Materials Science and Engineering B-advanced Functional Solid-state Materials最新文献

筛选
英文 中文
Study on the mechanism of photocatalytic activity enhancement of Ag/Ag3PO4/PDI-2 supramolecular Z-scheme heterojunction photocatalyst Ag/Ag3PO4/PDI-2 超分子 Z 型异质结光催化剂光催化活性增强机理研究
IF 3.9 3区 材料科学
Materials Science and Engineering B-advanced Functional Solid-state Materials Pub Date : 2024-11-17 DOI: 10.1016/j.mseb.2024.117845
Congzhi Hu, Yuye Li, Tingting Du, Youyong Pang, Yongping Liu, Botian Liu, Ling Li, Huidan Lu, Bin Huang
{"title":"Study on the mechanism of photocatalytic activity enhancement of Ag/Ag3PO4/PDI-2 supramolecular Z-scheme heterojunction photocatalyst","authors":"Congzhi Hu,&nbsp;Yuye Li,&nbsp;Tingting Du,&nbsp;Youyong Pang,&nbsp;Yongping Liu,&nbsp;Botian Liu,&nbsp;Ling Li,&nbsp;Huidan Lu,&nbsp;Bin Huang","doi":"10.1016/j.mseb.2024.117845","DOIUrl":"10.1016/j.mseb.2024.117845","url":null,"abstract":"<div><div>In this paper, a new supramolecular Z-scheme heterojunction photocatalyst, designated as Ag/Ag<sub>3</sub>PO<sub>4</sub>/Perylene diimide organic molecules after secondary acid-base self-assembly (PDI-2), was synthesized through precipitation and photoreduction techniques. Ag/Ag<sub>3</sub>PO<sub>4</sub>/60 %PDI-2 (APP-6) exhibited the best photocatalytic activity due to the synergistic effect of Z-scheme heterojunction and surface plasmon resonance (SPR) effect of Ag nanoparticles (Ag NPs). Under visible light (λ &gt; 420 nm), the degradation efficiency of APP-6 for Rhodamine B (RhB) and Bisphenol A (BPA) was 99.7 % and 90.7 %, respectively. Additionally, PDI-2 was transformed into smaller nanoclusters, which increased the specific surface area of the photocatalyst, and reduced the charge transport distance. Moreover, APP-6 exhibited the smallest electrochemical impedance, the largest photocurrent, the smallest fluorescence lifetime. Free radical trapping experiments showed that •O<sub>2</sub><sup>−</sup> was the main reactive group and a possible photocatalytic mechanism was proposed by combining the Ultraviolet–visible diffuse reflectance spectrophotometer (UV–vis DRS) and the Mott-Schottky plots.</div></div>","PeriodicalId":18233,"journal":{"name":"Materials Science and Engineering B-advanced Functional Solid-state Materials","volume":"311 ","pages":"Article 117845"},"PeriodicalIF":3.9,"publicationDate":"2024-11-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142657041","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Effect of temperature and capillary number on wettability and contact angle hysteresis of various materials. Modeling taking into account porosity 温度和毛细管数对各种材料润湿性和接触角滞后的影响考虑孔隙率的建模
IF 3.9 3区 材料科学
Materials Science and Engineering B-advanced Functional Solid-state Materials Pub Date : 2024-11-17 DOI: 10.1016/j.mseb.2024.117827
S.Y. Misyura , V.S. Morozov , V.A. Andryushchenko , E.G. Orlova
{"title":"Effect of temperature and capillary number on wettability and contact angle hysteresis of various materials. Modeling taking into account porosity","authors":"S.Y. Misyura ,&nbsp;V.S. Morozov ,&nbsp;V.A. Andryushchenko ,&nbsp;E.G. Orlova","doi":"10.1016/j.mseb.2024.117827","DOIUrl":"10.1016/j.mseb.2024.117827","url":null,"abstract":"<div><div>The effect of surface temperature and laser texturing on the wettability and contact angle hysteresis of Cu, Cu/G, AlMg3, Cu-SiC was considered. Modeling using molecular dynamics qualitatively confirms the experimental results: 1) an increase in the contact angle hysteresis on a textured surface; 2) influence of the surface wettability on