Reactive & Functional Polymers最新文献

{"title":"Energy and combustion performance of Al/PVDF composite films: Vapor-grown carbon fiber as a new additive","authors":"Wenyu Li ,&nbsp;Yajun Wang ,&nbsp;Ruihua Liu ,&nbsp;Zhengliang Deng ,&nbsp;Qiang Gan","doi":"10.1016/j.reactfunctpolym.2024.106121","DOIUrl":"10.1016/j.reactfunctpolym.2024.106121","url":null,"abstract":"<div><div>Vapor-grown carbon fibers (VGCF) have received significant attention due to their excellent properties, including low density, high specific modulus, super specific strength, and large specific surface area. To investigate the impact of VGCF on the energy and combustion performance of the aluminum (Al)/polyvinylidene fluoride (PVDF) metastable intermolecular composite (MIC) system, the composite films of Al/PVDF with varying VGCF contents were prepared using the spin-coating method. The micromorphology, crystal structure, mechanical property, energy, and combustion performance of the films were analyzed. The results demonstrate that the addition of VGCF greatly enhanced the system's performance, particularly in terms of hydrophobicity and tensile properties. Furthermore, the participation of VGCF also promoted gas generation during the combustion process, leading to an increase and subsequent decrease in reaction heat release and burning rate within a specific range. The optimal range for VGCF addition in composite films was determined to be 0.8 %–1.2 %. When the addition amount is 0.8 %, the heat release of total reaction, heat release of fluorination reaction, and burning rate reached maximum values of 4773 J·g⁻¹, 4551 J·g⁻¹, and 77.2 mm·s⁻¹, respectively. Compared with VGCF-0, the heat release increased by 687 J·g⁻¹ and 848 J·g⁻¹, respectively, and the combustion rate increased by nearly 13 %. When the addition of VGCF reached 2.0 %, a new product, Al₄C₃, appeared, deviating from the original performance trend and enhancing energy release and combustion performance. This study provides valuable insights for the application of VGCF as an additive in MIC materials.</div></div>","PeriodicalId":20916,"journal":{"name":"Reactive & Functional Polymers","volume":"207 ","pages":"Article 106121"},"PeriodicalIF":4.5,"publicationDate":"2025-02-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143144657","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"TPFPP@PMMA core-shell polymer modified flame retardant separator achieved by aqueous technique for high-voltage lithium metal batteries","authors":"Dongchun Chen ,&nbsp;Mingyao Hong ,&nbsp;Jianglong Wan ,&nbsp;Weishan Li ,&nbsp;Youhao Liao","doi":"10.1016/j.reactfunctpolym.2024.106130","DOIUrl":"10.1016/j.reactfunctpolym.2024.106130","url":null,"abstract":"<div><div>The safety of lithium metal batteries (LMBs) is a critical barrier to their further development towards achieving higher energy densities exceeding 400 Wh kg⁻¹. Although the incorporation of flame-retardant additives into the liquid electrolyte can enhance the safety of LMBs, it often compromises electrochemical performance. To achieve a balance, a flame-retardant separator with thermally responsive properties has been developed by coating a core-shell flame-retardant polymer (poly(methyl methacrylate) (PMMA) as the shell and tris (pentafluorophenyl) phosphine (TPFPP) as the core) onto a polyethylene (PE) separator using an aqueous technique. Compared to the original PE separator, the TPFPP@PMMA flame-retardant separator exhibits superior mechanical strength and electrolyte wettability, along with significantly improved flame retardancy and thermal stability. Due to the excellent compatibility of PMMA polymer with lithium anode, a stable cycle life of over 500 hours for the Li||Li symmetrical coin cell has been achieved. The capacity retention of the Li||LiNi_0.8Co_0.1Mn_0.1O₂ battery is higher than that of the PE separator (80.0% vs. 65.8%) after 100 cycles between 3.0 V and 4.35 V, ascribed to the formation of a stable and robust cathode electrolyte interface (CEI) film, primarily composed of rich LiF and poor Li₂CO₃ on the cathode surface, induced by the PT/PE separator. Thus, the developed flame-retardant separator offers new prospects to the revival of high-energy-density LMBs.