Phosphorus, Sulfur, and Silicon and the Related Elements最新文献_第10页

A facile ultrasonic synthesis approach to 3-H-quinazolinethione derivatives and their urease inhibition studies 3- H -喹唑啉硫酮衍生物的简便超声合成方法及其脲酶抑制研究

IF 1.3 4区化学

Phosphorus, Sulfur, and Silicon and the Related Elements Pub Date : 2024-04-02 DOI: 10.1080/10426507.2024.2333471

Nedime Çalışkan , Gülay Akyüz , Emre Menteşe

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Green conversion of CO2 by N-heterocyclic carbene-CO2 adducts grafted hierarchical porous silica microspheres N-heterocyclic carbene-CO 2 加合物接枝分层多孔二氧化硅微球实现 CO 2 的绿色转化

IF 1.3 4区化学

Phosphorus, Sulfur, and Silicon and the Related Elements Pub Date : 2024-04-02 DOI: 10.1080/10426507.2024.2332891

Xueting Liu , Kuayue Li , Wenkui Liu , Peng Cui , Fengyu Wei

{"title":"Green conversion of CO2 by N-heterocyclic carbene-CO2 adducts grafted hierarchical porous silica microspheres","authors":"Xueting Liu , Kuayue Li , Wenkui Liu , Peng Cui , Fengyu Wei","doi":"10.1080/10426507.2024.2332891","DOIUrl":"10.1080/10426507.2024.2332891","url":null,"abstract":"<div>The multiphase catalysts DMSNs-Cb-X containing NHC-CO2 adducts were synthesized by soft template method that is, first preparing dendritic multi-model pore silica nanoparticles (DMSNs) with central-radial structure, and then grafting imidazoline functional groups, and finally allowing to react with dimethyl carbonate to graft NHC-CO2 adducts. The investigations had the scope to improve the performance and to elucidate the effect of NHC-CO2 adducts on the CO2 cycloaddition reaction. The optimum catalyst DMSNs-Cb-1 and the optimum reaction conditions (200 mg, 100 °C, 10 h) were obtained via thermogravimetric analysis. CO2 cycloaddition reaction with epoxide DMSNs-Cb-1 can convert CO2 and epoxide to cyclic carbonate at ambient pressure without solvent and co-catalysts (1 bar, 100 °C). The reaction proceeds with high yield and high conversion frequency (TOF = 27.4 h−1). The prepared catalyst is easily recovered and still has high activity after five cycles of experiments. The excellent catalytic performance of the obtained catalyst can be attributed to the synergy of hierarchical porous structure and NHC-CO2 adducts acting as CO2 adsorption sites as well as zwitterionic catalytic sites. This work demonstrates an efficient strategy for green conversion of CO2 into cyclic carbonates.</div>","PeriodicalId":20056,"journal":{"name":"Phosphorus, Sulfur, and Silicon and the Related Elements","volume":"199 4","pages":"Pages 283-292"},"PeriodicalIF":1.3,"publicationDate":"2024-04-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140372102","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

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Investigation of the effect of halide counterions on the potential corrosion inhibitor in imidazolium-based ionic liquids 研究卤化物反离子对咪唑基离子液体中潜在缓蚀剂的影响

IF 1.3 4区化学

Phosphorus, Sulfur, and Silicon and the Related Elements Pub Date : 2024-04-02 DOI: 10.1080/10426507.2024.2340006

Abdelmajeed Adam Lagum , Saroj Sharma , Anupam Yadav , Parminder Singh , Shakir Mahmood Saeed , Russul R. Abbass , Ali H. Hameed , Mustafa M. Kadhim

