Journal of the Turkish Chemical Society, Section A: Chemistry最新文献_第10页

Determination of Antimicrobial and Biological Activities of Salvia sclarea L. (Lamiaceae) Extracts 丹参提取物的抗菌活性和生物活性测定

Journal of the Turkish Chemical Society, Section A: Chemistry Pub Date : 2019-05-15 DOI: 10.18596/JOTCSA.463681

Sevim Küçük, P. Soyer, Y. Tunalı

引用次数: 2

Salvadora persica Extract-laden Jellyfish Collagen Hybrid Constructs for Periodontal Tissue Regeneration 富含萨尔瓦多提取物的水母胶原蛋白杂交构建体用于牙周组织再生

Journal of the Turkish Chemical Society, Section A: Chemistry Pub Date : 2019-05-15 DOI: 10.18596/JOTCSA.484936

Y. E. Arslan, Ilkim Kantarcioglu

{"title":"Salvadora persica Extract-laden Jellyfish Collagen Hybrid Constructs for Periodontal Tissue Regeneration","authors":"Y. E. Arslan, Ilkim Kantarcioglu","doi":"10.18596/JOTCSA.484936","DOIUrl":"https://doi.org/10.18596/JOTCSA.484936","url":null,"abstract":"Considerable effort in the field of periodontal tissue engineering has been expended in the construction of advanced biomatrix for the treatment of periodontal diseases caused by poor oral hygiene, malnutrition, genetic factors, and systemic disorders. With this in mind, the ultimate goal of this investigation is to fabricate sophisticated scaffolds using jellyfish collagen (JC) and aqueous Salvadora persica (Miswak) extracts. Rhizostoma pulmo species JC was isolated and characterized in depth. Miswak was extracted using two different methods. The extraction yield was calculated to be 14.2 ± 0.9 % and 17.1 ± 0.4 % for the Method I and II, respectively. gas chromatography-mass spectroscopy (GC-MS) results revealed the extract to be composed of 1,8-cineole (49.3 %), benzyl nitrile (36.2 %), benzyl isothiocyanate (5.9 %), limonene (2.4 %), eugenol (0.8 %) and palmitic acid (0.3 %). Total phenolic content and antioxidant capacities of the extracts were also determined by spectrophotometrically. Human periodontal ligament fibroblast cells were isolated and expanded. Cell viability on JC and miswak extract-laden JC scaffolds was determined by 3-(4,5-Dimethylthiazol-2-yl)-2,5-Diphenyltetrazolium Bromide (MTT) assay. Microarchitectures of the JC, 0.05 and 0.1% miswak extract-laden JC scaffolds and also cellular behaviors on these surfaces were evaluated by scanning electron microscopy (SEM) analysis. This study suggests that miswak extract-laden JC scaffolds would present new opportunities for periodontal tissue engineering.","PeriodicalId":17402,"journal":{"name":"Journal of the Turkish Chemical Society, Section A: Chemistry","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2019-05-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"42957076","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 12

Study on the preparation and drug release property of Modified PEG-DA based hydrogels 改性PEG-DA基水凝胶的制备及释药性能研究

Journal of the Turkish Chemical Society, Section A: Chemistry Pub Date : 2019-05-15 DOI: 10.18596/JOTCSA.485817

Ş. Şenol, E. Akyol

引用次数: 4

Design, synthesis and biological evaluation of 1,3-diaryltriazene-substituted sulfonamides as antioxidant, acetylcholinesterase and butyrylcholinesterase inhibitors 1,3-二芳基三氮烯取代磺酰胺类抗氧化剂、乙酰胆碱酯酶和丁酰胆碱酯酶抑制剂的设计、合成及生物学评价

Journal of the Turkish Chemical Society, Section A: Chemistry Pub Date : 2019-05-15 DOI: 10.18596/JOTCSA.516444

