{"title":"A novel stacking ensemble learner for predicting residual strength of corroded pipelines","authors":"Qiankun Wang, Hongfang Lu","doi":"10.1038/s41529-024-00508-z","DOIUrl":"10.1038/s41529-024-00508-z","url":null,"abstract":"Accurately assessing the residual strength of corroded oil and gas pipelines is crucial for ensuring their safe and stable operation. Machine learning techniques have shown promise in addressing this challenge due to their ability to handle complex, non-linear relationships in data. Unlike previous studies that primarily focused on enhancing prediction accuracy through the optimization of single models, this work shifts the emphasis to a different approach: stacking ensemble learning. This study applies a stacking model composed of seven base learners and three meta-learners to predict the residual strength of pipelines using a dataset of 453 instances. Automated hyperparameter tuning libraries are utilized to search for optimal hyperparameters. By evaluating various combinations of base learners and meta-learners, the optimal stacking configuration was determined. The results demonstrate that the stacking model, using k-nearest neighbors as the meta-learner alongside seven base learners, delivers the best predictive performance, with a coefficient of determination of 0.959. Compared to individual models, the stacking model also significantly improves generalization performance. However, the stacking model’s effectiveness on low-strength pipelines is limited due to the small sample size. Furthermore, incorporating original features into the second-layer model did not significantly enhance performance, likely because the first-layer model had already extracted most of the critical features. Given the marginal contribution of model optimization to prediction accuracy, this work offers a novel perspective for improving model performance. The findings have important practical implications for the integrity assessment of corroded pipelines.","PeriodicalId":19270,"journal":{"name":"npj Materials Degradation","volume":" ","pages":"1-10"},"PeriodicalIF":6.6,"publicationDate":"2024-08-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.nature.com/articles/s41529-024-00508-z.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142091232","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Metallic coatings in offshore wind sector—a mini review","authors":"Berenika Syrek-Gerstenkorn, Shiladitya Paul","doi":"10.1038/s41529-024-00480-8","DOIUrl":"10.1038/s41529-024-00480-8","url":null,"abstract":"Offshore wind energy is pivotal for achieving global renewable energy targets. As of 2022, 12% of global electricity is derived from wind and solar power, with an imperative to reach 90% renewable energy by 2050. The offshore wind industry, constituting 7.1% of global wind power, plays a central role in meeting these goals. The Global Wind Energy Alliance envisions reaching 380 GW by 2030 and 2000 GW by 2050. This paper addresses corrosion challenges in the offshore environment, emphasising sacrificial coatings as an effective mitigation strategy. By critically evaluating the latest revisions of widely used international standards such as Norsok M-501, ISO 12944, and VGBE-S-021, the study focuses on zinc- and aluminium-rich coatings that form a galvanic couple with steel, providing cathodic protection. Liquid coatings, thermally sprayed coatings, and hot-dip galvanised coatings are examined for their applicability with discussion on the advantages and limitations of these systems. Considerations of cost, environmental impact, and testing methods are crucial in selecting corrosion mitigation strategies. The review alludes to these requirements and highlights the significance of durable solutions, such as sacrificial coatings, in ensuring the long-term integrity of offshore wind structures amid the sector’s rapid expansion. Further collaborative research, involving industry and academia, is recommended to refine testing regimes and explore innovative coating solutions.","PeriodicalId":19270,"journal":{"name":"npj Materials Degradation","volume":" ","pages":"1-11"},"PeriodicalIF":6.6,"publicationDate":"2024-08-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.nature.com/articles/s41529-024-00480-8.