{"title":"Investigation of the effect of halide counterions on the potential corrosion inhibitor in imidazolium-based ionic liquids","authors":"Abdelmajeed Adam Lagum , Saroj Sharma , Anupam Yadav , Parminder Singh , Shakir Mahmood Saeed , Russul R. Abbass , Ali H. Hameed , Mustafa M. Kadhim","doi":"10.1080/10426507.2024.2340006","DOIUrl":"10.1080/10426507.2024.2340006","url":null,"abstract":"<div>Imidazolium (IMZ)-based ionic liquids (ILs) with various counter ions were investigated as potential corrosion inhibitors. Furthermore, parameters such as bond lengths, bond angles, and dihedral bonds were investigated to demonstrate the adsorption sites of molecules. Moreover, in order to compare the efficiency of the inhibitors, other parameters such as energy gap, hardness, the LUMO, and the HOMO were investigated. The HOMO and LUMO values increased from −4.370 and −0.106 eV to −4.959 and −0.156 eV, respectively, by changing F− to I−. Moreover, the softness of the IMZ base changed from 0.469 to 0.417 eV by increasing the radius of the halide ion. The trend of the band gap value in going from F− to I− changes from 4.264 to 4.797 eV. The total electron density was computed to show the adsorption sites based on the electron density. According to the molecular reactivity results, the inhibitory efficiency of the inhibitors was in the following order: BMI-F > BMI-Cl > BMI-Br > BMI-I. Investigating the IMZ-based ILs with various counterions to evaluate the inhibition profile of molecules provides useful insights into computational protocols for the study of corrosion inhibitors.</div>","PeriodicalId":20056,"journal":{"name":"Phosphorus, Sulfur, and Silicon and the Related Elements","volume":"199 4","pages":"Pages 308-315"},"PeriodicalIF":1.3,"publicationDate":"2024-04-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140972124","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

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1-Phosphanorbornane aldehyde as precursor for enantiopure P,N,N ligands 作为对映体 P，N，N 配体前体的 1-膦基降冰片烷醛

IF 1.3 4区化学

Phosphorus, Sulfur, and Silicon and the Related Elements Pub Date : 2024-04-02 DOI: 10.1080/10426507.2024.2338393

Kyzgaldak Ramazanova , Nadja Kretzschmar , Peter Lönnecke , Evamarie Hey-Hawkins

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The syntheses of 2-hydroxybenzothiazole substituted cyclotriphosphazenes: Spectroscopic characterizations 2-hydroxybenzothiazole substituted cyclotriphosphazenes 的合成：光谱特性

IF 1.3 4区化学

Phosphorus, Sulfur, and Silicon and the Related Elements Pub Date : 2024-04-02 DOI: 10.1080/10426507.2024.2318600

Saliha Begeç

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Promising way for enhancing light absorption in silicon via silver nanoparticles: experimental and numerical study 通过银纳米粒子增强硅的光吸收的可行方法：实验和数值研究

IF 1.3 4区化学

Phosphorus, Sulfur, and Silicon and the Related Elements Pub Date : 2024-03-03 DOI: 10.1080/10426507.2024.2318593

Meriem Zineb Belmehdi , Fatiha Bechiri , Mohamed Amine Benali , Mokhtar Zerdali

{"title":"Promising way for enhancing light absorption in silicon via silver nanoparticles: experimental and numerical study","authors":"Meriem Zineb Belmehdi , Fatiha Bechiri , Mohamed Amine Benali , Mokhtar Zerdali","doi":"10.1080/10426507.2024.2318593","DOIUrl":"10.1080/10426507.2024.2318593","url":null,"abstract":"<div>Silver nanoparticles (Ag-Nps) were grown on the surface of a p-type crystalline silicon (C-Si) substrate using electroless metal deposition. It was found that the Ag-Nps distribution on C-Si was controlled by the silver nitrate (AgNO3) concentrations. Atomic force microscopy observations revealed the formation of a continuous layer at high concentration. In contrast, a distribution of Ag-Nps with a spherical shape was obtained at lower concentration. The samples were also examined by optical microscopy under dark field illumination. The light reflected from Ag-Nps was obtained with different colors. This difference indicates a slight change in particle size. It is demonstrated that a silicon substrate with deposited Ag-Nps shows a significant decrease in reflectance and an increase of the absorption in the region from 200 to 800 nm. Moreover, the behavior of small Ag-Nps while interacting with light (absorbed or scattered light) is theoretically described using the Mie theory based on the Drude model. The introduction of silver nanoparticles on silicon surface is used to improve the efficiency of solar cells by reducing reflection and increasing the light absorption.</div>","PeriodicalId":20056,"journal":{"name":"Phosphorus, Sulfur, and Silicon and the Related Elements","volume":"199 3","pages":"Pages 227-235"},"PeriodicalIF":1.3,"publicationDate":"2024-03-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139947199","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