</div></div>","PeriodicalId":20916,"journal":{"name":"Reactive & Functional Polymers","volume":"207 ","pages":"Article 106130"},"PeriodicalIF":4.5,"publicationDate":"2025-02-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143144833","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Adjustment in physicochemical properties of PMMA particles through different photopolymerization methods to achieve their functional applications in various scenarios","authors":"Siyuan Yu ,&nbsp;Boxuan Peng ,&nbsp;Zhen Wang ,&nbsp;Jinfeng Xing","doi":"10.1016/j.reactfunctpolym.2024.106141","DOIUrl":"10.1016/j.reactfunctpolym.2024.106141","url":null,"abstract":"<div><div>Poly(methyl methacrylate) (PMMA) is a polymeric compound synthesized from its monomer unit methyl methacrylate (MMA). PMMA is usually processed into particles and the functional application of these particles has been promoted in various fields such as biomedicine, coatings, and optical devices. At present, the preparation process for PMMA particles in industrialization mostly relies on thermal polymerization. Still, the traditional thermal-initiated mode has high energy consumption and long cycles, so it is urgent to explore new approaches for preparing PMMA particles with low energy and high efficiency. Photopolymerization is an effective medium for achieving this goal and has the advantages of fast curing, mild reaction conditions, and environmental protection. Therefore, this review summarizes the photoinitiated preparation methods of PMMA particles, including emulsion photopolymerization, dispersion photopolymerization, controlled/living radical photopolymerization, surface-initiated photopolymerization, and <em>in situ</em> photopolymerization. Furthermore, the functional application of PMMA particles based on these photopolymerization methods is further introduced and prospected.</div></div>","PeriodicalId":20916,"journal":{"name":"Reactive & Functional Polymers","volume":"207 ","pages":"Article 106141"},"PeriodicalIF":4.5,"publicationDate":"2025-02-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143144645","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Preparation and application of superhydrophobic polypropylene melt-blown nonwovens by organic solvent etch","authors":"Tianyi Ma ,&nbsp;Le Gan ,&nbsp;Yang Liu ,&nbsp;Shinan Xu ,&nbsp;Chenlong Han ,&nbsp;Xiaolin Zhao ,&nbsp;Xiaobei Zang ,&nbsp;Ning Cao","doi":"10.1016/j.reactfunctpolym.2024.106132","DOIUrl":"10.1016/j.reactfunctpolym.2024.106132","url":null,"abstract":"<div><div>Since the global outbreak of COVID-19, medical masks have become one of the most concerned pieces of epidemiological protection equipment. Polypropylene melt-blown nonwovens are the core filtration materials of medical masks, but the filtration performance deteriorates drastically with prolonged use and water vapor adherence. Here, a series of organic solvents were used to etch the melt-blown nonwovens to construct a graded rough structure and thus obtain durable superhydrophobic melt-blown nonwovens. The melt-blown nonwovens etched with a mixture of cyclohexane and n-hexane (volume ratio: 3:2) at 65 °C for 30 min exhibited excellent superhydrophobicity (water contact angle ∼153.5°, sliding angle ∼5.9°), high durability and great chemical resistance. The mechanical strength of the superhydrophobic melt-blown nonwoven has changed very little compared to the original melt- blown nonwoven, and it has a good filtration efficiency (89.2 %) and low wind resistance (24.3 Pa). In addition, the superhydrophobic melt-blown nonwoven can achieve more than 8.5 times its previous mass of organic solvent adsorption, with oil and water separation efficiency reaching over 91 %. Therefore, the PP melt-blowns prepared by the organic solvent etching method have greatly improved mask filtration performance and they also <u>have</u> great application prospect in oil-water separation.