Reactive & Functional Polymers最新文献

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Schiff base crosslinked soy protein/dialdehyde cellulose/jasmine residue extract films: Antioxidant, UV-shielding for fruit preservation 希夫碱交联大豆蛋白/双醛纤维素/茉莉渣提取物薄膜:抗氧化、防紫外线水果保鲜
IF 5.1 3区 工程技术
Reactive & Functional Polymers Pub Date : 2025-10-06 DOI: 10.1016/j.reactfunctpolym.2025.106504
Quanling Zhao , Lijun Qian , Jianshuo Miao , Ningjing Sun , Qiong Jiang , Lin Wen , Qing Lin , Shuduan Deng , Zhiyong Qin
{"title":"Schiff base crosslinked soy protein/dialdehyde cellulose/jasmine residue extract films: Antioxidant, UV-shielding for fruit preservation","authors":"Quanling Zhao ,&nbsp;Lijun Qian ,&nbsp;Jianshuo Miao ,&nbsp;Ningjing Sun ,&nbsp;Qiong Jiang ,&nbsp;Lin Wen ,&nbsp;Qing Lin ,&nbsp;Shuduan Deng ,&nbsp;Zhiyong Qin","doi":"10.1016/j.reactfunctpolym.2025.106504","DOIUrl":"10.1016/j.reactfunctpolym.2025.106504","url":null,"abstract":"<div><div>To address the limitations of petroleum-based plastic films and meet the growing demand for sustainable food packaging, a new biodegradable composite film was developed using soy protein isolate (SPI) as the matrix. The amino groups in SPI and the active aldehyde groups in water-soluble dialdehyde cellulose (S-DCF), extracted and modified from mulberry branches, were utilized to construct a three-dimensional network structure through a dynamic Schiff base reaction (-CH=N-). This cross-linking effect reduced the slippage of the protein molecular chain and improved the orderliness of the chain segments, increasing the tensile strength of the film by 154 %. Meanwhile, the polar groups introduced by aldehyde oxidation enhanced interfacial compatibility through hydrogen bonds, synergistically optimizing the water vapor barrier properties and forming a dual enhancement mechanism of “chemical cross-linking-physical entanglement.” Additionally, the flavonoids (JFE) extracted from jasmine residues synergistically achieved the dual functions of free radical scavenging (scavenging rate of 82 %) and UV shielding (transmittance in the 200–400 nm band &lt;1 %) through the phenolic hydroxyl hydrogen donation-conjugated aromatic ring structure. Furthermore, the composite film demonstrated excellent biodegradability in soil and effectively delayed the water loss and decay of fruits such as persimmons and blueberries, realizing a positive “packaging-environment” cycle and confirming its potential as an active and sustainable packaging material.</div></div>","PeriodicalId":20916,"journal":{"name":"Reactive & Functional Polymers","volume":"217 ","pages":"Article 106504"},"PeriodicalIF":5.1,"publicationDate":"2025-10-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145266082","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Self-healing and anti-freezing hydrogels based on the nanocomposite reinforcement strategy of cellulose nanocrystals and their applications in flexible sensors 基于纤维素纳米晶纳米复合增强策略的自愈抗冻水凝胶及其在柔性传感器中的应用
IF 5.1 3区 工程技术
Reactive & Functional Polymers Pub Date : 2025-10-06 DOI: 10.1016/j.reactfunctpolym.2025.106508
Xinhang Yu , Yu Sheng , Xinyue Zhang , Yijing Li , Wenxiang Wang , Kai Wei , Liangjiu Bai , Lixia Yang , Hou Chen
{"title":"Self-healing and anti-freezing hydrogels based on the nanocomposite reinforcement strategy of cellulose nanocrystals and their applications in flexible sensors","authors":"Xinhang Yu ,&nbsp;Yu Sheng ,&nbsp;Xinyue Zhang ,&nbsp;Yijing Li ,&nbsp;Wenxiang Wang ,&nbsp;Kai Wei ,&nbsp;Liangjiu Bai ,&nbsp;Lixia Yang ,&nbsp;Hou Chen","doi":"10.1016/j.reactfunctpolym.2025.106508","DOIUrl":"10.1016/j.reactfunctpolym.2025.106508","url":null,"abstract":"<div><div>In recent years, hydrogel-based flexible sensors have shown great potential in human motion tracking and biomedicine, but face challenges in mechanical strength, self-healing, and anti-freezing. This study presents a nanocomposite reinforcement strategy using phytic acid (PA), cellulose nanocrystals (CNCs), and polydopamine (PDA). A multifunctional nanofiller (CNCs@PDA@PA) was created through multi-level design. The resulting hydrogel has excellent properties: a tensile strength of 1.26 MPa and a self-healing efficiency of 71.9 %. It performs well at −30.0 °C, showing good frost resistance. The hydrogel-based sensor is highly sensitive (GF = 2.03), responds quickly (271.0 ms), and has stable cycling. It can detect various human movements, from large-scale actions to subtle ones. This work offers a new approach for designing hydrogel sensors in extreme conditions, with promising applications in wearable electronics and smart healthcare.