Elyse Barré, Medha Dandu, Sudipta Kundu, Aditya Sood, Felipe H. da Jornada, Archana Raja
{"title":"Engineering interlayer hybridization in van der Waals bilayers","authors":"Elyse Barré, Medha Dandu, Sudipta Kundu, Aditya Sood, Felipe H. da Jornada, Archana Raja","doi":"10.1038/s41578-024-00666-1","DOIUrl":"10.1038/s41578-024-00666-1","url":null,"abstract":"In the decade since the introduction of van der Waals (vdW) heterostructures for designer devices, there has been an abundance of studies on the artificial assembly of vdW heterostructures for light–matter interactions, charge and energy transport, and other condensed matter phenomena. The interlayer interactions or hybridization in these systems non-trivially impact their physical characteristics and are sensitive to a complex set of interdependent, externally tunable parameters. There lacks a coherent perspective on how these external stimuli can be used together to engineer materials with desired properties. Here, we systematically address how interlayer hybridization in semiconducting vdW bilayers can be controlled for the realization of different properties in vertically stacked structures. We also discuss new research directions to engineer the interactions beyond bilayers and highlight opportunities that arise when different tuning parameters are simultaneously coupled. Interlayer hybridization in van der Waals stacks is key to understanding their physical properties. This Perspective article discusses the various parameters influencing interlayer hybridization and how they can be controlled, providing a comprehensive guide for designing materials with desired properties.","PeriodicalId":19081,"journal":{"name":"Nature Reviews Materials","volume":"9 7","pages":"499-508"},"PeriodicalIF":79.8,"publicationDate":"2024-04-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140538264","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Protein materials, by blueprint","authors":"Ariane Vartanian","doi":"10.1038/s41578-024-00676-z","DOIUrl":"10.1038/s41578-024-00676-z","url":null,"abstract":"An article in Nature describes regular, modular protein building blocks that can be combined — following a standard blueprint — into a variety of architectures.","PeriodicalId":19081,"journal":{"name":"Nature Reviews Materials","volume":"9 5","pages":"301-301"},"PeriodicalIF":83.5,"publicationDate":"2024-04-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140349587","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"External-pressure–electrochemistry coupling in solid-state lithium metal batteries","authors":"Xia Hu, Zhijia Zhang, Xiang Zhang, Yao Wang, Xu Yang, Xia Wang, Miryam Fayena-Greenstein, Hadas Alon Yehezkel, Steven Langford, Dong Zhou, Baohua Li, Guoxiu Wang, Doron Aurbach","doi":"10.1038/s41578-024-00669-y","DOIUrl":"10.1038/s41578-024-00669-y","url":null,"abstract":"Solid-state lithium metal batteries (SSLBs) using inorganic solid-state electrolytes (SSEs) have attracted extensive scientific and commercial interest owing to their potential to provide higher energy density and safety than conventional Li-ion batteries. These batteries are subject to external pressure during both their manufacturing processes (fabrication pressure) and their operation (stack pressure). This pressure not only affects the intrinsic properties of both the electrolytes (such as ionic conductivity and electrochemical voltage window) and the electrodes (such as ion transport and structural variation) but also determines the cyclability and safety of the whole battery. Hence, understanding the effect of pressure is essential when designing high-performance SSLBs. This Review aims to elucidate the coupling between external pressure and electrochemistry in these batteries. We summarize the effects of external pressure on SSEs and electrodes, and on the interfaces between the components. We analyse the overall electrochemical performance and safety of the batteries under external pressure. Finally, we clarify the dominant challenges in achieving pressure-proof and low-pressure SSLBs, laying out a perspective for future breakthroughs. Solid-state lithium metal batteries have the potential to meet energy density and safety requirements that current commercial Li-ion batteries cannot. Given their solid-state components, these batteries are subject to — and strongly affected by — external pressure during their manufacturing and operation. This Review examines the relationship between external pressure and electrochemical behaviour in these batteries.","PeriodicalId":19081,"journal":{"name":"Nature Reviews Materials","volume":"9 5","pages":"305-320"},"PeriodicalIF":83.5,"publicationDate":"2024-04-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140346342","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Chemotherapy delivery activated by radiation","authors":"Charlotte Allard","doi":"10.1038/s41578-024-00674-1","DOIUrl":"10.1038/s41578-024-00674-1","url":null,"abstract":"An article in Advanced Materials presents a drug delivery platform for cancer chemotherapy that is activated by radiation.","PeriodicalId":19081,"journal":{"name":"Nature Reviews Materials","volume":"9 4","pages":"228-228"},"PeriodicalIF":83.5,"publicationDate":"2024-03-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140303740","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Thermoelectric copper selenide gets a boost","authors":"Giulia Pacchioni","doi":"10.1038/s41578-024-00673-2","DOIUrl":"10.1038/s41578-024-00673-2","url":null,"abstract":"An article in Nature Materials reports the use of a co-doping strategy to produce a Cu2Se-based superionic material that has a figure of merit of 3 at 1,050 K, an efficiency of over 13% when integrated into a thermoelectric module and good operational stability.","PeriodicalId":19081,"journal":{"name":"Nature Reviews Materials","volume":"9 4","pages":"227-227"},"PeriodicalIF":83.5,"publicationDate":"2024-03-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140303823","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Mijin Kim, Dana Goerzen, Prakrit V. Jena, Emma Zeng, Matteo Pasquali, Rachel A. Meidl, Daniel A. Heller
