{"title":"Numerical simulation using in the preparation process of micron-sized silica–aluminium composite powders by high-energy alloying: Building visualisation and guiding preparation","authors":"Zhen-yu Guo, Xin Zhang, Yan-jun Wang, Si-yuan Zhang, Yin Yin","doi":"10.1049/mna2.12165","DOIUrl":"https://doi.org/10.1049/mna2.12165","url":null,"abstract":"<p>Silica-aluminium composite powders are important precursors for the preparation of sealant coatings by supersonic flame spraying. Micron-scale silica-aluminium composite powders can be prepared using a planetary ball mill, but powder agglomeration often leads to composite failure. Using relevant modelling software to build the 3D modelling of the ball mill jar, which based on the discrete element method, using the Hertz–Mindlin contact model and after specifying the simulation boundary conditions, the ball mill process was simulated and analysed. Visualise the influence of important process parameters such as frequency, size and diameter of milling balls and ball-to-powder weight ratio, and systematically analyse the microscopic morphology and composite condition of the agglomerated and dispersed powders. The results show that the ball motion during the ball milling process is mainly divided into three representative types: ball–ball impact, ball crushing motion against the jar wall and ball–wall impact. The energy transfer efficiency of the milling balls to the powder system is highest when the ratio of the three types of motion is uniform. SEM images and EDS spectra showed that the aluminium powder was sufficiently crushed, with an average particle size below 1 μm. The aluminium powder was uniformly distributed on the surface of the silicon powder, and the particle size of the composite silicon aggregates was sufficiently reduced.</p>","PeriodicalId":18398,"journal":{"name":"Micro & Nano Letters","volume":"18 5","pages":""},"PeriodicalIF":1.3,"publicationDate":"2023-05-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1049/mna2.12165","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"50143214","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"A biodegradable nano-composite membrane for high-safety and durable lithium-ion batteries","authors":"Ting Wang, Na Liu, Hui Zhou, Ming-Jun Chen","doi":"10.1049/mna2.12168","DOIUrl":"https://doi.org/10.1049/mna2.12168","url":null,"abstract":"<p>As a key component of lithium-ion batteries (LIBs), separator plays a crucial role in the performance and safety of LIBs. In this paper, a cellulose-based porous membrane modified by nano CaCO<sub>3</sub> is prepared conveniently by electrospinning. The membrane exhibits rich fibrous porous networks and uniform distribution of nanoparticles. Strengthened by CaCO<sub>3</sub>, the tensile strength of the cellulose porous membrane elevates from 4.7 ± 0.4 MPa to 7.7 ± 0.7 MPa. Besides, the modified membranes possess improved thermal stability and can maintain their original size after treatment at 150°C and 180°C. Also, the electrolyte uptake of cellulose/CaCO<sub>3</sub> membrane is 73% higher than that of the pure cellulose membrane. Thus, the ionic conductivity of membrane achieves 1.08 mS cm<sup>−1</sup> and the electrochemical window is about 4.8 V, which meets the practical requirements of LIBs. Significantly, with LiFePO<sub>4</sub>/Li battery this membrane can run for 230 cycles with a capacity retention of 97.4% and a discharge capacity of 149.0 mAh g<sup>−1</sup>, demonstrating the huge potential for high safety and next-generation LIBs.</p>","PeriodicalId":18398,"journal":{"name":"Micro & Nano Letters","volume":"18 5","pages":""},"PeriodicalIF":1.3,"publicationDate":"2023-05-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1049/mna2.12168","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"50153379","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Regulating properties of Cu2ZnSn(S, Se)4 absorber layer via the extra tiny Mg2+","authors":"Mingyang Cao, Junting Ren, Yanchun Yang, Guonan Cui, Xin Zhao, Yanqing Liu, Yajin Mi, Xiao Tian, Chengjun Zhu","doi":"10.1049/mna2.12166","DOIUrl":"https://doi.org/10.1049/mna2.12166","url":null,"abstract":"<p>Extra cation incorporations have been proved to enhance the properties of Cu<sub>2</sub>ZnSn(S, Se)<sub>4</sub> materials, and help to obtain high-efficiency solar cells. In this work, the authors study the influence of the extra tiny Mg<sup>2+</sup> doping on the properties of Cu<sub>2</sub>ZnSn(S, Se)<sub>4</sub> films. Through tuning the amount of Mg into the precursor solution, the crystallization, morphology, light absorption, and electrical properties all have been improved and can reach the optimum at 3% Mg-doping, which is in favour of high-performance CZTSSe devices. The authors’ finding also demonstrates Mg element can be regarded as the new candidate for extra cation incorporations.