Phosphorus, Sulfur, and Silicon and the Related Elements最新文献_第6页

Composition and structural identification of silicon particles in diamond wire saw silicon powder 金刚石绳锯硅粉中硅颗粒的组成和结构鉴定

IF 1.3 4区化学

Phosphorus, Sulfur, and Silicon and the Related Elements Pub Date : 2024-01-02 DOI: 10.1080/10426507.2023.2242996

Tian Zhang , Kuixian Wei , Shicong Yang , Wenhui Ma

{"title":"Composition and structural identification of silicon particles in diamond wire saw silicon powder","authors":"Tian Zhang , Kuixian Wei , Shicong Yang , Wenhui Ma","doi":"10.1080/10426507.2023.2242996","DOIUrl":"10.1080/10426507.2023.2242996","url":null,"abstract":"<div>In this study, the content and calculation equations of each substance in diamond wire saw silicon powder (DWSSP) were determined. Initially, the presence of amorphous SiO2 was proven by crystal transformation. Then, the SiO2 content was determined by SiO2-CaO phase diagram analysis, and the SiOx content was determined by using the oxygen conservation rule. The variation trend between the SiO2, SiOx, and Si contents and the O content was determined, according to the calculated SiO2 and SiOx content. In addition, linear fitting was performed on the SiO2, SiOx, and Si contents of five DWSSP raw materials, and a calculation equation for SiO2, SiOx, and Si was obtained through the total O content. The three-layer structure of DWSSP was revealed, the DWSSP consisting of a Si core, an intermediate SiOx layer, and a SiO2 shell. This study can accurately identify the content of SiO2, SiOx, and Si in DWSSP based on the detected oxygen content, and provide a better theoretical basis for the process selection and design for silicon recovery or high value materials preparation.</div>","PeriodicalId":20056,"journal":{"name":"Phosphorus, Sulfur, and Silicon and the Related Elements","volume":null,"pages":null},"PeriodicalIF":1.3,"publicationDate":"2024-01-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"135741942","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Synthesis and applications of new chiral terpenyl organoselenium compounds 新手性萜基有机硒化合物的合成与应用

IF 1.3 4区化学

Phosphorus, Sulfur, and Silicon and the Related Elements Pub Date : 2024-01-02 DOI: 10.1080/10426507.2023.2243362

Jacek Ścianowski , Agata J. Pacuła-Miszewska , Anna Laskowska , Magdalena Obieziurska-Fabisiak

引用次数: 0

One-pot synthesis of (2,4,6-Trimethylbenzoyl)diphenylphosphine oxide from triphenylphosphine oxide 由三苯基氧化膦一步合成 (2,4,6-三甲基苯甲酰基) 二苯基氧化膦

IF 1.3 4区化学

Phosphorus, Sulfur, and Silicon and the Related Elements Pub Date : 2024-01-02 DOI: 10.1080/10426507.2023.2263132

Xianyang Xu , Jian-Qiu Zhang , Xin Wang , Teng Wang , Yan Liu , Li-Biao Han

引用次数: 0

Synthesis and Wittig olefination of (2-methyl-3-oxoisoindolin-1-yl)triphenylphosphonium tetrafluoroborate: facile access to 3-alkylidene-2-methylisoindolin-1-ones (2-甲基-3-氧代异吲哚啉-1-基)三苯基膦四氟硼酸盐的合成和 Wittig 烯化反应：3-亚烷基-2-甲基异吲哚啉-1-酮的简便获取途径

IF 1.3 4区化学

Phosphorus, Sulfur, and Silicon and the Related Elements Pub Date : 2024-01-02 DOI: 10.1080/10426507.2023.2263131

Wenhua Huang , Yan-Hong Wang

引用次数: 0

Design, synthesis, and biological activity of new 8-decylthio-10-methylthio-pyrimido[5,4-e][1,2,4]triazolo[1,5-c]pyrimidine derivatives 新的 8-癸硫基-10-甲硫基嘧啶并[5,4-e][1,2,4]三唑并[1,5-c]嘧啶衍生物的设计、合成和生物活性

IF 1.3 4区化学

Phosphorus, Sulfur, and Silicon and the Related Elements Pub Date : 2024-01-02 DOI: 10.1080/10426507.2023.2245528

