Reactive & Functional Polymers最新文献

{"title":"Preparation of TEMPO-modified PEDOT electrode via click reaction and its electrocatalytic properties for HMF oxidation","authors":"Haochen Wang,&nbsp;Xin Liu,&nbsp;Chenyang Ling,&nbsp;Zhenlu Shen,&nbsp;Meichao Li","doi":"10.1016/j.reactfunctpolym.2025.106300","DOIUrl":"10.1016/j.reactfunctpolym.2025.106300","url":null,"abstract":"<div><div>A novel TEMPO-modified poly(3,4-ethylenedioxythiophene) (PEDOT-T-TEMPO) electrode was prepared through click reaction between 4-(propargyloxy)-TEMPO and azide-functionalized poly(3,4-ethylenedioxythiophene). Successful modification of TEMPO on azide-functionalized PEDOT was verified by FTIR, SEM and cyclic voltammetry. PEDOT-T-TEMPO electrode exhibited high electrocatalytic activity for selective oxidation of 5-hydroxymethylfurfural (HMF) to 2,5-diformylfuran (DFF), achieving HMF conversion of 92 % and selectivity towards DFF more than 99 %. In addition, PEDOT-T-TEMPO electrode showed excellent cyclic stability in CH₃CN solution. A plausible reaction mechanism for the conversion of HMF to DFF on PEDOT-T-TEMPO electrode with <em>N</em>-methylimidazole (NMI) as the base has been proposed.</div></div>","PeriodicalId":20916,"journal":{"name":"Reactive & Functional Polymers","volume":"214 ","pages":"Article 106300"},"PeriodicalIF":4.5,"publicationDate":"2025-04-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143837886","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Simultaneous hypercrosslinking and functionalization of porous polystyrene adsorbent for protein-bound uraemic toxins removal","authors":"Lingyu Chen ,&nbsp;Yunhong Liu ,&nbsp;Xinyan Peng ,&nbsp;Yuelan Wei ,&nbsp;Ke Shao","doi":"10.1016/j.reactfunctpolym.2025.106265","DOIUrl":"10.1016/j.reactfunctpolym.2025.106265","url":null,"abstract":"<div><div>Protein-bound uremic toxins (PBUTs) play a crucial role in the progression of uremic complications. Due to the extremely high binding affinity to human serum albumin, PBUTs are poorly removed by traditional hemodialysis methods. As an advanced blood purification technology, hemoperfusion has been proven effective in removing PBUTs, and hyper-crosslinked polystyrene adsorbents have been widely commercialized as hemoperfusion adsorption materials. However, challenges still remain, including the need to enhance the adsorption efficiency of PBUTs and the simplification of the preparation and modification processes of the adsorbents. In this work, we report a one-step external crosslinking modification technique to prepare a functionalized hyper-crosslinked polystyrene adsorbent named HCP-DFDA, in which <em>N</em>,<em>N</em>-dimethylformamide dimethyl acetal (DFDA) with tertiary amine functional groups was used as a small-molecule external crosslinker to simultaneously carry out Friedel–Crafts alkylation crosslinking and functional group grafting modification. Experimental results showed that the prepared hypercrosslinked resin HCP-DFDA had abundant mesoporous/microporous structures and an extremely high specific surface area of up to 1030 m²/g. Adsorption experiments demonstrated that HCP-DFDA exhibited excellent adsorption performance for both uremic PBUTs like indoxyl sulfate (IS) and p-cresyl sulfate (PCS) and medium- to large-molecular-weight toxins such as β2-microglobulin (β2-MG) and interleukin-6 (IL-6). Moreover, similar to the commercial HA130 resin, HCP-DFDA exhibited low protein adsorption and hemolysis rates, demonstrating good blood compatibility. In summary, the facile preparation method of the modified hypercrosslinked adsorbent proposed in this study provides a new idea and solution for the efficient removal of PBUTs through whole-blood hemoperfusion in clinical applications.</div></div>","PeriodicalId":20916,"journal":{"name":"Reactive & Functional Polymers","volume":"214 ","pages":"Article 106265"},"PeriodicalIF":4.5,"publicationDate":"2025-04-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143816815","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Progress in high temperature resistant phthalonitrile resins and their composites for aerospace applications","authors":"Bing Han ,&nbsp;Yong Li ,&nbsp;Jing Wan ,&nbsp;Weiye Hu ,&nbsp;Qiyi Chu ,&nbsp;You Shi ,&nbsp;Lechen Yang ,&nbsp;Zehui Hu","doi":"10.1016/j.reactfunctpolym.2025.106293","DOIUrl":"10.1016/j.reactfunctpolym.2025.106293","url":null,"abstract":"<div><div>As a novel high-temperature-resistant thermosetting resin, phthalonitrile