Polymer Journal最新文献

{"title":"CO2 gas-triggered wettability control of silylation-modified CNC films by manipulating the surface structure and introducing tertiary amino groups","authors":"Hiroyuki Taniyama, Koji Takagi","doi":"10.1038/s41428-024-00888-8","DOIUrl":"10.1038/s41428-024-00888-8","url":null,"abstract":"Here, cellulose nanocrystal (CNC) films were chemically modified in a two-stage process to realize surface wettability control through the introduction of CO2 gas. In addition to controlling the surface structure of the silylation-modified CNC film, functional groups derived from silane compounds were installed, and the corresponding effects on the resulting chemical modification were investigated. In the first stage, methyltriethoxysilane (MTES) and hexyltriethoxysilane (HTES) combined with tetraethoxysilane (TEOS) were subjected to condensation under alkaline conditions. In the second stage, (3-(N,N-dimethylamino)propyl)trimethoxysilane (DMAPS) generated an amino group to control the surface wettability by adsorption CO2 gas. Then, the silylation-modified CNC film was fabricated on a glass substrate by spin coating. Fourier transform infrared (FT-IR), nuclear magnetic resonance (29Si-NMR), and X-ray photoelectron spectroscopy (XPS) inspection indicated that the silane compounds were bonded to the CNC film surface and that tertiary amino groups were successfully introduced. The surface structure of the silylation-modified CNC film was analyzed by atomic force microscopy (AFM), and the surface roughness calculating indicated a root-mean-square roughness (RMS) of 4.2 nm. The water contact angles before and after the CO2 gas treatment were evaluated as 73o and 22o, respectively. The modification of cellulose nanocrystal film using alkyl silane and silane containing tertiary amino groups was performed in a suspension state. Control of the surface structure and functionalization by silane compounds was conducted in the two-stage process. Wettability change property of the silylation-modified CNC triggered by CO2 was demonstrated.","PeriodicalId":20302,"journal":{"name":"Polymer Journal","volume":"56 6","pages":"609-617"},"PeriodicalIF":2.8,"publicationDate":"2024-02-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.nature.com/articles/s41428-024-00888-8.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139769496","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Melt adsorption of poly(tert-butyl methacrylate) and poly(ethyl methacrylate) on silica studied with chip nanocalorimetry","authors":"Minato Ishihara, Tomoya Watanabe, Toyoaki Hirata, Takashi Sasaki","doi":"10.1038/s41428-024-00895-9","DOIUrl":"10.1038/s41428-024-00895-9","url":null,"abstract":"Irreversible adsorption of polymer chains from a melt on a substrate surface can be strongly affected by interfacial interactions. In this study, we examined the adsorption of two polymers, poly(tert-butyl methacrylate) (PtBMA) and poly(ethyl methacrylate) (PEMA), on a silica surface at temperatures above their glass transition temperatures. The degree of adsorption γ(t) over time was evaluated with variations of storage heat capacity determined with alternating current chip nanocalorimetry (in-situ measurement of a buried interface). γ(t) revealed two-step profiles for both polymers. At the second stage of adsorption (regime II), the slope of a plot of γ(t) vs. log t increased as adsorption proceeded; this trend has not been reported for other polymers and may be characteristic of the present polymers. The trend observed in regime II suggested that the unadsorbed free chains near the interface became less mobile and were incorporated into the adsorbed layer via interactions with the tails of the chains directly attached to the substrate surface. The increasing slope in regime II was more prominent for PtBMA than for PEMA. In addition, a difference was observed for PtBMA and PEMA in the atomic force microscopy images of the exposed adsorption layer surfaces. We examined the adsorption behavior of poly(tert-butyl methacrylate) (PtBMA) and poly(ethyl methacrylate) (PEMA), on a silica surface. Time-evolution of the degree of adsorption γ(t) was evaluated with chip nanocalorimetry. γ(t) revealed a two-step profile for both polymers. At the second stage of adsorption, the slope of γ(t) vs. log t increased as adsorption proceeded; this trend has not been reported for other polymers so far. In addition, atomic force microscopy images of the adsorbed layers revealed corresponding evolutions of the morphologies.","PeriodicalId":20302,"journal":{"name":"Polymer Journal","volume":"56 6","pages":"619-628"},"PeriodicalIF":2.8,"publicationDate":"2024-02-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.nature.com/articles/s41428-024-00895-9.