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An in-depth NMR investigation of thermoresponsive unimer micelles loaded with the highly hydrophobic antitumor drug CA-4 对装载了高疏水性抗肿瘤药物 CA-4 的热粘弹性单分子胶束的深入核磁共振研究
IF 5 2区 材料科学
Polymer Testing Pub Date : 2025-04-01 DOI: 10.1016/j.polymertesting.2025.108784
Andrea Cesari , Elisa Guazzelli , Ester Scaiella , Marco Lessi , Elisa Martinelli , Fabio Bellina
{"title":"An in-depth NMR investigation of thermoresponsive unimer micelles loaded with the highly hydrophobic antitumor drug CA-4","authors":"Andrea Cesari ,&nbsp;Elisa Guazzelli ,&nbsp;Ester Scaiella ,&nbsp;Marco Lessi ,&nbsp;Elisa Martinelli ,&nbsp;Fabio Bellina","doi":"10.1016/j.polymertesting.2025.108784","DOIUrl":"10.1016/j.polymertesting.2025.108784","url":null,"abstract":"<div><div>Unimer micelles, a special class of single chains nanoparticles (SCNPs), are known to form in water solution by the self-folding of amphiphilic random copolymers via hydrophobic intramolecular interactions. The hydrophobic compartments, derived therefrom, can be usefully exploited for the encapsulation of highly water-insoluble drug for their potential use as drug delivery systems (DDSs). Because the knowledge-base of their self-assembling behaviour in water is of primary importance, in this work, a comprehensive NMR investigation is reported on the self-folding of a fluorinated random copolymer (PEGMA<sub>83</sub>-<em>co</em>-FA<sub>17</sub>) with the main aim to highlight the potential of this technique as a complementary tool with respect to the conventionally used DLS and more sophisticated analytical techniques, including SAXS and SANS. In particular, new experimental conformational details were described by using <sup>1</sup>H–<sup>1</sup>H, <sup>1</sup>H-<sup>19</sup>F and <sup>19</sup>F–<sup>19</sup>F 2D NOESY maps. Micelle size determination through DOSY and water solubility enhancement of Combretastatin A-4 (CA-4), a potent highly hydrophobic anticancer drug, were evaluated. Encapsulation efficiency (EE%) was also quantified. Details on PEGMA<sub>83</sub>-<em>co</em>-FA<sub>17</sub>/CA-4 molecular interactions were elucidated, and temperature-responsive properties were observed by recording measurements above and below the cloud point temperature typical of the formulation. The obtained results suggest that NMR spectroscopy represents a faceted and powerful analytical tool for the characterization at a molecular level of unimer micelles as innovative materials for the encapsulation of hydrophobic drugs, as CA-4, potentially applicable as drug delivery systems.</div></div>","PeriodicalId":20628,"journal":{"name":"Polymer Testing","volume":"146 ","pages":"Article 108784"},"PeriodicalIF":5.0,"publicationDate":"2025-04-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143783921","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Hydrothermal decomposition of virgin and waste polylactic acid with subcritical water under N2 and air atmospheres 亚临界水在N2和空气环境下对原聚乳酸和废聚乳酸的水热分解
IF 5 2区 材料科学
Polymer Testing Pub Date : 2025-03-27 DOI: 10.1016/j.polymertesting.2025.108783
Maja Čolnik , Mihael Irgolič , Mojca Škerget
{"title":"Hydrothermal decomposition of virgin and waste polylactic acid with subcritical water under N2 and air atmospheres","authors":"Maja Čolnik ,&nbsp;Mihael Irgolič ,&nbsp;Mojca Škerget","doi":"10.1016/j.polymertesting.2025.108783","DOIUrl":"10.1016/j.polymertesting.2025.108783","url":null,"abstract":"<div><div>Bio-based polymers are an important step towards solving environmental problems, but there is a need to consider and develop procedures for dealing with these materials at the end of their life and to ensure that effective disposal methods are available. Recently, polylactic acid (PLA) has replaced many plastics based on non-renewable resources. In this work, subcritical water was used for the chemical decomposition of virgin and waste PLA under different atmospheres. The main degradation product was lactic acid with very high yields. The highest yield of lactic acid was obtained under N<sub>2</sub> atmosphere, where