has garnered increasing attention in the aerospace field, which combines the excellent heat resistance and mechanical properties of polyimide resin, the machinability and low water absorption of cyanate ester resin, and the fire resistance of phenolic resin. Fiber-reinforced phthalonitrile resin matrix composites are lightweight and exhibit high-temperature resistance, making them highly potential for applications in missile bodies, fairings, satellite bearing structures, solid rocket engines and so on. However, the resin's brittleness, high melting point, and narrow processing window hinder the molding of its composites, potentially leading to internal defects then reduced quality and performance of the molded composites. Thus, a series of studies have been conducted on the synthesis, modification of phthalonitrile resin, and the molding processes of its composite materials, including monomer design, curing mechanism, toughening modification, and molding technologies. This paper primarily analyzes the existing issues and proposes future development directions, with the aim of promoting the application of phthalonitrile-based composite materials in aerospace high-temperature resistant structural components.</div></div>","PeriodicalId":20916,"journal":{"name":"Reactive & Functional Polymers","volume":"214 ","pages":"Article 106293"},"PeriodicalIF":4.5,"publicationDate":"2025-04-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143808098","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Synthesis of double-ended hydroxyl-terminated poly(cyclohexyl ethylene) via catalytic hydrogenation of double-ended hydroxyl terminated polystyrene","authors":"Alaaddin M.M. Saeed ,&nbsp;Gui-Ping Cao ,&nbsp;Mustapha Sani Shehu ,&nbsp;Ahmed S. Al-Fatesh ,&nbsp;Salwa B. Alreshaidan ,&nbsp;Hui Lv ,&nbsp;Xiao-Tian Han ,&nbsp;Jun-Yang Yan","doi":"10.1016/j.reactfunctpolym.2025.106294","DOIUrl":"10.1016/j.reactfunctpolym.2025.106294","url":null,"abstract":"<div><div>This study synthesized a novel double-ended hydroxyl-terminated poly(cyclohexyl ethylene) (HO-PCHE-OH), and investigated the individual and interactive effects of reaction temperature, time, and stirring speed on the synthesis of double-ended hydroxyl terminated polystyrene (HO-PS-OH) via the anionic polymerization of styrene, employing sodium-naphthalene as the initiator. A central composite design (CCD) combined with response surface methodology (RSM) was utilized for experimental design, process modelling, and optimization. The optimal reaction conditions were determined to be a temperature of 17.9 °C, a reaction time of 46.7 min, and a stirring speed of 189.1 rpm, yielding a styrene conversion of 91.1 %. The synthesized HO-PS-OH was subsequently subjected to catalytic hydrogenation to enhance its properties, achieving complete hydrogenation within 4 h at 170 °C. The successful transformation of HO-PS-OH into double-ended hydroxyl-terminated poly(cyclohexyl ethylene) (HO-PCHE-OH) was confirmed through nuclear magnetic resonance (¹H NMR and ¹³C NMR) spectroscopy and Fourier transform infrared (FTIR) analysis. Therefore, the complete saturation of the 6-member carbon ring in HO-PCHE-OH was chemically and photochemically inert. Furthermore, the thermogravimetric analysis revealed that HO-PS-OH exhibited thermal resistance, with a degradation onset temperature of 420.85 °C, while HO-PCHE-OH demonstrated a higher degradation onset temperature of 431.55 °C.</div></div>","PeriodicalId":20916,"journal":{"name":"Reactive & Functional Polymers","volume":"214 ","pages":"Article 106294"},"PeriodicalIF":4.5,"publicationDate":"2025-04-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143816814","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Swollen-induced facile in situ preparation of silver nanoparticles incorporated into UV-curable silicone rubber for durable antimicrobial activity","authors":"Guanwu Yin ,&nbsp;Quanbo Xu ,&nbsp;Xiaoyue Yang ,&nbsp;Xiaofan Chen ,&nbsp;Jiangbo Gao ,&nbsp;Haiyan Wang","doi":"10.1016/j.reactfunctpolym.2025.106295","DOIUrl":"10.1016/j.reactfunctpolym.2025.106295","url":null,"abstract":"<div><div>Silicone rubber plays a significant role in medical applications. However, its poor antibacterial characteristics often lead to related infections. Moreover, the presence of heavy metal residues in silicone rubber from conventional fabrication processes limits its application in medical devices. In this study, we developed a novel and