contact angle hysteresis; 3) influence of the contact line velocity on contact angle hysteresis. Heating the sample of different composite materials can lead to either an increase in the contact angle or a decrease. It was shown that after laser texturing, a system of nano-micro pores was formed in the surface layer of the material, which leads to an abnormally high contact angle hysteresis on the Cu-SiC composite. A new model is proposed that explains the different qualitative behavior of the contact angle hysteresis in different studies with increasing capillary number (<em>Ca</em>), as well as with increasing sample temperature.</div></div>","PeriodicalId":18233,"journal":{"name":"Materials Science and Engineering B-advanced Functional Solid-state Materials","volume":"311 ","pages":"Article 117827"},"PeriodicalIF":3.9,"publicationDate":"2024-11-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142657044","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Biocompatible Mn and Cu dual-doped ZnS nanosheets for enhanced the photocatalytic activity under sunlight irradiation for wastewater treatment and embedded with PVA polymer for reusability 生物相容性锰铜双掺杂 ZnS 纳米片在阳光照射下增强光催化活性,用于废水处理,并嵌入 PVA 聚合物以实现重复使用
IF 3.9 3区 材料科学
Materials Science and Engineering B-advanced Functional Solid-state Materials Pub Date : 2024-11-17 DOI: 10.1016/j.mseb.2024.117837
S. Murugan, M. Ashokkumar
{"title":"Biocompatible Mn and Cu dual-doped ZnS nanosheets for enhanced the photocatalytic activity under sunlight irradiation for wastewater treatment and embedded with PVA polymer for reusability","authors":"S. Murugan,&nbsp;M. Ashokkumar","doi":"10.1016/j.mseb.2024.117837","DOIUrl":"10.1016/j.mseb.2024.117837","url":null,"abstract":"<div><div>This study investigates the synthesis of Mn and Cu-doped ZnS nanosheets via the coprecipitation method, focusing on their structural, optical, photocatalytic, and hemolytic properties. XRD analysis confirmed a cubic structure, with crystallite size decreasing as doping levels increased. TEM identified crumpled nanosheets, while UV–Vis spectroscopy measured bandgaps of 3.98, 3.78, 3.93, and 4.09 eV for the ZM1, ZM2, ZM3, and ZM4 samples, respectively. The ZM3 nanosheets exhibited superior photocatalytic performance, achieving 99 % dye degradation in 110 min under sunlight. Kinetic analysis showed a rate constant of 46.91 × 10<sup>−3</sup> min<sup>−1</sup> for ZM3. When embedded in a PVA polymer membrane, the ZM3 nanosheets demonstrated 95 % degradation efficiency and excellent reusability. The study also explored the degradation mechanism, effects of dosage and dye variation, and hemolytic activity on human red blood cells, providing a comprehensive understanding of these doped ZnS nanosheets.</div></div>","PeriodicalId":18233,"journal":{"name":"Materials Science and Engineering B-advanced Functional Solid-state Materials","volume":"311 ","pages":"Article 117837"},"PeriodicalIF":3.9,"publicationDate":"2024-11-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142657040","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
A comparative study on the lamella effect and properties of atomized iron powder and reduced iron powder in Fe-based soft magnetic composites 雾化铁粉和还原铁粉在铁基软磁复合材料中的层状效应和性能比较研究
IF 3.9 3区 材料科学
Materials Science and Engineering B-advanced Functional Solid-state Materials Pub Date : 2024-11-17 DOI: 10.1016/j.mseb.2024.117844
Zhenjia Yang , Zigui Luo , Qi Jin , Xi’an Fan , Zhaoyang Wu , Jian Wang , Guangqiang Li