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139769377","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Crystallinity improvements in cellulose II after multiple posttreatment cycles with a dilute NaOH solution","authors":"Yuki Kugo, Satoshi Nomura, Takuya Isono, Masashi Fujiwara, Toshifumi Satoh, Hirofumi Tani, Tomoki Erata, Kenji Tajima","doi":"10.1038/s41428-024-00890-0","DOIUrl":"10.1038/s41428-024-00890-0","url":null,"abstract":"The low crystallinity of cellulose II makes industrial use a major challenge. In our previous report, we proposed a mechanism for improvement of the crystallinity of cellulose II during posttreatment with a dilute NaOH solution. Specifically, rearrangements of the cellulose molecules occurred only near inaccessible surfaces through which NaOH penetrated, resulting in conversion into crystalline regions. To verify our proposed mechanism and to improve the crystallinity further, we performed both long-term single-cycle and multicycle posttreatments with dilute NaOH solutions. Multiple posttreatment cycles under optimal conditions increased the crystallinity by up to approximately 20%. In contrast, long-term single-cycle posttreatment led to crystallinity improvements of only up to approximately 10%. Changes in the proportions of the regions during multiple cycles after treatment supported our proposed mechanism. During multiple posttreatment cycles, the products were converted to crystalline regions only on the inaccessible surfaces enlarged by the previous posttreatment cycle, which increased the crystal sizes in each cycle. Optimization of the treatment times used during the multiple posttreatment cycles led to crystallinity improvements with fewer posttreatment cycles. Our investigations of the mechanism for crystallinity improvement will contribute to structural elucidation of cellulose II and the efficient preparation of highly crystalline cellulose II. The study on the improvement of the crystallinity of cellulose II by post-treatment with dilute NaOH solution showed that the crystallinity was significantly improved by post-treatment with multiple cycles. The NaOH in an aqueous NaOH solution penetrated only inaccessible surface regions, and cellulose rearrangement occurred only in these regions during post-treatment, improving crystal size. In the second and subsequent posttreatment cycles, cellulose rearrangement occurred only at the inaccessible surfaces expanded during the previous post-treatment cycle, crystallization progressed toward amorphous regions away from the initial crystalline regions.","PeriodicalId":20302,"journal":{"name":"Polymer Journal","volume":"56 5","pages":"517-527"},"PeriodicalIF":2.8,"publicationDate":"2024-02-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139769511","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Fluorophore-glucan conjugate for oligosaccharide sensing in aqueous media","authors":"Hiroki Kurohara, Yumiko Hori, Munenori Numata, Gaku Fukuhara","doi":"10.1038/s41428-024-00889-7","DOIUrl":"10.1038/s41428-024-00889-7","url":null,"abstract":"The ability to sense saccharides in aqueous media using conventional supramolecular approaches was a turning point in modern chemistry. Herein, we performed oligosaccharide sensing using fluorophore-modified branched glucans. Through the newly developed glucan-based chemosensor, acarbose sensing was achieved in a selectively and sensitive manner. The optical properties and morphological changes in the chemosensor were investigated, revealing that the globule-to-coaggregation process plays a key role in oligosaccharide sensing. The fluorophore-modified glucan, TPE-6BG3 adopts an extended, random-coiled form in DMSO, which does not fluoresce. The morphology of the TPE-6BG3 chemosensor changes drastically to a dynamic globule in aqueous media. The dynamic, “induced-fit” globule selectively and sensitively recognizes the medicinally-useful tetrasaccharide, acarbose via glucan-saccharide coaggregation.","PeriodicalId":20302,"journal":{"name":"Polymer Journal","volume":"56 5","pages":"473-480"},"PeriodicalIF":2.8,"publicationDate":"2024-02-07","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.nature.com/articles/s41428-024-00889-7.