Phosphorus, Sulfur, and Silicon and the Related Elements最新文献_第3页

Evaluation of the degradation efficiency and possible mechanism of various chemical decontaminants on series of vesicant sulfur mustards 评价各种化学去污剂对一系列发泡剂硫芥菜的降解效率及可能机理

IF 1.4 4区化学

Phosphorus, Sulfur, and Silicon and the Related Elements Pub Date : 2025-03-04 DOI: 10.1080/10426507.2025.2464778

Mengyao Zhang , Wei You , Yulong Liu , Jinlong Cai , Bin Xu , Jia Chen , Yuxu Zhong , Jiyong Fan , Jianfeng Wu , Jianwei Xie

{"title":"Evaluation of the degradation efficiency and possible mechanism of various chemical decontaminants on series of vesicant sulfur mustards","authors":"Mengyao Zhang , Wei You , Yulong Liu , Jinlong Cai , Bin Xu , Jia Chen , Yuxu Zhong , Jiyong Fan , Jianfeng Wu , Jianwei Xie","doi":"10.1080/10426507.2025.2464778","DOIUrl":"10.1080/10426507.2025.2464778","url":null,"abstract":"<div><div>Decontamination is one of the most effective ways to reduce the hazards of different sulfur mustards. Herein, reactions of various sulfur mustards with four classic decontaminant agents were investigated and their products identified by UPLC-MS/HRMS and GC-MS. Quantitative determinations of individual products in the reaction mixture allows to evaluate the kinetic parameters of the mustard reactions. The degradation rate of 1,2-bis(2-chloroethylthio) ethane and bis(2-chloroethylthioethyl) ether is obviously faster than that of sulfur mustard (SM), but the degradation rate of bis(2-chloroethylthio) methane and bis(2-chloroethylthiomethyl) ether is slower than that of SM. Degradation occurred in a nucleophilic substitution reaction between 2,3-butanedione monoximate, sodium phenolate, and with susceptible sites in the mustards. DS2 mainly exerts its degradation function by elimination reactions. However, 2,3-monoximate degrades sulfur mustards through nucleophilic substitution and elimination reaction. Based on the results of quantumchemical calculations, we assume that the difference of the decontamination rate may be related to the electrostatic potential energy of mustards itself.</div></div>","PeriodicalId":20056,"journal":{"name":"Phosphorus, Sulfur, and Silicon and the Related Elements","volume":"200 3","pages":"Pages 251-260"},"PeriodicalIF":1.4,"publicationDate":"2025-03-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143834981","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

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Polyfunctional dithiocarbamato-containing pyrroles: Synthesis and evaluation of antimicrobial and antioxidant activities 含多官能团二硫代氨基橡胶吡咯：抗菌和抗氧化活性的合成与评价

IF 1.4 4区化学

Phosphorus, Sulfur, and Silicon and the Related Elements Pub Date : 2025-03-04 DOI: 10.1080/10426507.2025.2475948

Alina M. Grozav , Sergiy V. Kemskyi , Mariana Z. Fedoriv , Vitaliy O. Chornous , Lesya M. Saliyeva , Nataliia Yu. Slyvka , Nina D. Yakovychuk , Valentyna S. Dzhuriak , Mykhailo V. Vovk

