Rasayan Journal of Chemistry最新文献_第7页

NATURAL WATERS AND INDUSTRIAL WASTEWATER, WASTEWATER WITH PHENOL-CONTAINING COMPOUNDS, METHODS OF WATER PURIFICATION 天然水和工业废水，含酚类化合物废水，水净化方法

Rasayan Journal of Chemistry Pub Date : 2023-01-01 DOI: 10.31788/rjc.2023.1638403

None B.T. Dossumova, None L.R. Sassykova, None T.V. Shakiyeva, None D. Muktaly, None B. Baizhomartov, None F.M. Kanapiyeva, Hideki Kurоkawа

{"title":"NATURAL WATERS AND INDUSTRIAL WASTEWATER, WASTEWATER WITH PHENOL-CONTAINING COMPOUNDS, METHODS OF WATER PURIFICATION","authors":"None B.T. Dossumova, None L.R. Sassykova, None T.V. Shakiyeva, None D. Muktaly, None B. Baizhomartov, None F.M. Kanapiyeva, Hideki Kurоkawа","doi":"10.31788/rjc.2023.1638403","DOIUrl":"https://doi.org/10.31788/rjc.2023.1638403","url":null,"abstract":"Water pollution is one of the main causes of imbalance in the Earth’s ecosystem. Plant effluents have different compositions and concentrations of pollutants, depending on the kind of production and the water supply and sewerage system. The main sources of phenol-containing wastewater are coking plants, coke oven gas plants, semi-coking plants, gas generating stations, wood heat treatment plants, and the synthesis of artificial liquid fuels. They can also be the result of the activities of metallurgical plants, oil refineries, enterprises for the recovery of rubber, and the production of film, phenolphthalein, salicylic acid, and salol. Phenolic waters are dangerous for fishery reservoirs, worsen the organoleptic properties of water, and disrupt the natural processes of water self-purification. Water contaminated with phenolic wastewater contributes to the deterioration of groundwater quality. Thus, high-quality water purification from phenol to reduce/maximum prevent the ingress of phenols into industrial and drinking water is an urgent problem. Methods for deep treatment of phenolic wastewater are regenerative and destructive. The technology for purifying phenolic wastewater using the processes of oxidation of phenolic compounds with atmospheric oxygen on heterogeneous catalysts is one of the most promising technologies. Nanodisperse catalysts used to treat wastewater containing aromatic hydrocarbons and, in particular, phenolic compounds, should provide a high rate of oxidation of phenolic pollutants, efficient oxidation of a wide range of compounds with various functional groups, low cost, and long service life without a noticeable loss of catalytic properties, as well as high mechanical strength and immunity to catalytic poisons. Catalysts based on various metals and metal oxides and carrier-based systems, oxide-based magnetic composites show good efficiency in the oxidation of phenol with oxygen.","PeriodicalId":21063,"journal":{"name":"Rasayan Journal of Chemistry","volume":"71 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2023-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"135595646","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

EFFECT OF ELECTROSTIMULATION TREATMENTS APPLIED TO Manihot esculenta Crantz ASEXUAL SEEDS ON BIOMASS GAIN 电刺激处理对无性种子生物量增益的影响

Rasayan Journal of Chemistry Pub Date : 2023-01-01 DOI: 10.31788/rjc.2023.1638434

Luis M. Escobar, Enrique M. Combatt, Alvaro A. Arrieta

引用次数: 0

AGENTS FROM THE LICHEN SUBSTANCE OF Cladonia crispata (Ach.) Flot. AND THEIR IN-SILICO APPROACHES crisadonia crispata (Ach.)地衣物质中的药剂Flot。以及他们的计算机化方法

Rasayan Journal of Chemistry Pub Date : 2023-01-01 DOI: 10.31788/rjc.2023.1638258

None F. Ismed, None V. F. Sardi, None P. P. Putra, D.P. Putra

引用次数: 0

SYNTHESIS, CHARACTERISATION, AND BIOLOGICAL EVALUATION OF SOME CURCUMIN-BASED 4H-PYRAN DERIVATIVES USING DOPED POLYANILINE AS A NANOCATALYST 以掺杂聚苯胺为纳米催化剂的姜黄素基4h吡喃衍生物的合成、表征和生物学评价

Rasayan Journal of Chemistry Pub Date : 2023-01-01 DOI: 10.31788/rjc.2023.1638411

