Phosphorus, Sulfur, and Silicon and the Related Elements最新文献

On carbon nanocones CNCm[n] and their face index

IF 1.4 4区化学

Phosphorus, Sulfur, and Silicon and the Related Elements Pub Date : 2025-02-01 DOI: 10.1080/10426507.2025.2456205

Shriya Negi , Vijay Kumar Bhat

引用次数: 0

Synthesis and antimicrobial evaluation of new quinazolinone derivatives containing thiourea and thiazolidine moieties

IF 1.4 4区化学

Phosphorus, Sulfur, and Silicon and the Related Elements Pub Date : 2025-02-01 DOI: 10.1080/10426507.2025.2461044

Farzaneh Yazdan Kushkoo , Hojatollah Khabazzadeh , Moj Khaleghi

{"title":"Synthesis and antimicrobial evaluation of new quinazolinone derivatives containing thiourea and thiazolidine moieties","authors":"Farzaneh Yazdan Kushkoo , Hojatollah Khabazzadeh , Moj Khaleghi","doi":"10.1080/10426507.2025.2461044","DOIUrl":"10.1080/10426507.2025.2461044","url":null,"abstract":"<div><div>With the aim of finding novel compounds with good antimicrobial activity to counteract drug resistance, a new series of quinazolinones featuring thiourea and thiazole groups was synthesized through the reaction of 4-amino-N-(4-oxo-2-phenyl-1, 2-dihydroquinazolin-3(4H)-yl)benzamide with methyl isothiocyanate and subsequent treatment with dialkyl acetylene dicarboxylate. All synthesized compounds were characterized by spectroscopic data and elemental analysis. The antimicrobial activity of synthesized compounds was evaluated against two bacteria strains (<em>Escherichia coli</em> PTCC1330; <em>Staphylococcus aureus</em> PTCC 1431) and two fungi strains (<em>Aspergillus niger</em> PTCC5010; <em>Candida albicans</em> ATCC 10231). Almost all products exhibited good antibacterial and antifungal activities which indicated that insertion of thiourea and thiazolidine moieties considerably increased the antimicrobial properties of quinazolinones. Therefore, these compounds can be good candidates for clinical treatments, avoiding possible drug resistance problems in humans.</div></div>","PeriodicalId":20056,"journal":{"name":"Phosphorus, Sulfur, and Silicon and the Related Elements","volume":"200 2","pages":"Pages 152-163"},"PeriodicalIF":1.4,"publicationDate":"2025-02-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143601261","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Synthesis, crystal structure and evaluation of antibacterial activity of new hybrid systems containing furan-2-one and chromen-4-thione fragments

IF 1.4 4区化学

Phosphorus, Sulfur, and Silicon and the Related Elements Pub Date : 2025-02-01 DOI: 10.1080/10426507.2025.2461042

Ekaterina Mikhailovna Arzyamova , Alevtina Yur’evna Yegorova

引用次数: 0

Synthesis and characterization of diphenylether-based oxime ligands containing unilaterally substituted 1,3,4-thiadiazole groups and investigation of their some transition metal complexes

IF 1.4 4区化学

Phosphorus, Sulfur, and Silicon and the Related Elements Pub Date : 2025-02-01 DOI: 10.1080/10426507.2025.2456204

Ahmed Ali Jasim , Ahmed Hamdi Mirghani , Ahmed Saleem Otaiwi , Ahmet Coşkun , Hakan Tahtaci , Saban Uysal