the optimum conditions were 200 °C and 60 min and the yield was 88.96 ± 1.5 % for virgin PLA and 54.58 ± 1.3 % for waste PLA. In an air atmosphere, the maximum yields of lactic acid were obtained at 250 °C and 30 min and were slightly lower than in the N<sub>2</sub> atmosphere, i.e. 87.20 ± 0.9 % for virgin PLA and 49.29 ± 0.6 % for waste PLA. The lower yield of lactic acid from waste PLA is due to the impurities and additives in waste PLA. Other carboxylic acids were also formed in the aqueous phase, while the gas phase mainly contained CO<sub>2</sub>, N<sub>2</sub>/CO and C<sub>1</sub>-C<sub>5</sub> hydrocarbons. The hydrothermal degradation pathway was presented and the electricity costs for lab-scale PLA recycling were estimated. With this sustainable technology, PLA could be successfully recycled down to its monomer, providing a secondary raw material for the re-synthesis of the polymer, closing the loop and reducing the impact on the environment.</div></div>","PeriodicalId":20628,"journal":{"name":"Polymer Testing","volume":"146 ","pages":"Article 108783"},"PeriodicalIF":5.0,"publicationDate":"2025-03-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143739112","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Effect of proteins on the structure of crosslinking junctions and mechanical properties of vulcanized natural rubber 蛋白质对硫化天然橡胶交联结结构及力学性能的影响
IF 5 2区 材料科学
Polymer Testing Pub Date : 2025-03-27 DOI: 10.1016/j.polymertesting.2025.108782
Masaki Yamano , Takayuki Saito , Yoshimasa Yamamoto , Seiichi Kawahara
{"title":"Effect of proteins on the structure of crosslinking junctions and mechanical properties of vulcanized natural rubber","authors":"Masaki Yamano ,&nbsp;Takayuki Saito ,&nbsp;Yoshimasa Yamamoto ,&nbsp;Seiichi Kawahara","doi":"10.1016/j.polymertesting.2025.108782","DOIUrl":"10.1016/j.polymertesting.2025.108782","url":null,"abstract":"<div><div>Primary structure of vulcanized natural rubber was quantitatively analyzed by rubber state NMR spectroscopy to investigate a relationship between structure, strain-induced crystallization and mechanical properties of the rubber. The vulcanized natural rubber was prepared from deproteinized natural rubber (DPNR) and natural rubber, which were compounded with sulfur, ZnO, stearic acid, and <em>N</em>-<em>tert</em>-butyl-2-benzothiazole sulfenamide (TBBS), at temperatures of 110, 130, 150, and 170 °C under pressure of 15 MPa for optimal vulcanization time, <em>t</em><sub>90</sub>. The vulcanized rubbers were characterized by rubber-state NMR spectroscopy, swelling method, and wide angle X-ray diffraction measurement. Carbon-sulfur bonds of the vulcanized rubbers were quantitatively compared with crosslink density, and abnormal groups such as <em>trans</em>-1,4 isoprene units were analyzed as a side reaction product. Contents of carbon-sulfur bonds and <em>trans</em>-1,4 isoprene units of the vulcanized rubbers increased as the vulcanization temperature rose; that is, a sequence length of <em>cis</em>-1,4 isoprene units was shortened with the temperature. Accordingly, the strain-induced crystallization was suppressed and the mechanical properties were reduced as the vulcanization temperature rose. The strain-induced crystallinity and tensile strength of the vulcanized DPNR were higher than those of the corresponding vulcanized natural rubber while the crosslink density and <em>cis</em>-1,4 isoprene unit content of the vulcanized DPNR were lower.</div></div>","PeriodicalId":20628,"journal":{"name":"Polymer Testing","volume":"146 ","pages":"Article 108782"},"PeriodicalIF":5.0,"publicationDate":"2025-03-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143769041","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Cellulose-reinforced natural rubber microfibers with low mechanical hysteresis for wireless physiological monitoring 用于无线生理监测的低机械滞后的纤维素增强天然橡胶微纤维
IF 5 2区 材料科学
Polymer Testing Pub Date : 2025-03-27 DOI: 10.1016/j.polymertesting.2025.108781
Epsita Kar , Arti Singh , Bokyeoung Kang , Jinhwan Yoon