</p>","PeriodicalId":18398,"journal":{"name":"Micro & Nano Letters","volume":"18 5","pages":""},"PeriodicalIF":1.3,"publicationDate":"2023-05-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1049/mna2.12166","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"50147848","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
F. Dinelli, M. Brucale, F. Valle, C. Ascoli, B. Samorì, M. Sartore, M. Adami, Riccardo Galletti, S. Prato, B. Troian, C. Albonetti
{"title":"Probing Italy: A Scanning Probe Microscopy Storyline","authors":"F. Dinelli, M. Brucale, F. Valle, C. Ascoli, B. Samorì, M. Sartore, M. Adami, Riccardo Galletti, S. Prato, B. Troian, C. Albonetti","doi":"10.3390/micro3020037","DOIUrl":"https://doi.org/10.3390/micro3020037","url":null,"abstract":"Starting from the late 1980’s, scanning probe microscopy has progressively diffused in Italy until today. In this paper, we provide a brief account of the main historical events and a current picture of the distribution of the active groups. A survey was prepared by LimeSurvey, made of six sections asking for personal and institutional data, human resources, equipment available, fields of interest, research projects, educational/dissemination activities, and two relevant publications in the last six years. It turns out that the Italian community includes more than seventy groups and two companies. It is widely diffused, although mostly concentrated near large academic and research institutions, often in locations where prominent Italian researchers have operated. This community is active in many scientific fields and can produce research of high international quality. It shows a wide competence, as proven by the list of research works published in journals ranked within the top 20% class. The diffusion of SPM microscopes in industry is still sporadic, possibly due to extensive collaborations between the research institutions and industries themselves. The authors hope that this work might be useful to the community and beyond, and that it might stimulate the formation of a more structured network.","PeriodicalId":18398,"journal":{"name":"Micro & Nano Letters","volume":"1 1","pages":""},"PeriodicalIF":1.3,"publicationDate":"2023-05-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"87474430","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Sen Wang, Xue Zou, Henan Li, Dan Shan, Hongliang Fan
{"title":"Proposal for a spin logic device based on magneto-electric effect and spin Hall effect","authors":"Sen Wang, Xue Zou, Henan Li, Dan Shan, Hongliang Fan","doi":"10.1049/mna2.12164","DOIUrl":"https://doi.org/10.1049/mna2.12164","url":null,"abstract":"<p>Based on magneto-electric (ME) effect and spin Hall effect (SHE), the authors propose a novel spin logic device named MESH-SLD. In MESH-SLD, the charge current is transmitted in the channel by employing inverse SHE, which solves the dissipation problem of spin current in the channel of all-spin logic device (ASLD). By using a magnetization-dynamics/spin-transport hybrid model, the authors have investigated the influence of working voltage, channel lengths, and materials on the performance of the MESH-SLD. And the simulation results show that the energy dissipation of the MESH-SLD only increases approximately linearly with the increase of channel length, while the switching delay remains almost unchanged. In addition, with the increase of the spin Hall angle of the channel material, the energy dissipation and the minimum working voltage of the MESH-SLD decrease significantly. Most importantly, compared with conventional ASLD, the proposed MESH-SLD improve the switching delay and the energy dissipation by about 2.5 times and 851.8 times, respectively.