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139769536","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Hydrogel particles for CO2 capture","authors":"Yu Hoshino, Shoma Aki","doi":"10.1038/s41428-023-00850-0","DOIUrl":"10.1038/s41428-023-00850-0","url":null,"abstract":"Capturing CO2 from various sources, such as postcombustion exhaust gases and the atmosphere, is essential for a sustainable human society. Effective CO2 separation materials such as adsorbents and membranes are of utmost importance in efficient CO2 capture. This short review is focused on CO2 separation materials consisting of hydrogel particles. The first chapter introduces stimuli-responsive micro- and nanogel particles that reversibly absorb CO2 in response to thermal stimuli. The development of temperature-responsive hydrogel films comprising gel particles for reversible CO2 capture is introduced. The importance of choosing amines with optimal pKa values for efficient CO2 capture from various sources is explained in detail. The assembly of CO2 separation membranes consisting of amine-containing hydrogel particles is introduced in the final chapter. The paper highlights the promise of separation materials consisting of hydrogel particles for efficient CO2 capture from postcombustion gases and air and the prospects for further advances in this area. In this short review, we focus on the development of CO2 separation materials consisting of hydrogel particles. The review starts with development of stimuli responsive micro- and nano-gel particles that reversibly absorb CO2 isn response. The next chapter focuses on the development of temperature-responsive hydrogel films consisting of gel particles that reversibly absorb CO2 and the importance of optimizing the pKa values of the amines in the particles. In the end, assembly of defect-free nano-meter-thick CO2 separation membranes consisting of the amine containing hydrogel particles are introduced.","PeriodicalId":20302,"journal":{"name":"Polymer Journal","volume":"56 5","pages":"463-471"},"PeriodicalIF":2.8,"publicationDate":"2024-02-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.nature.com/articles/s41428-023-00850-0.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139664769","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Preparation of molecularly well-defined silicone resins based on trifluoropropyl-substituted trisilanol and their thermal, mechanical, and UV-resistance properties","authors":"Miku Kosaka, Taishi Nakano, Kenji Kanaori, Hiroaki Imoto, Kensuke Naka","doi":"10.1038/s41428-024-00886-w","DOIUrl":"10.1038/s41428-024-00886-w","url":null,"abstract":"We prepared flexible free-standing films of trifluoropropyl-substituted open-cage silsesquioxane-pendant polysiloxane by optimizing the sol-gel reaction conditions of tris(dimethoxysilyl-ethyl-dimethylsiloxy)-heptatrifluoropropyl-substituted open-cage silsesquioxane (1). The polycondensation of 1 was fully achieved even at 50 °C for 6 h under vacuo. 29Si CP-MAS NMR analysis indicated that the flexible free-standing films, polycondensed at 50 °C and 180 °C, included cyclotrisiloxane (D3) and linear siloxane (Dlinear) structures. The elastic modulus and decomposition temperature at 5% mass weight loss (Td5) of the product by polycondensation at 180 °C under N2 were significantly greater than those for the 50 °C product. Significant changes in the UV‒vis spectra of the resulting transparent films were not observed even after 13 days of UV irradiation in air. In contrast, UV irradiation of the isobutyl-substituted counterpart under air clearly caused a decrease in its transmittance due to autoxidative degradation. Free-standing films of trifluoropropyl-substituted open-cage silsesquioxane-pendant polysiloxane by optimizing sol-gel reaction condition of tris(dimethoxysilyl-ethyl-dimethylsiloxy)-heptatrifluoropropyl-substituted open-cage silsesquioxane. Elastic modulus and the decomposition temperature for 5% weight loss under N2 of the product by polycondensation at 180 °C were significantly higher than that by polycondensation at 50 °C. Significant changes in the UV-vis spectra of the resulting transparent films were hardly observed even after 13 days of UV irradiation.","PeriodicalId":20302,"journal":{"name":"Polymer Journal","volume":"56 5","pages":"481-489"},"PeriodicalIF":2.8,"publicationDate":"2024-02-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139664920","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Selective N-alkylation catalyzed by polymer gels with crosslinked domains containing iridium complexes","authors":"Shohichi Furukawa, Hiroki Takeshita, Ken-ichi Fujita, Shohei Ida","doi":"10.1038/s41428-024-00885-x","DOIUrl":"10.1038/s41428-024-00885-x","url":null,"abstract":"Polymer gel catalysts are attractive due not only to their recyclability but also to the unique reaction environment in the internal space of the network structure. Appropriate design of the nanostructure around catalytically active sites in the gel network is particularly important. In this work, we aimed to control the activity and selectivity of the iridium-catalyzed N-alkylation of amine substrates with alcohols by incorporating an iridium complex into the crosslinked domain (CD) nanostructure of amphiphilic gels. A variety of gels with homogeneously dispersed CD structures containing iridium