{"title":"A comparative study on the lamella effect and properties of atomized iron powder and reduced iron powder in Fe-based soft magnetic composites","authors":"Zhenjia Yang ,&nbsp;Zigui Luo ,&nbsp;Qi Jin ,&nbsp;Xi’an Fan ,&nbsp;Zhaoyang Wu ,&nbsp;Jian Wang ,&nbsp;Guangqiang Li","doi":"10.1016/j.mseb.2024.117844","DOIUrl":"10.1016/j.mseb.2024.117844","url":null,"abstract":"<div><div>We prepared Fe soft magnetic composites (SMCs) with lamellar structure by using the flaky Iron powder, and studied the effects of types of iron powder on the microstructure and properties of Fe SMCs. The results show that the atomized iron powder and the reduced iron powder are deformed into flaky structure after ball milling, and these flaky iron powder have greater magnetic susceptibility and eddy current diameter perpendicular to the magnetic flux direction. In addition, compared with flaky gas atomized iron powder, the flaky reduced iron powder has large aspect ratio and lower coercivity. Therefore, the Fe SMCs with flaky reduced iron powder exhibit relatively high permeability (82) and low eddy current loss (0.033 W/kg at 50 kHz, 0.05 T), which shows the potential possibility of application at high frequency.</div></div>","PeriodicalId":18233,"journal":{"name":"Materials Science and Engineering B-advanced Functional Solid-state Materials","volume":"311 ","pages":"Article 117844"},"PeriodicalIF":3.9,"publicationDate":"2024-11-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142657043","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Synthesis and enhanced electrical properties of Ag-doped α-Fe2O3 nanoparticles in PVA films for nanoelectronic applications 用于纳米电子应用的 PVA 薄膜中掺杂 Ag 的 α-Fe2O3 纳米粒子的合成及其增强的电学特性
IF 3.9 3区 材料科学
Materials Science and Engineering B-advanced Functional Solid-state Materials Pub Date : 2024-11-17 DOI: 10.1016/j.mseb.2024.117801
S. Vijayaraghavan , A. Rajasekaran , Abdullah N Alodhayb , Muthumareeswaran Muthuramamoorthy , M. Vimalan , K. Ganesh Kumar
{"title":"Synthesis and enhanced electrical properties of Ag-doped α-Fe2O3 nanoparticles in PVA films for nanoelectronic applications","authors":"S. Vijayaraghavan ,&nbsp;A. Rajasekaran ,&nbsp;Abdullah N Alodhayb ,&nbsp;Muthumareeswaran Muthuramamoorthy ,&nbsp;M. Vimalan ,&nbsp;K. Ganesh Kumar","doi":"10.1016/j.mseb.2024.117801","DOIUrl":"10.1016/j.mseb.2024.117801","url":null,"abstract":"<div><div>Rhombohedral α-Fe<sub>2</sub>O<sub>3</sub> nanoparticles doped with silver (Ag-α-Fe<sub>2</sub>O<sub>3</sub>) were successfully synthesized using a hydrothermal method. The structural characteristics and morphology of the synthesized nanoparticles were examined using X-ray diffraction (XRD), Raman spectroscopy, and scanning electron microscopy (SEM), wherein the Raman peak was observed at 218/cm. The electrical properties of the Ag-doped α-Fe<sub>2</sub>O<sub>3</sub> nanoparticles layered in polyvinyl alcohol (PVA) film were analyzed through I-V curves, impedance graphs, and measurements of dielectric constant (Ɛ) and dielectric loss (Ɛ′). Through the I-V curve, a current value of 3.68 × 10<sup>−2</sup> μA was obtained, which was 52 % greater than that of the PVA film at an applied voltage of ± 100 V. The results demonstrated that the Ag-doped α-Fe<sub>2</sub>O<sub>3</sub> in the PVA film exhibited enhanced electrical properties, with significant increases in both dielectric constant (0.5 × 10<sup>3</sup>) and dielectric loss (11 × 10<sup>3</sup>). Ag-doped α-Fe<sub>2</sub>O<sub>3</sub> in PVA film, therefore, appears to be a promising applicants in Nano electronics.</div></div>","PeriodicalId":18233,"journal":{"name":"Materials Science and Engineering B-advanced Functional Solid-state Materials","volume":"311 ","pages":"Article 117801"},"PeriodicalIF":3.9,"publicationDate":"2024-11-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142657460","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