</div></div>","PeriodicalId":20916,"journal":{"name":"Reactive & Functional Polymers","volume":"217 ","pages":"Article 106508"},"PeriodicalIF":5.1,"publicationDate":"2025-10-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145266154","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
A trilayered composite membrane with a pore-tunable interlayer for liquid management in wound dressing applications 一种具有孔可调中间层的三层复合膜,用于伤口敷料应用中的液体管理
IF 5.1 3区 工程技术
Reactive & Functional Polymers Pub Date : 2025-10-06 DOI: 10.1016/j.reactfunctpolym.2025.106507
Yujie Gao , Lei Liu , Zhiye Qiu, Haotian Ren, Dongming Qi, Jindan Wu
{"title":"A trilayered composite membrane with a pore-tunable interlayer for liquid management in wound dressing applications","authors":"Yujie Gao ,&nbsp;Lei Liu ,&nbsp;Zhiye Qiu,&nbsp;Haotian Ren,&nbsp;Dongming Qi,&nbsp;Jindan Wu","doi":"10.1016/j.reactfunctpolym.2025.106507","DOIUrl":"10.1016/j.reactfunctpolym.2025.106507","url":null,"abstract":"<div><div>Effective wound dressings must simultaneously drain excess exudate and maintain a moist microenvironment; however, facile fabrication of dressings enabling such bidirectional fluid management remains challenging. Herein, we report a structurally robust trilayered composite membrane engineered via sequential electrospinning and hot-pressing, featuring a pore-tunable interlayer for precise liquid manipulation. The hierarchical architecture comprises a hydrophilic cotton layer, an electrospun polyurethane (PU) adhesive interlayer, and a hydrophobic PU/ethylcellulose (EP) layer, where the interlayer serves as the critical regulator of liquid behavior. By tuning the porosity to range from 36.3 % to less than 1 % through controlling the electrospinning duration of the PU adhesive layer (30–90 min) and hot-pressing temperature (60–80 °C), we achieved synergistic bidirectional fluid control: efficient exudate drainage performance coupled with controllable backflow propensity. Specifically, the water droplets penetrated from the hydrophobic to the hydrophilic side within 7 s, and additionally, larger porosity correlated with enhanced backflow, thereby achieving balanced moisture retention. Systematic <em>in vitro</em> investigations revealed correlations between fabrication parameters and the membrane's morphological, wettability, air permeability (73.0 to 3.3 mm/s), and liquid management properties. Moreover, the trilayered composite membrane possessed great cytocompatibility (approximately 99 %) and maintained skin humidity above 44 %. This work presents a straightforward strategy for designing functional polymer composites with tunable bidirectional fluid transport, highlighting the trilayered membrane's promising application potential in advanced wound care based on <em>in vitro</em> evaluations.</div></div>","PeriodicalId":20916,"journal":{"name":"Reactive & Functional Polymers","volume":"217 ","pages":"Article 106507"},"PeriodicalIF":5.1,"publicationDate":"2025-10-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145266153","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
A gas-phase/condensed-phase synergistic flame retardant strategy towards high-efficiency fire safety of epoxy composites 面向环氧复合材料高效防火安全的气相/凝聚相协同阻燃策略
IF 5.1 3区 工程技术
Reactive & Functional Polymers Pub Date : 2025-10-06 DOI: 10.1016/j.reactfunctpolym.2025.106510
Hui Ge , Jingjing Gao , Jie Wang , Zongmin Zhu