</div></div>","PeriodicalId":20916,"journal":{"name":"Reactive & Functional Polymers","volume":"207 ","pages":"Article 106132"},"PeriodicalIF":4.5,"publicationDate":"2025-02-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143144658","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Schiff bases and oligomers derived from trifluoromethylaniline-based monomers: Thermal, optical, electrochemical properties and applications as fluorescent probes for Sn2+","authors":"Elif Karacan Yeldir,&nbsp;İsmet Kaya,&nbsp;Oğuzhan Tutluel","doi":"10.1016/j.reactfunctpolym.2024.106133","DOIUrl":"10.1016/j.reactfunctpolym.2024.106133","url":null,"abstract":"<div><div>Within the scope of the study, three different Schiff bases were synthesized from 3,5-bis(trifluoromethyl)aniline, a halogen-containing aniline derivative, with three different aldehydes, 3-hydroxy-4-methoxy-benzaldehyde, salicylaldehyde and 2-hydroxy-1-naphthaldehyde. These three synthesized Schiff bases were evaluated as monomers and oxidatively polymerized in the presence of sodium hypochlorite, a strong oxidant. The structural properties of these three monomers and three polymers were elucidated with the help of UV–Vis, FT-IR, ¹H NMR, ¹³C NMR spectra. Their molecular weights were determined by gel permeation chromatography (GPC) and it was determined that the macromolecules obtained as a result of the oxidation reaction were in the oligomer order. In order to investigate their electrochemical properties, cyclic voltammetry (CV) was used to find their oxidation-reduction potentials. The HOMO-LUMO potentials and electrochemical band gap values of the synthesized Schiff bases and oligomers were calculated. Thermal stabilities of the monomers and oligomers were determined by thermogravimetric-differantial thermal analysis (TG-DTA). It was determined that the thermal stabilities of the obtained oligomers were higher than those of the Schiff bases. The glass transition temperature (<em>T</em>_<em>g</em>) and surface morphologies of oligomers were determined from DSC and SEM measurements, respectively. Their optical properties were examined by UV–Vis and fluorescence spectra. It was found that 1-(((3,5-bis(trifluoromethyl)phenyl)imino)methyl) naphthalene-2-ol (TFMHN), one of the Schiff bases, has a turn-on fluorescence sensor property with increasing fluorescence emission intensity in the presence of Sn²⁺ among a series of metal ions and can be used as a selective and sensitive fluorescence probe for Sn²⁺ with a limit of dedection (<em>LOD</em>) value of 7.14 × 10⁻⁸ M.</div></div>","PeriodicalId":20916,"journal":{"name":"Reactive & Functional Polymers","volume":"207 ","pages":"Article 106133"},"PeriodicalIF":4.5,"publicationDate":"2025-02-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143144700","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Preparation of modified epoxy resin with high hydrophobicity, low dielectric constant, toughness, and flame retardant by epoxy-functionalized siloxanes","authors":"Yang Zhang,&nbsp;Yixiao Shi,&nbsp;Chen Jin,&nbsp;Chuan Wu,&nbsp;Hong Dong,&nbsp;Zhirong Qu,&nbsp;Yanjiang Song","doi":"10.1016/j.reactfunctpolym.2024.106114","DOIUrl":"10.1016/j.reactfunctpolym.2024.106114","url":null,"abstract":"<div><div>A series of <em>α</em>, <em>ω</em>-dimethylglycidoxypropyl-terminated PDMS oligomer (PDMS-GE) oligomers with different polymerization degrees were synthesized and used to modify the bisphenol-A diglycidyl ether E51 (DGEBA) / 4,4-diaminodiphenylmethane (DDM) epoxy resin, resulting in epoxy resins with high hydrophobicity, low dielectric constant, good impact toughness, low combustion heat release rate, and low total heat release. The combustion heat release rate and total heat release of the material decreased with the increase in the loadings of PDMS-GE. Relative to pure epoxy resin, the composite E51/D30–10, which using DGEBA as the matrix, PDMS-GE with a degree of polymerization of 30 as the modifier in an amount of 10 phr relative to the mass sum of DGEBA, PDMS-GE and DDM, exhibited the best comprehensive performance with a water contact angle of 102.42°, a dielectric strength of 6.49 kV/mm, a dielectric constant of 2.93 at 14.2 GHz, the peak rate of heat release (PRHR) and total heat release (THR) are of 378.3 kW/m² and 134.4 MJ/m², respectively. These comprehensive performances underscore the potential of PDMS-GE oligomers in significantly improving epoxy resin properties. When the loadings of PDMS-GE oligomers are less than 5 wt%, PDMS-GE with a lower degree of polymerization can improve the toughness of epoxy resins. The impact strength of the composite E51/D24–5, which uses DGEBA as the matrix, PDMS-GE with a degree of polymerization of 24 as the modifier in an amount of 5 phr relative to the mass sum of DGEBA, PDMS-GE, and DDM, reaches 98.1 kJ/m², which is about 28.9 % higher than that of pure epoxy resin. The results also indicated that the degree of polymerization of PDMS-GE oligomers has less influence on the dielectric properties and mechanical properties of composite materials.