{"title":"Synthesis and characterization of diphenylether-based oxime ligands containing unilaterally substituted 1,3,4-thiadiazole groups and investigation of their some transition metal complexes","authors":"Ahmed Ali Jasim , Ahmed Hamdi Mirghani , Ahmed Saleem Otaiwi , Ahmet Coşkun , Hakan Tahtaci , Saban Uysal","doi":"10.1080/10426507.2025.2456204","DOIUrl":"10.1080/10426507.2025.2456204","url":null,"abstract":"<div><div>In this study, we synthesized six novel oxime ligands derived from substituted 1,3,4-thiadiazoles, along with their corresponding monomeric transition metal complexes involving Co<sup>2+</sup>, Ni<sup>2+</sup>, and Cu<sup>2+</sup> ions. Comprehensive structural characterizations were then performed to analyze these compounds. To achieve this, 4-(chloroacetyl) diphenyl ether was synthesized by reacting diphenyl ether with chloroacetyl chloride using a Friedel–Crafts reaction. The starting oxime compound, (E)-N-hydroxy-2-oxo-2-(4-phenoxyphenyl)acetylmidoyl chloride, was synthesized by reacting 4-(chloroacetyl) diphenyl ether with butyl nitrite in a 1:1 molar ratio, with HCl as the catalyst. The target oxime compounds were subsequently synthesized by reacting substituted 2-amino-1,3,4-thiadiazole derivatives with (E)-N-hydroxy-2-oxo-2-(4-phenoxyphenyl)acetylmidoyl chloride, following established procedures from the literature. The structural characterizations of all synthesized organic compounds were carried out using elemental analysis, FTIR spectroscopy, <sup>1</sup>H and <sup>13</sup>C NMR spectroscopy, and mass spectrometry. The target complexes were synthesized by reacting the ligands with MCl<sub>2</sub>·nH<sub>2</sub>O salts (M = Co<sup>2+</sup>, Ni<sup>2+</sup>, Cu<sup>2+</sup>). Their structures were confirmed using FTIR spectroscopy, magnetic susceptibility measurements, elemental analysis, and ICP-OES.</div></div>","PeriodicalId":20056,"journal":{"name":"Phosphorus, Sulfur, and Silicon and the Related Elements","volume":"200 2","pages":"Pages 133-143"},"PeriodicalIF":1.4,"publicationDate":"2025-02-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143601186","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Review on the synthesis of thiourea-triazine hybrid derivatives and its applications primarily in biological context

IF 1.4 4区化学

Phosphorus, Sulfur, and Silicon and the Related Elements Pub Date : 2025-02-01 DOI: 10.1080/10426507.2025.2457458

Ainaa Nadiah Abd Halim , Zainab Ngaini

{"title":"Review on the synthesis of thiourea-triazine hybrid derivatives and its applications primarily in biological context","authors":"Ainaa Nadiah Abd Halim , Zainab Ngaini","doi":"10.1080/10426507.2025.2457458","DOIUrl":"10.1080/10426507.2025.2457458","url":null,"abstract":"<div><div>Thiourea and triazine are heteroatom scaffolds that have been intensively employed for structural modification, particularly in the development of new drugs and the exploration of new applications. Recent advances have initiated the concept of merging these two moieties, maximizing the potential and enhancing the properties. This review is a comprehensive compilation highlighting the various synthesis pathways of the compound comprised of both thiourea and triazine scaffolds expressed in the form of fused triazinethione as well as <em>mono</em>-, <em>bis</em>-, and <em>tris</em>-thiourea-triazine structures. The produced compounds indefinitely showed the potential to be applied to various fields and industries. While this compilation majorly highlighted the biological capabilities of the thiourea–triazine compounds, a glimpse of other material chemistry applications was also included on the basis of the respective compound as documented by precedent literature. Therefore, this review is significant for structural modification in the field of synthetic chemistry for intended applications.</div></div>","PeriodicalId":20056,"journal":{"name":"Phosphorus, Sulfur, and Silicon and the Related Elements","volume":"200 2","pages":"Pages 109-132"},"PeriodicalIF":1.4,"publicationDate":"2025-02-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143601264","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Reduction of organic sulfones, selenones and tellurones using magnesium and methanol as reductant

IF 1.4 4区化学

Phosphorus, Sulfur, and Silicon and the Related Elements Pub Date : 2025-02-01 DOI: 10.1080/10426507.2025.2463459

Kiran Arora , J. M. Khurana

引用次数: 0

Chemical and natural synthesis of hydroxyapatite nanoparticles for biomedical applications: a review

IF 1.4 4区化学

Phosphorus, Sulfur, and Silicon and the Related Elements Pub Date : 2025-01-02 DOI: 10.1080/10426507.2024.2437009

A. S. Shalfia Judit , R. Feyolah Herin , S. Sebastiammal , J. Henry , M. Santhosh , M. Santhamoorthy

引用次数: 0

On the catalytic nature of nitrided NiMo/γ-Al2O3 catalysts for dry reforming of methane

IF 1.4 4区化学

Phosphorus, Sulfur, and Silicon and the Related Elements Pub Date : 2025-01-02 DOI: 10.1080/10426507.2024.2435943

