Takashi Hisatomi, Taro Yamada, Hiroshi Nishiyama, Tsuyoshi Takata, Kazunari Domen
{"title":"Materials and systems for large-scale photocatalytic water splitting","authors":"Takashi Hisatomi, Taro Yamada, Hiroshi Nishiyama, Tsuyoshi Takata, Kazunari Domen","doi":"10.1038/s41578-025-00823-0","DOIUrl":"https://doi.org/10.1038/s41578-025-00823-0","url":null,"abstract":"<p>Sunlight-driven photocatalytic water splitting has been studied as a means of producing renewable green solar hydrogen on a large scale at low cost. However, the research community has yet to define a common vision for practical solar hydrogen production, which requires not only photocatalyst materials that drive water-splitting reactions with high efficiency under sunlight but also systems and processes that can be scaled up. Herein, we discuss the current status and challenges in the development of materials, systems and processes for solar hydrogen production via photocatalytic water splitting. Despite the remarkable scientific progress in the development of photocatalyst materials and reaction systems over the past decade, many technological challenges remain before this technology can be put to practical use in terms of efficiency improvement, mass production, large-scale application of photocatalysts, cost reduction, process-efficiency improvement for reaction systems, and societal acceptance. It is, therefore, imperative to stimulate and accelerate research and development and large-scale demonstrations of hydrogen production via photocatalytic water splitting through collaborative efforts among industry, government and academia.</p>","PeriodicalId":19081,"journal":{"name":"Nature Reviews Materials","volume":"15 1","pages":""},"PeriodicalIF":83.5,"publicationDate":"2025-07-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144629787","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Interfacial insight","authors":"Claire Ashworth","doi":"10.1038/s41578-025-00827-w","DOIUrl":"https://doi.org/10.1038/s41578-025-00827-w","url":null,"abstract":"An article in Science Advances reports a cryo-electron microscopy approach for the nanoscale imaging of dynamic interfaces in lithium metal batteries.","PeriodicalId":19081,"journal":{"name":"Nature Reviews Materials","volume":"148 1","pages":""},"PeriodicalIF":83.5,"publicationDate":"2025-07-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144547512","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Yun Zhao, Hao Du, Yuqiong Kang, Jie Zhang, Bo Lan, Zhenyu Guo, Maria-Magdalena Titirici, Yunlong Zhao, Naser Tavajohi, Feiyu Kang, Baohua Li
{"title":"Spent battery regeneration for better recycling","authors":"Yun Zhao, Hao Du, Yuqiong Kang, Jie Zhang, Bo Lan, Zhenyu Guo, Maria-Magdalena Titirici, Yunlong Zhao, Naser Tavajohi, Feiyu Kang, Baohua Li","doi":"10.1038/s41578-025-00816-z","DOIUrl":"https://doi.org/10.1038/s41578-025-00816-z","url":null,"abstract":"Current lithium-ion battery recycling extracts valuable metals while discarding much of the battery’s leftover value. An emerging strategy called direct battery regeneration upends this model, restoring the battery’s performance without taking it apart — presenting a more efficient, sustainable option for end-of-life batteries.","PeriodicalId":19081,"journal":{"name":"Nature Reviews Materials","volume":"22 1","pages":""},"PeriodicalIF":83.5,"publicationDate":"2025-07-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144520823","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Jesse Kok, Petru P. Albertini, Jari Leemans, Raffaella Buonsanti, Thomas Burdyny
{"title":"Publisher Correction: Overcoming copper stability challenges in CO2 electrolysis","authors":"Jesse Kok, Petru P. Albertini, Jari Leemans, Raffaella Buonsanti, Thomas Burdyny","doi":"10.1038/s41578-025-00825-y","DOIUrl":"https://doi.org/10.1038/s41578-025-00825-y","url":null,"abstract":"<p>Correction to: <i>Nature Reviews Materials</i> https://doi.org/10.1038/s41578-025-00815-0, published online 16 June 2025.</p>","PeriodicalId":19081,"journal":{"name":"Nature Reviews Materials","volume":"27 1","pages":""},"PeriodicalIF":83.5,"publicationDate":"2025-06-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144503462","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Paul Wrede, Eva Remlova, Yi Chen, Xosé Luís Deán-Ben, Metin Sitti, Daniel Razansky