Suleyman Akocak, M. Boğa, Nabih Lolak, Muhammed Tuneğ, R. K. Sanku

{"title":"Design, synthesis and biological evaluation of 1,3-diaryltriazene-substituted sulfonamides as antioxidant, acetylcholinesterase and butyrylcholinesterase inhibitors","authors":"Suleyman Akocak, M. Boğa, Nabih Lolak, Muhammed Tuneğ, R. K. Sanku","doi":"10.18596/JOTCSA.516444","DOIUrl":"https://doi.org/10.18596/JOTCSA.516444","url":null,"abstract":"1,3-diaryltriazenes are one of the most useful and important linkers for many pharmaceutical applications. Therefore, in the current work, a series of 1,3-diaryltriazene sulfonamides 4(a-k) were synthesized by reacting diazonium salt of sulfanilamide and substituted aromatic amine derivatives 3(a-k) . The obtained compounds were investigated for antioxidant properties by using different methods such as a DPPH radical scavenging assay, ABTS radical decolarization, cupric reducing antioxidant capacity (CUPRAC) and metal chelating methods. The cholinesterase inhibition activities (acetylcholinesterase and butyrylcholinesterase) of synthesized compounds were also tested. In general, compounds showed weak antioxidant activity, except compounds 4d (IC 50 =114.89 for DPPH activity), 4i (IC 50 =25.31 for ABTS activity), 4a (IC 50 = 86.33 for metal chelating activity), and 4k (absorbance value 1.229 µM for CUPRAC). Some of the compounds showed great % inhibition against both acetylcholinesterase and butyrylcholinesterase with % inhibition values ranging from 11.54 to 93.67 and 62.24 to 98.47, respectively.","PeriodicalId":17402,"journal":{"name":"Journal of the Turkish Chemical Society, Section A: Chemistry","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2019-05-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"44545419","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 21

LDH- ɣ-Fe2O3-MoS2 composite for Vegetable Oil and Pb2+ Removal From Water LDH- α - fe2o3 - mos2复合材料去除植物油和水中Pb2+的研究

Journal of the Turkish Chemical Society, Section A: Chemistry Pub Date : 2019-05-15 DOI: 10.18596/JOTCSA.466768

F. Emen, R. E. Demirdöğen, G. Avsar, A. I. Karaçolak

{"title":"LDH- ɣ-Fe2O3-MoS2 composite for Vegetable Oil and Pb2+ Removal From Water","authors":"F. Emen, R. E. Demirdöğen, G. Avsar, A. I. Karaçolak","doi":"10.18596/JOTCSA.466768","DOIUrl":"https://doi.org/10.18596/JOTCSA.466768","url":null,"abstract":"Water pollution is a global concern. Inorganic and organic pollutants constitute primary pollutants in water resources. Therefore, it is of great concern to develop advanced sorbent materials for effective and efficient removal of metals and oil from water. In this study, synthesis of new LDH composites which would be used for sorption of heavy metals and oils from polluted water. For this purpose, MgAlOH- ɣ -Fe 2 O 3 -MoS 2 composite was prepared and characterized were made via FT-IR and XRD. The XRD powder pattern of the composite showed that it contained g -Fe 2 O 3 (PDF card no:00-002-1047), MgAl(OH)14.XH 2 O (PDF card no:00-043-0072) and MoS 2 (PDF card no:00-037-4492). Thermal stability of the composite was investigated via DTA/TG technique. MgAlOH- ɣ -Fe 2 O 3 -MoS 2 composite was shows highly efficient sorption for vegetable oil up to 418% times its own weight. The ablity of MgAlOH- ɣ -Fe 2 O 3 -MoS 2 composite for removing Pb 2+ ions from aqueous solution. Pb 2+ analysis was made by ICP-OES. The effect of Pb 2+ amounts, PH, sorbent amounts and solvent flow rate on t he adsorption capacity of MgAlOH- ɣ -Fe 2 O 3 -MoS 2 composite were also ivestigated.","PeriodicalId":17402,"journal":{"name":"Journal of the Turkish Chemical Society, Section A: Chemistry","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2019-05-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"42477984","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

2-Chlorobenzoylthiourea-modified MCM-41 for Drug Delivery 2-氯苯甲酰硫脲修饰MCM-41给药

Journal of the Turkish Chemical Society, Section A: Chemistry Pub Date : 2019-05-15 DOI: 10.18596/JOTCSA.467177

F. Emen, R. E. Demirdöğen, G. Avsar, D. Kiliç

引用次数: 2

DETERMINATION AND EVALUATION OF METHANOL, ETHANOL AND HIGHER ALCOHOLS IN LEGALLY AND ILLEGALLY PRODUCED ALCOHOLIC BEVERAGES 合法和非法生产的酒精饮料中甲醇、乙醇和高级醇的测定与评价

Journal of the Turkish Chemical Society, Section A: Chemistry Pub Date : 2019-05-15 DOI: 10.18596/JOTCSA.481384

