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Phosphorus, Sulfur, and Silicon and the Related Elements最新文献

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The chemical behavior of the different impurities present in Phosphogypsum: a review 磷石膏中不同杂质的化学性质综述
IF 1.3 4区 化学
Phosphorus, Sulfur, and Silicon and the Related Elements Pub Date : 2024-02-01 DOI: 10.1080/10426507.2023.2281489
Yassine Ennaciri , Mohammed Bettach
{"title":"The chemical behavior of the different impurities present in Phosphogypsum: a review","authors":"Yassine Ennaciri ,&nbsp;Mohammed Bettach","doi":"10.1080/10426507.2023.2281489","DOIUrl":"10.1080/10426507.2023.2281489","url":null,"abstract":"<div><p>Phosphogypsum (PG) is an acidic by-product that is created during the production of phosphoric acid using the sulfuric acid route. The management of PG poses a significant environmental challenge worldwide due to its large quantity and chemical composition. While PG primarily consists of calcium sulfate dihydrate, it also contains various impurities such as phosphorus, fluoride, heavy metals, and radionuclides. These toxic impurities, when present in high concentrations, can have adverse effects on the environment and human health. In this review, we provide a detailed examination of the behavior of the most abundant impurities found in PG. Furthermore, we discuss the factors that influence the presence of different types of impurities in PG. Understanding the overall behavior of these impurities is crucial for selecting appropriate environmental methods for PG management and identifying suitable avenues for its valorization.</p></div>","PeriodicalId":20056,"journal":{"name":"Phosphorus, Sulfur, and Silicon and the Related Elements","volume":"199 2","pages":"Pages 129-148"},"PeriodicalIF":1.3,"publicationDate":"2024-02-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"138513463","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Synthesis, synthetic interests, and biological activities of β-substituted vinylphosphonates β-取代乙烯基膦酸盐的合成、合成兴趣和生物活性
IF 1.3 4区 化学
Phosphorus, Sulfur, and Silicon and the Related Elements Pub Date : 2024-02-01 DOI: 10.1080/10426507.2023.2281472
Cécile Garzon , Mireille Attolini , Michel Maffei
{"title":"Synthesis, synthetic interests, and biological activities of β-substituted vinylphosphonates","authors":"Cécile Garzon ,&nbsp;Mireille Attolini ,&nbsp;Michel Maffei","doi":"10.1080/10426507.2023.2281472","DOIUrl":"10.1080/10426507.2023.2281472","url":null,"abstract":"<div><p>β-Substituted vinylphosphonates constitute an original class of organophosphorus reagents of which several compounds exhibit attractive biological properties. The review exemplifies and discusses the different synthetic methods described for their synthesis, which involve well known reactions, but also more specifically designed methods. In addition, the uses as synthetic intermediates as well as the therapeutic uses of the title compounds are also summarized.</p></div>","PeriodicalId":20056,"journal":{"name":"Phosphorus, Sulfur, and Silicon and the Related Elements","volume":"199 2","pages":"Pages 112-128"},"PeriodicalIF":1.3,"publicationDate":"2024-02-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"138513447","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Metal–organic frameworks HKUST-1 embedded in amino-functionalized SBA-15: Efficient catalytic reduction of 4-nitrophenol to 4-aminophenol 嵌入氨基功能化 SBA-15 的金属有机框架 HKUST-1：高效催化 4-硝基苯酚还原为 4-氨基苯酚
IF 1.3 4区 化学
Phosphorus, Sulfur, and Silicon and the Related Elements Pub Date : 2024-02-01 DOI: 10.1080/10426507.2023.2271116
Cheng Qian , Yibo Zhang , Xifeng Chen , Wei Wang , Jianglei Hu , Sara Khan