{"title":"Synergistic integration of materials in medical microrobots for advanced imaging and actuation","authors":"Paul Wrede, Eva Remlova, Yi Chen, Xosé Luís Deán-Ben, Metin Sitti, Daniel Razansky","doi":"10.1038/s41578-025-00811-4","DOIUrl":"https://doi.org/10.1038/s41578-025-00811-4","url":null,"abstract":"<p>Medical microrobotics capitalizes on smart materials to target specific body sites effectively, precisely and locally, thus holding promise to revolutionize precision medicine in the future. Advances in material science and microfabrication or nanofabrication techniques have facilitated the implementation of a myriad of functionalities into microrobots. Efficient navigation and monitoring of microrobots within the highly dynamic and often inaccessible environment of living mammalian tissues is paramount for their effective in vivo applications and eventual clinical translation. This need calls for the deployment of biomedical imaging modalities with adequate sensitivity, penetration depth and spatiotemporal resolution, as well as for efficient integration of biocompatible contrast materials into microrobots. In this Review, we discuss emerging approaches for multiplexed imaging and actuation of microrobots within complex biological environments, focusing on the synergistic combination of responsive and contrasting materials to achieve desired morphological and functional properties, in vivo visibility and biosafety. The convergence between microrobotics and biomedical imaging paves the way for a new generation of medical microrobots enabling the use of energy for both mechanical actuation and efficient monitoring of their activity in vivo.</p>","PeriodicalId":19081,"journal":{"name":"Nature Reviews Materials","volume":"25 1","pages":""},"PeriodicalIF":83.5,"publicationDate":"2025-06-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144500785","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Ana C. C. Dutra, Benedek A. Goldmann, M. Saiful Islam, James A. Dawson
{"title":"Understanding solid-state battery electrolytes using atomistic modelling and machine learning","authors":"Ana C. C. Dutra, Benedek A. Goldmann, M. Saiful Islam, James A. Dawson","doi":"10.1038/s41578-025-00817-y","DOIUrl":"https://doi.org/10.1038/s41578-025-00817-y","url":null,"abstract":"<p>Solid-state batteries that use solid electrolytes are attracting interest for their potential safety, stability and high energy density, making them ideal for next-generation technologies including electric vehicles and grid-scale renewable energy storage. Advances in solid electrolytes require the design and optimization of current and new materials, informed by a deeper understanding of their properties on the atomic and nanoscale. This Review highlights progress in using atomistic modelling and machine learning techniques to gain valuable insights into inorganic crystalline solid electrolytes for lithium-based and sodium-based batteries. We discuss computational studies on oxide, sulfide and halide materials that examine three fundamental properties critical to their performance as solid electrolytes: fast-ion conduction mechanisms, interfacial effects and chemical stability. The resulting insights help to identify design strategies for the future development of improved solid-state batteries.</p>","PeriodicalId":19081,"journal":{"name":"Nature Reviews Materials","volume":"20 1","pages":""},"PeriodicalIF":83.5,"publicationDate":"2025-06-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144479162","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Ionic potential for battery materials","authors":"Qidi Wang, Yong-Sheng Hu, Hong Li, Hui-Ming Cheng, Tianshou Zhao, Chenglong Zhao","doi":"10.1038/s41578-025-00822-1","DOIUrl":"https://doi.org/10.1038/s41578-025-00822-1","url":null,"abstract":"<p>Developing high-performance rechargeable batteries requires a revolutionary advancement in battery materials, guided by a fundamental understanding of their underlying science and mechanisms. However, this task remains a challenge owing to the complex relationship among composition, structure and property in electrode and electrolyte materials. Ionic potential, a concept derived from geochemistry, has been incorporated into battery materials research since 2020 as a methodology for predicting and optimizing their functional properties. Defined as the ratio of charge number of an ion to its ionic radius, ionic potential serves as a measure of the interaction strength within the structure of a material. In this Perspective, we explore the role of ionic potential in guiding the design of advanced materials for rechargeable batteries. Specifically, we discuss how integrating ionic potential into material design frameworks can capture critical structural interactions, thereby enabling improvements in properties such as ionic conductivity, redox activity and phase transition behaviours. Furthermore, we identify the broader relevance of ionic potential in battery systems, highlighting its potential in advancing fundamental understanding and performance capabilities in battery technology.</p>","PeriodicalId":19081,"journal":{"name":"Nature Reviews Materials","volume":"20 1","pages":""},"PeriodicalIF":83.5,"publicationDate":"2025-06-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144370468","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Hye Jin Kim, Ja Hoon Koo, Seunghwan Lee, Taeghwan Hyeon, Dae-Hyeong Kim