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142021818","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Molten CMAS resistance strategy for PS-PVD TBCs based on laser textured and Al-modified bionic structure","authors":"Xueshi Zhuo, Xiaomao Sun, Jian Wu, Hao Dong, Peng Shen, Xiaofeng Zhang, Xuesong Mei, Jianlei Cui, Zhengjie Fan","doi":"10.1038/s41529-024-00505-2","DOIUrl":"10.1038/s41529-024-00505-2","url":null,"abstract":"Plasma spray-physical vapor deposition (PS-PVD) is a promising third-generation thermal barrier coatings (TBCs) technique. Feather-like columnar TBCs with excellent strain tolerance and low thermal conductivity can be achieved using PS-PVD. However, molten CMAS (CaO–MgO–Al2O3–SiO2) can penetrate coatings and accelerate PS-PVD TBCs failure due to the feather-like columnar structure. Hence, a strategy is proposed to alleviate molten CMAS corrosion. The super-hydrophobicity structure is fabricated via laser texturing on the surface of PS-PVD TBCs to repel molten CMAS wetting and spreading. Then, a thin layer of the Al-film is deposited on the laser-textured surface. Next, the Al-modified layer is in situ synthesized after vacuum heat treatment, preventing the infiltration of molten CMAS into the TBCs and reducing the coating damage. The results show that the contact angle of laser textured and Al-modified PS-PVD TBCs (LT-Al) at room temperature increased from 12.3° to 168.8°. The wetting and spreading behavior of molten CMAS of as-sprayed (AS), laser textured (LT), and LT-Al coatings is observed in situ at 1230 °C for 1800 s. The LT-Al coatings exhibited excellent CMAS corrosion resistance, attributed to the laser-textured micro-nano structures and Al-modified layer protection. The findings may be an effective approach for solving the disadvantage of PS-PVD feather-like columnar structure TBCs.","PeriodicalId":19270,"journal":{"name":"npj Materials Degradation","volume":" ","pages":"1-10"},"PeriodicalIF":6.6,"publicationDate":"2024-08-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.nature.com/articles/s41529-024-00505-2.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142021841","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Xin Chen, Marta Pozuelo, Maxim Gussev, Matthew Chancey, Yongqiang Wang, Magdalena Balonis, Mathieu Bauchy, Gaurav Sant
{"title":"Microstructurally resolved electrochemical evolution of mechanical- and irradiation-induced damage in nuclear alloys","authors":"Xin Chen, Marta Pozuelo, Maxim Gussev, Matthew Chancey, Yongqiang Wang, Magdalena Balonis, Mathieu Bauchy, Gaurav Sant","doi":"10.1038/s41529-024-00500-7","DOIUrl":"10.1038/s41529-024-00500-7","url":null,"abstract":"There is a need for high-throughput, scale-relevant, and direct electrochemical analysis to understand the corrosion behavior and sensitivity of nuclear materials that are exposed to extreme (high pressure, temperature, and radiation exposure) environments. We demonstrate the multi-scale, multi-modal application of scanning electrochemical cell microscopy (SECCM) to electrochemically profile corrosion alterations in nuclear alloys in a microstructurally resolved manner. Particularly, we identify that both mechanically deformed and irradiated microstructures show reduced charge-transfer resistance that leads to accelerated oxidation. We highlight that the effects of mechanical deformation and irradiation are synergistic, and may in fact, superimpose each other, with implications including general-, galvanic-, and/or irradiation-activated stress-corrosion cracking. Taken together, we highlight the ability of non-destructive, electrochemical interrogations to ascertain how microstructural alterations result in changes in the corrosion tendency of a nuclear alloy: knowledge which has implications to rank, qualify and examine alloys for use in nuclear construction applications.","PeriodicalId":19270,"journal":{"name":"npj Materials Degradation","volume":" ","pages":"1-8"},"PeriodicalIF":6.6,"publicationDate":"2024-08-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.nature.com/articles/s41529-024-00500-7.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142013703","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Sara E. Gilson, Volodymyr Svitlyk, Andrey A. Bukaemskiy, Jonas Niessen, Theresa Lender, Gabriel L. Murphy, Maximilian Henkes, Holger Lippold, Julien Marquardt, Shavkat Akhmadaliev, Christoph Hennig, Bjoern Winkler, Thorsten Tonnesen, Lars Peters, Cornelius Fischer, Nina Huittinen
{"title":"Microstructural investigation of Au ion-irradiated Eu-doped LaPO4 ceramics and single crystals","authors":"Sara E. Gilson, Volodymyr Svitlyk, Andrey A. Bukaemskiy, Jonas Niessen, Theresa Lender, Gabriel L. Murphy, Maximilian Henkes, Holger Lippold, Julien Marquardt, Shavkat Akhmadaliev, Christoph Hennig, Bjoern Winkler, Thorsten Tonnesen, Lars Peters, Cornelius Fischer, Nina Huittinen","doi":"10.1038/s41529-024-00504-3","DOIUrl":"10.1038/s41529-024-00504-3","url":null,"abstract":"Ceramics and single crystals of LaPO4 monazite doped with Eu(III) were irradiated with 14 MeV Au5+ ions at three different fluences. Changes to crystallinity, local coordination environments, and topography were probed using grazing-incidence X-ray diffraction (GIXRD), vertical scanning interferometry (VSI), scanning electron microscopy (SEM), Raman, and luminescence spectroscopy. GIXRD data of the ceramics revealed fluence dependent amorphization. A similar level of amorphization was detected for samples irradiated with 5 × 1013 ions/cm2 and 1 × 1014 ions/cm2, whereas the sample irradiated with the highest fluence of 1 × 1015 ions/cm2 appeared slightly less amorphous. VSI showed clear swelling of entire grains at the highest ion fluence, while more localized damage to grain boundaries