</p>","PeriodicalId":18398,"journal":{"name":"Micro & Nano Letters","volume":"18 5","pages":""},"PeriodicalIF":1.3,"publicationDate":"2023-05-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1049/mna2.12164","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"50136838","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Controllable synthesis of indium oxide nanorod-flowers for high field emission performance","authors":"Yuechuan Hu, Hange Feng, Lingwei Li, Menghao Luo, Zibo Dong, Shaolin Xue","doi":"10.1049/mna2.12163","DOIUrl":"https://doi.org/10.1049/mna2.12163","url":null,"abstract":"<p>In this paper, indium oxide (In<sub>2</sub>O<sub>3</sub>) nanomaterials are successfully synthesized on the silicon substrates by hydrothermal method and calcination. By changing the ratio of raw materials, In<sub>2</sub>O<sub>3</sub> exhibits three morphologies of nanorods, nanomaces, and nanorod-flowers. Among the three morphologies of In<sub>2</sub>O<sub>3</sub> nanomaterials, the nanorod-flowers shaped In<sub>2</sub>O<sub>3</sub> shows a strong field emission property, the turn-on electric field as low as 0.97 V/µm and the field enhancement factor <i>β</i> up to 1053. The excellent performance is attributed to the higher length to diameter (L/D) ratio of the emitting tips and the better crystal quality for nanorod-flowers shaped In<sub>2</sub>O<sub>3</sub>. The authors also show that for the nanorod-flowers shaped In<sub>2</sub>O<sub>3</sub>, increasing separation distance, the turn-on electric field increases up to about 3.67 V/µm and <i>β</i> decreases to 573 at <i>d</i> = 900 µm. This work provides new insights to design and synthesize nanomaterials with excellent field emission properties.</p>","PeriodicalId":18398,"journal":{"name":"Micro & Nano Letters","volume":"18 5","pages":""},"PeriodicalIF":1.3,"publicationDate":"2023-05-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1049/mna2.12163","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"50136837","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Denislav Markov, Emil Grigorov, B. Kirov, J. Denev, V. Galabov, M. Marinov
{"title":"Low-Cost Three-Dimensionally -Printed Inverted Plug and Play Optical Instrument for Microfluidic Imaging","authors":"Denislav Markov, Emil Grigorov, B. Kirov, J. Denev, V. Galabov, M. Marinov","doi":"10.3390/micro3020036","DOIUrl":"https://doi.org/10.3390/micro3020036","url":null,"abstract":"Microfluidics, also known as lab-on-a-chip or micro total analysis systems, can precisely regulate and manipulate micro-sized fluids. They have great potential in biology, chemistry, and medicine, as well as other fields of science. By definition, microfluidic devices operate with small-volume samples and small reactant quantities, which renders them both efficient and affordable. However, such small objects have very demanding requirements for the utilized optical detection system. Due to the specifics of those devices, monitoring the results of experiments is carried out with commercial inverted optical microscopes. Unfortunately, that type of optical device is still expensive. In this article, we present a truly functional, inexpensive, standalone, three-dimensionally printed, and inverted microscope, including the design, engineering, and manufacturing process and some of the experiments that have been conducted with it. Finally, we summarize the advantages of this three-dimensionally printed microscope (including the total fabrication costs) and the future improvements that will be introduced to it.","PeriodicalId":18398,"journal":{"name":"Micro & Nano Letters","volume":"53 1","pages":""},"PeriodicalIF":1.3,"publicationDate":"2023-05-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"80471119","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
M. Hubl, Raghied M. Atta, R. Kaufhold, Bei Wang, H. Ngo
{"title":"Nano-Materials-Based Printed Glucose Sensor for Use in Incontinence Products for Health-Care Applications","authors":"M. Hubl, Raghied M. Atta, R. Kaufhold, Bei Wang, H. Ngo","doi":"10.3390/micro3020035","DOIUrl":"https://doi.org/10.3390/micro3020035","url":null,"abstract":"Our recent development of a wireless humidity sensor system embedded in incontinence products enables new sensor applications to diagnose and supervise geriatric diseases (i.e., age-related diabetes mellitus type II). The measurement of glucose in urine, so-called glucosuria, is an early indicator for an incipient diabetes mellitus disease, whose symptoms are often age-related but misjudged. In this paper, an incontinence glucose sensor is printed with biocompatible ink and Prussian blue as an electron