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Cordylus cataphractus-scale-inspired composite materials for stab resistance
IF 5 2区 材料科学
Polymer Testing Pub Date : 2025-01-01 DOI: 10.1016/j.polymertesting.2024.108673
Ting Su , Xuliang Yu , Haijun He , Honglian Cong , Gaoming Jiang , Huajin Wu , Kezheng Zhao , Yanfeng Niu , Xinji Zhou , Guangjun Wu
{"title":"Cordylus cataphractus-scale-inspired composite materials for stab resistance","authors":"Ting Su ,&nbsp;Xuliang Yu ,&nbsp;Haijun He ,&nbsp;Honglian Cong ,&nbsp;Gaoming Jiang ,&nbsp;Huajin Wu ,&nbsp;Kezheng Zhao ,&nbsp;Yanfeng Niu ,&nbsp;Xinji Zhou ,&nbsp;Guangjun Wu","doi":"10.1016/j.polymertesting.2024.108673","DOIUrl":"10.1016/j.polymertesting.2024.108673","url":null,"abstract":"<div><div>Inspired by Cordylus cataphractus scales, two types of rectangular scale-like knitted fabrics (RSKF) were developed using ultra-high molecular weight polyethylene (UHMWPE) fibers. By constructing a unit geometry model and analyzing the knitting structure of RSKF, a scale-like knitted fabric imitating Cordylus cataphractus (SKFC) with multilayered and interlacing structures was designed. The SKFC can be combined with rigid composites to form a reinforced P-SKFC, exhibiting excellent protective properties (∼2203.98 N) and good flexibility (&lt;250 mN cm). Due to its removable and replaceable hard protective blocks, P-SKFC exhibits good durability. This study offers guidance for the rapid development of P-SKFC and proposes a novel strategy for designing flexible, lightweight stab-resistant fabrics, potentially offering substantial advantages for personal stab-resistance devices in various industrial fields.</div></div>","PeriodicalId":20628,"journal":{"name":"Polymer Testing","volume":"142 ","pages":"Article 108673"},"PeriodicalIF":5.0,"publicationDate":"2025-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143173210","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Construction of cross-linked PEO grafting copolymer for high-performance gel electrolyte
IF 5 2区 材料科学
Polymer Testing Pub Date : 2025-01-01 DOI: 10.1016/j.polymertesting.2024.108655
Shuangshuang Wang, Huizi Zhang, Jilu Ma, Dejia Liu, Tonghui Zhang, Yuchao Li, Guang Li
{"title":"Construction of cross-linked PEO grafting copolymer for high-performance gel electrolyte","authors":"Shuangshuang Wang,&nbsp;Huizi Zhang,&nbsp;Jilu Ma,&nbsp;Dejia Liu,&nbsp;Tonghui Zhang,&nbsp;Yuchao Li,&nbsp;Guang Li","doi":"10.1016/j.polymertesting.2024.108655","DOIUrl":"10.1016/j.polymertesting.2024.108655","url":null,"abstract":"<div><div>It is an urgent demand of polyethylene oxide with poor crystallinity, high electrolyte affinity and ionic conductivity in portable electronics usage. In the present work, crosslinked poly (glycidyl methacrylate) (PGMA) grafting modified PEO has been prepared. Firstly, PGMA with controlled chain length can be highly efficient covalent anchored on PEO main chain with the assistance of N-hydroxyphthalimide (NHPI) catalysis combined with activators regenerated by electron transfer ATRP (ARGET-ATRP). Then the grafted PGMA chains undergone crosslinked process in the presence of 4, 4-diaminodiphenyl sulfone (DDS) to produce crosslinked PEO<em>-g</em>-PGMA (C-PEO-<em>g</em>-PGMA) film. The film could be used in electronic devices, and it exhibit amorphous structure, higher electrolyte wettability and mechanical strength compared to that of pure PEO. Moreover, the performance for electrical double-layer capacitor (EDLC) assembled with electrolyte-soaked C-PEO-<em>g</em>-PGMA films were sharply higher than that of EDLC with PEO. The present study provides a novel and highly efficient methodology for the modification of poly (ethylene oxide) (PEO) through crosslinked grafting side chains.</div></div>","PeriodicalId":20628,"journal":{"name":"Polymer Testing","volume":"142 ","pages":"Article 108655"},"PeriodicalIF":5.0,"publicationDate":"2025-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143172169","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Research on tire tread abrasion performance considering the patten and slippage with verification
