Journal of Rare Earths最新文献

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Thermal stability improvement and microstructure optimization of high cobalt content Nd-Fe-B magnets via terbium grain boundary diffusion 通过铽晶界扩散改善高钴含量钕铁硼磁体的热稳定性并优化其微观结构
IF 5.2 1区 化学
Journal of Rare Earths Pub Date : 2024-08-01 DOI: 10.1016/j.jre.2023.10.023
{"title":"Thermal stability improvement and microstructure optimization of high cobalt content Nd-Fe-B magnets via terbium grain boundary diffusion","authors":"","doi":"10.1016/j.jre.2023.10.023","DOIUrl":"10.1016/j.jre.2023.10.023","url":null,"abstract":"<div><p>The substitution of Fe by Co in the 2:14:1 phase is an effective method to increase the Curie temperature and enhance the thermal stability of the Nd-Fe-B magnets. However, the accumulation of Co element at the grain boundaries (GBs) changes the GBs from nonmagnetic to ferromagnetic and causes the thin-layer GBs to become rare. In this paper, the method of diffusing Tb element was chosen to improve the microstructure and temperature stability of high-Co magnets. Three original sintered Nd<sub>28.5</sub>Dy<sub>3</sub>-Co<sub><em>x</em></sub>Fe<sub>bal</sub>M<sub>0.6</sub>B<sub>1</sub> (<em>x</em> = 0, 6 wt%, 12 wt%; M = Cu, Al, Zr) magnets with different Co contents were diffused with Tb by grain boundary diffusion (GBD). After GBD, high-Co magnets exhibit more continuously distributed thin-layer GBs, and their thermal stability is significantly improved. In high-Co magnets (<em>x</em> = 6 wt%), the absolute value of the temperature coefficient of coercivity decreases from 0.603%/K to 0.508%/K in the temperature range of 293–413 K, that of remanence decreases from 0.099%/K to 0.091%/K, and the coercivity increases from 18.44 to 25.04 kOe. Transmission electron microscopy (TEM) characterization reveals that there are both the 1:2 phase and the amorphous phase in the high-Co magnet before and after GBD. EDS elemental analysis shows that Tb element is more likely to preferentially replace the rare earth elements in the 2:14:1 main phase than in the 1:2 phase and the amorphous phase. The concentration of Tb at the edge of the main phase is much higher than that in the 1:2 phase and amorphous phase, which is beneficial to the improvement of the microstructure. The preferential replacement of Tb elements at the edge of the 2:14:1 phase and thin-layer GBs with a more continuous distribution are synergistically responsible for improving the thermal stability of high-Co magnets. The study indicates that GBD is an effective method to improve the microstructure and thermal stability of high-Co magnets.</p></div>","PeriodicalId":16940,"journal":{"name":"Journal of Rare Earths","volume":"42 8","pages":"Pages 1531-1538"},"PeriodicalIF":5.2,"publicationDate":"2024-08-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"136127992","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Crystallization of RE2(OH)2CO3SO4·nH2O as a new family of layered hydroxides (RE = Gd−Lu lanthanides and Y), derivation of RE2O2SO4, photoluminescence and optical thermometry RE2(OH)2CO3SO4·nH2O新层状氢氧化物(RE = Gd−Lu镧系元素和Y)的结晶、RE2O2SO4的衍生、光致发光和光学测温
IF 5.2 1区 化学
Journal of Rare Earths Pub Date : 2024-08-01 DOI: 10.1016/j.jre.2023.07.008
{"title":"Crystallization of RE2(OH)2CO3SO4·nH2O as a new family of layered hydroxides (RE = Gd−Lu lanthanides and Y), derivation of RE2O2SO4, photoluminescence and optical thermometry","authors":"","doi":"10.1016/j.jre.2023.07.008","DOIUrl":"10.1016/j.jre.2023.07.008","url":null,"abstract":"<div><p>Layered rare-earth hydroxides (LREHs) draw wide research interest because of their peculiar crystal structure, rich interlayer chemistry and abundant functionality of the RE element, but are limited to the two categories of RE<sub>2</sub>(OH)<sub>5</sub>A·<em>n</em>H<sub>2</sub>O (A: typical of Cl<sup>−</sup> or NO<sub>3</sub><sup>−</sup>) and RE<sub>2</sub>(OH)<sub>4</sub>SO<sub>4</sub>·<em>n</em>H<sub>2</sub>O. On the other hand, rare-earth oxysulfates (RE<sub>2</sub>O<sub>2</sub>SO<sub>4</sub>) have attracted