{"title":"Metal–organic frameworks HKUST-1 embedded in amino-functionalized SBA-15: Efficient catalytic reduction of 4-nitrophenol to 4-aminophenol","authors":"Cheng Qian ,&nbsp;Yibo Zhang ,&nbsp;Xifeng Chen ,&nbsp;Wei Wang ,&nbsp;Jianglei Hu ,&nbsp;Sara Khan","doi":"10.1080/10426507.2023.2271116","DOIUrl":"10.1080/10426507.2023.2271116","url":null,"abstract":"<div><p>The amino-functionalized SBA-15 silicon carrier (PMO-pr-NH<sub>2</sub>) was prepared by the one-pot method, and then HKUST-1 functional composites were synthesized by adsorption combined with in-situ preparation technology (HKUST-1@PMO-pr-NH<sub>2</sub>). A series of characterization techniques were used to analyze composites, such as BET, FTIR, TEM, XPS, TG, SEM, and XRD. The analysis showed that HKUST-1 was successfully prepared in the pores of the PMO-pr-NH<sub>2</sub> silicon-based carrier. The catalytic reduction activity and thermal stability of the composite material were investigated using the reaction of 4-nitrophenol (4-NP) to 4-aminophenol (4-AP). After 4 cycles, the catalytic performance of the composites was maintained without any obvious change.</p></div>","PeriodicalId":20056,"journal":{"name":"Phosphorus, Sulfur, and Silicon and the Related Elements","volume":"199 2","pages":"Pages 149-156"},"PeriodicalIF":1.3,"publicationDate":"2024-02-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"135405194","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Rh(I)-catalyzed enantioselective (3 + 2) transannulations of 1,2,3-thiadiazoles with P-chiral monodentate phosphines Rh(I)催化1,2,3-噻二唑与p -手性单齿膦的对映选择性(3 + 2)转环反应
IF 1.3 4区 化学
Phosphorus, Sulfur, and Silicon and the Related Elements Pub Date : 2024-02-01 DOI: 10.1080/10426507.2023.2281473
Hao Wei , Cunzhi Chen , Aijun Gao , Zhanhui Yang
{"title":"Rh(I)-catalyzed enantioselective (3 + 2) transannulations of 1,2,3-thiadiazoles with P-chiral monodentate phosphines","authors":"Hao Wei ,&nbsp;Cunzhi Chen ,&nbsp;Aijun Gao ,&nbsp;Zhanhui Yang","doi":"10.1080/10426507.2023.2281473","DOIUrl":"10.1080/10426507.2023.2281473","url":null,"abstract":"<div><p>As a proof of concept, <em>P</em>-chiral monodentate phosphines, which were inactive in promoting the transannulations of 1,2,3-thiadiazoles, were proven viable in the asymmetric catalytic (3 + 2) transannulations of 1,2,3-thiadiazoles with a strained bicyclic alkene. Polycyclic dihydrothiophenes with four newly formed stereocenters are generated in moderate 19-72% yields and 11-27% enantiopurities.</p></div>","PeriodicalId":20056,"journal":{"name":"Phosphorus, Sulfur, and Silicon and the Related Elements","volume":"199 2","pages":"Pages 157-161"},"PeriodicalIF":1.3,"publicationDate":"2024-02-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"138513446","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Visible light photoredox-catalyzed phosphorylation of α-bromostyrenes: a mild synthesis of β-ketophosphine oxides 可见光光氧化还原催化α-溴苯乙烯的磷酸化:β-酮膦氧化物的温和合成
IF 1.3 4区 化学
Phosphorus, Sulfur, and Silicon and the Related Elements Pub Date : 2024-02-01 DOI: 10.1080/10426507.2023.2281476
Rabin Kim , Dae Young Kim
{"title":"Visible light photoredox-catalyzed phosphorylation of α-bromostyrenes: a mild synthesis of β-ketophosphine oxides","authors":"Rabin Kim ,&nbsp;Dae Young Kim","doi":"10.1080/10426507.2023.2281476","DOIUrl":"10.1080/10426507.2023.2281476","url":null,"abstract":"<div><p>Visible light-mediated photocatalytic phosphorylation of α-bromostyrenes is described. The β-ketophosphine oxide derivatives were conveniently synthesized from α-bromostyrene derivatives, which are useful synthetic intermediates, using an inexpensive organic photocatalyst, Eosin Y.</p></div>","PeriodicalId":20056,"journal":{"name":"Phosphorus, Sulfur, and Silicon and the Related Elements","volume":"199 2","pages":"Pages 162-168"},"PeriodicalIF":1.3,"publicationDate":"2024-02-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"138542894","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Core-shell magnetic nanocomposite Fe3O4@SiO2@CS@POCl2-x for alcohols to alkyl halides transformation 核壳磁性纳米复合材料Fe3O4@SiO2@CS@POCl2-x用于醇类向烷基卤化物的转化
IF 1.3 4区 化学
Phosphorus, Sulfur, and Silicon and the Related Elements Pub Date : 2024-02-01 DOI: 10.1080/10426507.2023.2279614