{"title":"Polyfunctional dithiocarbamato-containing pyrroles: Synthesis and evaluation of antimicrobial and antioxidant activities","authors":"Alina M. Grozav , Sergiy V. Kemskyi , Mariana Z. Fedoriv , Vitaliy O. Chornous , Lesya M. Saliyeva , Nataliia Yu. Slyvka , Nina D. Yakovychuk , Valentyna S. Dzhuriak , Mykhailo V. Vovk","doi":"10.1080/10426507.2025.2475948","DOIUrl":"10.1080/10426507.2025.2475948","url":null,"abstract":"<div><div>A new effective method for the synthesis of 4- and 2-dithiocarbamato methyl substituted polyfunctional pyrroles <strong>5</strong> and <strong>8</strong> that is based on reduction of the corresponding 5-chloro-4-chloromethyl-1<em>H</em>-pyrrol-3-carboxylates <strong>3</strong> and 2-bromomethyl-5-chloro-4-cyano-1<em>H</em>-pyrrol-3-carboxylates <strong>7</strong> with dithiocarbamates of alkali metals or zinc <strong>4</strong> in a solution of DMF at 50 °C has been developed. The structural composition of all synthesized compounds was established by IR, <sup>1</sup>H NMR, and <sup>13</sup>C NMR spectroscopy and chromatography combined with mass spectrometry. Then the antimicrobial activity of all synthesized compounds was checked against the bacterial strains (<em>Staphylococcus aureus ATCC 25923, Escherichia coli ATCC 25922</em>, <em>Proteus vulgaris АТСС 4636</em>, <em>Pseudomonas aeruginosa АТСС 27853</em>, and <em>Klebsiella pneumoniae АТСС 13883</em>) and fungi (<em>Candida albicans АТСС 885/653</em> and <em>Aspergillus niger K9</em>). In addition, the inhibition ability of the compounds against radicals has also been checked. As can be seen from the obtained results, the MIC of the synthesized compounds against the germs ranges between 31.25 and 125 µg/mL, MBC – 31.25–250 µg/mL, and MFC – 62.5–125 µg/mL. On the other hand, the absorption value for the DPPH radicals in ethyl 5-chloro-4-cyano-2-{[(thiomorpholin-4-ylcarbonothioyl)thio]methyl}-1-methyl-1<em>H</em>-pyrrole-3-carboxylate <strong>8b</strong> was 97.3%, while for ethyl 5-chloro-4-cyano-2-({[(dimethylamino)carbonothioyl]thio}methyl)-1-butyl-1<em>H</em>-pyrrole-3-carboxylate <strong>8e</strong> it was 95.6%.</div></div>","PeriodicalId":20056,"journal":{"name":"Phosphorus, Sulfur, and Silicon and the Related Elements","volume":"200 3","pages":"Pages 313-324"},"PeriodicalIF":1.4,"publicationDate":"2025-03-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143834785","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

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On carbon nanocones CNCm[n] and their face index 碳纳米锥CNCm[n]及其表面指数

IF 1.4 4区化学

Phosphorus, Sulfur, and Silicon and the Related Elements Pub Date : 2025-02-01 DOI: 10.1080/10426507.2025.2456205

Shriya Negi , Vijay Kumar Bhat

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Synthesis and antimicrobial evaluation of new quinazolinone derivatives containing thiourea and thiazolidine moieties 含硫脲和噻唑烷的新型喹唑啉酮衍生物的合成及抗菌性能评价

IF 1.4 4区化学

Phosphorus, Sulfur, and Silicon and the Related Elements Pub Date : 2025-02-01 DOI: 10.1080/10426507.2025.2461044

Farzaneh Yazdan Kushkoo , Hojatollah Khabazzadeh , Moj Khaleghi

{"title":"Synthesis and antimicrobial evaluation of new quinazolinone derivatives containing thiourea and thiazolidine moieties","authors":"Farzaneh Yazdan Kushkoo , Hojatollah Khabazzadeh , Moj Khaleghi","doi":"10.1080/10426507.2025.2461044","DOIUrl":"10.1080/10426507.2025.2461044","url":null,"abstract":"<div><div>With the aim of finding novel compounds with good antimicrobial activity to counteract drug resistance, a new series of quinazolinones featuring thiourea and thiazole groups was synthesized through the reaction of 4-amino-N-(4-oxo-2-phenyl-1, 2-dihydroquinazolin-3(4H)-yl)benzamide with methyl isothiocyanate and subsequent treatment with dialkyl acetylene dicarboxylate. All synthesized compounds were characterized by spectroscopic data and elemental analysis. The antimicrobial activity of synthesized compounds was evaluated against two bacteria strains (<em>Escherichia coli</em> PTCC1330; <em>Staphylococcus aureus</em> PTCC 1431) and two fungi strains (<em>Aspergillus niger</em> PTCC5010; <em>Candida albicans</em> ATCC 10231). Almost all products exhibited good antibacterial and antifungal activities which indicated that insertion of thiourea and thiazolidine moieties considerably increased the antimicrobial properties of quinazolinones. Therefore, these compounds can be good candidates for clinical treatments, avoiding possible drug resistance problems in humans.</div></div>","PeriodicalId":20056,"journal":{"name":"Phosphorus, Sulfur, and Silicon and the Related Elements","volume":"200 2","pages":"Pages 152-163"},"PeriodicalIF":1.4,"publicationDate":"2025-02-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143601261","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

