Progress in Organic Coatings最新文献

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Active-passive synergistic protection of LDH functionalized microcapsules in construction steel coating for enhanced anti-corrosion LDH功能化微胶囊在建筑钢涂层中的主-被动协同保护,增强其防腐性能
IF 7.3 2区 材料科学
Progress in Organic Coatings Pub Date : 2026-04-01 Epub Date: 2026-01-16 DOI: 10.1016/j.porgcoat.2026.109960
Yiwei Zhong , Xingang Wang , Weichen Tian , Tan Wang , Fubing Zou , Wenxiang Cao
{"title":"Active-passive synergistic protection of LDH functionalized microcapsules in construction steel coating for enhanced anti-corrosion","authors":"Yiwei Zhong ,&nbsp;Xingang Wang ,&nbsp;Weichen Tian ,&nbsp;Tan Wang ,&nbsp;Fubing Zou ,&nbsp;Wenxiang Cao","doi":"10.1016/j.porgcoat.2026.109960","DOIUrl":"10.1016/j.porgcoat.2026.109960","url":null,"abstract":"<div><div>To address the issue of construction steel corrosion caused by protective coating failure, this work synthesized Layered double hydroxides (LDH) functionalized microcapsules to enhance active-passive synergistic protection of coating. The composite shell of the microcapsules provides passive protection through enhanced hydrophobicity and chloride adsorption, while the core material isophorone diisocyanate (IPDI) offers active self-healing functionality. The wettability, particle morphology, physicochemical properties, and chloride adsorption behavior of the microcapsules were investigated. The state, mechanical properties, self-healing characteristics, and anti-corrosion performance of the construction steel coatings were systematically evaluated. Experimental results demonstrated that the microcapsules exhibited passive hydrophobicity and improved chloride adsorption performance by mitigating LDH agglomeration. These passive anti-corrosion properties provided enhanced resistance to the penetration of corrosive media in the steel coatings, delaying the onset of steel corrosion. Ultra-depth quantitative analysis provided evidence of the active self-healing performance in the microcapsule-containing coatings. Furthermore, neutral salt spray tests revealed that the microcapsules significantly improved the anti-corrosion performance of the steel coating in simulated chloride-rich humid atmospheric environments. Electrochemical tests recorded an exceptional inhibition efficiency above 97% for the coating with 15% microcapsule content, reaching a peak at 98.95% within 4 days. In summary, the microcapsules synergistically enhanced the anti-corrosion properties of construction steel coatings through combined active-passive protection mechanisms.</div></div>","PeriodicalId":20834,"journal":{"name":"Progress in Organic Coatings","volume":"213 ","pages":"Article 109960"},"PeriodicalIF":7.3,"publicationDate":"2026-04-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145978395","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Effect of POSS-functionalized GO arrangement pattern on the wear resistance and corrosion resistance of PI coatings poss功能化氧化石墨烯排列模式对PI涂层耐磨性和耐腐蚀性的影响
IF 7.3 2区 材料科学
Progress in Organic Coatings Pub Date : 2026-04-01 Epub Date: 2026-01-17 DOI: 10.1016/j.porgcoat.2026.109975
Zhicheng Zhang , Rui Yuan , Donghao Xiang , Qianjun Ma , Jing Yuan
{"title":"Effect of POSS-functionalized GO arrangement pattern on the wear resistance and corrosion resistance of PI coatings","authors":"Zhicheng Zhang ,&nbsp;Rui Yuan ,&nbsp;Donghao Xiang ,&nbsp;Qianjun Ma ,&nbsp;Jing Yuan","doi":"10.1016/j.porgcoat.2026.109975","DOIUrl":"10.1016/j.porgcoat.2026.109975","url":null,"abstract":"<div><div>This paper focused on how the arrangement of nanofillers in coatings affected their reinforcement of resins. Mono-aminopropyllsobutyl polyhedral oligomeric silsesquioxane (MAPOSS) was employed to modify graphene oxide (GO) to address their dispersion issues (PG). By controlling the spray method, the arrangement of PG within the polyimide (PI) was regulated, resulting in the preparation of M-PG/PI (spraying after uniformly mixing PG and PI), L-PG/PI (alternately spraying PI and GO to form a single-layer interleaved coating), and