straightforward approach for the preparation of UV-curable silicone rubber composites (PDMS@AgNPs) with durable antibacterial properties through a rapid and facile swollen-induced <em>in situ</em> reduction method without any heavy metal catalysts. The UV-curable silicone rubbers (PDMS-SH) were prepared using poly[(mercaptopropyl)methylsiloxane] (PMMS) and vinyl silicone, where the excessive thiol groups in PMMS not only facilitate a uniform cross-link network formation but also act as a reducing agent for silver nanoparticles (AgNPs). The mechanical properties, including hardness and swelling ratio, were found to be influenced by the molar ratio of sulfhydryl to vinyl groups. Remarkably, PDMS@AgNPs exhibited excellent antibacterial activity against <em>S. aureus</em> and <em>E. coli</em>, maintaining high efficacy even after 5 days of immersion, attributed to the stable incorporation of AgNPs within the cross-linked matrix. Furthermore, the composites exhibited low hemolysis rates and minimal cytotoxicity, indicating their potential as biocompatible materials for medical applications.</div></div>","PeriodicalId":20916,"journal":{"name":"Reactive & Functional Polymers","volume":"214 ","pages":"Article 106295"},"PeriodicalIF":4.5,"publicationDate":"2025-04-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143791231","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Hydrophilic magnetic molecularly imprinted polymers based on chitosan for the selective removal and rapid detection of ibuprofen in environment","authors":"Fan Lu ,&nbsp;Hongbo Mo ,&nbsp;Yu Wan ,&nbsp;Biying Tian ,&nbsp;Chuan Wang ,&nbsp;Ting Qiao ,&nbsp;Weigang Fan ,&nbsp;Yuepeng Fan ,&nbsp;Li Ran ,&nbsp;Yuhu Zhang","doi":"10.1016/j.reactfunctpolym.2025.106292","DOIUrl":"10.1016/j.reactfunctpolym.2025.106292","url":null,"abstract":"<div><div>In order to improve the toxicity of traditional molecularly imprinted polymers and their limited application in water environment, chitosan was introduced as a green functional monomer into molecular imprinting technology. Chitosan-based hydrophilic magnetic molecularly imprinted polymers (CS-MMIPs) were prepared on the surface of Fe₃O₄-COOH for selective removal of IBP in water environment. The adsorption of IBP by CS-MMIPs followed the quasi-second-order kinetic model and the Freundlich isotherm model, with the maximum adsorption capacity of 123.17 mg·g⁻¹ for IBP and an imprinting factor of 2.17. Characterization, data fitting, and parametric analysis revealed that hydrogen bonding, lewis acid-base interactions and electrostatic interactions were the primary forces between CS-MMIPs and IBP. Furthermore, CS-MMIPs were successfully used as magnetic solid-phase extraction (MSPE) sorbents in combination with high-performance liquid chromatography (HPLC) for the detection of IBP. Under optimized MSPE conditions, a rapid and economical method for detecting IBP in aqueous environments was established, with the extraction process required only 3.5 min and recovery rates ranging from 89.46 to 106.12 %, relative standard deviations (RSD) of 1.2 % to 4.2 %, and limit of detection (LOD) of 0.08 μg·mL⁻¹. Therefore, CS-MMIPs demonstrate considerable potential and utility for the removal and detection of IBP.</div></div>","PeriodicalId":20916,"journal":{"name":"Reactive & Functional Polymers","volume":"214 ","pages":"Article 106292"},"PeriodicalIF":4.5,"publicationDate":"2025-04-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143791232","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Biporous polycaprolactone-like networks from 2-methylene-1,3-dioxepane: A versatile platform towards functional and reactive polyesters","authors":"B. Barber Nunez ,&nbsp;B. Carbonnier ,&nbsp;D. Grande ,&nbsp;B. Le Droumaguet","doi":"10.1016/j.reactfunctpolym.2025.106284","DOIUrl":"10.1016/j.reactfunctpolym.2025.106284","url":null,"abstract":"<div><div>In this study, we report on the preparation of doubly porous “polycaprolactone-like” networks using a unique combination of 2-methylene-1,3-dioxepane, divinyl adipate, and either 2-chloroethyl vinyl ether or azidoethyl vinyl ether, allowing for the generation of functionalizable polyesters. Such reactive networks were synthesized via a free-radical ring-opening polymerization mechanism, employing a double porogen templating approach to generate a bimodal porosity. This resulted in macropores of around 200 μm generated after removal of a sieved and sintered NaCl template and