Journal of the Turkish Chemical Society, Section A: Chemistry最新文献

Investigating the Effects of Fluorine Substituents on Organic Dyes in Dye-Sensitized Solar Cells 染料敏化太阳能电池中氟取代基对有机染料影响的研究

Journal of the Turkish Chemical Society, Section A: Chemistry Pub Date : 2023-10-16 DOI: 10.18596/jotcsa.1355244

Saifaldeen ABDALHADİ, Nabeel MOHAMMED, Khalida ALİ, Hazim AL-ZUBAİDİ

{"title":"Investigating the Effects of Fluorine Substituents on Organic Dyes in Dye-Sensitized Solar Cells","authors":"Saifaldeen ABDALHADİ, Nabeel MOHAMMED, Khalida ALİ, Hazim AL-ZUBAİDİ","doi":"10.18596/jotcsa.1355244","DOIUrl":"https://doi.org/10.18596/jotcsa.1355244","url":null,"abstract":"We synthesized and evaluated five organic dyes that featured both mono- and di-substituted fluorine atoms for application in dye-sensitized solar cells (DSSCs). The dye structure was designed with N, N-dimethylaniline as a donor, fluorophenyl as an π-conjugated bridge, and cyanoacetic acid as an anchoring and acceptor group. The fluorine substituents are strong electron-withdrawing groups, introducing different numbers and positions of fluorine atoms (ortho and meta) that were expected to the ability of the acceptor parts of the dye. The results showed that adding the fluorine mono-substitution in the ortho position can enhance the efficiency of the solar cells in comparison with the meta-substitution and unsubstituted one. However, the di-substitution by fluorine atoms in two ortho positions and ortho, meta positions reduced the performance of the solar cells. The reason was related to the effect of π-conjugation between the fluorine substituent and the carbonyl group of the carboxylic acid. The DSSCs based on dye 14 achieved the best results with power conversion efficiency (PCE) = 3.33%, (Jsc = 5.43 mA cm-2, Voc = 0.81V and FF = 75.85%) under standard conditions with I3-/I- as the electrolyte.","PeriodicalId":17402,"journal":{"name":"Journal of the Turkish Chemical Society, Section A: Chemistry","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2023-10-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"136184131","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Creating Nano-Sulfur from Sulfur Wastes in Mishraq 米什拉克从硫废料中制造纳米硫

Journal of the Turkish Chemical Society, Section A: Chemistry Pub Date : 2023-10-15 DOI: 10.18596/jotcsa.1362128

Saad AHMED, Mote`a ABDULLA, Ammar HAMDOON

引用次数: 0

Synthesis of Manganese(II), Iron(III), and Vanadium(IV) Complexes with New Schiff Bases and their Spectroscopic and Thermal Studies and Evaluation of their Antimicrobial Activity 锰(II)、铁(III)、钒(IV)新型席夫碱配合物的合成、光谱、热研究及抗菌活性评价

Journal of the Turkish Chemical Society, Section A: Chemistry Pub Date : 2023-10-11 DOI: 10.18596/jotcsa.1250844

Sinan AL-BAYATİ, Sarab ALAZAWİ, Sadeem AL-BARODY, Anaam MAJEED, Rehab ALHASSANİ

{"title":"Synthesis of Manganese(II), Iron(III), and Vanadium(IV) Complexes with New Schiff Bases and their Spectroscopic and Thermal Studies and Evaluation of their Antimicrobial Activity","authors":"Sinan AL-BAYATİ, Sarab ALAZAWİ, Sadeem AL-BARODY, Anaam MAJEED, Rehab ALHASSANİ","doi":"10.18596/jotcsa.1250844","DOIUrl":"https://doi.org/10.18596/jotcsa.1250844","url":null,"abstract":"Heterocyclic 3-acetyl coumarin with hydrazide derivatives and their metal complexes are a substantial family of pharmaceutical drugs used to treat infection, anti-inflammatory issues, diabetes, and neurological disorders in the field of medicinal chemistry. Cyclization of 5- floro-2-furaldehyde, ethyl acetoacetate, and urea or thiourea by LaCl3.7H2O, addition of hydrazine to form amine derivatives were performed, and respective Schiff base derivatives (L1, L2) were produced by adding acetyl coumarin in an ethanolic solution at ambient temperature. New ligands and its complexes of the V (IV), Fe (III) and Mn (II) ions were characterized using (FT-IR, UV, MS) and nuclear magnetic resonance (1H-NMR) as well as elemental analysis (CHN). The synthesized complexes chelate with ligands L1, L2 via (N, O2) atoms. The structural geometry of the complexes was illustrated in the solid phase using FT-IR and UV-VIS spectroscopy, elemental analysis (CHNS), and flame atomic absorption, in addition to magnetic susceptibility and conductivity measurement. The antibacterial activity of the newly prepared ligands and their metal complexes was evaluated against Pseudonomous aerugionosa as a gram negative and Bacillus subtilis as a gram positive microorganism. Moreover, the antifungal activity against two fungi Aspergillus flavus, and Saccharomyces cerevisiae was studied for all compounds. The coordinated ligands significantly increased their bactericidal and fungicidal action compared to the free ligands, which did not exhibit any activity against the selected fungal and bacterial strains. The results focused on the synergetic relationship between the metal ion and the ligand, in addition to the structural variation.","PeriodicalId":17402,"journal":{"name":"Journal of the Turkish Chemical Society, Section A: Chemistry","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2023-10-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"136253930","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Preparation of PLGA-PEG/Hydroxyapatite Composites via Simple Methodology of Film Formation and Assessment of Their Structural, Thermal, and Biological Features PLGA-PEG/羟基磷灰石复合材料的简单成膜方法制备及其结构、热、生物学特性评价

