Journal of The Electrochemical Society最新文献_第8页

Accelerated High-Temperature Oxidation Behavior of Ferritic Stainless Steel under Air/H2+H2O Dual Atmosphere 铁素体不锈钢在空气/H2+H2O 双重气氛下的加速高温氧化行为

IF 3.9 4区工程技术

Journal of The Electrochemical Society Pub Date : 2024-08-28 DOI: 10.1149/1945-7111/ad6bc4

Riko Inuzuka, Norikazu Osada, Kiyoshi Imai, Tsuneji Kameda, Tatsumi Ishihara

{"title":"Accelerated High-Temperature Oxidation Behavior of Ferritic Stainless Steel under Air/H2+H2O Dual Atmosphere","authors":"Riko Inuzuka, Norikazu Osada, Kiyoshi Imai, Tsuneji Kameda, Tatsumi Ishihara","doi":"10.1149/1945-7111/ad6bc4","DOIUrl":"https://doi.org/10.1149/1945-7111/ad6bc4","url":null,"abstract":"Improvement in durability is one of the important subjects for utilizing solid oxide electrolyzer cell (SOEC) systems widely. In SOEC stacks, separators are exposed to complexed dual atmosphere (i.e. hydrogen - steam mixed gases and oxygen rich air are on each side). In this study, the degradation phenomena of separator materials (SUS430, ZMG232G10, Crofer22APU) in SOEC dual atmosphere were investigated. The samples were exposed in SOEC dual and simple atmospheres at 700 °C for 500 h. Then, their cross sections were analyzed by X-ray diffraction and scanning electron microscopy/energy-dispersive X-ray analysis. The degradation mechanisms of the separator materials in the SOEC stack operating conditions were discussed. ZMG232G10 and Crofer22APU with high Cr content showed thin oxide layer under both the dual or single atmosphere, while SUS430 with low Cr content showed significant oxidation in the H2-steam atmosphere and on the air side under the dual atmosphere condition. The significant oxidation on the air side of the dual atmosphere of SUS430 observed in this study is a unique phenomenon under the dual atmosphere condition and not observed in a single air atmosphere.","PeriodicalId":17364,"journal":{"name":"Journal of The Electrochemical Society","volume":"60 1","pages":""},"PeriodicalIF":3.9,"publicationDate":"2024-08-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142222461","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Electrochemical Dissolution Behavior of ZCuPb10Sn10 Alloy in NaNO3 Solution ZCuPb10Sn10 合金在 NaNO3 溶液中的电化学溶解行为

IF 3.9 4区工程技术

Journal of The Electrochemical Society Pub Date : 2024-08-28 DOI: 10.1149/1945-7111/ad6eba

Qingliang Zhang, Ningsong Qu

{"title":"Electrochemical Dissolution Behavior of ZCuPb10Sn10 Alloy in NaNO3 Solution","authors":"Qingliang Zhang, Ningsong Qu","doi":"10.1149/1945-7111/ad6eba","DOIUrl":"https://doi.org/10.1149/1945-7111/ad6eba","url":null,"abstract":"Copper alloys, such as ZCuPb10Sn10, have been widely applied to friction pairs in various products. Surface texture, such as micro-dimple array has attracted significant attention from researchers worldwide to improve tribological performance. To generate micro-dimple array on ZCuPb10Sn10 alloy by electrochemical machining, it is essential to investigate the electrochemical dissolution behavior of ZCuPb10Sn10 in NaNO3 solution. In this paper, the electrochemical dissolution behavior of ZCuPb10Sn10 alloy in NaNO3 solution is investigated through experimental tests. Anodic polarization, Tafel polarization, and electrochemical impedance spectroscopy were conducted to investigate its passive and corrosion behavior. The microstructure and composition of the dissolved surfaces were analyzed under various conditions. Additionally, a model was proposed to explain the electrochemical dissolution process of ZCuPb10Sn10 alloy in NaNO3 solution under high pressure hydrostatic conditions. Ultimately, a NaNO3 solution with 10% in concentration and 20 °C in temperature was selected as the electrolyte and a micro-dimple array with an average diameter of 119.7 μm and a depth of 7.4 μm was successfully generated with through-mask electrochemical micromachining on the surface of ZCuPb10Sn10 alloy.","PeriodicalId":17364,"journal":{"name":"Journal of The Electrochemical Society","volume":"176 1","pages":""},"PeriodicalIF":3.9,"publicationDate":"2024-08-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142222464","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Activity and Selectivity in the Electrochemical Reduction of CO2 at CuSnx Electrocatalysts Using a Zero-Gap Membrane Electrode Assembly 使用零间隙膜电极组件的 CuSnx 电催化剂在电化学还原 CO2 过程中的活性和选择性