smaller pores between 1 and 10 μm obtained through a phase separation process during the free-radical copolymerization of comonomers in the presence of a porogenic solvent. The incorporation of functional monomeric units into the copolymer backbone was evidenced by ATR-FTIR, while the concentration of reactive groups was controlled by finely adjusting the proportion of functional monomers in the copolymerization feed, as verified by EDX spectroscopy and elemental analysis. To demonstrate the versatility and potential applications of these functional degradable networks, a series of post-polymerization modifications was conducted. On the one hand, the pore surface associated with networks containing chloro pending groups was modified through nucleophilic substitution with different amino-compounds. On the other hand, for networks displaying azido groups at the pore surface, the Huisgen copper-catalyzed azide-alkyne cycloaddition modification was implemented for grafting a model fluorescent alkyne-modified compound. A comprehensive set of characterization techniques confirmed the successful completion of these post-polymerization modifications. These functionalized materials offer promising possibilities for applications in diverse fields, thanks to their tunable structure and physico-chemical properties, such as in biomedicine and notably for tissue engineering.</div></div>","PeriodicalId":20916,"journal":{"name":"Reactive & Functional Polymers","volume":"214 ","pages":"Article 106284"},"PeriodicalIF":4.5,"publicationDate":"2025-04-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143791130","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"A cell-free composite hydrogel scaffold promotes in situ cartilage regeneration via adjusted stiffness","authors":"Hao Liu ,&nbsp;Bo Wu ,&nbsp;Qing-Yuan Zheng ,&nbsp;Yun-Chang Wu ,&nbsp;Guo-Qiang Zhang ,&nbsp;Xue-Song Zhang","doi":"10.1016/j.reactfunctpolym.2025.106288","DOIUrl":"10.1016/j.reactfunctpolym.2025.106288","url":null,"abstract":"<div><div>The repair of articular cartilage injuries is challenging due to their limited regenerative ability. Cell-based tissue engineering strategies are effective for cartilage repair. However, they are primarily in the preclinical stage and face challenges such as lengthy in vitro culture times, high costs, and regulatory restrictions. Cell-free scaffolds can recruit endogenous cells to the defect site to achieve in situ cartilage repair, and avoiding many complications related to cell use, and have therefore received increasing attention. In this study, we blended gellan gum (GG) and hyaluronic acid (HA) in a specific proportion to form an interpenetrating network, and then added cations (Ca²⁺) for physical crosslinking to prepare a composite hydrogel with good biophysical and chemical properties. The stiffness of the hydrogel can be adjusted by changing concentrations of Ca²⁺. In vitro experiments, we evaluated the effect of hydrogels with different matrix stiffness on promoting the proliferation, migration and chondrogenic differentiation of bone marrow mesenchymal stem cells. In vivo experiments revealed that the hydrogel group achieved cartilage repair effect comparable to that of the group loaded with mesenchymal stem cells 12 weeks after surgery, without adding exogenous cells and growth factors. The composite hydrogel is an ideal cell-free scaffold material with good cartilage repair effect. Moreover, it is suitable for injection, easily translatable into clinical practice, and shows great potential for applications.</div></div>","PeriodicalId":20916,"journal":{"name":"Reactive & Functional Polymers","volume":"214 ","pages":"Article 106288"},"PeriodicalIF":4.5,"publicationDate":"2025-04-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143816817","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Reaction mechanism of graft copolymerization in bulk-polymerized ABS resins and its effect on mechanical and combustion properties","authors":"Yuhang Lin ,&nbsp;Shengjie Li ,&nbsp;Lei Du ,&nbsp;Wenhao Dong ,&nbsp;Xilei Chen ,&nbsp;Ben Wang","doi":"10.1016/j.reactfunctpolym.2025.106289","DOIUrl":"10.1016/j.reactfunctpolym.2025.106289","url":null,"abstract":"<div><div>Graft copolymerization in bulk-polymerized Acrylonitrile–Butadiene–Styrene (ABS) resins significantly affects both the polymerization processes and the combustion properties of ABS resins, but the reaction mechanism underlying the bulk polymerization of ABS