Journal of the Turkish Chemical Society, Section A: Chemistry Pub Date : 2023-09-30 DOI: 10.18596/jotcsa.1313562

Fatih ÇİFTÇİ, Ali Can ÖZARSLAN

{"title":"Preparation of PLGA-PEG/Hydroxyapatite Composites via Simple Methodology of Film Formation and Assessment of Their Structural, Thermal, and Biological Features","authors":"Fatih ÇİFTÇİ, Ali Can ÖZARSLAN","doi":"10.18596/jotcsa.1313562","DOIUrl":"https://doi.org/10.18596/jotcsa.1313562","url":null,"abstract":"This study aimed to develop polymeric composite films suitable for applications in the field of bone tissue engineering. The preparation of PLGA-PEG/HAP composite films was achieved using a simple methodology, including mixing, sonication, and casting-drying stages. Characterization analyses, including FTIR, SEM, TGA-DSC, and XRD, were conducted to assess the properties of the composite films. The results showed that the PEG polymer decreased the glass transition temperature of the composite, while the HAP did not change. Further, weight remaining (%) values of HAP, PLGA-PEG, and PLGA-PEG/HAP were found as 94.04, 88.28, and 90.57, respectively. Thus, it can be concluded that HAP improves the thermal stability of PLGA-PEG. The outcomes of the analysis, encompassing the evaluation of physical, morphological, and thermal properties, demonstrate that the composite structure comprising PLGA and PEG polymers along with HAP ceramic material may attain the intended quality. Moreover, fluorescence microscopy was employed to visualize the interaction between cells and the composite films following DAPI staining to evaluate cell adhesion and proliferation on the PLGA-PEG/HAP composite films. PLGA-PEG/HAP composite films have no adverse effects on cells, such as toxicity, and they have also exhibited a favorable influence on cell proliferation, supporting an augmentation in cellular growth and adhesion. Overall, the results indicate that the synthesized PLGA-PEG/HAP composite films may hold the potential to serve as a promising candidate for applications in the field of bone tissue engineering.","PeriodicalId":17402,"journal":{"name":"Journal of the Turkish Chemical Society, Section A: Chemistry","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2023-09-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"135131788","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Effect of AOT/Heptane Reverse Micelles on Oxidation of Ferroin by Metaperiodate: Kinetic and Mechanistic Aspects AOT/庚烷反胶束对超碘酸氧化亚铁的影响:动力学和机理研究

Journal of the Turkish Chemical Society, Section A: Chemistry Pub Date : 2023-09-19 DOI: 10.18596/jotcsa.1226805

Leela Kumari BODASİNGİ, Shyamala PULİPAKA, Venkata Nagalakshmi KİLANA

引用次数: 0

Aqueous Extract of Onion Peels as A Biowaste-Based Sensitizer for Photovoltaic Cells 洋葱皮水提物作为光伏电池生物废弃物敏化剂的研究

Journal of the Turkish Chemical Society, Section A: Chemistry Pub Date : 2023-09-15 DOI: 10.18596/jotcsa.1260709

Rısna Ernı Yatı ADU, Gebhardus Djugian GELYAMAN

引用次数: 0

Surface Physicochemical Characterization of Shepherd’s Purse (Capsella bursa-pastoris) by Inverse Gas Chromatography 荠菜(Capsella bursa-pastoris)的表面理化性质

Journal of the Turkish Chemical Society, Section A: Chemistry Pub Date : 2023-09-10 DOI: 10.18596/jotcsa.1278025