The effect of Mo and Sc dopants on the performance of an Sr2Fe2O6 cathode for use in proton-conducting solid oxide fuel cells 掺杂钼和钪对用于质子传导型固体氧化物燃料电池的 Sr2Fe2O6 阴极性能的影响
IF 3.9 3区 材料科学
Materials Science and Engineering B-advanced Functional Solid-state Materials Pub Date : 2024-11-16 DOI: 10.1016/j.mseb.2024.117836
Shu Yang, Yueyuan Gu, Shoufu Yu
{"title":"The effect of Mo and Sc dopants on the performance of an Sr2Fe2O6 cathode for use in proton-conducting solid oxide fuel cells","authors":"Shu Yang,&nbsp;Yueyuan Gu,&nbsp;Shoufu Yu","doi":"10.1016/j.mseb.2024.117836","DOIUrl":"10.1016/j.mseb.2024.117836","url":null,"abstract":"<div><div>Sr<sub>2</sub>Fe<sub>2</sub>O<sub>6</sub> was doped with Sc and Mo ions to investigate the effect of these dopants on the material properties and cathode performance. Both Sc and Mo were doped into Sr<sub>2</sub>Fe<sub>2</sub>O<sub>6</sub> as pure phases, and the thermal expansion coefficient (TEC) increased with the Sc content of the material. A first-principles calculation at the atomic level indicated that Mo facilitated hydration, whereas Sc doping facilitated the formation of oxygen vacancies. Simulation results showed that the lowest energy barrier to O<sub>2</sub> adsorption and dissociation was obtained by co-doping Sc and Mo into Sr<sub>2</sub>Fe<sub>2</sub>O<sub>6</sub>, facilitating the cathode reaction. The results of fuel cell tests indicated that co-doping with Sc and Mo resulted in higher fuel-cell performance for Sr<sub>2</sub>Fe<sub>2</sub>O<sub>6</sub> than doping with Sc or Mo alone. An impedance analysis for Sr<sub>2</sub>Fe<sub>2</sub>O<sub>6</sub> co-doped with Sc and Mo indicated a good balance between hydration and oxygen vacancy formation, as well as a low energy barrier to O<sub>2</sub> adsorption and dissociation, which resulted in this material exhibiting the lowest polarization resistance among the tested cathodes. This study demonstrates that each dopant has unique advantages and disadvantages in terms of cathode properties, and it is necessary to strike a balance among the parameters involved to enhance the cathode performance.</div></div>","PeriodicalId":18233,"journal":{"name":"Materials Science and Engineering B-advanced Functional Solid-state Materials","volume":"311 ","pages":"Article 117836"},"PeriodicalIF":3.9,"publicationDate":"2024-11-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142656987","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Synthesis, characterization, and application of Ba3V2O8 ceramics in cylindrical dielectric resonator antenna: Simulation and experimental study 圆柱形介质谐振器天线中 Ba3V2O8 陶瓷的合成、表征和应用:仿真与实验研究
IF 3.9 3区 材料科学
Materials Science and Engineering B-advanced Functional Solid-state Materials Pub Date : 2024-11-16 DOI: 10.1016/j.mseb.2024.117791
M.A. Dinesh , Raghvendra Kumar , Vibha Rani Gupta , Vijaylakshmi Dayal