T-PG/PI (alternately spraying PI and GO to form a thick interleaved coating). GO/PI coatings were obtained using the same methods for comparative explorations. Further investigate the effects of nanoflakes arrangement on coating hardness, friction and wear resistance, and corrosion resistance. Research has found that the hardness of the L-PG/PI coating increased by 4% compared to the M-PG/PI, while its coefficient of friction decreased by 6.95% and the wear rate was decreased by 0.3%. However, the M-PG/PI has the best corrosion resistance with a lower corrosion current density, followed by L-PG/PI and T-PG/PI. In summary, the L-type coating formed by alternating single-layer stacking of nanosheets and resin was more conducive to enhancing tribological properties, while the uniformly mixed M-type coating was more effective at improving corrosion resistance. Conversely, thick coating with alternating stack structures has a significant negative impact on enhancing coating performance.</div></div>","PeriodicalId":20834,"journal":{"name":"Progress in Organic Coatings","volume":"213 ","pages":"Article 109975"},"PeriodicalIF":7.3,"publicationDate":"2026-04-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145978392","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
A two-step method to construct a superhydrophobic, ceramicizable intumescent fire-retardant coating suitable for steel and RPU 一种两步法制备超疏水陶瓷膨胀防火涂料的方法
IF 7.3 2区 材料科学
Progress in Organic Coatings Pub Date : 2026-04-01 Epub Date: 2026-01-12 DOI: 10.1016/j.porgcoat.2026.109951
Dongdong Tang , Huizhi Huang , Yao Ren , Qiuru Bao , Dawei Luo , Kai Zhang , Yuan Liu
{"title":"A two-step method to construct a superhydrophobic, ceramicizable intumescent fire-retardant coating suitable for steel and RPU","authors":"Dongdong Tang ,&nbsp;Huizhi Huang ,&nbsp;Yao Ren ,&nbsp;Qiuru Bao ,&nbsp;Dawei Luo ,&nbsp;Kai Zhang ,&nbsp;Yuan Liu","doi":"10.1016/j.porgcoat.2026.109951","DOIUrl":"10.1016/j.porgcoat.2026.109951","url":null,"abstract":"<div><div>As the demand for flame-retardant materials grows, intumescent fire-retardant coatings (IFC) have attracted significant attention due to advantages such as ease of application, minimal impact on substrate properties, and high flame-retardant efficiency. However, conventional IFC exhibit limitations including low char strength and hygroscopic components. To address these issues, this study introduced low-melting-point glass powder (LMGP) as a ceramic-forming filler into IFCs, preparing a ceramicizable IFC (C-IFC) with higher char layer strength. Furthermore, TiO<sub>2</sub> was surface-modified with 1H,1H,2H,2H-perfluorodecyltriethoxysilane (PFDTS) to produce superhydrophobic PFDTS@TiO<sub>2</sub> powder. By combining the aforementioned coating and modified powder through a two-step process, a superhydrophobic ceramicizable IFC (C<sub>20</sub>-IFC/ PFDTS@TiO<sub>2</sub>) was successfully developed. This coating demonstrated excellent fire-retardant and thermal insulation performance on steel structures and rigid polyurethane foam (RPU).Additionally, the coating surface exhibited exceptional hydrophobicity, with a water contact angle (WCA) of 157.5 ± 0.7° and a water roll-off angle(WRA) of 4 ± 0.3°. This hydrophobic surface gives the coating excellent water resistance. This work provides a universal and efficient solution for developing high-performance, durable fire-retardant protective coatings integrating ‘fire and water non-invasion’ and self-cleaning capabilities.</div></div>","PeriodicalId":20834,"journal":{"name":"Progress in Organic Coatings","volume":"213 ","pages":"Article 109951"},"PeriodicalIF":7.3,"publicationDate":"2026-04-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145978412","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Mechanistic advances in graphene-based nanofiller epoxy coatings for corrosion protection of reinforcing steel: Performance and practical outlook 钢筋防腐用石墨烯基纳米环氧涂层的机理研究进展:性能与应用前景
IF 7.3 2区 材料科学
Progress in Organic Coatings Pub Date : 2026-04-01 Epub Date: 2026-01-06 DOI: 10.1016/j.porgcoat.2025.109900