IF 5 2区 材料科学
Polymer Testing Pub Date : 2025-01-01 DOI: 10.1016/j.polymertesting.2024.108684
Huaqiao Liu , Yao Xiao , Kongshuo Wang , Yukun Zhou , Huiguang Bian , Chuansheng Wang
{"title":"Research on tire tread abrasion performance considering the patten and slippage with verification","authors":"Huaqiao Liu ,&nbsp;Yao Xiao ,&nbsp;Kongshuo Wang ,&nbsp;Yukun Zhou ,&nbsp;Huiguang Bian ,&nbsp;Chuansheng Wang","doi":"10.1016/j.polymertesting.2024.108684","DOIUrl":"10.1016/j.polymertesting.2024.108684","url":null,"abstract":"<div><div>The wear, rolling resistance, and wet grip are the most important performance of tires. The wear of tires rubber is influenced by various factors such as formula composition (such as butadiene rubber content), rubber strength, heat generation performance, etc. It is a complex problem involving mechanics and thermodynamics. Unfortunately, commonly used wear testing equipment in the tire industry, such as DIN abrasion, Akron abrasion, and Lambourn abrasion, cannot accurately characterize the wear performance of tires. The ABS control slippage during vehicle acceleration and braking provides sufficient grip in contact with the road surface, which is the most critical cause of tire wear. The wear performance of rubber at different slippage is a key factor affecting tire life. In this study, three compounds were developed, differing significantly in hardness, modulus, and the filling ratio of silica, to be manufactured as tire tread. The slippage was calculated with the results of the tire pattern model and pressure blanket tests. Subsequent wear performance tests were conducted on a fully automated wear testing machine under different slippage. Compared to the DIN and Cut-chip test results, the correlation with the taxi road test outcomes was enhanced when different slip rates were considered. This study introduces a novel method for assessing wear by calculating the tire slippage. By accounting for variables such as tire pattern and rubber rigidity, the slippage under ABS-controlled conditions was determined. Consequently, the wear performance demonstrated a stronger correlation with tire mileage as evidenced by the taxi road tests.</div></div>","PeriodicalId":20628,"journal":{"name":"Polymer Testing","volume":"142 ","pages":"Article 108684"},"PeriodicalIF":5.0,"publicationDate":"2025-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143172168","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
A comprehensive review of research on organic-based phase-change thermal interface materials for thermal management of electric devices: Methods, performance, and applications
IF 5 2区 材料科学
Polymer Testing Pub Date : 2025-01-01 DOI: 10.1016/j.polymertesting.2024.108677
Wondu Lee , Jooheon Kim
{"title":"A comprehensive review of research on organic-based phase-change thermal interface materials for thermal management of electric devices: Methods, performance, and applications","authors":"Wondu Lee ,&nbsp;Jooheon Kim","doi":"10.1016/j.polymertesting.2024.108677","DOIUrl":"10.1016/j.polymertesting.2024.108677","url":null,"abstract":"<div><div>Efficient thermal management is crucial for the optimal performance and longevity of electronic devices. With continuous advancements in technology and the ongoing miniaturization of electronic components, the requirement for effective heat-dissipation materials has become increasingly imperative. In this regard, organic phase-change materials (PCMs) have emerged as promising candidates for thermal management applications due to their unique properties. This paper explores the utilization of organic PCM-based heat dissipation materials for electronic devices, aiming to enhance their thermal performance and reliability. Through a comprehensive review of recent research and developments in this field, the paper discusses the fundamental principles underlying the thermal properties of organic PCMs and their suitability for electronic applications. The paper also discusses the challenges and opportunities associated with the integration of organic PCM-based materials into electronic devices, emphasizing the importance of addressing issues such as material compatibility, durability, and scalability. Overall, this review provides valuable insights into the utilization of organic PCM-based materials as efficient heat dissipation solutions for electronic devices, contributing to the advancement of thermal management technologies in the electronics industry.