{"title":"Synthesis, characterization, and application of Ba3V2O8 ceramics in cylindrical dielectric resonator antenna: Simulation and experimental study","authors":"M.A. Dinesh ,&nbsp;Raghvendra Kumar ,&nbsp;Vibha Rani Gupta ,&nbsp;Vijaylakshmi Dayal","doi":"10.1016/j.mseb.2024.117791","DOIUrl":"10.1016/j.mseb.2024.117791","url":null,"abstract":"<div><div>This study focuses on synthesizing dielectric ceramic material Ba<sub>3</sub>V<sub>2</sub>O<sub>8</sub> (BVO) and its application in Cylindrical Dielectric Resonator Antennas (CDRAs) fabrication. The investigation involves a comprehensive parametric study combining software simulations and experimental validation to understand the performance characteristics of the CDRA using the synthesized material. The ceramics were sintered at 900 °C and 950 °C. X-ray diffraction (XRD) confirmed the phase formation, indicating a Rhombohedral structure with the space group <span><math><mrow><mi>R</mi><mover><mrow><mn>3</mn></mrow><mrow><mo>¯</mo></mrow></mover><mi>m</mi></mrow></math></span>. Dielectric properties were characterized, revealing temperature-independent structures. The dielectric properties of BVO ceramics (BVO-900: <span><math><mrow><msub><mi>ε</mi><mi>r</mi></msub></mrow></math></span>=13.1, <span><math><mrow><mi>Q</mi><mo>×</mo><mi>f</mi></mrow></math></span>=4000, <span><math><mrow><mi>t</mi><mi>a</mi><mi>n</mi><mi>δ</mi></mrow></math></span>=0.00222, <span><math><mrow><msub><mi>τ</mi><mi>f</mi></msub></mrow></math></span>=0; BVO-950: <span><math><mrow><msub><mi>ε</mi><mi>r</mi></msub></mrow></math></span>=13, <span><math><mrow><mi>Q</mi><mo>×</mo><mi>f</mi></mrow></math></span> = 5000, <span><math><mrow><mi>t</mi><mi>a</mi><mi>n</mi><mi>δ</mi></mrow></math></span>=0.00173, <span><math><mrow><msub><mi>τ</mi><mi>f</mi></msub></mrow></math></span>=0) were utilized to model CDRAs using the High-Frequency Structure Simulator (HFSS) suite. The designs were optimized for effective performance and used to fabricate CDRAs, which were subsequently characterized using a network analyzer and a double-ridge horn antenna. The CDRA using BVO-900 exhibited resonance frequency (<span><math><mrow><msub><mi>f</mi><mi>r</mi></msub><mrow><mo>)</mo></mrow></mrow></math></span> = 8.06 GHz, S<sub>11</sub> = -44.02 dB, Voltage Standing Wave Ratio (VSWR) = 1.07, and Bandwidth (BW) = 16.25 %, while the BVO-950-based antenna displayed<span><math><mrow><msub><mi>f</mi><mi>r</mi></msub></mrow></math></span> = 8.09 GHz, S<sub>11</sub> = -30.49 dB, VSWR = 1.06, and BW = 13.1 %. Measured values closely matched simulated values, demonstrating the effectiveness of the synthesized ceramics in CDRA applications.</div></div>","PeriodicalId":18233,"journal":{"name":"Materials Science and Engineering B-advanced Functional Solid-state Materials","volume":"311 ","pages":"Article 117791"},"PeriodicalIF":3.9,"publicationDate":"2024-11-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142656983","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Comparative study of electronic, thermoelectric, and transport properties in germanene and carbon nanotubes 锗和碳纳米管的电子、热电和传输特性比较研究
IF 3.9 3区 材料科学
Materials Science and Engineering B-advanced Functional Solid-state Materials Pub Date : 2024-11-16 DOI: 10.1016/j.mseb.2024.117826
Somayeh Behzad
{"title":"Comparative study of electronic, thermoelectric, and transport properties in germanene and carbon nanotubes","authors":"Somayeh Behzad","doi":"10.1016/j.mseb.2024.117826","DOIUrl":"10.1016/j.mseb.2024.117826","url":null,"abstract":"<div><div>This study investigates the electronic, thermoelectric, and transport properties of Germanene nanotubes (GeNTs) using a tight-binding calculations and explores their potential advantages over carbon nanotubes (CNTs) in thermoelectric applications. The effect of external electric and magnetic fields, nanotube radius, and temperature on heat capacity, electrical conductivity, power factor, and Seebeck coefficient are