Olajide T. Sanya, Daman K. Panesar
{"title":"Mechanistic advances in graphene-based nanofiller epoxy coatings for corrosion protection of reinforcing steel: Performance and practical outlook","authors":"Olajide T. Sanya,&nbsp;Daman K. Panesar","doi":"10.1016/j.porgcoat.2025.109900","DOIUrl":"10.1016/j.porgcoat.2025.109900","url":null,"abstract":"<div><div>This review explores the use of graphene-based nanofillers to enhance the corrosion resistance of epoxy-coated steel. While epoxy coatings are widely applied, their inherent defects allow water and corrosive ions to penetrate. Graphene (G) and its derivatives, graphene oxide (GO) and reduced graphene oxide (rGO), offer barrier properties but may also promote micro-galvanic corrosion due to agglomeration. This paper critically assesses the corrosion performance, and the corresponding mechanisms of epoxy coatings modified with G, GO, and rGO based on 51 published literature sources. The role of controlling mechanisms on the corrosion resistance efficiency are examined, including optimal nanofiller loading, surface functionalization, hybrid nanofiller coatings, and filler orientation within the epoxy matrix. Two categorizations of chloride exposure durations ≤24 h and &gt;24 h on the corrosion resistance efficiency of epoxy coatings modified with G, GO, and rGO are reviewed. The inclusion of G-based nanofillers into epoxy coatings significantly enhances corrosion resistance in chloride-rich environments for both short-term (≤24 h) and long-term (&gt;24 h) studies compared to a neat epoxy coating. Compared to neat epoxy, G-based epoxy coatings demonstrate superior barrier properties, with several studies reporting protection efficiencies exceeding 99 % under both short- and long-term chloride exposure. Despite this high initial corrosion efficiency, some coatings exhibited elevated delamination index (<em>DI</em>) values, indicating potential long-term interfacial degradation. In contrast, coatings incorporating oriented or functionalized G-based fillers demonstrated significantly lower <em>DI</em> values, suggesting more stable interfacial adhesion, in turn underscoring the complex interplay between initial barrier performance and long-term durability. These improvements are primarily attributed to enhanced impermeability, suppressed electrochemical activity, and optimized nanofiller dispersion. Among the synthesis methods reviewed, in situ polymerization ensures better structural uniformity and bonding, while optimized solution mixing offers a scalable, cost-effective option. While common techniques such as transmission electron microscopy (TEM), scanning electron microscopy (SEM), atomic force microscopy (AFM), ultraviolet–visible spectroscopy (UV–vis), and Fourier transform infrared spectroscopy (FTIR) are used to assess G dispersion in epoxy, each presents limitations—including sample artifacts, shallow probing depth, and resolution constraints—emphasizing the value of a complementary, multiscale approach for reliable characterization.</div></div>","PeriodicalId":20834,"journal":{"name":"Progress in Organic Coatings","volume":"213 ","pages":"Article 109900"},"PeriodicalIF":7.3,"publicationDate":"2026-04-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145927722","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Enhancing mechanical and tribological performance of polyimide coatings using MXene@ZrO2 hybrid fillers 使用MXene@ZrO2杂化填料增强聚酰亚胺涂层的机械和摩擦学性能
IF 7.3 2区 材料科学
Progress in Organic Coatings Pub Date : 2026-04-01 Epub Date: 2026-01-09 DOI: 10.1016/j.porgcoat.2025.109942
Rui Nie , Wenfu Zeng , Hongyu Shi , Jia Wei , Cheng Qian