</div></div>","PeriodicalId":20916,"journal":{"name":"Reactive & Functional Polymers","volume":"207 ","pages":"Article 106114"},"PeriodicalIF":4.5,"publicationDate":"2025-02-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143144702","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"An approach to analytical prediction of optimal curing mode of thermosetting systems","authors":"E.S. Zhavoronok ,&nbsp;I.N. Senchikhin","doi":"10.1016/j.reactfunctpolym.2024.106143","DOIUrl":"10.1016/j.reactfunctpolym.2024.106143","url":null,"abstract":"<div><div>An approach to the analytical prediction of the optimal curing mode of thermosetting systems is proposed. The published literature on epoxy-amine systems has been analyzed, and a correlation between the parameters of the DiBenedetto and Arrhenius equations and the glass transition temperature of uncured epoxy-amine systems was established. On the basis of the data, the approach proposed by Gillham and Enns was employed to calculate a time required for thermosetting system to reach the glassy state, and the mode of two-stage curing through the use of TTT (time-temperature-transformation) diagrams was determined as well. The optimal curing mode was proposed and calculated for the DGEBA-based epoxy resin Epikote 828 and its mixture with aliphatic resin Laproxide 703 with curing agent oligooxypropylenediamine Jeffamine D-230, with the resulting temperatures and times demonstrating satisfactory agreement with those calculated from experimental TTT diagrams. It is suggested that the proposed approach for predicting the optimal curing mode be employed for new epoxy-amine systems, for which the time-consuming experiment, required for the construction of TTT diagrams has not yet been performed.</div></div>","PeriodicalId":20916,"journal":{"name":"Reactive & Functional Polymers","volume":"207 ","pages":"Article 106143"},"PeriodicalIF":4.5,"publicationDate":"2025-02-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143144826","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"The hidden power of a novel collagen octapeptide: Unveiling its antioxidant and cofactors releasing capacity from polyurethane based systems","authors":"Alexandra Lupu ,&nbsp;Luiza Madalina Gradinaru ,&nbsp;Mihaela Balan-Porcarasu ,&nbsp;Laura Darie-Ion ,&nbsp;Brindusa-Alina Petre ,&nbsp;Vasile-Robert Gradinaru","doi":"10.1016/j.reactfunctpolym.2024.106131","DOIUrl":"10.1016/j.reactfunctpolym.2024.106131","url":null,"abstract":"<div><div>Aromatic antioxidant peptides are attractive biomolecules that can be used to design supramolecular structures useful in various biomedical applications. Collagen-derived peptides proved to be suitable for a wide range of biological applications. Herein, we introduced a novel amphipathic octapeptide as an essential component in hybrid peptide-polyurethane materials. The octapeptide was synthesized by SPPS, followed by mass confirmation using MALDI-ToF mass spectrometry and characterized by nuclear magnetic resonance and fluorescence spectroscopy. The peptide antioxidant capacity was demonstrated through FRAP and DPPH assays. Our data indicate that the presence of peptide slightly slows down the polyurethane ability to form hydrogels at salt concentration higher than 150 mM. Moreover, the gel formed in the presence of octapeptide can release FAD much faster than NADPH. Preferential weak interactions between peptide and polyurethane structures increase FAD releasing capacity. Our findings will pave the way for the development of new biocompatible materials containing an antioxidant peptide and FAD, a cofactor that modulates the antioxidant function of multiple enzymes simultaneously. These controlled-release platforms created by simple mixing may be suitable for injectable formulation.