systematically investigated. The heat capacity C(T) of GeNTs shows a more pronounced increase with the application of external fields, especially electric field and exceeds that of CNTs. GeNTs also exhibit a lower threshold temperature for non-zero electrical conductivity attributed to their smaller energy gap, which results from easier thermal excitation of charge carriers. This property becomes more pronounced as the electrical conductivity of GeNTs increases more rapidly with temperature than that of CNTs, particularly under stronger external fields. Additionally, the thermoelectric properties of GeNTs can be further enhanced under external fields. While CNTs possess higher Seebeck coefficients and Lorenz numbers, GeNTs demonstrate distinct advantages in tunable heat capacity and conductivity, making them promising candidates for efficient thermoelectric and nanoelectronic devices. These results underscore the potential of GeNTs as an effective alternative to CNTs for advanced energy conversion applications, demonstrating their promise as high-performance thermoelectric materials for energy conversion applications.</div></div>","PeriodicalId":18233,"journal":{"name":"Materials Science and Engineering B-advanced Functional Solid-state Materials","volume":"311 ","pages":"Article 117826"},"PeriodicalIF":3.9,"publicationDate":"2024-11-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142656982","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Cobalt iron oxide (CoFe2O4) reinforced polyvinyl alcohol (PVA) based magnetoactive polymer nanocomposites for remote actuation 基于氧化钴(CoFe2O4)增强聚乙烯醇(PVA)的磁活性聚合物纳米复合材料,用于远程致动
IF 3.9 3区 材料科学
Materials Science and Engineering B-advanced Functional Solid-state Materials Pub Date : 2024-11-16 DOI: 10.1016/j.mseb.2024.117838
Ans Al Rashid , Noor A. Al-Maslamani , Anas Abutaha , Mokarram Hossain , Muammer Koç
{"title":"Cobalt iron oxide (CoFe2O4) reinforced polyvinyl alcohol (PVA) based magnetoactive polymer nanocomposites for remote actuation","authors":"Ans Al Rashid ,&nbsp;Noor A. Al-Maslamani ,&nbsp;Anas Abutaha ,&nbsp;Mokarram Hossain ,&nbsp;Muammer Koç","doi":"10.1016/j.mseb.2024.117838","DOIUrl":"10.1016/j.mseb.2024.117838","url":null,"abstract":"<div><div>Magnetoactive polymer composites (MAPCs) are materials composed of a polymer matrix embedded with magnetic particles that mechanically respond to external magnetic fields. MAPCs can be programmed to be adjusted remotely without physical interventions using a magnetic field to generate the desired response; therefore, MAPCs are being actively explored for their applications in remote sensing, soft robotics, electronics, and biomedical areas. In this work, novel MAPCs were synthesised comprising polyvinyl alcohol (PVA) as the matrix and cobalt iron oxide (CoFe<sub>2</sub>O<sub>4</sub>) nanoparticles as the magnetic component with varying concentrations (i.e., 1.25%, 2.5%, and 5%). MAPCs were synthesised using the solution casting technique, and field emission scanning electron microscopy (FE-SEM) and x-ray diffraction (XRD) results revealed the successful integration of CoFe<sub>2</sub>O<sub>4</sub> nanoparticles within the polymer matrix. The synthesised MAPC films were also characterised for their chemical, thermal, magnetic, and biological properties. The incorporation of CoFe<sub>2</sub>O<sub>4</sub> nanoparticles resulted in an improved magnetic and biological response, with improvements in these properties with increasing CoFe<sub>2</sub>O<sub>4</sub> content. However, PVA/5% CoFe<sub>2</sub>O<sub>4</sub> revealed toxicity and requires further investigation of using these materials with higher CoFe<sub>2</sub>O<sub>4</sub> concentrations. The magnetic response and biological properties of the PVA/CoFe<sub>2</sub>O<sub>4</sub> MAPCs revealed their potential uses for remote actuation and sensing in the biomedical sector.