{"title":"Enhancing mechanical and tribological performance of polyimide coatings using MXene@ZrO2 hybrid fillers","authors":"Rui Nie ,&nbsp;Wenfu Zeng ,&nbsp;Hongyu Shi ,&nbsp;Jia Wei ,&nbsp;Cheng Qian","doi":"10.1016/j.porgcoat.2025.109942","DOIUrl":"10.1016/j.porgcoat.2025.109942","url":null,"abstract":"<div><div>Under extreme operating conditions, the bearing bush pair in swashplate-type variable displacement axial piston pumps is prone to wear, which compromises the safety and reliability of the overall hydraulic system. To enhance the tribological performance of the tin-bronze bearing bushes, in this study, MXene@ZrO<sub>2</sub> hybrid fillers were synthesized through surface modification with dopamine and KH550. Subsequently, five polyimide (PI) coatings—pure PI, ZrO<sub>2</sub>/PI, MXene/PI, ZrO<sub>2</sub> + MXene/PI, and MXene@ZrO<sub>2</sub>/PI—were prepared on tin-bronze substrate surfaces via in-situ polymerization. Finally, the tribological properties of the five PI coatings were then evaluated through friction testing. The results indicated that ZrO<sub>2</sub> was successfully grafted onto the surface and interlayer regions of MXene, forming a distinctive “particle-on-plane” structure. Compared to the tin-bronze substrate, t the coefficient of friction and wear rate of the MXene@ZrO<sub>2</sub>/PI composite coating reduced by approximately 48 % and 91 %, respectively. This was accompanied by the formation of a continuous and uniform transfer film on the steel ball surface. Among the investigated coatings, MXene@ZrO<sub>2</sub>/PI demonstrated the best overall tribological performance. These findings provide theoretical guidance for the design of high-performance solid lubricants and PI-based composite coatings.</div></div>","PeriodicalId":20834,"journal":{"name":"Progress in Organic Coatings","volume":"213 ","pages":"Article 109942"},"PeriodicalIF":7.3,"publicationDate":"2026-04-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145927879","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Durable multifunctional cotton: Flame retardancy, hydrophobicity, and salt-free dyeing 耐用多功能棉:阻燃、疏水、无盐染色
IF 7.3 2区 材料科学
Progress in Organic Coatings Pub Date : 2026-04-01 Epub Date: 2026-01-07 DOI: 10.1016/j.porgcoat.2025.109943
Dan Yu , Kang Yang , Yun Liu , Bin Zhao , Cong-Yun Zhang
{"title":"Durable multifunctional cotton: Flame retardancy, hydrophobicity, and salt-free dyeing","authors":"Dan Yu ,&nbsp;Kang Yang ,&nbsp;Yun Liu ,&nbsp;Bin Zhao ,&nbsp;Cong-Yun Zhang","doi":"10.1016/j.porgcoat.2025.109943","DOIUrl":"10.1016/j.porgcoat.2025.109943","url":null,"abstract":"<div><div>Developing multifunctional cellulose textiles with durable flame retardancy, hydrophobicity, and efficient coloration via environmentally benign processes is essential for high-performance surface treatments. Conventional finishing strategies often rely on formaldehyde, excessive dyeing salts, or weakly adherent finishes, all of which compromise durability and environmental compatibility. Herein, we present a scalable finishing strategy that integrates durable flame retardancy, salt-free dyeing, and hydrophobicity without compromising environmental or mechanical performance. The process involves mercerization pretreatment, covalent bonding of ammonium polyphosphate to cellulose for formaldehyde-free and wash-durable flame retardancy, salt-free reactive dyeing with Reactive Red 120, and surface hydrophobization via hexadecyltrimethoxysilane crosslinking coating. Structural analyses using scanning electron microscopy, X-ray photoelectron spectroscopy, and Fourier transform infrared spectroscopy demonstrated successful multifunctional integration on fiber interface. The treated fabrics exhibited superior fire resistance, with a limiting oxygen index (LOI) of 41.3 %, a 77.4 % reduction in peak heat release rate, and retained self-extinguishing capability with LOI ≥32.9 % after 500 laundering cycles. The hydrophobic finishing achieved a water contact angle above 127°, maintaining repellency to water and beverages after repeated washing. Dye uptake was substantially improved (color strength, K/S = 30.5) without salt additives, reducing wastewater salinity. This integrated, formaldehyde-free modification strategy offers an eco-friendly and durable approach for producing multifunctional cellulose textiles.</div></div>","PeriodicalId":20834,"journal":{"name":"Progress in Organic Coatings","volume":"213 ","pages":"Article 109943"},"PeriodicalIF":7.3,"publicationDate":"2026-04-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145927876","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Long-term durability comparison of commercial waterborne and solvent-based polyurethane coatings for steel bridges 钢桥用商用水性和溶剂型聚氨酯涂料的长期耐久性比较