None S. N. Pawar, D. M. Nagrik

引用次数: 0

THE EFFECT OF COATING IN INCREASING THE EFFICIENCY OF SOLAR CELLS BY USING QUERCETIN POLY AS A DYE 以槲皮素聚为染料，研究涂层对提高太阳能电池效率的影响

Rasayan Journal of Chemistry Pub Date : 2023-01-01 DOI: 10.31788/rjc.2023.1638143

None Hardeli, None F. Hijri, None H. Sanjaya, None Y.P. Putri, None P. Permatasari

{"title":"THE EFFECT OF COATING IN INCREASING THE EFFICIENCY OF SOLAR CELLS BY USING QUERCETIN POLY AS A DYE","authors":"None Hardeli, None F. Hijri, None H. Sanjaya, None Y.P. Putri, None P. Permatasari","doi":"10.31788/rjc.2023.1638143","DOIUrl":"https://doi.org/10.31788/rjc.2023.1638143","url":null,"abstract":"The efficiency obtained by using TiO 2 semiconductors is still low due to interfacial charge recombination. In this research, two coating methods were carried out, namely doping and bilayer using ZnO as a semiconductor to reduce recombination to collect charge and increase the efficiency of Dye-Sensitized Solar Cells. The use of UV-DRS in this study to see the band gap shows a decrease in the band gap after doping and bilayer processes. The XRD used in the study to look at the phase and molecular structure showed that the intensity of TiO 2 was lower due to doping and bilayer. The dye used is Quercetin which is polymerized to increase conjugated bonds. To see the polymerized Quercetin tested using FTIR. In the quercetin crosslinker polymerization process varied to 1.5 ml; 2.5 ml; and 3.5 ml to see how many conjugate bonds are formed so that the efficiency obtained is also high. Efficiency measurement using a multimeter. Based on the results of this study, it was found that the efficiency of solar cells increased. In the doping process, the highest efficiency was 11.3%, while the highest efficiency in the coating process was 9.1%.","PeriodicalId":21063,"journal":{"name":"Rasayan Journal of Chemistry","volume":"14 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2023-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"136256756","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

STUDY OF In-silico ADMET, MOLECULAR DOCKING, AND STABILITY POTENTIAL OF SYNTHESIZED NOVEL TETRAZOLE BEARING CURCUMIN DERIVATIVES AND EVALUATION OF THEIR ANTICANCER POTENTIAL ON PANC-1 CELL LINES 新型含四氮唑姜黄素衍生物的硅合成、分子对接和稳定性研究及其在PANC-1细胞系上的抗癌潜力评价

Rasayan Journal of Chemistry Pub Date : 2023-01-01 DOI: 10.31788/rjc.2023.1618114

G. Krishnamurthy, Lairikyengbam Deepti Roy, J. Kumar, P. Gour, S. Arland, M. Prabu, Srinivasa Gr, Shreenivas Mt

{"title":"STUDY OF In-silico ADMET, MOLECULAR DOCKING, AND STABILITY POTENTIAL OF SYNTHESIZED NOVEL TETRAZOLE BEARING CURCUMIN DERIVATIVES AND EVALUATION OF THEIR ANTICANCER POTENTIAL ON PANC-1 CELL LINES","authors":"G. Krishnamurthy, Lairikyengbam Deepti Roy, J. Kumar, P. Gour, S. Arland, M. Prabu, Srinivasa Gr, Shreenivas Mt","doi":"10.31788/rjc.2023.1618114","DOIUrl":"https://doi.org/10.31788/rjc.2023.1618114","url":null,"abstract":"Amplified expression of mutations in proteins is an important hallmark of malignant cancer. In all RAS-mutant human cancers, pancreatic ductal adenocarcinoma (PDAC) is considered the most RAS-fanatic cancer, with a frequency of 100% KRAS (Kirsten rat sarcoma virus) mutation. In the present work, curcumin, a dietary phytochemical, was used to design a series of novel curcumin analogues aiming to regulate KRAS protein. The molecular docking study revealed the ligand efficacy and binding affinity of designed curcumin analogues against target proteins. Drug-like behaviour and ADMET (absorption, distribution, metabolism, excretion, and toxicity) prediction of identified molecules were done, and most of the pharmacokinetic parameters were found to be quite satisfactory and within an acceptable range. Three of the most potent drug candidates have been synthesized and characterized by FTIR, 1HNMR, and LC-MS spectral analysis. Results of the in vitro anti-proliferative activities of curcumin analogues showed persuasive anticancer activity against the PANC-1 cell lines. The present study will be helpful in exploring the new series of cogent curcumin analogues as anticancer agents.","PeriodicalId":21063,"journal":{"name":"Rasayan Journal of Chemistry","volume":"1 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2023-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"69410467","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 1