Birol ISİK

{"title":"Surface Physicochemical Characterization of Shepherd’s Purse (Capsella bursa-pastoris) by Inverse Gas Chromatography","authors":"Birol ISİK","doi":"10.18596/jotcsa.1278025","DOIUrl":"https://doi.org/10.18596/jotcsa.1278025","url":null,"abstract":"Shepherd’s purse (Capsella bursa-pastoris) is one of the plants widely utilized in conventional medicine and can grow in different parts of the world. The determination of the surface properties of a solid material is extremely important for the industrial use of the material and the improvement of material properties. Therefore, in this study, this plant was used as a stationary phase, and its surface characterization was performed by inverse gas chromatography technique. In this context, firstly, the plant was prepared with several pretreatments to be used in the experimental tests. The V_N values were found from the retention data obtained by passing organic solvents over the plant filled into the chromatographic column in the temperature range of 303.2–328.2 K and linear retention diagrams were drawn. The γ_S^D of the plant was calculated according to Schultz, Dorris-Gray, and Donnet-Park methods, and the suitability of the methods was compared. The 〖∆G〗_A^S values were calculated with the data obtained from the Schultz method, and the 〖∆H〗_A^S values were calculated using these data. The acidity and basicity of the plant surface were examined. According to the K_D⁄K_A value (0.93), it was determined that the surface of the plant was acidic.","PeriodicalId":17402,"journal":{"name":"Journal of the Turkish Chemical Society, Section A: Chemistry","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2023-09-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"136072474","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Microencapsulation of Hemp Oil in Gelatin and Gum Arabic and Investigation of Cumulative Release Properties in n-Hexane Medium 大麻油在明胶和阿拉伯胶中的微胶囊化及其在正己烷介质中累积释放特性的研究

Journal of the Turkish Chemical Society, Section A: Chemistry Pub Date : 2023-09-06 DOI: 10.18596/jotcsa.1292222

Okan BAYRAM, Fethiye GÖDE

引用次数: 0

Recent Developments in Nanostructured Materials for Supercapacitor Electrodes 超级电容器电极纳米结构材料的研究进展

Journal of the Turkish Chemical Society, Section A: Chemistry Pub Date : 2023-09-06 DOI: 10.18596/jotcsa.1320655

Emre YILMAZOĞLU, Selcan KARAKUŞ

{"title":"Recent Developments in Nanostructured Materials for Supercapacitor Electrodes","authors":"Emre YILMAZOĞLU, Selcan KARAKUŞ","doi":"10.18596/jotcsa.1320655","DOIUrl":"https://doi.org/10.18596/jotcsa.1320655","url":null,"abstract":"This review focuses on nanostructures-based systems and aims to provide a comprehensive overview of recent advancements in energy storage technologies and modified energy storage materials. The transition towards a sustainable and carbon-free energy system hinges on the progress of efficient and safe energy storage technologies. Supercapacitors have garnered significant interest in diverse energy storage applications due to their rapid charge/discharge rates, high power density, and extended cycle life. Nanostructures have conclusively demonstrated their capability to significantly enhance supercapacitor electrodes' performance. MXene, an innovative category of 2D materials, has emerged as a promising candidate for energy storage applications due to its substantial surface area, exceptional electrical conductivity, and versatile characteristics. Supercapacitors, nanostructures, and MXene are the main topics of the research articles and reviews in this special issue, highlighting recent developments in the design, synthesis, and characterization of advanced energy storage materials and devices. Additionally, this study presents an in-depth investigation of various carbon-based nanomaterials, their synthesis techniques, and their performance in supercapacitors. It also emphasizes the potential of recycling waste materials for developing high-performance nanomaterials for energy storage applications. Finally, this review encourages further research and development of advanced energy storage technologies by giving readers a thorough overview of the current state-of-the-art and future directions in this rapidly expanding sector.","PeriodicalId":17402,"journal":{"name":"Journal of the Turkish Chemical Society, Section A: Chemistry","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2023-09-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"135205419","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

SYNTHESIS AND BIOLOGICAL EVALUATION OF 1H-(INDOLE-5-YL)-3-SUBSTITUTED-1,2,4-OXADIAZOLES AS NOVEL 5-LOX INHIBITORS 新型5-氧抑制剂1h -(吲哚-5-基)-3-取代-1,2,4-恶二唑的合成及生物学评价

Journal of the Turkish Chemical Society, Section A: Chemistry Pub Date : 2023-09-06 DOI: 10.18596/jotcsa.1334005

Berihu TEKLUU, Siddaiah VİDAVALUR, Sunanda Kumari KADİRİ

引用次数: 0