{"title":"A gas-phase/condensed-phase synergistic flame retardant strategy towards high-efficiency fire safety of epoxy composites","authors":"Hui Ge ,&nbsp;Jingjing Gao ,&nbsp;Jie Wang ,&nbsp;Zongmin Zhu","doi":"10.1016/j.reactfunctpolym.2025.106510","DOIUrl":"10.1016/j.reactfunctpolym.2025.106510","url":null,"abstract":"<div><div>In this study, phosphorus-containing flame retardant (PDA) was synthesized from 9,10-dihydro-9-oxa-10-phosphaphenanthrene-10-oxide (DOPO) and protocatechualdehyde through simple chemical reactions, and subsequently employed as additive for the flame-retardant modification of epoxy resin (EP). The experimental results show that when the addition amount of PDA is 5 wt%, the peak heat release rate (pHRR) and total smoke emission (TSP) of the composite are significantly reduced by 50.9 % and 33.7 % respectively compared with pure EP, and it has successfully passed the UL94 <em>V</em>-0 rating. This excellent flame-retardant performance primarily stems from the synergistic interaction between the DOPO and protocatechualdehyde structural units in the PDA molecular architecture. The mechanism operates through a dual-action approach: radical scavenging to inhibit combustion chain reactions, and catalyzing the formation of a robust char layer that effectively impedes heat and oxygen transfer.</div></div>","PeriodicalId":20916,"journal":{"name":"Reactive & Functional Polymers","volume":"217 ","pages":"Article 106510"},"PeriodicalIF":5.1,"publicationDate":"2025-10-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145266076","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Phytol and metal oxide-loaded electrospun polyvinylidene fluoride nanofibers for infection control and regenerative wound healing 负载叶绿醇和金属氧化物的静电纺聚偏氟乙烯纳米纤维用于感染控制和再生伤口愈合
IF 5.1 3区 工程技术
Reactive & Functional Polymers Pub Date : 2025-10-06 DOI: 10.1016/j.reactfunctpolym.2025.106506
Shibasini Murugan , Arjun Velusamy , Girija Srinivasan , Gopalakrishnan Manigandan , Karuppuchamy Subbian , Wilson Jeyaraj , Kavitha Thangavel
{"title":"Phytol and metal oxide-loaded electrospun polyvinylidene fluoride nanofibers for infection control and regenerative wound healing","authors":"Shibasini Murugan ,&nbsp;Arjun Velusamy ,&nbsp;Girija Srinivasan ,&nbsp;Gopalakrishnan Manigandan ,&nbsp;Karuppuchamy Subbian ,&nbsp;Wilson Jeyaraj ,&nbsp;Kavitha Thangavel","doi":"10.1016/j.reactfunctpolym.2025.106506","DOIUrl":"10.1016/j.reactfunctpolym.2025.106506","url":null,"abstract":"<div><div>Bacterial infections of the integumentary system remain a major health concern, with carbapenem-resistant pathogens creating critical challenges in wound management. Conventional therapies often fail to combine infection control with tissue regeneration, emphasizing the need for advanced multifunctional dressings. In this study, we developed electrospun nanofibers were fabricated using polyvinylidene difluoride as polymer substrate loaded with phytol as a natural bioactive compound, and a combination of silver oxide and zinc oxide nanoparticles as nanofiller ingredients. This novel composition was designed to combat drug resistant infection and promoting wound healing. The nanofibers were characterized by Fourier-transform infrared spectroscopy, X-ray diffraction, scanning electron microscopy, energy-dispersive X-ray spectroscopy, thermogravimetric analysis, and differential scanning calorimetry techniques. Physicochemical analyses confirmed uniform distribution of active components and favourable properties including swelling, flexibility, porosity, drug release properties and controlled degradation. <em>In vitro</em> biological studies revealed strong antibacterial activity, excellent hemocompatibility, and non-cytotoxicity toward HaCaT cells. Importantly, the nanofibers exhibited angiogenic potential in the chorioallantoic membrane assay and enhanced cell adhesion, migration, and proliferation in wound scratch experiments. Overall, the integration of phytol with metal oxide nanofillers in a PVDF matrix represents a novel approach to designing next-generation wound dressings. The developed electrospun nanofibers showed significant potential for accelerating tissue regeneration while addressing the urgent clinical need to control multidrug-resistant infections.</div></div>","PeriodicalId":20916,"journal":{"name":"Reactive & Functional Polymers","volume":"217 ","pages":"Article 106506"},"PeriodicalIF":5.1,"publicationDate":"2025-10-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145266077","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Development and application of recombinant collagen in dermatology 重组胶原蛋白在皮肤病学中的发展与应用