{"title":"Cellulose-reinforced natural rubber microfibers with low mechanical hysteresis for wireless physiological monitoring","authors":"Epsita Kar ,&nbsp;Arti Singh ,&nbsp;Bokyeoung Kang ,&nbsp;Jinhwan Yoon","doi":"10.1016/j.polymertesting.2025.108781","DOIUrl":"10.1016/j.polymertesting.2025.108781","url":null,"abstract":"<div><div>Unprecedented demand for wearable electronics has stimulated the development of highly elastic strain sensors that monitor human motion. This study presents a highly stretchable, lightweight, and wearable strain sensor composed of natural rubber (NR) and cellulose nanofibers (CNF). It addresses the challenge of developing highly sensitive sensors with good linearity and low hysteresis for wireless physiological monitoring. By incorporating CNF as a reinforcing agent along with carbon nanotubes and PEDOT:PSS for conductivity, we have achieved significant improvements in sensor performance. The optimized wearable device exhibited an increase in fracture stress while maintaining high stretchability (over 600 %) with minimal hysteresis loss (approximately 2.7 % at 100 % strain), low response time (approximately 43 ms), and good mechanical durability. Furthermore, an integrated system based on the device was assembled to detect real-time fine wireless physiological signals generated from human motions, including walking, joint movements, and subtle finger bending. The ability of the system to wirelessly transmit data in real time enhances its potential for continuous health monitoring and human-machine interfaces as next-generation smart wearable electronics.</div></div>","PeriodicalId":20628,"journal":{"name":"Polymer Testing","volume":"146 ","pages":"Article 108781"},"PeriodicalIF":5.0,"publicationDate":"2025-03-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143739113","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Investigation of thermal transport across volume-controlled thermal interface materials 体积控制热界面材料的热传递研究
IF 5 2区 材料科学
Polymer Testing Pub Date : 2025-03-26 DOI: 10.1016/j.polymertesting.2025.108780
Jungmin Lee , Woosung Park
{"title":"Investigation of thermal transport across volume-controlled thermal interface materials","authors":"Jungmin Lee ,&nbsp;Woosung Park","doi":"10.1016/j.polymertesting.2025.108780","DOIUrl":"10.1016/j.polymertesting.2025.108780","url":null,"abstract":"<div><div>For thermal management, thermal interface materials are essential to reduce parasitic thermal resistance by filling microscopic gaps at interface. While much of previous research has focused on enhancing the thermal conductivity of the materials, the inconsistency in experimental data limits fundamental investigation in the thermal interface materials. In this work, we use a screen printing and pressing method to apply thermal interface material in a consistent manner, enabling fundamental investigation to identify an optimal bond line thickness for thermal interface material. Specifically, we apply two-dimensional array of cylindrical pillars and modulate its diameter and pitch to find an optimal volume experimentally. The thermal resistance is measured using a standard thermal interface test method, and an optimal volume of thermal interface material is experimentally determined. We apply a rheological model for the thermal interface material to estimate the optimal bond line thickness under pressure, and the model prediction agrees with experimental data within ∼89.4 %. This work establishes an experimental methodology for thermal interface material, bridging a gap between its theoretical and practical approaches.</div></div>","PeriodicalId":20628,"journal":{"name":"Polymer Testing","volume":"146 ","pages":"Article 108780"},"PeriodicalIF":5.0,"publicationDate":"2025-03-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143715860","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Bending behavior of additively manufactured short fiber reinforced composite sandwich structures based on triply periodic minimal surface 基于三周期极小面增材制造短纤维增强复合材料夹层结构的弯曲性能
IF 5 2区 材料科学
Polymer Testing Pub Date : 2025-03-20 DOI: 10.1016/j.polymertesting.2025.108779