</div></div>","PeriodicalId":20916,"journal":{"name":"Reactive & Functional Polymers","volume":"207 ","pages":"Article 106131"},"PeriodicalIF":4.5,"publicationDate":"2025-02-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143144834","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Methoxyl-Containing Hyper-Crosslinked Polymer from Largely Bio-Based Biphenyl Methyl Ether and Its Application in Lithium-Sulfur Battery","authors":"Apparav K. Wale ,&nbsp;Anoushka K. Das ,&nbsp;Nita R. Patil ,&nbsp;Manjusha V. Shelke ,&nbsp;Ashootosh V. Ambade ,&nbsp;Prakash P. Wadgaonkar","doi":"10.1016/j.reactfunctpolym.2024.106139","DOIUrl":"10.1016/j.reactfunctpolym.2024.106139","url":null,"abstract":"<div><div>A new biphenyl methyl ether <em>viz</em> 2,2′,3,3′-tetramethoxy-5,5′-bis(methoxymethyl)-1,1′-biphenyl (TBMB) was synthesized starting from vanillin <em>via</em> three-step reaction sequence. The self-polycondensation of TBMB by employing two Bronsted acid catalysts, <em>viz</em>, <em>p-</em>toluenesulfonic acid (PTSA) and trifluoromethanesulfonic acid (TFSA) led to the formation of organic hyper-crosslinked polymers (HCPs) containing built-in methoxyl groups. HCPs were characterized by FTIR, solid state ¹³C NMR, XPS, XRD, TGA, BET, and FESEM analysis techniques. HCPs synthesized using PTSA (HCP-PTSA) and TFSA (HCP-TFSA) exhibited a Brunauer–Emmett–Teller (BET) surface area of 480 ± 5 and 590 ± 4 m²/g, respectively and consisted of hierarchical pore structures with both micropores and mesopores. HCP-TFSA was evaluated as an active coating layer on conventional polypropylene (PP) separator in lithium-sulfur batteries to suppress the polysulfide shuttling on account of the ability of methoxyl groups to anchor soluble polysulfide species <em>via</em> coordination. The significant polysulfide adsorption capacity and improved cycling stability with a capacity of 617.2 mAh g⁻¹ at 0.5C and 99% capacity retention highlighted the potential of porous HCP containing built-in methoxyl groups in the development of attractive lithium-sulfur battery systems.</div></div>","PeriodicalId":20916,"journal":{"name":"Reactive & Functional Polymers","volume":"207 ","pages":"Article 106139"},"PeriodicalIF":4.5,"publicationDate":"2025-02-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143144830","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Preparation of magnetic molecular imprinted polymers based on deep eutectic solvent and its application in the specific adsorption and detection of fluoxetine hydrochloride","authors":"Yanbo Tian,&nbsp;Liju Tan,&nbsp;Huiru Li,&nbsp;Yu Qiao,&nbsp;Na Wang,&nbsp;Jiangtao Wang","doi":"10.1016/j.reactfunctpolym.2024.106122","DOIUrl":"10.1016/j.reactfunctpolym.2024.106122","url":null,"abstract":"<div><div>Magnetic molecular imprinted polymers (MMIPs) for specific adsorption of fluoxetine hydrochloride (FXT) were prepared by using a new solvent, deep eutectic solvents (DESs) as the porogen, magnetic Fe₃O₄ nanoparticles modified twice as the carrier and methacrylic acid (MAA) as the functional monomer. The effects of DESs type, molar ratio of functional monomer to template molecule and amount of crosslinker on the adsorption properties of MMIPs were investigated. The characterization results showed that the optimized MMIPs is a rough porous material with a particle size between 300 and 500 nm, and the magnetic properties and thermal properties are satisfactory. The adsorption of MMIPs for FXT reached the equilibrium within 30 min. The equilibrium absorption capacity was 38.54 mg·g⁻¹ with an imprinting factor of 1.88. The constructed MMIPs showed good specificity and reusability. A rapid, simple and economical detection method for residual FXT in environmental water samples was established with the recovery rate between 94.4 and 102.2 %, and LOD and LOQ of 4.0 μg·L⁻¹ and 1.2 μg·L⁻¹, respectively.</div></div>","PeriodicalId":20916,"journal":{"name":"Reactive & Functional Polymers","volume":"207 ","pages":"Article 106122"},"PeriodicalIF":4.5,"publicationDate":"2025-02-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143144659","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}