complexes with various crosslinking densities were prepared by the reversible addition–fragmentation chain transfer (RAFT) polymerization of N-isopropylacrylamide and an iridium complex monomer using a poly(N,N-dimethylacrylamide) macro-chain transfer agent (CTA) in the presence of a divinyl crosslinker. The resulting CD gel showed catalytic activity for the N-alkylation of aniline with benzyl alcohol, and importantly, the steric effect of the CD structure allowed the selective formation of a secondary amine product by controlling the access of the substrate to the iridium complex. Thus, we demonstrated selectivity control through the design of the nanospace surrounding the catalytic center using a nanostructured amphiphilic gel. To develop a novel gel catalyst system for a selective reaction, we prepared a variety of gels with homogeneously dispersed crosslinked domain (CD) structures containing iridium complexes with various crosslinking densities. The designed CD gel catalyst catalyzed the N-alkylation of aniline with benzyl alcohol, and the steric effect of the CD structure allowed the selective formation of the secondary amine product by controlling the access of the substrate to the iridium complex.","PeriodicalId":20302,"journal":{"name":"Polymer Journal","volume":"56 5","pages":"561-565"},"PeriodicalIF":2.8,"publicationDate":"2024-01-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.nature.com/articles/s41428-024-00885-x.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139584140","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Photooxidative degradation and fragmentation behaviors of oriented isotactic polypropylene","authors":"Yingjun An, Tomoko Kajiwara, Adchara Padermshoke, Thinh Van Nguyen, Sinan Feng, Hiroyasu Masunaga, Yutaka Kobayashi, Hiroshi Ito, Sono Sasaki, Atsuhiko Isobe, Atsushi Takahara","doi":"10.1038/s41428-023-00876-4","DOIUrl":"10.1038/s41428-023-00876-4","url":null,"abstract":"The photooxidative degradation and fragmentation behaviors of isotactic polypropylene (itPP) were simulated in laboratory after various postconditions, such as quenching, gradual cooling and drawing, using an artificial weathering machine and a blender. The crystallinity of the itPP films and orientation of the molecular chains play important roles in the photooxidation of the itPP films. Compared to quenched itPP films with the same ultraviolet (UV) exposure time, highly oriented itPP films and gradually cooled itPP films with higher crystallinity exhibited a lower rate of photooxidative degradation. To clarify the photooxidative degradation mechanism, the surface morphology, chemical structure, and microstructure of the UV-exposed itPP films were investigated using scanning electron microscopy, infrared spectroscopy, differential scanning calorimetry, and wide- and small-angle X-ray scattering. Photooxidative degradation was inhibited as the orientation degree of the itPP film increased. These results indicate that photooxidation likely occurs in the amorphous phase of itPP. Oriented molecular chains effectively slowed the photooxidative degradation of the itPP films. The artificial fragmentation test of UV-exposed itPP films showed that itPP films with lower crystallinity and orientation degrees were crushed into microplastics that were much smaller in size than those with higher crystallinity or orientation degrees. Photooxidation and fragmentation behaviors of itPP were studied. Photooxidation likely occurred in the amorphous regions of itPP due to the higher oxygen diffusion. Surface deterioration was observed on the UV-exposed itPP films. Pressed films exhibited much denser cracks compared to uniaxially oriented itPP films. Notably, cracks in the uniaxially oriented itPP films were formed along the direction of orientation and decreased with increasing draw ratio. The crystalline structure and oriented molecular chains notably inhibited the photooxidative degradation and fragmentation of the itPP films.","PeriodicalId":20302,"journal":{"name":"Polymer Journal","volume":"56 4","pages":"379-389"},"PeriodicalIF":2.8,"publicationDate":"2024-01-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.nature.com/articles/s41428-023-00876-4.