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Synthesis, crystal structure and evaluation of antibacterial activity of new hybrid systems containing furan-2-one and chromen-4-thione fragments 呋喃-2-酮和铬-4-硫酮杂化体系的合成、晶体结构及抗菌活性评价

IF 1.4 4区化学

Phosphorus, Sulfur, and Silicon and the Related Elements Pub Date : 2025-02-01 DOI: 10.1080/10426507.2025.2461042

Ekaterina Mikhailovna Arzyamova , Alevtina Yur’evna Yegorova

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Synthesis and characterization of diphenylether-based oxime ligands containing unilaterally substituted 1,3,4-thiadiazole groups and investigation of their some transition metal complexes 单侧取代1,3,4-噻二唑基二苯醚肟配体的合成、表征及其过渡金属配合物的研究

IF 1.4 4区化学

Phosphorus, Sulfur, and Silicon and the Related Elements Pub Date : 2025-02-01 DOI: 10.1080/10426507.2025.2456204

Ahmed Ali Jasim , Ahmed Hamdi Mirghani , Ahmed Saleem Otaiwi , Ahmet Coşkun , Hakan Tahtaci , Saban Uysal

{"title":"Synthesis and characterization of diphenylether-based oxime ligands containing unilaterally substituted 1,3,4-thiadiazole groups and investigation of their some transition metal complexes","authors":"Ahmed Ali Jasim , Ahmed Hamdi Mirghani , Ahmed Saleem Otaiwi , Ahmet Coşkun , Hakan Tahtaci , Saban Uysal","doi":"10.1080/10426507.2025.2456204","DOIUrl":"10.1080/10426507.2025.2456204","url":null,"abstract":"<div><div>In this study, we synthesized six novel oxime ligands derived from substituted 1,3,4-thiadiazoles, along with their corresponding monomeric transition metal complexes involving Co<sup>2+</sup>, Ni<sup>2+</sup>, and Cu<sup>2+</sup> ions. Comprehensive structural characterizations were then performed to analyze these compounds. To achieve this, 4-(chloroacetyl) diphenyl ether was synthesized by reacting diphenyl ether with chloroacetyl chloride using a Friedel–Crafts reaction. The starting oxime compound, (E)-N-hydroxy-2-oxo-2-(4-phenoxyphenyl)acetylmidoyl chloride, was synthesized by reacting 4-(chloroacetyl) diphenyl ether with butyl nitrite in a 1:1 molar ratio, with HCl as the catalyst. The target oxime compounds were subsequently synthesized by reacting substituted 2-amino-1,3,4-thiadiazole derivatives with (E)-N-hydroxy-2-oxo-2-(4-phenoxyphenyl)acetylmidoyl chloride, following established procedures from the literature. The structural characterizations of all synthesized organic compounds were carried out using elemental analysis, FTIR spectroscopy, <sup>1</sup>H and <sup>13</sup>C NMR spectroscopy, and mass spectrometry. The target complexes were synthesized by reacting the ligands with MCl<sub>2</sub>·nH<sub>2</sub>O salts (M = Co<sup>2+</sup>, Ni<sup>2+</sup>, Cu<sup>2+</sup>). Their structures were confirmed using FTIR spectroscopy, magnetic susceptibility measurements, elemental analysis, and ICP-OES.</div></div>","PeriodicalId":20056,"journal":{"name":"Phosphorus, Sulfur, and Silicon and the Related Elements","volume":"200 2","pages":"Pages 133-143"},"PeriodicalIF":1.4,"publicationDate":"2025-02-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143601186","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Review on the synthesis of thiourea-triazine hybrid derivatives and its applications primarily in biological context 硫脲-三嗪杂化衍生物的合成及其在生物领域的应用综述

IF 1.4 4区化学

Phosphorus, Sulfur, and Silicon and the Related Elements Pub Date : 2025-02-01 DOI: 10.1080/10426507.2025.2457458