IF 7.3 2区 材料科学
Progress in Organic Coatings Pub Date : 2026-04-01 Epub Date: 2026-01-08 DOI: 10.1016/j.porgcoat.2025.109924
Sang-Hyung Lee , Young-Soo Jeong , In-Tae Kim
{"title":"Long-term durability comparison of commercial waterborne and solvent-based polyurethane coatings for steel bridges","authors":"Sang-Hyung Lee ,&nbsp;Young-Soo Jeong ,&nbsp;In-Tae Kim","doi":"10.1016/j.porgcoat.2025.109924","DOIUrl":"10.1016/j.porgcoat.2025.109924","url":null,"abstract":"<div><div>Waterborne coatings have garnered attention as a low-volatile organic compound alternative to conventional solvent-based coatings. However, their field use and long-term performance data are limited. This study compares a standard-specified commercial waterborne polyurethane system with a conventional solvent-based system using coated panels exposed to two indoor tests (16,000-h fluorescent ultraviolet light and 13,200-h cyclic corrosion) and a 3-year outdoor marine exposure. Performance is evaluated based on gloss retention, color difference, chalking, rust area, and adhesion strength. The gloss retention of both systems converge to less than 20 % after a certain exposure period. In cyclic corrosion, rust propagation on waterborne panels progress approximately 75 % faster than that on solvent-based panels, whereas after three years of outdoor weathering tests, the difference in the rust-propagation rate is minimal. This divergence is attributed to the different primer mechanisms. The adhesion satisfies the minimum criteria required for both systems.</div></div>","PeriodicalId":20834,"journal":{"name":"Progress in Organic Coatings","volume":"213 ","pages":"Article 109924"},"PeriodicalIF":7.3,"publicationDate":"2026-04-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145927847","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Dual strategy of surface fluorination and textured structure to enhance wettability, corrosion resistance and tribological property of epoxy resin coatings 采用表面氟化和织构结构的双重策略提高环氧树脂涂层的润湿性、耐腐蚀性和摩擦学性能
IF 7.3 2区 材料科学
Progress in Organic Coatings Pub Date : 2026-04-01 Epub Date: 2026-01-07 DOI: 10.1016/j.porgcoat.2026.109947
Gaoyu Wang , Ting Dai , Ping An , Ping Chen
{"title":"Dual strategy of surface fluorination and textured structure to enhance wettability, corrosion resistance and tribological property of epoxy resin coatings","authors":"Gaoyu Wang ,&nbsp;Ting Dai ,&nbsp;Ping An ,&nbsp;Ping Chen","doi":"10.1016/j.porgcoat.2026.109947","DOIUrl":"10.1016/j.porgcoat.2026.109947","url":null,"abstract":"<div><div>This study proposes a dual-strategy approach, combining surface fluorination with texture design, to fabricate superhydrophobic epoxy resin (ER) coatings with simultaneously enhanced wettability, corrosion resistance, and tribological property. Textures with different parameters were prepared via a templating method, and surface fluorination was carried out using FAS-17 to obtain fluorinated and textured ER coating (FTEC). The synergistic effects of texture side length, spacing, height, and surface fluorination were systematically investigated. The results demonstrate that fluorination coupled with textures markedly improved the surface hydrophobicity of the coatings, with the S5-15 sample exhibiting a contact angle of 154° at a texture height of 15 μm. In terms of corrosion resistance, FTEC exhibits an impedance enhancement of two orders of magnitude compared to ER coatings produced by single-texturing and single-fluorination strategies, with the S5-15 sample reaching the highest value of 2.058 × 10<sup>10</sup> Ω·cm<sup>2</sup>. Tribological tests revealed that the coefficient of friction decreased with increasing texture spacing, achieving a minimum of 0.382 for the S10-30 sample with texture height of 5 μm. Meanwhile, the wear rate reached its lowest value of 1.916 × 