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139552875","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Characteristics of the steam degradation of poly(lactic acid) and poly(3-hydroxybutyrate-co-3-hydroxyhexanoate)","authors":"Zhuze Shao, Shogo Kumagai, Yuko Saito, Toshiaki Yoshioka","doi":"10.1038/s41428-024-00883-z","DOIUrl":"10.1038/s41428-024-00883-z","url":null,"abstract":"The introduction of biodegradable plastics is considered a practical approach to reducing plastic waste accumulation in the environment. Regardless of their biodegradability, plastics should be recycled to effectively utilize and circulate carbon as a resource. Herein, the use of pyrolysis was examined as a method for recycling two common biobased/biodegradable plastics: PLA and PHBH. The pyrolysis of PLA produced lactides (10.7 wt% at 400 °C), but the yield was decreased when the pyrolysis temperature was increased. The presence of steam promoted the hydrolysis of PLA: a steam concentration of 25 vol % increased, the production of lactides at 400 °C to 17.4 wt%. The pyrolysis of PHBH primarily yielded crotonic acid (30.1 wt% at 400 °C), and the yield increased with increasing pyrolysis temperature (71.8 wt% at 800 °C). Steam injection increased the hydrolysis of oligomers, resulting in a 76.1 wt% yield of crotonic acid at 600 °C with a steam concentration of 25 vol %. Thus, we determined that hydrolysis and pyrolysis progress simultaneously under a steam atmosphere, increasing the chemical feedstock recovery from PLA and PHBH. These findings may lead to the proposal of effective degradation methods for treating biobased/biodegradable plastic wastes and ways to maximize the conversion efficiency and target product yields. Steam decomposition of poly(lactic acid) (PLA) and poly(3-hydroxybutyrate-co-3-hydroxyhexanoate) (PHBH) enhanced the recovery of chemical feedstock compared with simple pyrolysis. Steam enhanced the hydrolysis of PLA and resulted in the formation of short-chain compounds with hydroxyl end groups, and subsequent pyrolysis of them improved lactide recovery. Monomer production from PHBH was also enhanced by simultaneous hydrolysis and pyrolysis under steam decomposition.","PeriodicalId":20302,"journal":{"name":"Polymer Journal","volume":"56 4","pages":"455-462"},"PeriodicalIF":2.8,"publicationDate":"2024-01-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.nature.com/articles/s41428-024-00883-z.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139552984","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Synthesis and urea adsorption capacity of a strong, acidic hollow nanoparticle","authors":"Yiheng Huang, Yifan Jiang, Youyou Mou, Maoyun Li, Hong Yu, Jia-Wei Shen, Yong Guo","doi":"10.1038/s41428-024-00884-y","DOIUrl":"10.1038/s41428-024-00884-y","url":null,"abstract":"To increase the quality of life of dialysis patients while maintaining economic efficiency, the concept of a wearable artificial kidney was proposed and designed approximately two decades ago. However, the primary challenge in the development of a wearable artificial kidney is the adequate removal of urea from dialysate due to the chemical inertness of urea under physiological conditions. Herein, a hollow polystyrene nanoparticle with sulfonic acid groups, named H-CPS-SO3H, was synthesized that could efficiently adsorb urea. H-CPS-SO3H was produced in three steps. First, a core-shell polystyrene nanoparticle with a linear core and cross-linked shell was prepared using modified emulsion polymerization. Second, the core-shell nanoparticles were treated with DMF to create hollow nanoparticles. Finally, the hollow nanoparticles were subjected to sulfuric acid treatment to produce H-CPS-SO3H, which was confirmed by both TEM and FTIR analysis. The urea adsorption capacity and kinetics of the as-synthesized H-CPS-SO3H were evaluated in a 30 mM urea aqueous solution. The results indicated that H-CPS-SO3H had a urea absorption capacity of up to 1 mmol/g, which was achieved after only two hours of adsorption at 37 °C. These findings demonstrated the high adsorption capacity and favorable adsorption kinetics of H-CPS-SO3H. Additionally, the adsorption capacity first increased and then slightly decreased with decreasing pH or increasing solution volume, while the adsorption capacity sharply decreased with increasing ionic strength. The results suggest that the prepared H-CPS-SO3H has promising application potential in the field of wearable artificial kidney devices. Achieving a wearable artificial kidney hinges on overcoming the critical challenge of developing efficient urea adsorption materials for dialysate regeneration. An acidic hollow polystyrene nanoparticle was synthesized by modified emulsion polymerization, DMF etching and sulfuric acid treatment sequentially. The nanoparticles had a urea absorption capacity of up to 1 mmol/g after two hours of adsorption in a 30 mM urea aqueous solution at 37 °C. Additionally, the adsorption capacity dramatically increased with increasing urea concentration, while sharply decreased with increasing ionic strength.","PeriodicalId":20302,"journal":{"name":"Polymer Journal","volume":"56 5","pages":"553-560"},"PeriodicalIF":2.8,"publicationDate":"2024-01-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139507209","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}