Yaozhong Wu , Xuepeng Li , Shaoan Li , HuaWei Wang , Peng Wang , Weijia Li
{"title":"Bending behavior of additively manufactured short fiber reinforced composite sandwich structures based on triply periodic minimal surface","authors":"Yaozhong Wu ,&nbsp;Xuepeng Li ,&nbsp;Shaoan Li ,&nbsp;HuaWei Wang ,&nbsp;Peng Wang ,&nbsp;Weijia Li","doi":"10.1016/j.polymertesting.2025.108779","DOIUrl":"10.1016/j.polymertesting.2025.108779","url":null,"abstract":"<div><div>Triply periodic minimal surfaces (TPMSs) have gained increasing attention because of their excellent mechanical properties and scalability. The Gyroid TPMS core sandwich (G-TPMS sandwich) structure was designed, and its bending performance and failure behavior were studied through experimental, theoretical, and numerical approaches. The test samples were prepared by the fused deposition modeling (FDM) method using the carbon fiber reinforced nylon filament. Theoretical and numerical models were established and verified using experimental results. In addition, the influence of geometrical parameters on the bending performance and failure behavior of the G-TPMS sandwich structures was studied by parametric studies. The results show that the flexural modulus and peak load of the sandwich structures can be enhanced by increasing the relative density of the G-TPMS core and the face sheet thickness. The flexural modulus and the peak load of the G-TPMS sandwich structure with a face sheet thickness of 2.5 mm are 35.46 % and 36 % higher than that of the G-TPMS sandwich structure with a face sheet thickness of 1.5 mm, respectively. The flexural modulus and the peak load of the G-TPMS sandwich structure with a relative density of 0.35 are 37.5 % and 41.02 % higher than that of the G-TPMS sandwich structure with a relative density of 0.25. Meanwhile, the G-TPMS sandwich structures with a lower relative density of the core are prone to shear failure mode. The proposed G-TPMS sandwich has the potential to be applied in lightweight structures for aerospace, automotive, or marine engineering.</div></div>","PeriodicalId":20628,"journal":{"name":"Polymer Testing","volume":"146 ","pages":"Article 108779"},"PeriodicalIF":5.0,"publicationDate":"2025-03-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143695975","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Isatin-based microporous polymer membranes with tunable building blocks: Understanding structural effects on gas transport properties and plasticization behavior 具有可调构件的isatin基微孔聚合物膜:理解结构对气体传输性能和塑化行为的影响
IF 5 2区 材料科学
Polymer Testing Pub Date : 2025-03-18 DOI: 10.1016/j.polymertesting.2025.108775
Eun Ji An , Seungbae Jeon , Guk-Yun Noh , Jieun Lee , Yunji Kim , Hyomin Choi , Chang Soo Lee , Sungmin Park , Won Seok Chi
{"title":"Isatin-based microporous polymer membranes with tunable building blocks: Understanding structural effects on gas transport properties and plasticization behavior","authors":"Eun Ji An ,&nbsp;Seungbae Jeon ,&nbsp;Guk-Yun Noh ,&nbsp;Jieun Lee ,&nbsp;Yunji Kim ,&nbsp;Hyomin Choi ,&nbsp;Chang Soo Lee ,&nbsp;Sungmin Park ,&nbsp;Won Seok Chi","doi":"10.1016/j.polymertesting.2025.108775","DOIUrl":"10.1016/j.polymertesting.2025.108775","url":null,"abstract":"<div><div>In this study, we synthesized microporous polymer membranes using electrophilic isatin and nucleophilic aromatic building blocks via super-acid-catalyzed Friedel‒Crafts polycondensation to investigate the influence of polymer chain packing structures on gas transport properties and plasticization characteristics. By tuning the aromatic building blocks without modifying isatin, we controlled key structural parameters, including repeating unit chain length, planar conformation, rotational freedom, and inter-segmental interactions. The thermal and mechanical properties, fractional free volume, and chain packing structures of the synthesized polymers were thoroughly characterized to elucidate the impact of structural variations on gas separation performance. Further, variations in gas separation properties owing to different building blocks were