</div></div>","PeriodicalId":20628,"journal":{"name":"Polymer Testing","volume":"142 ","pages":"Article 108677"},"PeriodicalIF":5.0,"publicationDate":"2025-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143173126","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
The nonlinear viscoelasticity and its asymmetry of UV-cured resin under large amplitude oscillatory axial (LAOA) loading
IF 5 2区 材料科学
Polymer Testing Pub Date : 2025-01-01 DOI: 10.1016/j.polymertesting.2024.108661
Qiang Zhang , Yangguang Xu , Rui Xiao , Xiangyu Li
{"title":"The nonlinear viscoelasticity and its asymmetry of UV-cured resin under large amplitude oscillatory axial (LAOA) loading","authors":"Qiang Zhang ,&nbsp;Yangguang Xu ,&nbsp;Rui Xiao ,&nbsp;Xiangyu Li","doi":"10.1016/j.polymertesting.2024.108661","DOIUrl":"10.1016/j.polymertesting.2024.108661","url":null,"abstract":"<div><div>Solid viscoelastic materials often undergo large amplitude oscillatory axial (LAOA) loading and exhibit complex asymmetric nonlinear viscoelasticity in many practical applications. The methods used to analyze the nonlinear viscoelasticity of non-Newtonian fluid under large amplitude oscillatory shear (LAOS) cannot be directly applied to the corresponding situation of solid viscoelastic materials due to strict symmetry of LAOS. In this work, a typical UV-cured resin mainly used for 3D printing is chosen to investigate the nonlinear viscoelasticity and its asymmetry under LAOA loading. Based on Fourier transform, the geometric description of stress–strain curve is used to quantitatively characterize the asymmetric nonlinear viscoelasticity. Further, the global asymmetry ratios of nonlinear viscoelasticity under LAOA loading are developed based on the sequence of physical process (SPP) approach throughout the entire oscillatory cycle. We also define an asymmetric ratio of nonlinear viscoelasticity with clear physical meaning from the perspective of energy, which can comprehensively characterize the nonlinear elastic and viscous behavior during the tensile and compressive phases within an oscillatory cycle. Besides, the influences of oscillatory frequency and UV exposure time on asymmetric nonlinear viscoelasticity of UV-cured resin under LAOA loading can be captured as well. These approaches are suitable for evaluating the asymmetric nonlinear viscoelasticity of a large category of viscoelastic solid materials under LAOA loading, which is crucial for analyzing the nonlinear viscoelastic mechanism and for corresponding engineering applications.</div></div>","PeriodicalId":20628,"journal":{"name":"Polymer Testing","volume":"142 ","pages":"Article 108661"},"PeriodicalIF":5.0,"publicationDate":"2025-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143173206","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
β-crystals aied greater energy absorbing ethylene–propylene rubber in polypropylene blends for outstanding low-temperature toughness
IF 5 2区 材料科学
Polymer Testing Pub Date : 2025-01-01 DOI: 10.1016/j.polymertesting.2024.108670
Ruimiao Liang , Wenwen Yu , Jiahao Shen , Zhiyi Zhang , Zaifu Lin , Jiayi Wang , Lan Jia , Feng Chen , Yonggang Shangguan , Qiang Zheng