{"title":"Author Correction: Human and environmental safety of carbon nanotubes across their life cycle","authors":"Mijin Kim, Dana Goerzen, Prakrit V. Jena, Emma Zeng, Matteo Pasquali, Rachel A. Meidl, Daniel A. Heller","doi":"10.1038/s41578-024-00670-5","DOIUrl":"10.1038/s41578-024-00670-5","url":null,"abstract":"","PeriodicalId":19081,"journal":{"name":"Nature Reviews Materials","volume":"9 5","pages":"374-374"},"PeriodicalIF":83.5,"publicationDate":"2024-03-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.nature.com/articles/s41578-024-00670-5.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140077144","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Materials research will be central to India’s technology missions, but a culture shift is needed","authors":"Arindam Ghosh, A. K. Sood","doi":"10.1038/s41578-024-00667-0","DOIUrl":"10.1038/s41578-024-00667-0","url":null,"abstract":"India’s commitment to its ambitious technology goals brings a unique opportunity for the materials science community in the country to achieve synergy, focus, large-scale employment and global impact. However, scientists need to engage more spontaneously in goal-oriented collaborations along with stakeholders in industry and government.","PeriodicalId":19081,"journal":{"name":"Nature Reviews Materials","volume":"9 4","pages":"223-225"},"PeriodicalIF":83.5,"publicationDate":"2024-03-07","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140067701","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Simon Schweidler, Miriam Botros, Florian Strauss, Qingsong Wang, Yanjiao Ma, Leonardo Velasco, Gabriel Cadilha Marques, Abhishek Sarkar, Christian Kübel, Horst Hahn, Jasmin Aghassi-Hagmann, Torsten Brezesinski, Ben Breitung
{"title":"High-entropy materials for energy and electronic applications","authors":"Simon Schweidler, Miriam Botros, Florian Strauss, Qingsong Wang, Yanjiao Ma, Leonardo Velasco, Gabriel Cadilha Marques, Abhishek Sarkar, Christian Kübel, Horst Hahn, Jasmin Aghassi-Hagmann, Torsten Brezesinski, Ben Breitung","doi":"10.1038/s41578-024-00654-5","DOIUrl":"10.1038/s41578-024-00654-5","url":null,"abstract":"High-entropy materials (HEMs) hold promise for a variety of applications because their properties can be readily tailored by selecting specific elements and altering stoichiometry. In this Perspective, we highlight the emerging potential of HEMs in energy and electronic applications. We place particular emphasis on (ionic and covalent) ceramics that have only emerged in powder form since 2015. Although the discovery of opportunities is in its early stages, we discuss a few case studies in which the use of HEMs has led to improved material properties and device performance. We also correlate features with the respective properties and identify topics and effects for future investigations. An overview of these intrinsic properties, such as cocktail effects, lattice distortions and compositional freedom, as well as a list of general attributes, is given and linked to changes in material characteristics. High-entropy materials (HEMs) are characterized by their high configurational entropy, providing unique property-tuning capabilities for a variety of applications. This Perspective discusses the potential of HEMs for applications in energy storage, energy conversion and electronics.","PeriodicalId":19081,"journal":{"name":"Nature Reviews Materials","volume":"9 4","pages":"266-281"},"PeriodicalIF":83.5,"publicationDate":"2024-03-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140104623","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Alessandro Innocenti, Simon Beringer, Stefano Passerini
{"title":"Cost and performance analysis as a valuable tool for battery material research","authors":"Alessandro Innocenti, Simon Beringer, Stefano Passerini","doi":"10.1038/s41578-024-00657-2","DOIUrl":"10.1038/s41578-024-00657-2","url":null,"abstract":"Cost and performance analysis is a powerful tool to support material research for battery energy storage, but it is rarely applied in the field and often misinterpreted. Widespread use of such an analysis at the stage of material discovery would help to focus battery research on practical solutions. When correctly used and well detailed, it can effectively direct efforts towards selecting appropriate materials for commercial applications. Using sodium-ion batteries as an example, we simulate the energy density and the cost of battery packs with several sodium-ion cathode materials taken from the literature in three case studies that illustrate how to identify the most promising solutions from the results of the model. Using publicly available information on material properties and open-source software, we demonstrate how a battery cost and performance analysis could be implemented using typical data from laboratory-scale studies on new energy storage materials. Cost and performance analysis, if applied properly, can guide the research of new energy storage materials. In three case studies on sodium-ion batteries, this Perspective illustrates how to implement this type of analysis at the battery material discovery phase to identify the most promising active materials and treatments.","PeriodicalId":19081,"journal":{"name":"Nature Reviews Materials","volume":"9 5","pages":"347-357"},"PeriodicalIF":83.5,"publicationDate":"2024-03-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140067731","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Design and microstructuring of materials to boost spacecraft ion propulsion","authors":"Paulo C. Lozano","doi":"10.1038/s41578-024-00664-3","DOIUrl":"10.1038/s41578-024-00664-3","url":null,"abstract":"As new materials and manufacturing techniques are discovered, their benefits transform every branch of science and engineering. In spacecraft propulsion, a new generation of ion engines could provide unprecedented performance and flexibility in space mission design.","PeriodicalId":19081,"journal":{"name":"Nature Reviews Materials","volume":"9 11","pages":"757-758"},"PeriodicalIF":79.8,"publicationDate":"2024-03-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140067626","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}