elucidated through structural characterization. Notably, among the synthesized polymer membranes, the one with planar building blocks demonstrated the highest selectivity between H<sub>2</sub> and CO<sub>2</sub>, attributed to its reduced symmetry and relatively polar characteristics. Meanwhile, the microporous polymer membrane with restricted rotational freedom exhibited the highest dimensional stability and plasticization resistance, enhancing stability during gas separation. Overall, this study provides fundamental insights into the structure–property relationships of isatin-based microporous polymers, offering guidance for the rational design of polymer materials for efficient and stable gas separation.</div></div>","PeriodicalId":20628,"journal":{"name":"Polymer Testing","volume":"146 ","pages":"Article 108775"},"PeriodicalIF":5.0,"publicationDate":"2025-03-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143746434","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Evaluation of the time–temperature superposition by comparing neat and glass-fibre-reinforced epoxy using dynamic mechanical thermal analysis 用动态力学热分析方法比较纯环氧树脂和玻璃纤维增强环氧树脂的时间-温度叠加性
IF 5 2区 材料科学
Polymer Testing Pub Date : 2025-03-18 DOI: 10.1016/j.polymertesting.2025.108747
Daniel Esse , Benedikt Scheuring , Frank Henning , Wilfried V. Liebig
{"title":"Evaluation of the time–temperature superposition by comparing neat and glass-fibre-reinforced epoxy using dynamic mechanical thermal analysis","authors":"Daniel Esse ,&nbsp;Benedikt Scheuring ,&nbsp;Frank Henning ,&nbsp;Wilfried V. Liebig","doi":"10.1016/j.polymertesting.2025.108747","DOIUrl":"10.1016/j.polymertesting.2025.108747","url":null,"abstract":"<div><div>Dynamic mechanical thermal analysis is a well-established method to determine the influence of temperature and frequencies on polymers. One challenge inherent to this method is the potential for significant changes in material properties, which can exceed several orders of magnitude and rapidly approach the accuracy or mechanical limits of measurement systems or actuators. In this work, it is shown that a change in the magnitude of the mechanical load within the linear elastic region does not affect the results. Consequently, the test parameters during the DMTA to be adapted to the stiffness of the specimens, allowing materials and volumes closer to the limits of the testing system to be measured. Furthermore, master curves were generated according to the temperature–time superposition for the frequency from the measured sections using a modified method. This was achieved by shifting the loss factor and applying the shift factor to the storage modulus. The tests presented in this work were carried out on continuous fibre-reinforced epoxy resin with a [<span><math><mrow><mo>+</mo><mn>45</mn><mo>/</mo><mo>−</mo><mn>45</mn></mrow></math></span>]<sub>2s</sub> fibre orientation and the neat matrix material itself, up to temperatures above the glass transition area. Wicket plots indicated thereby that the temperature–time superposition is applicable for both material systems. A comparison of the two material systems showed, that the fibre-reinforced specimen is shifted horizontally to a greater extent.</div></div>","PeriodicalId":20628,"journal":{"name":"Polymer Testing","volume":"146 ","pages":"Article 108747"},"PeriodicalIF":5.0,"publicationDate":"2025-03-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143643651","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Debonding-on-demand reversible adhesives via heat or light with competitive adhesion strength to conventional epoxy adhesives 按需脱胶,可通过热或光脱胶,具有与传统环氧胶粘剂竞争的粘合强度
IF 5 2区 材料科学
Polymer Testing Pub Date : 2025-03-18 DOI: 10.1016/j.polymertesting.2025.108776
Samantha J. (Lindholm) Knight , John D. McCoy , Sanchari Chowdhury , Youngmin Lee