IF 3.9 4区工程技术

Journal of The Electrochemical Society Pub Date : 2024-08-28 DOI: 10.1149/1945-7111/ad6fd7

Monsuru Dauda, John Hendershot, Mustapha Bello, Junghyun Park, Alvaro Loaiza Orduz, Orhan Kizilkaya, Phillip Sprunger, Anthony Engler, Koffi Yao, Craig Plaisance, John Flake

{"title":"Activity and Selectivity in the Electrochemical Reduction of CO2 at CuSnx Electrocatalysts Using a Zero-Gap Membrane Electrode Assembly","authors":"Monsuru Dauda, John Hendershot, Mustapha Bello, Junghyun Park, Alvaro Loaiza Orduz, Orhan Kizilkaya, Phillip Sprunger, Anthony Engler, Koffi Yao, Craig Plaisance, John Flake","doi":"10.1149/1945-7111/ad6fd7","DOIUrl":"https://doi.org/10.1149/1945-7111/ad6fd7","url":null,"abstract":"In this study Cu, Sn, and bimetallic CuSnx nanoparticles were synthesized and evaluated as electrocatalysts for CO2 reduction using zero gap membrane electrode assemblies. Results show bimetallic electrocatalysts with Sn contents above 10% yield formate as a primary product with Faradaic Efficiencies near 70% at 350 mA cm−2. Cu-Snx electrocatalysts with less than 10% Sn yield CO at current densities below 350 mA cm−2 and relatively lower cell potentials. When the low-Sn content bimetallic electrocatalysts were evaluated in alkaline anolytes at 350 mA cm−2, ethanol was recorded as the primary product (FE = 48.5% at Ecell ≥ 3.0 V). We propose enhanced C2 activity and selectivity originate from Cu dimers adjacent to Sn atoms for bimetallic electrocatalyst with low-Sn content. The C2 active sites are lost when the surface Sn content exceeds 25%–38%.","PeriodicalId":17364,"journal":{"name":"Journal of The Electrochemical Society","volume":"2 1","pages":""},"PeriodicalIF":3.9,"publicationDate":"2024-08-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142222466","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

The Effect of the Rare Earth Element Cerium on the Electrocrystallization and Microstructure of Nickel Electrodeposits in Industrial Electrolytes 稀土元素铈对工业电解液中镍电沉积物的电晶化和微观结构的影响

IF 3.9 4区工程技术

Journal of The Electrochemical Society Pub Date : 2024-08-28 DOI: 10.1149/1945-7111/ad70da