10<sup>−6</sup> cm<sup>3</sup>/N·m in the S10-30 sample with texture height of 15 μm. Mechanistic analysis indicates that surface fluorination reduces surface energy, while textures introduce air layers and lubricant storage channels. Their synergistic effect establishes an enhanced mechanism of “air cushion effect and hydrodynamic lubrication”, leading to the comprehensive performance improvement of the ER coatings. This dual-strategy design not only provides a novel approach for developing multifunctional superhydrophobic coatings but also offers promising application potential in harsh-service environments such as marine protection, aerospace systems, and energy equipment.</div></div>","PeriodicalId":20834,"journal":{"name":"Progress in Organic Coatings","volume":"213 ","pages":"Article 109947"},"PeriodicalIF":7.3,"publicationDate":"2026-04-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145927848","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Fabrication of LDH-MoO₄2−-Si coatings with enhanced anti-corrosion and self-repairing properties 具有增强抗腐蚀和自修复性能的LDH-MoO₄2−si涂层的制备
IF 7.3 2区 材料科学
Progress in Organic Coatings Pub Date : 2026-04-01 Epub Date: 2026-01-22 DOI: 10.1016/j.porgcoat.2026.109987
Xuming Fang , Zhelun Mai , Yingjian Guan , Guoliang Wu , Xiaoqing Du , Dongchu Chen
{"title":"Fabrication of LDH-MoO₄2−-Si coatings with enhanced anti-corrosion and self-repairing properties","authors":"Xuming Fang ,&nbsp;Zhelun Mai ,&nbsp;Yingjian Guan ,&nbsp;Guoliang Wu ,&nbsp;Xiaoqing Du ,&nbsp;Dongchu Chen","doi":"10.1016/j.porgcoat.2026.109987","DOIUrl":"10.1016/j.porgcoat.2026.109987","url":null,"abstract":"<div><div>In this study, an LDH–MoO₄<sup>2−</sup>–Si composite coating, composed of layered double hydroxides (LDH), molybdate ions (MoO₄<sup>2−</sup>), and silane, was successfully fabricated on an aluminum alloy substrate. The morphology, structure, composition, corrosion resistance, and self-healing behavior of the coating were systematically investigated using scanning electron microscopy (SEM), X-ray diffraction (XRD), Fourier-transform infrared spectroscopy (FTIR), X-ray photoelectron spectroscopy (XPS), electrochemical impedance spectroscopy (EIS), and electrochemical noise (EN) techniques. Results show that the as-prepared coating is compact and homogeneous, with MoO₄<sup>2−</sup> and silane uniformly distributed within the vertical lamellae of LDH, forming a distinctive “vertical sandwich” architecture of LDH → MoO₄<sup>2−</sup> → silane → LDH. In 3.5 wt% NaCl solution, the coated aluminum alloy exhibits a corrosion current density approximately five orders of magnitude lower and a total impedance about six orders of magnitude higher than those of the bare substrate, demonstrating excellent corrosion resistance. After 90 days of immersion in the same solution, the coating retained a corrosion protection efficiency of 99.36%, confirming its long-term stability. The self-healing behavior of scratched coating was monitored via EN and further validated by SEM and XPS analyses. The release of MoO₄<sup>2−</sup> ions from the LDH interlayers showed an intelligent stimulus-responsive characteristic, effectively promoting the self-repair process. After 7 days of immersion in 3.5 wt% NaCl solution, the damaged coating nearly recovered its original morphology, structure, and composition, achieving a self-healing efficiency of 97.73% and exhibiting remarkable autonomous recovery capability.</div></div>","PeriodicalId":20834,"journal":{"name":"Progress in Organic Coatings","volume":"213 ","pages":"Article 109987"},"PeriodicalIF":7.3,"publicationDate":"2026-04-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"146023627","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Pseudorotaxane-based hydrogel coatings with dual functions of lubrication and antibacterial activity 具有润滑和抗菌双重功能的假紫杉烷基水凝胶涂料
IF 7.3 2区 材料科学
Progress in Organic Coatings Pub Date : 2026-04-01 Epub Date: 2026-01-17 DOI: 10.1016/j.porgcoat.2026.109974
Jiqun Wang , Qiang Zhou , Yang Sun , Ming Liu , Ruipeng Zheng
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