Huixiang Nie , Linghui He , Anlin Zhao , Haijin Huang , Tao Wang , Jin Luo

{"title":"Design, synthesis, and biological activity of new 8-decylthio-10-methylthio-pyrimido[5,4-e][1,2,4]triazolo[1,5-c]pyrimidine derivatives","authors":"Huixiang Nie , Linghui He , Anlin Zhao , Haijin Huang , Tao Wang , Jin Luo","doi":"10.1080/10426507.2023.2245528","DOIUrl":"10.1080/10426507.2023.2245528","url":null,"abstract":"<div>A series of new 8-decylthio-10-methylthio-pyrimido[5,4-e][1,2,4]triazolo[1,5-c]pyrimidine derivatives was prepared and characterized by FTIR, 1H NMR, 13C NMR, and HRMS. The bioassay results revealed that the title compounds had moderate to excellent insecticidal activities against Aphis fabae at a concentration of 500 mg/L. Among them, 8-(decylthio)-2-((4-chlorophenoxy)methyl)-5-propyl-10-(methylthio)-5,6-dihydropyrimido[5,4-e][1,2,4]triazolo[1,5-c]pyrimidine (4l) exhibited the highest insecticidal activity, with 95% mortality. Moreover, 8-(decylthio)-2-((2,4-dichlorophenoxy)methyl)-5-propyl-10-(methylthio)-5,6-dihydropyrimido[5,4-e][1,2,4]triazolo[1,5-c]pyrimidine (4i) showed broad-spectrum postemergence herbicidal activities against Abutilon theophrasti, Amaranthus spinosus, Chenopodium album, Digitaria sanguinalis, Echinochloa crusgalli, and Setaria viridis, which were equivalent to the positive control flumetsulam. However, all new synthesized compounds displayed weak fungicidal activity against four kinds of phytopathogenic fungi including Botrytis cinerea, phytophythora capsici, Elsinoe fewcetti, and Diaporthe medusaea. Compound 4l with remarkable insecticidal activity, and compound 4i with excellent herbicidal activity could be promising lead compounds for further investigation.</div>","PeriodicalId":20056,"journal":{"name":"Phosphorus, Sulfur, and Silicon and the Related Elements","volume":null,"pages":null},"PeriodicalIF":1.3,"publicationDate":"2024-01-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"135114873","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Synthesis and properties of methanesulfonyl derivatives of diethyl esters of 5-(hydroxyalkylamino)-1,3-oxazol-4-yl-phosphonic acids 5-(羟基烷基氨基)-1,3-恶唑-4-基膦酸二乙酯甲磺酰衍生物的合成及其性质

IF 1.3 4区化学

Phosphorus, Sulfur, and Silicon and the Related Elements Pub Date : 2024-01-02 DOI: 10.1080/10426507.2023.2251639

O. V. Golovchenko , M. Yu. Brusnakov , Yu. O. Shabelko , V. S. Brovarets , R. M. Vydzhak , O. S. Bahrieieva , L. M. Potikha , S. V. Shishkina

{"title":"Synthesis and properties of methanesulfonyl derivatives of diethyl esters of 5-(hydroxyalkylamino)-1,3-oxazol-4-yl-phosphonic acids","authors":"O. V. Golovchenko , M. Yu. Brusnakov , Yu. O. Shabelko , V. S. Brovarets , R. M. Vydzhak ,  O. S. Bahrieieva , L. M. Potikha , S. V. Shishkina","doi":"10.1080/10426507.2023.2251639","DOIUrl":"10.1080/10426507.2023.2251639","url":null,"abstract":"<div>A number of {[4-(diethoxyphosphoryl)-2-R-1,3-oxazol-5-yl]amino}alkyl methanesulfonates were synthesized and the peculiarities of their reaction with triethylamine were studied. The influence of the structure of the 5-alkanolamine substituent on the efficiency of their transformation into 7-R-1-ethoxy-5-methyl-1,3,4,5-tetrahydro-1λ5-[1,3]oxazolo[4,5-c][1,5,2]oxazaphosphepine-1-ones was clarified. The structure of the [1,3]oxazolo[4,5-c][1,5,2]oxazaphosphepine derivatives has been reliably proven by elemental analysis, IR, 1H, 13C, and 31P NMR spectroscopy (including 1D and 2D experiments), mass spectrometry and single crystal X-ray diffraction. The oxazole cycle in [1,3]oxazolo[4,5-c][1,5,2]oxazaphosphepines is easily cleaved by water in an acidic environment, which leads to the formation of derivatives of the new heterocyclic system – N-(2-ethoxy-5-methyl-2-oxido-4-oxo-1,5,2-oxazaphosphepan-3-yl)arylamides.</div>","PeriodicalId":20056,"journal":{"name":"Phosphorus, Sulfur, and Silicon and the Related Elements","volume":null,"pages":null},"PeriodicalIF":1.3,"publicationDate":"2024-01-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"81272594","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Potassium salts catalyzed oxidative coupling of alkanethiols with sulfur: the effect of solid-liquid phase transfer of crown ether 钾盐催化烷硫醇与硫的氧化偶联：冠醚固液相转移的影响

IF 1.3 4区化学

Phosphorus, Sulfur, and Silicon and the Related Elements Pub Date : 2024-01-02 DOI: 10.1080/10426507.2023.2263134