Yang-Tao Xu, Yan-Hong Li, Yin Peng, Zhi-Qiang Zhong

{"title":"The Effect of the Rare Earth Element Cerium on the Electrocrystallization and Microstructure of Nickel Electrodeposits in Industrial Electrolytes","authors":"Yang-Tao Xu, Yan-Hong Li, Yin Peng, Zhi-Qiang Zhong","doi":"10.1149/1945-7111/ad70da","DOIUrl":"https://doi.org/10.1149/1945-7111/ad70da","url":null,"abstract":"To meet the industrial production needs for high-quality and precisely controllable structured high-end nickel foils, rare Earth compounds are added as additives in complex industrial electrolytes to improve the quality of the nickel deposition layer. This study investigates the effects of adding rare Earth compounds to the existing industrial production electrolytes (which already contain various organic and inorganic additives in a mixed acid solution) on the surface microstructure, cerium content, grain size, and crystal orientation of the nickel deposition layer. Using direct current electrodeposition, different concentrations of rare Earth compounds were added to the industrial electrolyte, and the cerium content, grain size, and crystal orientation were characterized. The results show that adding 0.8 g·l−1 CeCl3 accelerates the nucleation rate and shortens the nucleation relaxation time. The addition of rare Earth elements promotes multi-directional preferential growth, resulting in uniform and fine grain size, improved grain structure of the deposition layer, and reduced surface roughness of the nickel plating layer. Therefore, rare Earth elements can be used to regulate the structure, microstructure, and grain refinement of the nickel deposition layer without affecting its composition.","PeriodicalId":17364,"journal":{"name":"Journal of The Electrochemical Society","volume":"20 1","pages":""},"PeriodicalIF":3.9,"publicationDate":"2024-08-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142222482","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Controlling Oxygen Vacancy Content by Varying Calcination Temperature to Enhance the Gas Sensing Performance of BiVO4 Material 通过改变煅烧温度控制氧空位含量以提高 BiVO4 材料的气体传感性能

IF 3.9 4区工程技术

Journal of The Electrochemical Society Pub Date : 2024-08-28 DOI: 10.1149/1945-7111/ad6ef6

Si-Qi Jiao, Yu-Feng Liu, Xiao-Hong Zheng, Cheng Zhang, Xiao-Rui Wang

引用次数: 0

CoFe2O4 Nanoparticles on Bio-Based Polymer Derived Nitrogen Doped Carbon as Bifunctional Electrocatalyst for Li-Air Battery 生物基聚合物掺氮碳上的 CoFe2O4 纳米粒子作为锂空气电池的双功能电催化剂

IF 3.9 4区工程技术

Journal of The Electrochemical Society Pub Date : 2024-08-27 DOI: 10.1149/1945-7111/ad69c9

Pirapath Arkasalerks, Amarshi Patra, Kottisa Sumala Patnaik, Koichi Higashimine, Noriyoshi Matsumi

{"title":"CoFe2O4 Nanoparticles on Bio-Based Polymer Derived Nitrogen Doped Carbon as Bifunctional Electrocatalyst for Li-Air Battery","authors":"Pirapath Arkasalerks, Amarshi Patra, Kottisa Sumala Patnaik, Koichi Higashimine, Noriyoshi Matsumi","doi":"10.1149/1945-7111/ad69c9","DOIUrl":"https://doi.org/10.1149/1945-7111/ad69c9","url":null,"abstract":"Lithium-air batteries (LABs) are gaining attention as a promising energy storage solution. Their theoretical energy density of 3,505 Whkg−1 exceeds that of conventional lithium-ion batteries (500–800 Whkg−1). The commercial viability and widespread adoption of lithium-air batteries face challenges such as poor cycling stability, limited lifespan, and unresolved side reactions. In this study, we synthesized spinel CoFe2O4-decorated on bio-based poly(2,5-benzimidazole) derived N-doped carbon for electrocatalysts. Notably, strong metal-substrate interaction (SMSI) was observed through various characterizations. The bifunctional electrocatalytic activity and stability toward oxygen reduction reaction and oxygen evolution reaction were significantly enhanced by the SMSI, The LAB demonstrated a high discharge capacity of 18,356 mAhg−1 at a current density of 200 mAg−1, maintaining a remarkable discharge capacity of 1,000 mAhg−1 even at a high current density of 400 mAg−1 for 200 cycles. CoFe2O4-decorated on bio-derived ABPBI holds promise as a practical air-breathing electrode for high-capacity rechargeable LABs.","PeriodicalId":17364,"journal":{"name":"Journal of The Electrochemical Society","volume":"23 1","pages":""},"PeriodicalIF":3.9,"publicationDate":"2024-08-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142222469","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Formation of Through-Hole Porous Anodic Aluminum Oxide Layer Locally with 3D Printed Solution Flow Type Microdroplet Cell 利用 3D 打印溶液流式微滴池在局部形成通孔多孔阳极氧化铝层