was detected for ceramic samples irradiated at the lowest fluence. Single crystal specimens showed no pronounced topography changes following irradiation. SEM images of the ceramic irradiated at the highest fluence showed topological features indicative of grain surface melting. Raman and luminescence data showed a different degree of disorder in polycrystalline vs. single crystal samples. While changes to PO4 vibrational modes were observed in the ceramics, changes were more subtle or not present in the single crystals. The opposite was observed when probing the local Ln-O environment using Eu(III) luminescence, where the larger changes in terms of an elongation of the Eu-O (or La-O) bond and an increasing relative disorder with increasing fluence were observed only for the single crystals. The dissimilar trends observed in irradiated single crystals and ceramics indicate that grain boundary chemistry likely plays a significant role in the radiation response.","PeriodicalId":19270,"journal":{"name":"npj Materials Degradation","volume":" ","pages":"1-11"},"PeriodicalIF":6.6,"publicationDate":"2024-08-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.nature.com/articles/s41529-024-00504-3.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142002624","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Léa Brunswic, Frédéric Angeli, Thibault Charpentier, Stéphane Gin, Pierre Asplanato, Huseyin Kaya, Seong H. Kim
{"title":"Comparative study of the structure and durability of commercial silicate glasses for food consumption and cosmetic packaging","authors":"Léa Brunswic, Frédéric Angeli, Thibault Charpentier, Stéphane Gin, Pierre Asplanato, Huseyin Kaya, Seong H. Kim","doi":"10.1038/s41529-024-00502-5","DOIUrl":"10.1038/s41529-024-00502-5","url":null,"abstract":"Four commercial glass compositions were investigated to understand their mechanisms of alteration in light of the current and future regulations on food contact materials. Lead crystal (fine glassware), soda-lime (food and cosmetic containers), borosilicate (cookware) and barium glass (tableware) powders and slabs were altered for 3 years, in acetic acid (4% vol) at pH = 2.4 and 70 °C. The leaching solution was analyzed by ICP-AES while glass slabs were investigated by ToF-SIMS and Spectroscopic Ellipsometry. As a result, in acidic medium, the polymerization of the silicate network as well as the glass composition impacted the alteration rates and depleted depths of alkalis and earth-alkalis elements. Yet the rate of hydrolysis measured from the release of Si, remained similar under identical alteration conditions, whatever the glass structure and composition. For lead crystal glass, repolymerization of the silicate network was observed in the course of alteration.","PeriodicalId":19270,"journal":{"name":"npj Materials Degradation","volume":" ","pages":"1-12"},"PeriodicalIF":6.6,"publicationDate":"2024-08-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.nature.com/articles/s41529-024-00502-5.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142002632","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Nicolas Pinochet, Lucie Pirot-Berson, Romain Couderc, Sandrine Therias
{"title":"UV LED ageing of polymers for PV cell encapsulation","authors":"Nicolas Pinochet, Lucie Pirot-Berson, Romain Couderc, Sandrine Therias","doi":"10.1038/s41529-024-00501-6","DOIUrl":"10.1038/s41529-024-00501-6","url":null,"abstract":"Encapsulation polymers in terrestrial solar modules degrade due to ultraviolet radiation from the sun. To assess a polymer’s durability under UV light, accelerated aging tests can be conducted. A new LEDs device allows us to investigate the effects of temperature, irradiation, and UV source spectrum on the photooxidation mechanism and kinetics of two polyethylene-based commercial encapsulants, differentiated by the presence or absence of UV absorbers. The photooxidation rate of the polymer matrix increases as the temperature and irradiance increase between 62 and 82 °C, and 12 and 28 W.m−2, respectively. In the last case, the photooxidation rate is not proportional to the number of photons. Finally, we observed different distributions of degradation products under UVB radiation at 305 nm compared to those under UVA radiation at 365 nm. UVB photons enable Norrish reactions that are not possible with UVA alone. Special care is needed to maintain a balance between UVA and UVB photons to ensure representative durability tests. With a few adjustments to their emission spectrum, UV LED devices appear to be good candidates for accelerated aging of encapsulation polymers.","PeriodicalId":19270,"journal":{"name":"npj Materials Degradation","volume":" ","pages":"1-8"},"PeriodicalIF":6.6,"publicationDate":"2024-08-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.nature.com/articles/s41529-024-00501-6.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141986147","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Nakkyu Chae, Seungjin Seo, Richard I. Foster, Sungyeol Choi