mediator on foil and functionalized with immobilized glucose oxidase. Inkjet printing of multiple layers of Nafion prevents large interference substances from diffusing into the measuring electrode and allows precise adjustment of the linear working range, which is significantly different from blood glucose measurement. Performance tests show the potential to detect minimum glucose values and store the sensor over a prolonged period at room temperature. The printed glucose sensor can be embedded into the absorber material of incontinence products, where capillary forces transport the urine analyte to the detection area. An attached readout module with an integrated potentiostat measures the glucose concentration in urine, which is transmitted wirelessly with incontinence events and stored in a cloud service for further analysis by medical staff and care workers.","PeriodicalId":18398,"journal":{"name":"Micro & Nano Letters","volume":"28 1","pages":""},"PeriodicalIF":1.3,"publicationDate":"2023-05-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"78956927","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Assessment of Pharmaco-Technological Parameters of Solid Lipid Nanoparticles as Carriers for Sinapic Acid","authors":"Stefano Russo, Giuliana Greco, M. Sarpietro","doi":"10.3390/micro3020034","DOIUrl":"https://doi.org/10.3390/micro3020034","url":null,"abstract":"Sinapic acid, 3,5-dimethoxyl-4-hydroxycinnamic acid, belonging to the class of hydroxycinnamic acids, shows antioxidant, anti-inflammatory, anticancer, hepatoprotective, cardioprotective, renoprotective, neuroprotective, antidiabetic, anxiolytic, and antibacterial activity. The aim of this work was to incorporate sinapic acid into solid lipid nanoparticles in order to improve its bioavailability. SLNs were prepared using the hot high-speed homogenization method. The pharmaco-technological properties and thermotropic profile of SLNs encapsulated with sinapic acid, as well as their interaction with biomembrane models, were evaluated. SLNs showed promising physicochemical properties and encapsulation efficiency, as well as a desirable release profile; moreover, they facilitated the interaction of sinapic acid with a biomembrane model made of multilamellar vesicles. In conclusion, this formulation can be used in further studies to assess its suitability to improve sinapic acid activity.","PeriodicalId":18398,"journal":{"name":"Micro & Nano Letters","volume":"9 1","pages":""},"PeriodicalIF":1.3,"publicationDate":"2023-05-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"79656627","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Quentin Drouhet, F. Touchard, L. Chocinski-Arnault
{"title":"Tensile Behavior of [0/90]7 Hemp/Elium Biocomposites after Water Aging: In-Situ Micro-CT Testing and Numerical Analysis","authors":"Quentin Drouhet, F. Touchard, L. Chocinski-Arnault","doi":"10.3390/micro3020033","DOIUrl":"https://doi.org/10.3390/micro3020033","url":null,"abstract":"This paper aims to study the tensile behavior of a woven [0/90]7 hemp/Elium composite after three different conditionings: “Ambient storage”, “Saturated at 60 °C” and “15 wet/dry cycles”. Instrumented repeated progressive tensile loading tests were carried out and showed an unexpected increase in the secant modulus for the aged samples at the end of the test. An in-situ micro-CT tensile test was then performed on a “15 wet/dry cycles” aged sample. The analysis of the tomographic images showed the damage development with interfacial debonding and matrix cracks in the specimen volume, and also the decrease in the curvature radius of the warp yarns during tensile loading facilitated by the plasticization of the resin. Finite element calculations were thus performed and demonstrated that the increase in the modulus is directly linked to the straightening of warp yarns, showing that the evolution of the modulus on a macroscopic scale can be explained by the deformations of the yarns on a microscopic level. These results allow us to better understand the mechanical behavior and the damage mechanisms that occur in biocomposites during tensile testing after water aging.","PeriodicalId":18398,"journal":{"name":"Micro & Nano Letters","volume":"42 1","pages":""},"PeriodicalIF":1.3,"publicationDate":"2023-05-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"84860345","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}