{"title":"β-crystals aied greater energy absorbing ethylene–propylene rubber in polypropylene blends for outstanding low-temperature toughness","authors":"Ruimiao Liang ,&nbsp;Wenwen Yu ,&nbsp;Jiahao Shen ,&nbsp;Zhiyi Zhang ,&nbsp;Zaifu Lin ,&nbsp;Jiayi Wang ,&nbsp;Lan Jia ,&nbsp;Feng Chen ,&nbsp;Yonggang Shangguan ,&nbsp;Qiang Zheng","doi":"10.1016/j.polymertesting.2024.108670","DOIUrl":"10.1016/j.polymertesting.2024.108670","url":null,"abstract":"<div><div>Modulating the <em>β</em>-crystalline phase and adding elastomers have traditionally been used to overcome the brittleness of polypropylene (PP); however, the synergistic mechanisms of these components in enhancing low temperatures toughness remain insufficiently explored. A <em>β</em>-nucleating agent (TMB-5) was incorporated into the polypropylene/ethylene–propylene rubber (PP/EPR) system to address the challenges of enhancing low-temperature toughness. Under an extreme low-temperature condition of −40 °C, the PP/EPR/TMB-5 blends exhibit a remarkable enhancement in low-temperature toughness compared with PP/EPR blends, showing a 138 % increase to reach 38.3 kJ/m<sup>2</sup>. In addition, these blends demonstrate an 8.47 % increase in tensile strength at room temperature. The addition of TMB-5 provides numerous nucleation sites that facilitate the <em>β</em>-crystallization of polypropylene, leading to an increased content of <em>β</em>-crystals and a reduction in crystal grain size. Broadband dielectric relaxation spectroscopy shows that the constrained relaxation of EPR near the crystals shifts to higher temperatures with the formation of <em>β</em>-crystals. The lamellar structure of the <em>β</em>-crystals prevents the aggregation of EPR rubber domains during cooling process, resulting in reduced rubber particle spacing. Observations of remarkable shear deformation and extensive stress-whitening areas on the fracture surfaces of PP/EPR/TMB-5 blends upon impact at −40 °C, as opposed to PP/EPR blends, underpin that the lamellar structure of <em>β</em>-crystals within the composite material efficiently transmits stress further away, facilitating the involvement of more EPR particles in energy dissipation. This finding enables an in-depth investigation into the synergistic toughening mechanism and provides new insights into blends design with conventional rubber for extreme conditions.</div></div>","PeriodicalId":20628,"journal":{"name":"Polymer Testing","volume":"142 ","pages":"Article 108670"},"PeriodicalIF":5.0,"publicationDate":"2025-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143173207","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Synthesis of Fe3O4@MIL-101-OH/Chitosan for adsorption and release of doxorubicin
IF 5 2区 材料科学
Polymer Testing Pub Date : 2025-01-01 DOI: 10.1016/j.polymertesting.2024.108659
Iman Najafipour , Nafiseh Emami , Pegah Sadeh , Adonis Amoli , Sareh Mosleh-Shirazi , Ali Mohammad Amani , Hesam Kamyab , Shreeshivadasan Chelliapan , Seyed Reza Kasaee , Ehsan Vafa
{"title":"Synthesis of Fe3O4@MIL-101-OH/Chitosan for adsorption and release of doxorubicin","authors":"Iman Najafipour ,&nbsp;Nafiseh Emami ,&nbsp;Pegah Sadeh ,&nbsp;Adonis Amoli ,&nbsp;Sareh Mosleh-Shirazi ,&nbsp;Ali Mohammad Amani ,&nbsp;Hesam Kamyab ,&nbsp;Shreeshivadasan Chelliapan ,&nbsp;Seyed Reza Kasaee ,&nbsp;Ehsan Vafa","doi":"10.1016/j.polymertesting.2024.108659","DOIUrl":"10.1016/j.polymertesting.2024.108659","url":null,"abstract":"<div><div>This study reports the synthesis and characterization of a magnetic composite metal-organic framework, The Fe<sub>3</sub>O<sub>4</sub>@MIL-101-OH/Chitosan nanocomposite was used for the first time to adsorb and release the drug doxorubicin (DOX). The nanocomposite was characterized using scanning electron microscopy (SEM), Fourier transform infrared spectroscopy (FTIR), Brunauer-Emmett-Teller (BET), X-ray diffraction (XRD), and vibrating sample magnetometry (VSM). The characterization results showed that the synthesized nanocomposite has a crystalline structure and good magnetic properties. Also, this nanocomposite has a high specific surface area (610.36 m<sup>2</sup>/g). In this article, the effect of pH, contact time, and drug concentration on DOX adsorption were investigated, and the results showed that at optimal conditions, pH = 8, contact time = 90 min, and drug concentration is 350 ppm, the adsorption capacity of MIL-101-OH/Chitosan and Fe<sub>3</sub>O<sub>4</sub>@MIL-101-OH/Chitosan are equal to 185 and 174.3 mg/g. The adsorption data follows pseudo-second-order kinetic and Langmuir isotherm models. The adsorption was physical and reversible. As a result, drug release was checked. The Fe<sub>3</sub>O<sub>4</sub>@MIL-101-OH/Chitosan exhibited a controlled release over the period of 84 h at pH 5 and reached 80 % of the DOX release rate after 60 h. In conclusion, the Fe<sub>3</sub>O<sub>4</sub>@MIL-101-OH/Chitosan composite has great potential as a drug delivery system as a result of its high adsorption capacity and magnetic properties. This research provides a promising approach for the development of novel drug delivery systems for cancer therapy.