Ainaa Nadiah Abd Halim , Zainab Ngaini

{"title":"Review on the synthesis of thiourea-triazine hybrid derivatives and its applications primarily in biological context","authors":"Ainaa Nadiah Abd Halim , Zainab Ngaini","doi":"10.1080/10426507.2025.2457458","DOIUrl":"10.1080/10426507.2025.2457458","url":null,"abstract":"<div><div>Thiourea and triazine are heteroatom scaffolds that have been intensively employed for structural modification, particularly in the development of new drugs and the exploration of new applications. Recent advances have initiated the concept of merging these two moieties, maximizing the potential and enhancing the properties. This review is a comprehensive compilation highlighting the various synthesis pathways of the compound comprised of both thiourea and triazine scaffolds expressed in the form of fused triazinethione as well as <em>mono</em>-, <em>bis</em>-, and <em>tris</em>-thiourea-triazine structures. The produced compounds indefinitely showed the potential to be applied to various fields and industries. While this compilation majorly highlighted the biological capabilities of the thiourea–triazine compounds, a glimpse of other material chemistry applications was also included on the basis of the respective compound as documented by precedent literature. Therefore, this review is significant for structural modification in the field of synthetic chemistry for intended applications.</div></div>","PeriodicalId":20056,"journal":{"name":"Phosphorus, Sulfur, and Silicon and the Related Elements","volume":"200 2","pages":"Pages 109-132"},"PeriodicalIF":1.4,"publicationDate":"2025-02-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143601264","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

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Reduction of organic sulfones, selenones and tellurones using magnesium and methanol as reductant 以镁和甲醇为还原剂还原有机砜、硒酮和碲酮

IF 1.4 4区化学

Phosphorus, Sulfur, and Silicon and the Related Elements Pub Date : 2025-02-01 DOI: 10.1080/10426507.2025.2463459

Kiran Arora , J. M. Khurana

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Chemical and natural synthesis of hydroxyapatite nanoparticles for biomedical applications: a review 用于生物医学应用的羟基磷灰石纳米颗粒的化学和自然合成：综述

IF 1.4 4区化学

Phosphorus, Sulfur, and Silicon and the Related Elements Pub Date : 2025-01-02 DOI: 10.1080/10426507.2024.2437009

A. S. Shalfia Judit , R. Feyolah Herin , S. Sebastiammal , J. Henry , M. Santhosh , M. Santhamoorthy

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Experimental investigation of pyridine removal using vulcanized oil shale 硫化油页岩脱除吡啶的实验研究

IF 1.4 4区化学

Phosphorus, Sulfur, and Silicon and the Related Elements Pub Date : 2025-01-02 DOI: 10.1080/10426507.2025.2452211

Qinqin Li , Xiaochun Tian , Ao Sun , Chengyu Wang , Kangle Ding

{"title":"Experimental investigation of pyridine removal using vulcanized oil shale","authors":"Qinqin Li , Xiaochun Tian , Ao Sun , Chengyu Wang , Kangle Ding","doi":"10.1080/10426507.2025.2452211","DOIUrl":"10.1080/10426507.2025.2452211","url":null,"abstract":"<div><div>The study systematically conducted orthogonal and univariate experiments to determine the optimal parameters for pyridine removal using vulcanized oil shale. The findings revealed that the key determinants of pyridine adsorption onto vulcanized oil shale included the pH level of the pyridine solution, contact time, initial pyridine concentration, and the quantity of vulcanized oil shale introduced into the system. Under optimal adsorption conditions, the vulcanized oil shale achieved a 48.00% adsorption efficiency and an equilibrium adsorption capacity of 4.83 mg·g<sup>−1</sup>. In contrast, the untreated oil shale exhibited a comparatively reduced adsorption efficiency of 22.88% under its respective optimal conditions. The research further examined the adsorption kinetics and isothermal adsorption models for both types of oil shale. The kinetic data indicated that pyridine adsorption followed a pseudo-second-order model. The pyridine adsorption isotherms for both oil shale and vulcanized oil shale were best described by the Freundlich model, compared to the Langmuir model. These findings provide significant insights into the utilization of vulcanized oil shale for the efficient treatment of low-concentration pyridine wastewater, potentially contributing to environmental remediation and pollution control strategies.</div></div>","PeriodicalId":20056,"journal":{"name":"Phosphorus, Sulfur, and Silicon and the Related Elements","volume":"200 1","pages":"Pages 90-100"},"PeriodicalIF":1.4,"publicationDate":"2025-01-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143360823","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0