resins remains unclear. Here, the graft copolymerization occurring during the synthesis of ABS resins via bulk polymerization was characterized using Attenuated Total Reflection-Fourier Transform Infrared Spectroscopy (ATR-FTIR). It was found that the interaction between the amidine produced by the intermediate poly(conjugated) structure (-C=N-)n and the mobile α-H atoms of the acrylonitrile moiety generated the β-diketone structure, which induced a bridging reaction and enhanced cross-linking and grafting density of bulk-polymerized ABS. Additionally, the effect of the initiation system on the grafting rate and β-diketone structure of ABS resin was investigated. The results confirm that modifying the structure of β-diketone through the initiation system, the distribution of the rubber phase and the grafting density can be improved, thereby enhancing the mechanical, thermal stability and combustion performance of ABS. Thermogravimetric analysis indicated that the char yield of ABS with β-diketone structure and high grafting rate increased by 1.42 folds compared with that of ABS with low grafting rate. Combustion tests demonstrated that that the peak heat release rate (PHRR), peak smoke production rate (PSPR) with high grafting degree were reduced by 18.43 %, 14.50 %, 10.72 %, and 17.01 % in comparison to those of ABS with low grafting rate, respectively. This work provides a new angle for improving the fire safety performance of bulk-polymerized ABS resins, holding a promising industrial application.</div></div>","PeriodicalId":20916,"journal":{"name":"Reactive & Functional Polymers","volume":"214 ","pages":"Article 106289"},"PeriodicalIF":4.5,"publicationDate":"2025-04-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143848539","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Preparation and performance evaluation of multi-template thermo-responsive imprinted polymers for simultaneous and proportional adsorption-desorption of Ga3+, In3+, and SeO32−","authors":"Jinhan Zhang ,&nbsp;Caixia Yuan ,&nbsp;Bingqian Wang ,&nbsp;Yuan Sun ,&nbsp;Yongsheng Xiang ,&nbsp;Lihua Wu ,&nbsp;Yanjun Cui ,&nbsp;Zhenbin Chen","doi":"10.1016/j.reactfunctpolym.2025.106291","DOIUrl":"10.1016/j.reactfunctpolym.2025.106291","url":null,"abstract":"<div><div>The recovery of valuable elements from spent copper–indium–gallium–diselenide solar cells has been a topic of considerable interest. In this study, based on the elemental ratios in the leachate of spent solar cells, a multi-template thermos-responsive imprinted polymer (GIS-TIIP) was prepared by combining thermo-responsive technology and imprinted technology. This polymer was used for the simultaneous and proportional selective separation and purification of gallium, indium, and selenium from the leachate. The structure and performance of GIS-TIIP were systematically characterized through Fourier Transform Infrared Spectroscopy, Scanning Electron Microscopy-Energy Dispersive Spectrometry, Transmission Electron Microscopy, Brunauer-Emmett-Teller surface area and pore size analysis, Thermogravimetric Analysis, X-ray Photoelectron Spectroscopy, and Inductively Coupled Plasma-Atomic Emission Spectroscopy. The structure of GIS-TIIP responded to temperature changes. At 35 °C, maximum adsorption capacities were 0.0162 mmol/g for Ga³⁺, 0.0671 mmol/g for In³⁺, and 0.1001 mmol/g for SeO₃²⁻. At 25 °C, maximum desorption ratios were 72.65 % for Ga³⁺, 75.33 % for In³⁺, and 69.34 % for SeO₃²⁻. The ratio of maximum adsorption capacities for the three target ions (1: 4.142: 6.179) was close to the ratio of the molar amounts of template substances added during the synthesis (1:4:8). The adsorption process of GIS-TIIP fitted better with the pseudo-first-order kinetic model and the Langmuir model. When GIS-TIIP was applied to the diluted leaching solution, the purity of the target elements increased from 55.99 % to 80.98 % after a single adsorption/desorption cycle. The ratio of gallium, indium, and selenium was found to be 1: 4.263: 5.509, indicating the potential for alloy recovery and recycling. After 10 cycles of repeated use, GIS-TIIP still retained 75.71 % of its original adsorption capacity.</div></div>","PeriodicalId":20916,"journal":{"name":"Reactive & Functional Polymers","volume":"214 ","pages":"Article 106291"},"PeriodicalIF":4.5,"publicationDate":"2025-04-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143816816","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}