</div></div>","PeriodicalId":20628,"journal":{"name":"Polymer Testing","volume":"142 ","pages":"Article 108659"},"PeriodicalIF":5.0,"publicationDate":"2025-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143171840","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Enhanced oxidation resistance of polyphenylene sulfide using organic–inorganic composite antioxidant via melt blending
IF 5 2区 材料科学
Polymer Testing Pub Date : 2025-01-01 DOI: 10.1016/j.polymertesting.2024.108679
Jian Xing , Rongnan Li , Zhenzhen Xu , Chunhong Zhu , Qingqing Ni
{"title":"Enhanced oxidation resistance of polyphenylene sulfide using organic–inorganic composite antioxidant via melt blending","authors":"Jian Xing ,&nbsp;Rongnan Li ,&nbsp;Zhenzhen Xu ,&nbsp;Chunhong Zhu ,&nbsp;Qingqing Ni","doi":"10.1016/j.polymertesting.2024.108679","DOIUrl":"10.1016/j.polymertesting.2024.108679","url":null,"abstract":"<div><div>Polyphenylene sulfide (PPS) has become the primary material for controlling gas emissions at high-temperature; however, the oxidation reactions of sulfur within PPS macromolecules can deteriorate the mechanical properties. In this study, to enhance the oxidation resistance of PPS, composite antioxidants were introduced. Composite antioxidants (GO-sHP) were prepared by chemically grafting semi-hindered phenol antioxidants (sHP) onto graphite oxide (GO) layers and then melt-blending them with PPS resin. The grafting of sHP onto the GO surface was achieved through esterification, which enhanced the thermal stability of GO. The resulting GO-sHP exhibited partial exfoliation and a uniform distribution within the PPS matrix. Owing to heterogeneous nucleation, the introduction of GO-sHP significantly enhanced the crystallinity (from 24.4 % to 59.9 %), crystal perfection and tensile properties (from 88.25 MPa to 97.55 MPa) of PPS. The thermal decomposition residue of PPS increased from 45.1 % to 50.8 % and the dynamic oxidation induction temperature of PPS was also significantly improved (increased by 18.1 °C) by the addition of GO-sHP. Moreover, lower chromatic value changes (from 8.25 to 0.95), higher tensile strength retention (from 94.59 % to 98.57 %) and greater C–S bond content (from 10.9 % to 54.4 %) were achieved after oxidation treatment. Additionally, the antioxidative mechanism of GO-sHP on PPS revealed that GO-sHP inhibits the formation of S=O bonds, retards the breakage of C–S bonds, eliminates the oxidative free radicals, and restricts the diffusion of free radicals and oxidizing substances within the PPS matrix.</div></div>","PeriodicalId":20628,"journal":{"name":"Polymer Testing","volume":"142 ","pages":"Article 108679"},"PeriodicalIF":5.0,"publicationDate":"2025-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143172164","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Quantitative characterization of crystallinity in semi-crystalline fluoropolymer through 19F LF-NMR relaxometry 用19F LF-NMR弛豫法定量表征半结晶含氟聚合物的结晶度
IF 5 2区 材料科学
Polymer Testing Pub Date : 2024-12-01 DOI: 10.1016/j.polymertesting.2024.108654
Zhangyu Wu , Xianru He , Chunhua Zhu , Huaisong Yong , Xueyan Zhao