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Design, synthesis and antibacterial evaluation of N-substituted indole derivatives containing 1,3,4-thiadiazole and amide moieties 含有 1,3,4-噻二唑和酰胺分子的 N-取代吲哚衍生物的设计、合成和抗菌评价

IF 1.3 4区化学

Phosphorus, Sulfur, and Silicon and the Related Elements Pub Date : 2024-03-03 DOI: 10.1080/10426507.2024.2318584

Chenghao Tang , Chou Si , Yidan Zhang , Shengzhou Yang , Xingju Chen , Pei Li , Xiang Wang

{"title":"Design, synthesis and antibacterial evaluation of N-substituted indole derivatives containing 1,3,4-thiadiazole and amide moieties","authors":"Chenghao Tang , Chou Si , Yidan Zhang , Shengzhou Yang , Xingju Chen , Pei Li , Xiang Wang","doi":"10.1080/10426507.2024.2318584","DOIUrl":"10.1080/10426507.2024.2318584","url":null,"abstract":"<div>A total of eighteen novel 2-(1H-indol-1-yl)-N-(5-phenyl-1,3,4-thiadiazol-2-yl) acetamide derivatives were synthesized through the condensation reaction of 2-(1H-indol-1-yl) acetic acid and 5-phenyl-1,3,4-thiadiazol-2-amine via fragment-based design strategy. The target compounds were subjected to screening for antibacterial activity against Xanthomonas oryzae pv. Oryzae, Xanthomonas axonopodis pv. Citri and Pseudomonas syringae pv. Actinidiae. The preliminary antibacterial evaluation of the target compounds showed that some target compounds possessed moderate to good activities against Xoo and Xac. Among them, compound 3p exhibited best inhibition effects against Xoo (77.85% and 62.15%, respectively) and Xac (52.51% and 36.48%, respectively) at 100 μg/mL and 50 μg/mL, which were superior to Thiodiazole-copper and Bismerthiazol. To the best of our knowledge, it is the first report on the design, synthesis, and antibacterial evaluation of novel indole-derived compounds containing 1,3,4-thiadiazole and amide moieties.</div>","PeriodicalId":20056,"journal":{"name":"Phosphorus, Sulfur, and Silicon and the Related Elements","volume":"199 3","pages":"Pages 193-200"},"PeriodicalIF":1.3,"publicationDate":"2024-03-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139947230","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Removal of Ca(II) and Mg(II) ions from solutions to sulfonic cation exchanger based on plasticized polyvinylchloride 用基于塑化聚氯乙烯的磺酸阳离子交换剂去除溶液中的 Ca(II) 和 Mg(II) 离子

IF 1.3 4区化学

Phosphorus, Sulfur, and Silicon and the Related Elements Pub Date : 2024-03-03 DOI: 10.1080/10426507.2024.2315530

