Hg(OTf)2催化炔烃的氧合反应使得恶唑和1,2-二酮的发散合成成为可能

IF 1.6 4区 化学 Q4 CHEMISTRY, INORGANIC & NUCLEAR
Jian Guan (Investigation) , Yikang Ding (Methodology) , Xin Qian (Validation) , Haoxian Lin (Data curation) , Wenxuan Wang (Investigation) , Zhouting Rong (Supervision Writing – original draft)
{"title":"Hg(OTf)2催化炔烃的氧合反应使得恶唑和1,2-二酮的发散合成成为可能","authors":"Jian Guan (Investigation) ,&nbsp;Yikang Ding (Methodology) ,&nbsp;Xin Qian (Validation) ,&nbsp;Haoxian Lin (Data curation) ,&nbsp;Wenxuan Wang (Investigation) ,&nbsp;Zhouting Rong (Supervision Writing – original draft)","doi":"10.1080/10426507.2025.2547034","DOIUrl":null,"url":null,"abstract":"<div><div>A Hg(OTf)<sub>2</sub>-catalyzed oxygenation reaction has been developed for the divergent synthesis of various oxazoles and 1,2-diketones under mild conditions. This method extends the potential of mercury catalysis and promises to be an inexpensive alternative for the synthesis of oxazoles and 1,2-diketones from a wide range of aryl alkynes.</div></div>","PeriodicalId":20056,"journal":{"name":"Phosphorus, Sulfur, and Silicon and the Related Elements","volume":"200 10","pages":"Pages 814-820"},"PeriodicalIF":1.6000,"publicationDate":"2025-08-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Hg(OTf)2-catalyzed oxygenation of alkynes enables the divergent synthesis of oxazoles and 1,2-diketones\",\"authors\":\"Jian Guan (Investigation) ,&nbsp;Yikang Ding (Methodology) ,&nbsp;Xin Qian (Validation) ,&nbsp;Haoxian Lin (Data curation) ,&nbsp;Wenxuan Wang (Investigation) ,&nbsp;Zhouting Rong (Supervision Writing – original draft)\",\"doi\":\"10.1080/10426507.2025.2547034\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><div>A Hg(OTf)<sub>2</sub>-catalyzed oxygenation reaction has been developed for the divergent synthesis of various oxazoles and 1,2-diketones under mild conditions. This method extends the potential of mercury catalysis and promises to be an inexpensive alternative for the synthesis of oxazoles and 1,2-diketones from a wide range of aryl alkynes.</div></div>\",\"PeriodicalId\":20056,\"journal\":{\"name\":\"Phosphorus, Sulfur, and Silicon and the Related Elements\",\"volume\":\"200 10\",\"pages\":\"Pages 814-820\"},\"PeriodicalIF\":1.6000,\"publicationDate\":\"2025-08-13\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Phosphorus, Sulfur, and Silicon and the Related Elements\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://www.sciencedirect.com/org/science/article/pii/S1042650725000772\",\"RegionNum\":4,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q4\",\"JCRName\":\"CHEMISTRY, INORGANIC & NUCLEAR\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Phosphorus, Sulfur, and Silicon and the Related Elements","FirstCategoryId":"92","ListUrlMain":"https://www.sciencedirect.com/org/science/article/pii/S1042650725000772","RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"CHEMISTRY, INORGANIC & NUCLEAR","Score":null,"Total":0}
引用次数: 0

摘要

在温和条件下,建立了Hg(OTf)2催化的氧化反应,用于各种恶唑和1,2-二酮的发散合成。该方法扩展了汞催化的潜力,并有望成为一种廉价的替代方法,用于从各种芳基炔合成恶唑和1,2-二酮。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Hg(OTf)2-catalyzed oxygenation of alkynes enables the divergent synthesis of oxazoles and 1,2-diketones
A Hg(OTf)2-catalyzed oxygenation reaction has been developed for the divergent synthesis of various oxazoles and 1,2-diketones under mild conditions. This method extends the potential of mercury catalysis and promises to be an inexpensive alternative for the synthesis of oxazoles and 1,2-diketones from a wide range of aryl alkynes.
求助全文
通过发布文献求助,成功后即可免费获取论文全文。 去求助
来源期刊
CiteScore
2.60
自引率
7.70%
发文量
103
审稿时长
2.1 months
期刊介绍: Phosphorus, Sulfur, and Silicon and the Related Elements is a monthly publication intended to disseminate current trends and novel methods to those working in the broad and interdisciplinary field of heteroatom chemistry.
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
确定
请完成安全验证×
copy
已复制链接
快去分享给好友吧!
我知道了
右上角分享
点击右上角分享
0
联系我们:info@booksci.cn Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。 Copyright © 2023 布克学术 All rights reserved.
京ICP备2023020795号-1
ghs 京公网安备 11010802042870号
Book学术文献互助
Book学术文献互助群
群 号:604180095
Book学术官方微信