{"title":"Quantitative characterization of crystallinity in semi-crystalline fluoropolymer through 19F LF-NMR relaxometry","authors":"Zhangyu Wu ,&nbsp;Xianru He ,&nbsp;Chunhua Zhu ,&nbsp;Huaisong Yong ,&nbsp;Xueyan Zhao","doi":"10.1016/j.polymertesting.2024.108654","DOIUrl":"10.1016/j.polymertesting.2024.108654","url":null,"abstract":"<div><div>Crystallinity is important to the properties of a semi-crystalline fluoropolymer, such as solubility, mechanical property, bonding strength, etc. This study extended the use of <sup>19</sup>F Low-Field Nuclear Magnetic Resonance (<sup>19</sup>F LF-NMR) to the measurement of crystallinity in the semi-crystalline fluoropolymer F2314, which is the copolymer of vinylidene fluoride (VDF) and chlorotrifluoroethylene (CTFE) with a molar ratio of 1:4 and commonly used as binder in polymer-bonded explosives (PBXs). Based on the difference between spin-spin relaxometry of the <sup>19</sup>F in crystalline region and in amorphous region, the crystallinity of F2314 can be qualitatively characterized. The obtained crystallinity exhibited a positive correlation to the time duration of thermal treatment, which is in consistent to the result of Differential Scanning Calorimetry (DSC) and X-Ray Diffraction (XRD). Moreover, <sup>19</sup>F LF-NMR detected the slight decrease in segmental motion of crystalline region with the increase of crystallinity, and on-line monitored the evolution of segmental motion during heating. This study not only demonstrates the practicality and reliability of <sup>19</sup>F LF-NMR in quantification of crystallinity, but also laid the foundation for in-situ characterization of fluoropolymers in PBXs in future work.</div></div>","PeriodicalId":20628,"journal":{"name":"Polymer Testing","volume":"141 ","pages":"Article 108654"},"PeriodicalIF":5.0,"publicationDate":"2024-12-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142748467","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Negative temperature coefficient effect of TPU/SWCNT/PEDOT:PSS polymer matrices for wearable temperature sensors TPU/SWCNT/PEDOT:PSS聚合物基体对可穿戴温度传感器的负温度系数效应
IF 5 2区 材料科学
Polymer Testing Pub Date : 2024-12-01 DOI: 10.1016/j.polymertesting.2024.108652
Yeongu Choi , Minhyeok Kim , Hongyun So
{"title":"Negative temperature coefficient effect of TPU/SWCNT/PEDOT:PSS polymer matrices for wearable temperature sensors","authors":"Yeongu Choi ,&nbsp;Minhyeok Kim ,&nbsp;Hongyun So","doi":"10.1016/j.polymertesting.2024.108652","DOIUrl":"10.1016/j.polymertesting.2024.108652","url":null,"abstract":"<div><div>Composite-based temperature sensors utilizing the negative temperature coefficient (NTC) effect have gained significant attention across various fields, particularly in healthcare. However, the development of innovative, highly linear, and high-performance NTC-based temperature sensors remains a challenge. In this study, we developed a composite temperature sensor comprising thermoplastic polyurethane (TPU), single-walled carbon nanotubes (SWCNTs), and poly(3,4-ethylenedioxythiophene):poly(styrene sulfonate) (PEDOT:PSS). A series of performance tests demonstrated that the TPU/SWCNT/PEDOT:PSS (TSP) composite effectively monitors temperature variations with both linearity and superior performance, attributed to the synergistic NTC effects of SWCNTs and PEDOT:PSS. This flexible temperature sensor retained its sensing functionality after repeated cycles of temperature fluctuations and multiple bending tests. Moreover, due to the unique properties of CNTs, the TSP sensor exhibited photothermal responses, showing highly sensitive resistance changes upon exposure to infrared radiation. The TSP sensor proved to be effective for various practical applications, including biosignal monitoring through thermal detection, temperature tracking during phone charging, and accurate temperature sensing on curved surfaces. Additionally, non-contact heat detection can be reliably performed regardless of whether tensile stress is applied. These findings underscore the immense potential of TSP sensors for future use in wearable healthcare technologies.</div></div>","PeriodicalId":20628,"journal":{"name":"Polymer Testing","volume":"141 ","pages":"Article 108652"},"PeriodicalIF":5.0,"publicationDate":"2024-12-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142748509","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
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