Zhaoyang Xu , Zihan Zhang , Rui Wang , Fei Li , Heng Jiang

{"title":"Potassium salts catalyzed oxidative coupling of alkanethiols with sulfur: the effect of solid-liquid phase transfer of crown ether","authors":"Zhaoyang Xu , Zihan Zhang , Rui Wang , Fei Li , Heng Jiang","doi":"10.1080/10426507.2023.2263134","DOIUrl":"10.1080/10426507.2023.2263134","url":null,"abstract":"<div>Potassium salts (KA, A = anion) that catalyzed the oxidative coupling of alkanethiols (RSH) to dialkyl disulfide (R2S2) were investigated by using sulfur as oxidant and 18-crown-6 ether as phase transfer agent under solvent-free conditions at atmospheric pressure. Crown ether (15-crown-5 ether, 18-crown-6 ether, dibenzo-18-crown-6 ether) showed excellent solid-liquid phase transfer effect in solid KA catalyzed reaction. RS− is the key active species of the KA catalyzed reaction. The catalytic activity of KA is affected by the pKa of conjugated acid (HA) of anion A− in KA. The larger the pKa of the corresponding HA, the more active for KA to activate RSH to generate RS−. Among the KA investigated, the yield of (n-C8H17)2S2 for the K2CO3, K3PO4·3H2O and K2SnO3·3H2O catalyzed reaction reached more than 98.0%. The yield of R2S2 can reach more than 95.0% by 0.1 mol% 18-C-6 (based on sulfur) and 0.1 mol% K2CO3 (based on sulfur) catalyzed the oxidative coupling of different alkanethiols.</div>","PeriodicalId":20056,"journal":{"name":"Phosphorus, Sulfur, and Silicon and the Related Elements","volume":null,"pages":null},"PeriodicalIF":1.3,"publicationDate":"2024-01-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"135644679","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

One-pot synthesis and fluorescent property of novel syringaldehyde α-aminophosphonate derivatives 新型丁香醛α-氨基膦酸衍生物的一锅合成及其荧光性质

IF 1.3 4区化学

Phosphorus, Sulfur, and Silicon and the Related Elements Pub Date : 2023-01-01 DOI: 10.1080/10426507.2023.2187798

Si Ke , Duanyi Zhang , Yu Li , Ziwei Gong , Pengcheng Tang , Wanxia Tang

{"title":"One-pot synthesis and fluorescent property of novel syringaldehyde α-aminophosphonate derivatives","authors":"Si Ke , Duanyi Zhang , Yu Li , Ziwei Gong , Pengcheng Tang , Wanxia Tang","doi":"10.1080/10426507.2023.2187798","DOIUrl":"https://doi.org/10.1080/10426507.2023.2187798","url":null,"abstract":"<div>Seven novel syringaldehyde α-aminophosphonate derivatives (1–7) were synthesized based on syringaldehyde together with different aryl amines and diethyl phosphite in a one-pot, solvent free, and catalyst free reaction. All of the obtained compounds were characterized by analysis of their 1H NMR and 13C NMR, IR spectra, and FT mass spectra. The UV and fluorescence emission spectra of 1–7 were investigated in the concentration range of 0.1–250 μM. As the results, the maximum emission wavelength of 1–7 was observed between 600 and 700nm under the exciting wavelength of 250nm for 1–5 and 300nm for 6 and 7. The emission intensity is the strongest at a concentration of 60μm for 2, 3, and 5–7, 30μm for 1, and 0.1μm for 4.</div>","PeriodicalId":20056,"journal":{"name":"Phosphorus, Sulfur, and Silicon and the Related Elements","volume":null,"pages":null},"PeriodicalIF":1.3,"publicationDate":"2023-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"49700422","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Efficacy of an organic–inorganic hybrid phosphorus compound in corrosion mitigation of reinforcement steel in concrete. I. Gravimetric and electrochemical analysis 有机-无机杂化磷化合物对混凝土中钢筋的缓蚀效果。1、重量和电化学分析

IF 1.3 4区化学

Phosphorus, Sulfur, and Silicon and the Related Elements Pub Date : 2023-01-01 DOI: 10.1080/10426507.2023.2191959

M.V.S. Raju , K. Anjaneyula Naik , K. Chaitanya Kumar , S. Srinivasa Rao

引用次数: 0

A review on the synthesis and biological relevance of benzo[b]thiophene derivatives 苯并[b]噻吩衍生物的合成及其生物学意义综述

IF 1.3 4区化学

Phosphorus, Sulfur, and Silicon and the Related Elements Pub Date : 2023-01-01 DOI: 10.1080/10426507.2022.2145476

T.M. Dhanya , G. Anjali Krishna , D.P. Savitha , A.A. Shanty , K.M. Divya , Shenoi K. Priya , P.V. Mohanan

引用次数: 2