Farzaneh Ebrahimzadeh , Arezoo Jamalain , Somaie Zaree
{"title":"Core-shell magnetic nanocomposite Fe3O4@SiO2@CS@POCl2-x for alcohols to alkyl halides transformation","authors":"Farzaneh Ebrahimzadeh ,&nbsp;Arezoo Jamalain ,&nbsp;Somaie Zaree","doi":"10.1080/10426507.2023.2279614","DOIUrl":"10.1080/10426507.2023.2279614","url":null,"abstract":"<div><p>In this study, we examined the efficiency of a new magnetic core-shell nanocomposite, Fe<sub>3</sub>O<sub>4</sub>@SiO<sub>2</sub>@CS@POCl<sub>2-x</sub> (NCP@ POCl<sub>2-x</sub>), which carries POCl<sub>2-x</sub> functional groups (where X can be 0, 1, or 2) on its surface. The nanocomposite was explored as a reagent for converting alcohols into alkyl halides using molecular bromine (Br<sub>2</sub>) or iodine (I<sub>2</sub>) as a model organic transformation. The conversion process demonstrated promising practical applications with ease of operation, and the pure product could be conveniently isolated through magnetic filtration, simplifying the synthesis process. The surface characteristics of the nanocomposite were thoroughly investigated using vibrating-sample magnetometer (VSM) spectrum analysis, field emission scanning electron microscopy (FESEM) images, and Fourier-transform infrared spectroscopy (FT-IR). TEM imaging also confirmed the core-shell structure of the nanocomposite, and XRD analysis revealed distinct peaks corresponding to the presence of Fe<sub>3</sub>O<sub>4</sub>. The study demonstrates that NCP@ POCl<sub>2-x</sub> is an effective reagent for alkyl halide transformations, offering various possibilities for applications in organic synthesis.</p></div>","PeriodicalId":20056,"journal":{"name":"Phosphorus, Sulfur, and Silicon and the Related Elements","volume":"199 2","pages":"Pages 169-177"},"PeriodicalIF":1.3,"publicationDate":"2024-02-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"138513464","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Synthetic methodologies and applications of chalcogen (S, Se, Te) ionic liquids: a review 查耳根（S、Se、Te）离子液体的合成方法和应用：综述
IF 1.3 4区 化学
Phosphorus, Sulfur, and Silicon and the Related Elements Pub Date : 2024-02-01 DOI: 10.1080/10426507.2023.2263135
Ekta Arora
{"title":"Synthetic methodologies and applications of chalcogen (S, Se, Te) ionic liquids: a review","authors":"Ekta Arora","doi":"10.1080/10426507.2023.2263135","DOIUrl":"10.1080/10426507.2023.2263135","url":null,"abstract":"<div><p>Ionic liquids (ILs) have emerged as an environmentally friendly alternative to the volatile organic solvents. Though primarily used as solvents, ILs synthesized with specific desired chemical properties have gained significant attention in recent years due to their unique properties and versatile applications in various areas of chemical synthesis and beyond. The present review is aimed at exploring the synthetic methods for chalcogen (S, Se, Te) ionic liquids along with the study of their role as solvent, catalyst, reactant in various chemical reactions like oxidation reactions, hydrothiolation transformations etc., thus showing the contribution of ILs toward the development of sustainable organo-chalcogen chemistry.</p></div>","PeriodicalId":20056,"journal":{"name":"Phosphorus, Sulfur, and Silicon and the Related Elements","volume":"199 2","pages":"Pages 103-111"},"PeriodicalIF":1.3,"publicationDate":"2024-02-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"135386922","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Synthesis and bioactivity evaluation of novel acetamide-derived compounds bearing a methylsulfonyl unit 含有甲基磺酰基单元的新型乙酰胺衍生化合物的合成与生物活性评估
IF 1.3 4区 化学
Phosphorus, Sulfur, and Silicon and the Related Elements Pub Date : 2024-01-02 DOI: 10.1080/10426507.2023.2249179
Pei Li , Zhenchao Wang , Lei Yu