</div></div>","PeriodicalId":18233,"journal":{"name":"Materials Science and Engineering B-advanced Functional Solid-state Materials","volume":"311 ","pages":"Article 117838"},"PeriodicalIF":3.9,"publicationDate":"2024-11-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142657458","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
MXene decorated ZnO-tetrapod for efficient degradation of Methyl Orange, Methylene Blue, and Rhodamine B dyes 用于高效降解甲基橙、亚甲基蓝和罗丹明 B 染料的 MXene 装饰氧化锌四元结构
IF 3.9 3区 材料科学
Materials Science and Engineering B-advanced Functional Solid-state Materials Pub Date : 2024-11-16 DOI: 10.1016/j.mseb.2024.117832
Sahil Jangra , Azam Raza , Bhushan Kumar , Jaishree Sharma , Subhankar Das , Kailash Pandey , Yogendra Kumar Mishra , M.S. Goyat
{"title":"MXene decorated ZnO-tetrapod for efficient degradation of Methyl Orange, Methylene Blue, and Rhodamine B dyes","authors":"Sahil Jangra ,&nbsp;Azam Raza ,&nbsp;Bhushan Kumar ,&nbsp;Jaishree Sharma ,&nbsp;Subhankar Das ,&nbsp;Kailash Pandey ,&nbsp;Yogendra Kumar Mishra ,&nbsp;M.S. Goyat","doi":"10.1016/j.mseb.2024.117832","DOIUrl":"10.1016/j.mseb.2024.117832","url":null,"abstract":"<div><div>For the first time, Methyl Orange (MO), Methylene Blue (MB), and Rhodamine B (RhB) dyes degradation using MXene decorated ZnO-tetrapod (MZT) has been reported. MXene was derived from MAX phase using HF etching and ZT was produced using flame transport synthesis (FTS) technique. MXene was decorated on ZT using blending and sonication of deionized water consisting of MXene and ZT. The MZT was characterized using X-ray diffraction (XRD), UV–visible spectroscopy, Tauc plot analysis, Brunauer-Emmett-Teller (BET) surface area measurement, field emission scanning electron microscopy (FESEM) and High-Resolution Transmission Electron Microscopy (HRTEM) to ensure the successful decoration. The dye degradation capability of the MZT was tested against three dyes: MO, MB, and RhB. Photodegradation tests under sunlight showed RhB had the highest efficiency (77.60 %), followed by MO (76.79 %) and MB (50.83 %), respectively. The kinetic rate constants confirmed RhB’s superior degradation. Furthermore, Electron paramagnetic resonance (EPR) spectroscopy revealed oxygen vacancies, enhancing photocatalytic performance. MZT maintained high efficiency, with less than 20 % loss after 4 cycles, demonstrating its potential for repeated use in wastewater treatment and environmental pollution mitigation. The results reveal the potential of MZT in photocatalytic degradation of harmful organic dyes, very promising solution for combating environmental pollution.</div></div>","PeriodicalId":18233,"journal":{"name":"Materials Science and Engineering B-advanced Functional Solid-state Materials","volume":"311 ","pages":"Article 117832"},"PeriodicalIF":3.9,"publicationDate":"2024-11-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142657459","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
0
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
确定
请完成安全验证×
相关产品
×
本文献相关产品
联系我们:info@booksci.cn Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。 Copyright © 2023 布克学术 All rights reserved.
京ICP备2023020795号-1
ghs 京公网安备 11010802042870号
Book学术文献互助
Book学术文献互助群
群 号:481959085
Book学术官方微信