{"title":"Materials design and integration strategies for soft bioelectronics in digital healthcare","authors":"Hye Jin Kim, Ja Hoon Koo, Seunghwan Lee, Taeghwan Hyeon, Dae-Hyeong Kim","doi":"10.1038/s41578-025-00819-w","DOIUrl":"https://doi.org/10.1038/s41578-025-00819-w","url":null,"abstract":"<p>Advancements in bioelectronics are revolutionizing traditional healthcare by shifting the focus from in-hospital disease diagnosis and treatment to at-home continuous preventive care. This transformation integrates real-time health monitoring and point-of-care interventional therapies and enables artificial intelligence-based health management strategies. However, the mechanical mismatch between rigid bioelectronic devices and soft biological tissues presents important challenges, particularly in long-term applications, including poor adhesion, tissue degeneration, high noise level, signal interference and device instability. To address these challenges, soft bioelectronics — leveraging high-performance, tissue-mimicking and mechanically soft materials — has emerged as a disruptive solution. This Review highlights advancements in materials design and system-level integration strategies for soft bioelectronics, driving the development of next-generation digital healthcare technologies. We categorize materials design approaches, introduce fabrication techniques for soft bioelectronics and explore integration methods. Furthermore, we showcase applications of wearable and implantable soft bioelectronics, demonstrating their potential for continuous health monitoring and therapeutic interventions, ultimately enabling closed-loop health management.</p>","PeriodicalId":19081,"journal":{"name":"Nature Reviews Materials","volume":"18 1","pages":""},"PeriodicalIF":83.5,"publicationDate":"2025-06-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144341368","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Roy van der Meel, Paul A. Wender, Olivia M. Merkel, Irene Lostalé-Seijo, Javier Montenegro, Ali Miserez, Quentin Laurent, Hanadi Sleiman, Paola Luciani
{"title":"Next-generation materials for nucleic acid delivery","authors":"Roy van der Meel, Paul A. Wender, Olivia M. Merkel, Irene Lostalé-Seijo, Javier Montenegro, Ali Miserez, Quentin Laurent, Hanadi Sleiman, Paola Luciani","doi":"10.1038/s41578-025-00814-1","DOIUrl":"https://doi.org/10.1038/s41578-025-00814-1","url":null,"abstract":"Efficient and targeted delivery of nucleic acids is critical for realizing the full therapeutic potential of gene editing, vaccines and RNA-based drugs, and emerging delivery platforms offer innovative solutions through their diverse architectures, tunable properties and distinct biological interactions. In this Viewpoint, researchers working across different delivery platforms — including lipid nanoparticles, synthetic polymers, peptide amphiphiles, coacervate microdroplets, DNA nanostructures and extracellular vesicles — discuss the most promising directions and the main challenges in shaping the future of nucleic acid delivery.","PeriodicalId":19081,"journal":{"name":"Nature Reviews Materials","volume":"43 1","pages":""},"PeriodicalIF":83.5,"publicationDate":"2025-06-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144296065","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Jesse Kok, Petru P. Albertini, Jari Leemans, Raffaella Buonsanti, Thomas Burdyny
{"title":"Overcoming copper stability challenges in CO2 electrolysis","authors":"Jesse Kok, Petru P. Albertini, Jari Leemans, Raffaella Buonsanti, Thomas Burdyny","doi":"10.1038/s41578-025-00815-0","DOIUrl":"https://doi.org/10.1038/s41578-025-00815-0","url":null,"abstract":"<p>Copper and copper-based catalysts can electrochemically convert CO<sub>2</sub> into ethylene and higher alcohols, among other products, at room temperature and pressure. This approach may be suitable for the production of high-value compounds. However, such a promising reaction is heavily burdened by the instability of copper during CO<sub>2</sub> reduction. To date, non-copper catalysts have also failed to supplant the activity and selectivity of copper, leaving CO<sub>2</sub>-to-C<sub>2</sub> electrolysis in the balance. In this Perspective, we discuss copper catalyst instability from both the atomistic and the microstructure viewpoint. We motivate that increased fundamental understanding, material design and operational approaches, along with increased reporting of failure mechanisms, will contribute to overcoming the barriers to multi-year operation. Our narrative focuses on the copper catalyst reconstruction occurring during CO<sub>2</sub> reduction as one of the major causes inducing loss of C<sub>2</sub> activity. We conclude with a rational path forward towards longer operations of CO<sub>2</sub>-to-C<sub>2</sub> electrolysis.</p>","PeriodicalId":19081,"journal":{"name":"Nature Reviews Materials","volume":"230 1","pages":""},"PeriodicalIF":83.5,"publicationDate":"2025-06-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144296063","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}