IF 5.1 3区 工程技术
Reactive & Functional Polymers Pub Date : 2025-10-02 DOI: 10.1016/j.reactfunctpolym.2025.106495
Le Li , Wan Liu , Xiaofei Xie , Huan Lei
{"title":"Development and application of recombinant collagen in dermatology","authors":"Le Li ,&nbsp;Wan Liu ,&nbsp;Xiaofei Xie ,&nbsp;Huan Lei","doi":"10.1016/j.reactfunctpolym.2025.106495","DOIUrl":"10.1016/j.reactfunctpolym.2025.106495","url":null,"abstract":"<div><div>Various skin diseases have become increasingly common in people's daily lives due to adverse environmental factors, unhealthy lifestyle habits, and the influence of diseases, such as dermatitis, acne, scars, skin photoaging, and various skin injuries, which have a serious impact on people's physical and mental health. Recombinant collagen is a recombinant protein synthesized by transferring human collagen gene into expression host, such as plant, animal or microorganism, and successfully expressing it. Compared with traditional animal derived collagen, it has advantages such as good moisturizing properties, low immunogenicity, biocompatibility, anti-inflammatory properties, antioxidant properties, promotion of cell proliferation and collagen expression, and has shown broad application prospects in the field of dermatology. However, there are several inadequacies in the current technology that limit the application of recombinant collagen in dermatology: (1) whether the purity and impurities of recombinant collagen meet medical standards; (2) further research is needed on the effectiveness and safety of recombinant collagen in medicine. Therefore, we reviewed the preparation, basic properties, applications, and prospects of recombinant collagen in the field of dermatology, providing insights for its wider application in dermatology and clinical treatment.</div></div>","PeriodicalId":20916,"journal":{"name":"Reactive & Functional Polymers","volume":"217 ","pages":"Article 106495"},"PeriodicalIF":5.1,"publicationDate":"2025-10-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145266079","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Advancement of thermal stability and flame retardancy of polyvinyl alcohol films for heat management featured with recyclability 聚乙烯醇热管理膜的热稳定性和阻燃性研究进展
IF 5.1 3区 工程技术
Reactive & Functional Polymers Pub Date : 2025-09-30 DOI: 10.1016/j.reactfunctpolym.2025.106496
Kshama D. Lokhande, Kartiki Bhosale, Madhuri A. Bhakare, Mahesh P. Bondarde, Pratik S. Dhumal, Surajit Some
{"title":"Advancement of thermal stability and flame retardancy of polyvinyl alcohol films for heat management featured with recyclability","authors":"Kshama D. Lokhande,&nbsp;Kartiki Bhosale,&nbsp;Madhuri A. Bhakare,&nbsp;Mahesh P. Bondarde,&nbsp;Pratik S. Dhumal,&nbsp;Surajit Some","doi":"10.1016/j.reactfunctpolym.2025.106496","DOIUrl":"10.1016/j.reactfunctpolym.2025.106496","url":null,"abstract":"<div><div>The incorporation of graphene in polymer matrices have become the topic of interest in the field of developing bioplastics. Dispersion and interfacial interaction of graphene with polymers are two indispensable factors in empowering the mechanical properties of polymers. Polyvinyl alcohol (PVA) excellent film-forming, emulsifying, and adhesive properties, which makes it a versatile candidate in various fields. However, the high flammability of PVA limited its applications in fields where flame retardancy is crucial. In this article, the combustibility of PVA has been successfully reduced by inclusion of graphene and phosphorus (PVA/G/APP) with enhanced mechanical properties. The film of PVA/G/APP has been prepared using the solution casting method, with ammonium polyphosphate serving as the phosphorus source. The obtained film shows massive flame retardancy and good mechanical strength. Moreover, flame retardancy has been achieved by limiting the oxygen index (LOI) to 41 % of LOI value, and no dripping of the polymer matrices was observed during the UL-94 test with a V-0 rating. The flame retardancy and durability of these composite films can make them ideal for use in electronic device enclosures, construction materials, and the automotive industry, where heat management and fire resistance are critical.</div></div>","PeriodicalId":20916,"journal":{"name":"Reactive & Functional Polymers","volume":"217 ","pages":"Article 106496"},"PeriodicalIF":5.1,"publicationDate":"2025-09-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145266081","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