{"title":"Debonding-on-demand reversible adhesives via heat or light with competitive adhesion strength to conventional epoxy adhesives","authors":"Samantha J. (Lindholm) Knight ,&nbsp;John D. McCoy ,&nbsp;Sanchari Chowdhury ,&nbsp;Youngmin Lee","doi":"10.1016/j.polymertesting.2025.108776","DOIUrl":"10.1016/j.polymertesting.2025.108776","url":null,"abstract":"<div><div>Stimuli responsive debonding-on-demand (DoD) reversible adhesives are of great interest for the circular economy. However, the reversible adhesives developed so far often lack competitive adhesion strength in a bonding state. In this work, reversible epoxy adhesives based on Diels–Alder (DA) chemistry were developed and exhibited a competitive adhesion strength (e.g., 12–16 MPa of a lap shear strength) to commercial non-reversible epoxy adhesives. The reversible epoxy formulation showed superior thermal stability up to 110 °C, and transition to a debonding state in the order of 0.1 MPa at 140 °C, consequently, an on/off-type debonding behavior. The transition to a debonding state was attributed to crosslinking density control (e.g., decrease by 33 %–49 %) through the reversible DA chemistry and the proximity to the glass transition. Next, for debonding by light stimulus, photothermal refractory plasmonic titanium nitride (TiN) nanoparticles were incorporated in the reversible epoxy, which can generate the required heat for debonding upon exposure to visible light. Photothermal debonding allows for precise debonding at target areas and tunable adhesion strength by controlling the exposure area and light intensity. The DA adhesive formulations containing 0.5 wt% TiN nanoparticles presented a debonding state with zero adhesion under light exposure with intensity of 1670 mW/cm<sup>2</sup> (inducing 140 °C). Even after three cycles of reattachment, the DA adhesive formulations retained 96 % of the pristine sample's adhesion strength measured at 110 °C. Therefore, the DA adhesives are attractive candidates as reversible DoD systems applicable in higher temperatures.</div></div>","PeriodicalId":20628,"journal":{"name":"Polymer Testing","volume":"146 ","pages":"Article 108776"},"PeriodicalIF":5.0,"publicationDate":"2025-03-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143686324","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Correlations between blowability and uniaxial stretchability of PET before and after mechanical recycling 机械回收前后PET吹塑性能与单轴拉伸性能的关系
IF 5 2区 材料科学
Polymer Testing Pub Date : 2025-03-17 DOI: 10.1016/j.polymertesting.2025.108774
Nathan Sylvestre , Jean-Luc Bouvard , Guillaume Corvec , Mikaël Derrien , Xavier Monnier , Christelle Combeaud
{"title":"Correlations between blowability and uniaxial stretchability of PET before and after mechanical recycling","authors":"Nathan Sylvestre ,&nbsp;Jean-Luc Bouvard ,&nbsp;Guillaume Corvec ,&nbsp;Mikaël Derrien ,&nbsp;Xavier Monnier ,&nbsp;Christelle Combeaud","doi":"10.1016/j.polymertesting.2025.108774","DOIUrl":"10.1016/j.polymertesting.2025.108774","url":null,"abstract":"<div><div>In the literature, previous studies have linked the behaviour of PET under stretch-blowing and under uniaxial stretching thanks to the time-temperature equivalence principle. Other works showed variations of microstructural, thermal and mechanical properties of PET submitted to mechanical recycling, but blowability was not measured. In this article, the behaviour during free stretch-blowing tests was investigated for a virgin commercial PET before and after mechanical recycling with a step of solid-state post-condensation. For the same physical state, the lower stretch-blown volumes obtained for the recycled PET were correlated with a sooner nucleation leading to a lower Natural Draw Ratio, as observed during uniaxial tensile tests. Our results confirm that the uniaxial stretching tests used in the past to discriminate the behaviours of neat PET resins in blowing, can also be used to predict variations of blowability under mechanical recycling.</div></div>","PeriodicalId":20628,"journal":{"name":"Polymer Testing","volume":"146 ","pages":"Article 108774"},"PeriodicalIF":5.0,"publicationDate":"2025-03-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143686329","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
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