COMBINED In-silico AND In-vitro APPROACHES TO EVALUATE THE INHIBITORY THE POTENTIAL OF BIFLAVONOIDS FROM ARAUCARIA PLANTS AGAINST α-GLUCOSIDASE AS TARGET PROTEIN 摘要利用体外和硅相结合的方法，研究了石南芥中生物黄酮类化合物作为靶蛋白对α-葡萄糖苷酶的抑制作用

Rasayan Journal of Chemistry Pub Date : 2023-01-01 DOI: 10.31788/rjc.2023.1618147

P. Sugita, S.D.P. Handayani, D.D. Agusta, L. Ambarsari, H. Dianhar, D. Rahayu

{"title":"COMBINED In-silico AND In-vitro APPROACHES TO EVALUATE THE INHIBITORY THE POTENTIAL OF BIFLAVONOIDS FROM ARAUCARIA PLANTS AGAINST α-GLUCOSIDASE AS TARGET PROTEIN","authors":"P. Sugita, S.D.P. Handayani, D.D. Agusta, L. Ambarsari, H. Dianhar, D. Rahayu","doi":"10.31788/rjc.2023.1618147","DOIUrl":"https://doi.org/10.31788/rjc.2023.1618147","url":null,"abstract":"Biflavonoids are dimers of flavonoids created by a covalent connection of C-C or C-O-C between two flavonoids and have been found to have a variety of pharmacological effects, including the ability to treat diabetes mellitus (DM). In the current investigation, the inhibitory effect of biflavonoids extracted from Araucaria hunsteinii K. Schum towards the target protein α-glucosidase was assessed using a combination of in-vitro experiments and in-silico molecular docking approach. The biflavonoids' inhibition properties were contrasted with those of acarbose, a widely used pharmaceutical for treating type 2 DM. AutoDock Vina was employed to analyze the conformational sites and docking parameters, such as binding affinity and inhibition constant. In-silico studies showed that biflavonoids effectively interacted with the active site of the α-glucosidase enzyme, which is in charge of cleaving not only bonding of the α1,4 but also the α-1,6 glycosidic on the exterior of amylose or amylopectin residues to obtain simple sugars. The docking experiments revealed that biflavonoids had tighter binding forces than acarbose against α-glucosidase. The selected biflavonoids, 7-O-methylcupressuflavone; 7,7\"-di-O-methylagathisflavone, 4′,4′′′-di-O-methylamentoflavone and 4''',7-di-O-methylcupresuflavone showed an IC50 of 78.32±0.52; 388.39±0.68; 389.76±1.55 and 537.98±2,35 µM, respectively. These biflavonoids had a low binding affinity and more hydrogen bond interactions with the target enzyme, which had several important amino acid residues. The effectiveness of these compounds in inhibiting the enzyme may be explained by some of their hydrophobic interactions. Therefore, the study comes to the conclusion that biflavonoids are prospective antidiabetic agents and should be taken into consideration when developing candidates for new antidiabetic medicines.","PeriodicalId":21063,"journal":{"name":"Rasayan Journal of Chemistry","volume":"1 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2023-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"69410998","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

GOLD AND SILVER NANOPARTICLES AS COMPUTED TOMOGRAPHY (CT) CONTRAST AGENTS PRODUCED BY A PULSED LASER ABLATION TECHNIQUE: STUDY In-vitro AND In-vivo 金和银纳米颗粒作为脉冲激光消融技术产生的计算机断层扫描(CT)造影剂:体外和体内研究

Rasayan Journal of Chemistry Pub Date : 2023-01-01 DOI: 10.31788/rjc.2023.1618202