ZnO nanoparticle-reinforced lignin-phenol-formaldehyde foam: Formulation, optimization and properties ZnO纳米颗粒增强木质素-酚醛泡沫:配方、优化及性能研究
IF 5.1 3区 工程技术
Reactive & Functional Polymers Pub Date : 2025-09-29 DOI: 10.1016/j.reactfunctpolym.2025.106500
P.R. Sarika, Hessa Rashid Bhughanim AlSuwaidi, Roudha Saeed Alhelli Alhajeri, Sara Ahmed Alhammadi, Mariyam Jassim Aljasmi, Paul Nancarrow
{"title":"ZnO nanoparticle-reinforced lignin-phenol-formaldehyde foam: Formulation, optimization and properties","authors":"P.R. Sarika,&nbsp;Hessa Rashid Bhughanim AlSuwaidi,&nbsp;Roudha Saeed Alhelli Alhajeri,&nbsp;Sara Ahmed Alhammadi,&nbsp;Mariyam Jassim Aljasmi,&nbsp;Paul Nancarrow","doi":"10.1016/j.reactfunctpolym.2025.106500","DOIUrl":"10.1016/j.reactfunctpolym.2025.106500","url":null,"abstract":"<div><div>In this work, the formulation of ZnO nanoparticle-reinforced lignin phenol formaldehyde foam (ZnO-LPF) has been optimized and the potential for enhancing its mechanical properties has been evaluated. The insulation material industry is shifting towards a more sustainable future by developing foams through partial replacement of petroleum-resourced raw materials with bio-based alternatives. LPF foams represent one such alternative to phenolic foams synthesized from phenol and formaldehyde. While the partial replacement of phenol with lignin can potentially reduce environmental impacts, some of the key characteristics of phenolic foams, such as mechanical strength, are compromised. In this study, LPF resin was prepared by replacing certain percentages of phenol with lignin, and the various LPF foams were prepared by varying the formulation and measuring the key properties to obtain a formulation with optimal characteristics. Later, the selected formulation was further improved by incorporating ZnO nanoparticles, and the impact of its concentration on enhancing the key properties was analyzed. The resin and foams were characterized using scanning electron microscopy, thermogravimetry analysis, thermal conductivity, and mechanical property analysis. The compressive strength of the 10LPF foams initially increased with ZnO addition and later decreased at higher nanoparticle concentrations. The foam with 0.1 % (<em>w</em>/w) ZnO exhibited excellent compressive strength and thermal conductivity.</div></div>","PeriodicalId":20916,"journal":{"name":"Reactive & Functional Polymers","volume":"217 ","pages":"Article 106500"},"PeriodicalIF":5.1,"publicationDate":"2025-09-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145266080","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Piezoresistive materials based on natural polymers for medical device applications 基于天然聚合物的压阻材料,用于医疗器械
IF 5.1 3区 工程技术
Reactive & Functional Polymers Pub Date : 2025-09-29 DOI: 10.1016/j.reactfunctpolym.2025.106502
E. Pimentel , P. Costa , J. Vilaça , C.M. Costa , S. Lanceros-Méndez , D. Miranda
{"title":"Piezoresistive materials based on natural polymers for medical device applications","authors":"E. Pimentel ,&nbsp;P. Costa ,&nbsp;J. Vilaça ,&nbsp;C.M. Costa ,&nbsp;S. Lanceros-Méndez ,&nbsp;D. Miranda","doi":"10.1016/j.reactfunctpolym.2025.106502","DOIUrl":"10.1016/j.reactfunctpolym.2025.106502","url":null,"abstract":"<div><div>In nowadays society it has been an increase of life expectancy which has been accompanied by an increase in chronic diseases and loss of autonomy which promotes a constant demand for advanced healthcare treatments and diagnostic methods to improve the quality of life of the populations. Flexible detection devices have attracted increasing attention in recent years and are expected to continue to grow over the next decade due to their advantages in terms of user compliance for long term