IF 3.9 4区工程技术

Journal of The Electrochemical Society Pub Date : 2024-08-27 DOI: 10.1149/1945-7111/ad6fd6

Adane Adugna Ayalew, Xiaole Han, Yoganandan Govindaraj, Masatoshi Sakairi

引用次数: 0

Enhanced Porous Electrode Theory Based Electrochemical Model for Higher Fidelity Modelling and Deciphering of the EIS Spectra 基于多孔电极理论的增强型电化学模型，用于更高保真建模和解密 EIS 光谱

IF 3.9 4区工程技术

Journal of The Electrochemical Society Pub Date : 2024-08-27 DOI: 10.1149/1945-7111/ad6eb9

Igor Mele, Klemen Zelič, Marko Firm, Jože Moškon, Miran Gaberšček, Tomaž Katrašnik

{"title":"Enhanced Porous Electrode Theory Based Electrochemical Model for Higher Fidelity Modelling and Deciphering of the EIS Spectra","authors":"Igor Mele, Klemen Zelič, Marko Firm, Jože Moškon, Miran Gaberšček, Tomaž Katrašnik","doi":"10.1149/1945-7111/ad6eb9","DOIUrl":"https://doi.org/10.1149/1945-7111/ad6eb9","url":null,"abstract":"Electrochemical impedance spectroscopy (EIS) is essential for non-invasive battery characterization. This paper addresses the challenge of adequate interpretation of EIS spectra, which are often complicated by overlapping internal phenomena occurring on similar time scales. We present, for the first time, a high-fidelity numerical time-domain electrochemical model that can virtually replicate experimental EIS spectra with three superimposed high-frequency semicircles, a transition to the diffusion tail at elevated imaginary values, and a tilted diffusion tail at low frequencies. These advanced features were made possible by extending state-of-the-art porous electrode model with innovative sub-models for the double layer phenomenon at the carbon black/electrolyte and metal Li-anode/electrolyte interfaces, and transport phenomena of charged species through the solid electrolyte interphase at the Li-anode interface. Additionally, we modelled the diffusion tail inclination by introducing representative active particles of varying sizes. Results from custom-made half-cells confirm the model’s ability to decipher EIS spectra more accurately compared to existing models. Moreover, innovative physics-based battery model that is capable of accurately modelling intra-cell phenomena can reveal internal states and physical parameters of batteries using measured EIS spectra. The model, therefore, also enables functionality of an advanced virtual sensor, which is an important diagnostics feature in next-generation battery management systems.","PeriodicalId":17364,"journal":{"name":"Journal of The Electrochemical Society","volume":"9 1","pages":""},"PeriodicalIF":3.9,"publicationDate":"2024-08-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142222468","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Review—Advances in Rechargeable Lithium-Ion Batteries Utilizing Polyoxometalate-Functionalized Nanocarbon Materials 综述--利用聚氧化金属功能化纳米碳材料的可充电锂离子电池的研究进展

IF 3.9 4区工程技术

Journal of The Electrochemical Society Pub Date : 2024-08-27 DOI: 10.1149/1945-7111/ad6b46

Samaneh Shahsavarifar, Morteza Rezapour, Mehdi Mehrpooya, Hermann Ehrlich, Teofil Jesionowski, Mohammad Reza Ganjali, Rafael Luque, Mehdi Rahimi-Nasrabadi