O. Destanoğlu, I. Ateş

{"title":"DETERMINATION AND EVALUATION OF METHANOL, ETHANOL AND HIGHER ALCOHOLS IN LEGALLY AND ILLEGALLY PRODUCED ALCOHOLIC BEVERAGES","authors":"O. Destanoğlu, I. Ateş","doi":"10.18596/JOTCSA.481384","DOIUrl":"https://doi.org/10.18596/JOTCSA.481384","url":null,"abstract":"In this paper, we demonstrated the results of ethanol, methanol and higher alcohols contents of the legally and illegally produced alcoholic beverage samples after analyzing headspace gas chromatographic methods conducted in Council of Forensic Medicine (ATK), Department of Chemistry, Istanbul, TURKEY between years 2015-2017. Fast and reliable analysis of the alcoholic beverages, especially in terms of methanol concentration, has vital importance primarily due to the cases of death arose from metabolic acidosis after consumption of illicit alcoholic beverages with high concentration of methanol produced in clandestine laboratories. 96 Turkish Raki samples, 8 beer samples, 1 wine sample, 101 other strong drink samples, totaling to 206 samples, and 2 industrial ethanol samples were thoroughly investigated. An HS-GC-MS system was utilized for qualitative analysis of the higher alcohols and for scanning any volatile compound, whereas the determination of ethanol and methanol concentrations HS-GC-FID system was performed. So, after all results were investigated in detail, mentioning the key points for evaluations, it was clearly described whether the drinks comply with criteria set by Turkish Food Codex Communique on Distilled Alcoholic Beverages. 89 of 96 Raki samples and 90 of 101 strong alcoholic beverages were not definitely compliant with the Communique since they contained either high concentration levels of methanol or tert-butanol, which is a denaturant.","PeriodicalId":17402,"journal":{"name":"Journal of the Turkish Chemical Society, Section A: Chemistry","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2019-05-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"48401252","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 13

PREPARATION OF POLY(PYROMELLITIC DIANHYDRIDE-CO-THIONIN) MODIFIED VOLTAMMETRIC SENSOR FOR THE DETERMINATION OF EPICATECHIN 聚焦二酸酐- co -硫氨酸修饰伏安传感器测定表儿茶素的制备

Journal of the Turkish Chemical Society, Section A: Chemistry Pub Date : 2018-09-08 DOI: 10.18596/jotcsa.446953

Serap Titretir Duran

引用次数: 4

Syntheses and Spectroscopic Characterization on New [O–3-phenyl-1-propyl-(4-methoxyphenyl)dithiophosphonato] Ni(II), Cd(II) and Hg(II) Complexes 新型[O–3-苯基-1-丙基-（4-甲氧基苯基）二硫代膦酸酯]Ni（II）、Cd（II）和Hg（II）配合物的合成及光谱表征

Journal of the Turkish Chemical Society, Section A: Chemistry Pub Date : 2018-09-01 DOI: 10.18596/JOTCSA.468027

Ertuğrul Gazi SAĞLAM SAĞLAM, Ahmet Ebinç

{"title":"Syntheses and Spectroscopic Characterization on New [O–3-phenyl-1-propyl-(4-methoxyphenyl)dithiophosphonato] Ni(II), Cd(II) and Hg(II) Complexes","authors":"Ertuğrul Gazi SAĞLAM SAĞLAM, Ahmet Ebinç","doi":"10.18596/JOTCSA.468027","DOIUrl":"https://doi.org/10.18596/JOTCSA.468027","url":null,"abstract":"In this study, four new dithiophosphonic acid complexes, namely, trans- bis-[ O– 3-phenyl-1-prop yl- (4-methoxyphenyl) dithiophosphonato ] nickel (II), {Bis-pyridine-bis-(O–3–phenylpropyl (4-methoxyphenyl) dithiophosphonato ]} nickel (II), bis-{bis-( O– 3-phenyl-1-prop yl- (4-methoxyphenyl) dithiophosphonato ] cadmium (II)} and bis - { bis - ( O– 3 - phenyl – 1 - prop yl- ( 4-methoxyphenyl ) dithiophosphonato ] mercury (II)} were syntheszed. The complexes were of the general structure [Ni(L) 2 ] and [M(µ-L) 2 (L) 2 ], M= Cd 2+ and Hg 2+ . The nickel(II) complex was capable of coordinating two moles of pyridine per mole as many four-coordinated nickel(II) complex do leading to the six-coordinated complex, [Ni(L) 2 (Py) 2 ]. All the compounds were characterized by elemental analysis; MS; FTIR and Raman spectroscopies. The [ Ni( L ) 2 ], [Cd(µ-L) 2 (L) 2 ] and [Hg(µ-L) 2 (L) 2 ] were also investigated by 1 H-, 13 C- and 31 P-NMR. The magnetic susceptibility of the pyridine nickel complex was measured to confirm the hybridization patterns and the geometry.","PeriodicalId":17402,"journal":{"name":"Journal of the Turkish Chemical Society, Section A: Chemistry","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2018-09-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"42007700","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 2

Mineralization of Hydrochlorothiazide using Hydrogen Peroxide in Subcritical Water 亚临界水中过氧化氢对氢氯噻嗪的矿化作用

Journal of the Turkish Chemical Society, Section A: Chemistry Pub Date : 2018-09-01 DOI: 10.18596/jotcsa.449979

Erdal Yabalak, Özkan Görmez, Yahya Nural

引用次数: 2