monitoring, improved skin-device coupling and the ability to develop low-cost and recyclable devices. Several of those sensing devices are based on the piezoresistive effect which have been used to monitor heart pulse, respiratory rate, and blood pressure, among others. Typically, these sensors are based on synthetic polymer, though the related environmental concerns are promoting their replacement by natural polymers, allowing to reduce waste and electronic waste (e-waste) accumulation in landfills and oceans, as well as the presence of microplastics. Thus, the main goal is incorporating flexible natural polymers that can replicate or even improve the properties of traditional synthetic materials while offering advantages such as non-toxicity, biocompatibility, durability, and biodegradability. In this review, flexible and sustainable piezoresistive sensors based on natural polymers for biomedical applications are presented, with potential use in areas including invasive blood pressure devices measurements, multivital signal monitoring, respiration rate monitoring and in catheter medical devices. This topic is highly relevant in current society as it bridges environmental concerns such as microplastics formation, climate change and waste management, with healthcare concerns, such ageing population, through the development of advanced environmentally friendly biomedical applications.</div></div>","PeriodicalId":20916,"journal":{"name":"Reactive & Functional Polymers","volume":"217 ","pages":"Article 106502"},"PeriodicalIF":5.1,"publicationDate":"2025-09-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145220486","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Application of agar-based adsorbents in the removal of dyes and heavy metals from wastewater: Current advances, challenges, and future perspectives 琼脂基吸附剂在废水中染料和重金属去除中的应用:现状、挑战和未来展望
IF 5.1 3区 工程技术
Reactive & Functional Polymers Pub Date : 2025-09-29 DOI: 10.1016/j.reactfunctpolym.2025.106501
Noureddine El Messaoudi , Youssef Miyah , Jordana Georgin , Dison S.P. Franco , Başak Temur Ergan , Bienvenu Gaël Fouda Mbanga , Salah Knani , Mouslim Messali
{"title":"Application of agar-based adsorbents in the removal of dyes and heavy metals from wastewater: Current advances, challenges, and future perspectives","authors":"Noureddine El Messaoudi ,&nbsp;Youssef Miyah ,&nbsp;Jordana Georgin ,&nbsp;Dison S.P. Franco ,&nbsp;Başak Temur Ergan ,&nbsp;Bienvenu Gaël Fouda Mbanga ,&nbsp;Salah Knani ,&nbsp;Mouslim Messali","doi":"10.1016/j.reactfunctpolym.2025.106501","DOIUrl":"10.1016/j.reactfunctpolym.2025.106501","url":null,"abstract":"<div><div>Excessive release of toxic dyes and heavy metals into water bodies has become a significant environmental and public health issue. Therefore, research into environmentally friendly, low-cost, and efficient adsorbents has been a critical area of study in wastewater treatment. This review discusses agar-based adsorbents for the removal of dyes and heavy metals from wastewater, highlighting agar as a biodegradable and renewable polysaccharide derived from red algae, rich in functional groups that enhance its adsorption potential. It focuses on recent advancements in agar modification, i.e., cross-linking, grafting, and composite preparation using nanomaterials, to enhance its mechanical strength, selectivity, and adsorption capacity. The various methods of synthesis and their impact on the adsorption capacities of contaminants are critically reviewed. Although promising, others, such as regeneration frontiers, mechanical instability in water, and scalability boundaries, still prevail. Overall, this paper provides useful information on the latest developments and emphasizes the importance of interdisciplinary microbiology research to use agar-based adsorbents in real wastewater treatment.</div></div>","PeriodicalId":20916,"journal":{"name":"Reactive & Functional Polymers","volume":"217 ","pages":"Article 106501"},"PeriodicalIF":5.1,"publicationDate":"2025-09-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145220555","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
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