A. Khumaeni, W. Setia Budi, S. Avicenna, M. Muniroh, N. Kusumaningrum, Oktarina Damayanti, Shoimatul Fitria

{"title":"GOLD AND SILVER NANOPARTICLES AS COMPUTED TOMOGRAPHY (CT) CONTRAST AGENTS PRODUCED BY A PULSED LASER ABLATION TECHNIQUE: STUDY In-vitro AND In-vivo","authors":"A. Khumaeni, W. Setia Budi, S. Avicenna, M. Muniroh, N. Kusumaningrum, Oktarina Damayanti, Shoimatul Fitria","doi":"10.31788/rjc.2023.1618202","DOIUrl":"https://doi.org/10.31788/rjc.2023.1618202","url":null,"abstract":"High-purity metal nanoparticles such as gold and silver nanoparticles become an interesting subject for application in the medical field. Using the laser ablation approach, these nanoparticles were successfully synthesized in this present work. Experimentally, a pulse neodymium yttrium aluminum garnet laser (1064 nm, 30 mJ, 10 Hz) was used to irradiate high-purity metals immersed in an iodine liquid medium. Purple, yellow, and dark purple colloidal nanoparticles of Au, Ag, and Au-Ag were successfully synthesized. The results certified that all nanoparticles have a spherical shape; Au nanoparticles had an average diameter of 26 nm and a standard deviation of 4 nm, while Ag nanoparticles had an average diameter of 24 nm and a standard deviation of 5 nm. The diameter distribution of AuAg nanoparticles is extraordinarily vast, ranging from 18 to 80 nm. Colloids of mixed Au-Ag nanoparticles had the highest Hounsfield Units (HU) value in an in vivo test, with a value of 302. This was supported by the results of an in vitro contrast enhancement evaluation, which determined that a mixture of Au-Ag nanoparticles provided the best contrast enhancement compared to other colloids. These results confirmed that the Au-Ag nanoparticles are very suitable as contrast agents in CT.","PeriodicalId":21063,"journal":{"name":"Rasayan Journal of Chemistry","volume":"1 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2023-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"69411160","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 2

A NOVEL APPROACH OF USING BAMBOO ROOT CELLULOSE: AN ALTERNATIVE FOR IRON(II) REMOVAL FROM WASTEWATER 一种利用竹根纤维素的新方法:从废水中去除铁(ii)的替代方法

Rasayan Journal of Chemistry Pub Date : 2023-01-01 DOI: 10.31788/rjc.2023.1628307

M. Wulandari, N. Nofrizal, S. Sulaiman

{"title":"A NOVEL APPROACH OF USING BAMBOO ROOT CELLULOSE: AN ALTERNATIVE FOR IRON(II) REMOVAL FROM WASTEWATER","authors":"M. Wulandari, N. Nofrizal, S. Sulaiman","doi":"10.31788/rjc.2023.1628307","DOIUrl":"https://doi.org/10.31788/rjc.2023.1628307","url":null,"abstract":"A novel approach was taken using the bamboo root transformed into activated cellulose, implying dilute nitric acid as the agent activator. The activated bio-sorbent was applied for Iron(II) (Fe(II)) adsorption in batch mode. Then, biosorbent characterization was established using infrared spectroscopy and a scanning electron microscope (SEM). The effect of acid variation, iodine number, contact time, particle size, temperature, and concentration on the Fe(II) adsorption was determined in the batch method. The Freundlich and Langmuir isotherm were analyzed for determining the isotherm of adsorption. The Langmuir model of adsorption is the most suitable for illustrating Fe(II) adsorption. The optimum adsorption capacity occurred at the bio-sorbent particle size of 50 µm, contact time of 300 minutes, a temperature of 50˚C, a pH of 5, and 150 ppm. The bamboo roots have been applied to remove Fe(II) from wastewater, and the recovery% shows 100%. Comparative studies were analyzed with some bio-sorbents for further development. It is hoped that this novel alternative can be applied as bamboo is abundant in Indonesia and many countries in Asia regions.","PeriodicalId":21063,"journal":{"name":"Rasayan Journal of Chemistry","volume":"1 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2023-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"69411362","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

OPTIMIZATION SYNTHESIS OF ZINC OXIDE NANOPARTICLES USING FACTORIAL DESIGN AND ITS ANTIBACTERIAL ACTIVITY 利用析因设计优化氧化锌纳米颗粒的合成及其抑菌活性

Rasayan Journal of Chemistry Pub Date : 2023-01-01 DOI: 10.31788/rjc.2023.1628213

N.C. Endriyatno, E.R. Wikantyasning, P. Indrayudha

引用次数: 0