{"title":"Synthesis and bioactivity evaluation of novel acetamide-derived compounds bearing a methylsulfonyl unit","authors":"Pei Li ,&nbsp;Zhenchao Wang ,&nbsp;Lei Yu","doi":"10.1080/10426507.2023.2249179","DOIUrl":"10.1080/10426507.2023.2249179","url":null,"abstract":"<div><p>This study reports the synthesis and structural characterization of a series of novel acetamide-derived compounds containing a methylsulfonyl unit. The <em>in vitro</em> antibacterial activity results demonstrated that compound 2-((4-fluorophenyl)sulfonyl)-<em>N</em>-(4-(methylsulfonyl)phenyl)acetamide (<strong>6b</strong>) exhibited superior antibacterial activities against <em>Xanthomonas oryzae</em> pv. <em>oryzicolaby</em> (<em>Xoc</em>), <em>Xanthomonas oryzae</em> pv. <em>oryzae</em> (<em>Xoo</em>), and <em>Xanthomonas axonopodis</em> pv. <em>citri</em> (<em>Xac</em>) at 100 μg/mL concentration, with the inhibition rates of 86.24%, 81.59%, and 75.65%, respectively, compared to Bismerthiazol and Thiodiazole copper. Meanwhile, the <em>in vitro</em> antifungal activities of all target compounds were found to be lower against <em>Mucor fragilis</em> (<em>M. fragilis</em>), <em>Mucor bainieri</em> (<em>M. bainieri</em>), and <em>Trichoderma atroviride</em> (<em>T. atroviride</em>) at 50 μg/mL concentration, with the inhibition rates of 0–45.21%, 0–30.24%, and 0–12.65%, respectively, compared to Carbendazim. Moreover, bioassay results of the target compounds against prostate cancer (PC3), hepatocellular carcinoma (HepG2), and leukemia (K562) cells at 10 μM concentration demonstrated that, compared to 5-fluorouracil, compound 2-((4-fluorophenyl)thio)-<em>N</em>-(4-(methylsulfonyl)phenyl)acetamide (<strong>4c</strong>) illustrated obvious antitumor activity (56.87%) against K562. This work first highlights the effect of the modification of the acetamide-derived compounds bearing a methylsulfonyl unit on the bioactivity evaluation.</p></div>","PeriodicalId":20056,"journal":{"name":"Phosphorus, Sulfur, and Silicon and the Related Elements","volume":"199 1","pages":"Pages 54-57"},"PeriodicalIF":1.3,"publicationDate":"2024-01-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"135420914","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Obituary 讣告
IF 1.3 4区 化学
Phosphorus, Sulfur, and Silicon and the Related Elements Pub Date : 2024-01-02 DOI: 10.1080/10426507.2023.2292430
Kaleigh Sunday
{"title":"Obituary","authors":"Kaleigh Sunday","doi":"10.1080/10426507.2023.2292430","DOIUrl":"10.1080/10426507.2023.2292430","url":null,"abstract":"","PeriodicalId":20056,"journal":{"name":"Phosphorus, Sulfur, and Silicon and the Related Elements","volume":"199 1","pages":"Page 1"},"PeriodicalIF":1.3,"publicationDate":"2024-01-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139452905","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Nickel catalysis synthesis of 2,5-disubstituted furans from aryl (alkyl) iodide 镍催化碘化芳基（烷基）合成 2,5-二取代呋喃
IF 1.3 4区 化学
Phosphorus, Sulfur, and Silicon and the Related Elements Pub Date : 2024-01-02 DOI: 10.1080/10426507.2023.2249576
Zhongqiang Sun
{"title":"Nickel catalysis synthesis of 2,5-disubstituted furans from aryl (alkyl) iodide","authors":"Zhongqiang Sun","doi":"10.1080/10426507.2023.2249576","DOIUrl":"10.1080/10426507.2023.2249576","url":null,"abstract":"<div><p>A new methodology using various aryl(alkyl)iodides and CaC<sub>2</sub> as coupling partners has been developed for the successful preparation of 2,5-disubstituted furans in good to excellent yields. The broad substrate range makes this method a practical and versatile approach for the preparation of (hetero)aryl- and alkyl-substituted furans, which are valuable building blocks in many biologically active compounds and functional materials.</p></div>","PeriodicalId":20056,"journal":{"name":"Phosphorus, Sulfur, and Silicon and the Related Elements","volume":"199 1","pages":"Pages 63-70"},"PeriodicalIF":1.3,"publicationDate":"2024-01-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"72989460","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
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