Jiaqi Wang , Ying Zhang , Qingshan Rong , Yan Shi , Zhiwei Yao

{"title":"On the catalytic nature of nitrided NiMo/γ-Al2O3 catalysts for dry reforming of methane","authors":"Jiaqi Wang , Ying Zhang , Qingshan Rong , Yan Shi , Zhiwei Yao","doi":"10.1080/10426507.2024.2435943","DOIUrl":"10.1080/10426507.2024.2435943","url":null,"abstract":"<div><div>Nitrogen and phosphorus are one of the most common Group 15 elements. The chemistry of nitrogen and phosphorus is very important in the field of catalysis. Three types of nitride containing NiMo/γ-Al<sub>2</sub>O<sub>3</sub> catalysts were synthesized using different loading-nitriding sequences and oxide precursor types for dry reforming of methane (DRM). The active components (Ni<sub>2</sub>Mo<sub>3</sub>N and Ni/Mo<sub>2</sub>N) firstly reacted with CO<sub>2</sub>, transforming into NiO and MoO<sub>2</sub>. They were then carburized with CH<sub>4</sub> to produce Ni/Mo<sub>2</sub>C during the DRM process. From that point on, a redox cycle, viz. NiO/MoO<sub>2</sub> ⇆ Ni/Mo<sub>2</sub>C, occurred during the DRM reaction. The low activity of nitriding-first NiMo nitride catalyst can be attributed to bulk oxidation. The observed gradual decline in performance of loading-first Ni/Mo nitride catalyst was due to coking. Noticeably, the loading-first NiMo nitride catalyst can demonstrate superiority in both activity and resistance to coking, which was due to its strong metal–Al<sub>2</sub>O<sub>3</sub> interaction and high metal dispersion.</div></div>","PeriodicalId":20056,"journal":{"name":"Phosphorus, Sulfur, and Silicon and the Related Elements","volume":"200 1","pages":"Pages 46-53"},"PeriodicalIF":1.4,"publicationDate":"2025-01-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143350032","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Experimental investigation of pyridine removal using vulcanized oil shale

IF 1.4 4区化学

Phosphorus, Sulfur, and Silicon and the Related Elements Pub Date : 2025-01-02 DOI: 10.1080/10426507.2025.2452211

Qinqin Li , Xiaochun Tian , Ao Sun , Chengyu Wang , Kangle Ding

{"title":"Experimental investigation of pyridine removal using vulcanized oil shale","authors":"Qinqin Li , Xiaochun Tian , Ao Sun , Chengyu Wang , Kangle Ding","doi":"10.1080/10426507.2025.2452211","DOIUrl":"10.1080/10426507.2025.2452211","url":null,"abstract":"<div><div>The study systematically conducted orthogonal and univariate experiments to determine the optimal parameters for pyridine removal using vulcanized oil shale. The findings revealed that the key determinants of pyridine adsorption onto vulcanized oil shale included the pH level of the pyridine solution, contact time, initial pyridine concentration, and the quantity of vulcanized oil shale introduced into the system. Under optimal adsorption conditions, the vulcanized oil shale achieved a 48.00% adsorption efficiency and an equilibrium adsorption capacity of 4.83 mg·g<sup>−1</sup>. In contrast, the untreated oil shale exhibited a comparatively reduced adsorption efficiency of 22.88% under its respective optimal conditions. The research further examined the adsorption kinetics and isothermal adsorption models for both types of oil shale. The kinetic data indicated that pyridine adsorption followed a pseudo-second-order model. The pyridine adsorption isotherms for both oil shale and vulcanized oil shale were best described by the Freundlich model, compared to the Langmuir model. These findings provide significant insights into the utilization of vulcanized oil shale for the efficient treatment of low-concentration pyridine wastewater, potentially contributing to environmental remediation and pollution control strategies.</div></div>","PeriodicalId":20056,"journal":{"name":"Phosphorus, Sulfur, and Silicon and the Related Elements","volume":"200 1","pages":"Pages 90-100"},"PeriodicalIF":1.4,"publicationDate":"2025-01-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143360823","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

A review on chemical and biological studies of thiopyran derivatives

IF 1.4 4区化学

Phosphorus, Sulfur, and Silicon and the Related Elements Pub Date : 2025-01-02 DOI: 10.1080/10426507.2024.2435939

Mohamed Ibrahim Hegab

引用次数: 0