{"title":"Oxic corrosion model for KAERI Reference disposal system via O2 consumption reactions and mixed-potential theory","authors":"Nakkyu Chae, Seungjin Seo, Richard I. Foster, Sungyeol Choi","doi":"10.1038/s41529-024-00497-z","DOIUrl":"10.1038/s41529-024-00497-z","url":null,"abstract":"The durability of copper (Cu) canisters against corrosion is critical for the licensing of deep geological repositories. Assessing oxic corrosion, a primary degradation mechanism, is essential for ensuring the reliability of such repositories. Due to the complex interactions influencing oxic corrosion, a comprehensive model is necessary for evaluating Cu canister corrosion. This study develops a model for the KAERI Reference Disposal System (KRS), incorporating mixed-potential theory with key O2 consumption reactions, including Cu corrosion, Cu(I) oxidation, FeS2 oxidation, aerobic microbial activity, and O2 dissolution and consumption. Simulation of 11 scenarios revealed that the representative KRS case would experience a maximum corrosion depth of 9.3 μm on the Cu canister after 2.3 years due to oxic corrosion, under conditions that are unfavorable for the initiation of pitting corrosion. These results suggest that oxic corrosion is not a threat to the isolation of spent nuclear fuels in KRS.","PeriodicalId":19270,"journal":{"name":"npj Materials Degradation","volume":" ","pages":"1-12"},"PeriodicalIF":6.6,"publicationDate":"2024-08-07","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.nature.com/articles/s41529-024-00497-z.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141939484","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
D. C. Williams, A. Riahi, A. Carcea, J. D. Giallonardo, P. Keech, S. Y. Persaud, M. R. Daymond, R. C. Newman
{"title":"Hydrogen embrittlement and strain rate sensitivity of electrodeposited copper: part I – the effect of hydrogen content","authors":"D. C. Williams, A. Riahi, A. Carcea, J. D. Giallonardo, P. Keech, S. Y. Persaud, M. R. Daymond, R. C. Newman","doi":"10.1038/s41529-024-00498-y","DOIUrl":"10.1038/s41529-024-00498-y","url":null,"abstract":"Slow strain rate tensile testing was conducted on electrodeposited copper, which is a candidate coating material for used nuclear fuel containers. Embrittlement was observed in electrodeposited copper containing 26.4 ± 1.0 ppm hydrogen, with a strain rate sensitivity such that the embrittlement was exacerbated at lower strain rate (5 × 10−7 s−1). Tensile tests conducted at 100° and 200 °C also intensified embrittlement when compared with tests conducted at room temperature. In contrast, electrodeposited copper containing only 5.25 ± 0.97 ppm hydrogen exhibited ductile behavior at all tested strain rates and temperatures. These findings suggest that a previously unexplained slow strain rate hydrogen embrittlement can operate in electrodeposited copper provided that the hydrogen concentration is sufficiently high. Further analyses revealed that the deformation of embrittled copper is achieved by the formation of internal microcracks which coalesce at the point of failure.","PeriodicalId":19270,"journal":{"name":"npj Materials Degradation","volume":" ","pages":"1-9"},"PeriodicalIF":6.6,"publicationDate":"2024-08-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.nature.com/articles/s41529-024-00498-y.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141939417","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
A. D. Malla, J. H. Sullivan, D. J. Penney, M. Goldsworthy, D. Britton, G. Williams, F. Goodwin, A. P. Cardoso
{"title":"Mechanistic investigation on the influence of coating weights on the corrosion behaviour of hot-dip-galvanised Zn-Mg-Al coatings","authors":"A. D. Malla, J. H. Sullivan, D. J. Penney, M. Goldsworthy, D. Britton, G. Williams, F. Goodwin, A. P. Cardoso","doi":"10.1038/s41529-024-00494-2","DOIUrl":"10.1038/s41529-024-00494-2","url":null,"abstract":"Time-lapse Microscopy, scanning vibrating electrode technique and potentiodynamic methods were used to study the influence of increasing coating weight (80–310 gm–2) on microstructure, cut-edge and surface corrosion of Zn-Mg-Al coatings in 0.17 M NaCl. Cut-edge corrosion was similar for all coatings due to the oxygen reduction reaction becoming diffusion-limited. A 64% reduction in surface corrosion was observed for high coating weights through increases in eutectic volume fraction. Spatial and temporal corrosion mechanisms were controlled by microstructural morphological differences as coating weight varied. 80 g.m–2 coatings demonstrated lateral anodic spreading potentially reducing coating penetration rates despite their higher surface corrosion rate.","PeriodicalId":19270,"journal":{"name":"npj Materials Degradation","volume":" ","pages":"1-14"},"PeriodicalIF":6.6,"publicationDate":"2024-07-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.nature.com/articles/s41529-024-00494-2.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141871726","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}