Davron Bekchanov , Mukhtar Mukhamediev , Murod Juraev , Rasim Alosmanov

{"title":"Removal of Ca(II) and Mg(II) ions from solutions to sulfonic cation exchanger based on plasticized polyvinylchloride","authors":"Davron Bekchanov , Mukhtar Mukhamediev , Murod Juraev , Rasim Alosmanov","doi":"10.1080/10426507.2024.2315530","DOIUrl":"10.1080/10426507.2024.2315530","url":null,"abstract":"<div>The ion-exchange material was obtained by oxidation of the product of the interaction of polyvinyl chloride with an aqueous solution of calcium polysulfide. The structure of the resulting cation exchanger and metal-containing hybrid material was identified by IR spectroscopy and elemental analysis. The kinetics of absorption of metal ions in cation exchange resin was analyzed by using pseudo-first and pseudo-second order models. The rate constants in the adsorption process were calculated. According to the correlation coefficient, it was determined that the sorption process proceeds according to the laws of a pseudo-second order reaction. Based on the equilibrium sorption it was evaluated according to the isotherm models of Langmuir, Freundlich, Temkin, and Dubinin-Radushkevich (D-R). The results showed that the absorption of Ca2+ and Mg2+ ions from aqueous solutions in cation exchange resin displays the best accordance with the Langmuir monomolecular theory. In addition, the results showed that the cation exchanger (PVC-SO3H) effectively cleans river water from Ca2+ and Mg2+ ions for industrial enterprises.</div>","PeriodicalId":20056,"journal":{"name":"Phosphorus, Sulfur, and Silicon and the Related Elements","volume":"199 3","pages":"Pages 201-209"},"PeriodicalIF":1.3,"publicationDate":"2024-03-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139902544","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

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Synthesis and anticancer evaluation of new disulfides incorporating naphthalimide moiety 含有萘二甲酰亚胺分子的新型二硫化物的合成与抗癌评估

IF 1.3 4区化学

Phosphorus, Sulfur, and Silicon and the Related Elements Pub Date : 2024-03-03 DOI: 10.1080/10426507.2024.2323018

Lu Xu , Shuangyan He , Chunlan Chi , Caiwen Li , Peipei Cui , Hongying Wang , Baoquan Chen

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Synthesis and in vitro carbonic anhydrase and acetylcholinesterase inhibitory activities of novel hydrazide–hydrazone compounds containing 1,2,4-triazole ring 含 1,2,4-三唑环的新型酰肼化合物的合成及其体外碳酸酐酶和乙酰胆碱酯酶抑制活性

IF 1.3 4区化学

Phosphorus, Sulfur, and Silicon and the Related Elements Pub Date : 2024-03-03 DOI: 10.1080/10426507.2024.2320672

Efe Doğukan Dincel , Ebru Didem Kuran , Beyza Onarer , Yusuf Fıstıkçı , İlhami Gülçin , Nuray Ulusoy-Güzeldemirci

{"title":"Synthesis and in vitro carbonic anhydrase and acetylcholinesterase inhibitory activities of novel hydrazide–hydrazone compounds containing 1,2,4-triazole ring","authors":"Efe Doğukan Dincel , Ebru Didem Kuran , Beyza Onarer , Yusuf Fıstıkçı , İlhami Gülçin , Nuray Ulusoy-Güzeldemirci","doi":"10.1080/10426507.2024.2320672","DOIUrl":"10.1080/10426507.2024.2320672","url":null,"abstract":"<div>In this work, 1,2,4-triazole derived hydrazide–hydrazones were synthesized with a five-step synthesis pathway. The novel derivatives were characterized by various analytical methods. Acetylcholinesterase (AChE), and human carbonic anhydrase (hCA) inhibitory qualifications of these thirteen original compounds (4, 5a–l) were also determined. The overall biological activity results were very interesting. The reported compounds were found to be very effective inhibitors of hCA I, hCA II, and AChE enzymes with IC50 values in the range of 17.33−77.00 nM for hCA I (Acetazolamide IC50: 62.80 nM), 13.07−46.20 nM for hCA II (Acetazolamide IC50: 57.75 nM) and 4.91−36.47 nM for AChE (Tacrine IC50: 28.88 nM). Within the new compounds, 5i displayed the best hCA I, hCA II and AChE inhibitory activities with IC50 values of 17.33 nM, 13.07 nM, and 4.91 nM, respectively.</div>","PeriodicalId":20056,"journal":{"name":"Phosphorus, Sulfur, and Silicon and the Related Elements","volume":"199 3","pages":"Pages 236-244"},"PeriodicalIF":1.3,"publicationDate":"2024-03-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140032930","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0