{"title":"Review—Advances in Rechargeable Lithium-Ion Batteries Utilizing Polyoxometalate-Functionalized Nanocarbon Materials","authors":"Samaneh Shahsavarifar, Morteza Rezapour, Mehdi Mehrpooya, Hermann Ehrlich, Teofil Jesionowski, Mohammad Reza Ganjali, Rafael Luque, Mehdi Rahimi-Nasrabadi","doi":"10.1149/1945-7111/ad6b46","DOIUrl":"https://doi.org/10.1149/1945-7111/ad6b46","url":null,"abstract":"Polyoxometalates (POMs) are inorganic nanoclusters that consist of oxygen and transition metals. These nanoclusters serve as excellent precursors for creating electrode materials that contain transition metals. Additionally, the interaction between POMs and carbon substrates produces positive synergistic effects. There has been considerable attention on employing POMs and carbon nanostructures (for example carbon nanotubes, graphene, and mesoporous carbon) in composite materials for diverse purposes including catalysis, transformation, storage of energy, molecular detection, and electrical detection. By combining the reactive nature of POMs with the exceptional electrical properties of carbon nanostructures, highly desirable composite features can be achieved. This review delves into the extensive use of POM/nanocarbon materials for constructing rechargeable lithium-ion batteries, providing an in-depth analysis of the characteristics of POMs and the techniques employed for binding carbon.","PeriodicalId":17364,"journal":{"name":"Journal of The Electrochemical Society","volume":"40 1","pages":""},"PeriodicalIF":3.9,"publicationDate":"2024-08-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142222484","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Influence of Potential and the Presence of Boric Acid on Pt1-xCox Alloy Electrodeposition and Magnetic Properties 电位和硼酸对 Pt1-xCox 合金电沉积和磁性能的影响

IF 3.9 4区工程技术

Journal of The Electrochemical Society Pub Date : 2024-08-26 DOI: 10.1149/1945-7111/ad6b48

Eric D. Rus, Eduardo L. Corrêa, Cindi L. Dennis, Thomas P. Moffat

{"title":"Influence of Potential and the Presence of Boric Acid on Pt1-xCox Alloy Electrodeposition and Magnetic Properties","authors":"Eric D. Rus, Eduardo L. Corrêa, Cindi L. Dennis, Thomas P. Moffat","doi":"10.1149/1945-7111/ad6b48","DOIUrl":"https://doi.org/10.1149/1945-7111/ad6b48","url":null,"abstract":"The effects of potential and the presence of B(OH)3 on Pt1-xCox alloy electrodeposition from aqueous chloride-based solutions on Ru substrates was investigated. Films deposited at potentials more reducing than −0.65 V vs SCE were hexagonal close packed and greater than 90% Co (mole basis), and films deposited at potentials more oxidizing than −0.65 V were face centered cubic and showed a monotonic decrease in cobalt content as the potential increased. The composition and structure-potential dependences were not strongly affected by the presence of B(OH)3. Structural change coincided with a distinct knee-like feature in the composition-potential relationship, along with a prominent narrow voltammetric peak associated with Co deposition, possibly related to nucleation and growth of the hcp phase. The presence of B(OH)3 produced a sharp minimum in both Coulombic efficiency and deposition rate at potentials near −0.65 V and almost entirely suppressed the voltammetric feature. This may be associated with a combination of B(OH)3-derived proton reduction and inhibition of metal deposition by adsorbed B(OH)3 or B(OH)3-derived species. The presence of B(OH)3 affected the magnetic behavior of films deposited at potentials more oxidizing than −0.55 V (i.e., those with compositions less than about 40% Co) only weakly, but resulted in generally smaller maximum magnetizations for films deposited at more reducing potentials, and notably a much lower magnetization for films deposited at −0.65 V.","PeriodicalId":17364,"journal":{"name":"Journal of The Electrochemical Society","volume":"5 1","pages":""},"PeriodicalIF":3.9,"publicationDate":"2024-08-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142222478","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0