the polycrystalline CsPbBr₃ film had a low density of defect structures that promote nonradiative recombination. Furthermore, we applied this process to fabricate a LED device using halide perovskite heterostructures. This resulted in a strong green electroluminescence emission. The laser ablation process using ultraviolet and infrared light is suitable for forming heterostructures with an electron transportation layer of oxide Mg_0.3Zn_0.7O film and a hole transportation layer of an organic α-NPD film. The film synthesis process is likely to be effective for evaluating heterointerfaces of various materials displaying remarkable crystallinity without exposure to air.