attention due to their properties of large-capacity oxygen storage, low-temperature magnetism and luminescence, but their preparation procedure mostly involves toxic SO<sub><em>x</em></sub> gases and/or complicated procedures. In this work, RE<sub>2</sub>(OH)<sub>2</sub>CO<sub>3</sub>SO<sub>4</sub>·<em>n</em>H<sub>2</sub>O as a new family of LREHs (RE = Gd‒Lu lanthanides and Y) were produced via hydrothermal reaction, from which phase-pure RE<sub>2</sub>O<sub>2</sub>SO<sub>4</sub> was derived via subsequent annealing at 800 °C in air without the involvement of SO<sub><em>x</em></sub>. The compounds were thoroughly characterized to reveal the intrinsic influence of lanthanide contraction (RE<sup>3+</sup> radius) on crystal structure, thermal behavior (dehydroxylation/decarbonation/desulfurization), vibrational property and crystallite morphology. Through analyzing the photoluminescence of Eu<sup>3+</sup> and Sm<sup>3+</sup> in the Gd<sub>2</sub>O<sub>2</sub>SO<sub>4</sub> typical host it is found that the 617 nm (Eu<sup>3+</sup>, <em>λ</em><sub>ex</sub> = 275 nm) and 608 nm (Sm<sup>3+</sup>, <em>λ</em><sub>ex</sub> = 407 nm) main emissions can retain as high as ∼79.6% and 85.5% of their room-temperature intensities at 423 K, with activation energies of ∼0.19 and 0.21 eV for thermal quenching, respectively. Application also indicates that both the phosphors have the potential for optical temperature sensing via the fluorescence intensity ratio (FIR) technology, whose maximum relative sensitivity reaches ∼2.70%/K for Eu<sup>3+</sup> and 1.73%/K for Sm<sup>3+</sup> at 298 K.</p></div>","PeriodicalId":16940,"journal":{"name":"Journal of Rare Earths","volume":"42 8","pages":"Pages 1496-1506"},"PeriodicalIF":5.2,"publicationDate":"2024-08-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"45334846","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Investigation of Ce/BEA as a passive NOx adsorber: 2. Hydrothermal aging deactivation mechanism Ce/BEA作为NO被动吸附剂的研究:2。水热老化失活机理
IF 5.2 1区 化学
Journal of Rare Earths Pub Date : 2024-08-01 DOI: 10.1016/j.jre.2023.05.009
{"title":"Investigation of Ce/BEA as a passive NOx adsorber: 2. Hydrothermal aging deactivation mechanism","authors":"","doi":"10.1016/j.jre.2023.05.009","DOIUrl":"10.1016/j.jre.2023.05.009","url":null,"abstract":"<div><p>Ce/BEA has the potential to be applied as a novel passive NO<sub><em>x</em></sub> absorber (PNA) in the after-treatment of vehicles due to its considerable NO<sub><em>x</em></sub> storage capacity. However, as a vehicle exhaust after-treatment material, it must withstand the test of long-term hydrothermal aging. This work examined the deactivation mechanism of Ce/BEA during hydrothermal aging. 3.0 wt% Ce/BEA was prepared using the ion-exchange method, and then subjected to hydrothermal treatment at 650 °C with 10% H<sub>2</sub>O for 1<strong>–</strong>12 h to obtain samples with different aging extent. For comparison, the H-BEA support was aged under the same conditions. Brunauer-Emmett-Teller (BET) method, X-ray diffraction (XRD), NH<sub>3</sub> temperature programmed reduction (NH<sub>3</sub>-TPD), <sup>27</sup>Al MAS nuclear magnetic resonance (<sup>27</sup>Al MAS NMR), H<sub>2</sub> temperature programmed reduction (H<sub>2</sub>-TPR), and high resolution-transmission electron microscopy (HR-TEM) were performed to characterize the changes in PNA performance, structure, Ce species, and acidity. The HR-TEM and H<sub>2</sub>-TPR results show that CeO<sub><em>x</em></sub> particles appear after hydrothermal aging, which results from the detachment and aggregation of active Ce species. Based on the <sup>27</sup>Al MAS NMR results, we conclude that BEA zeolite dealumination leads to the loss of acidic sites and the transformation of active Ce species on the acidic sites into the less active CeO<sub><em>x</em></sub>. This is the primary reason for the hydrothermal aging deactivation of Ce/BEA.</p></div>","PeriodicalId":16940,"journal":{"name":"Journal of Rare Earths","volume":"42 8","pages":"Pages 1524-1530"},"PeriodicalIF":5.2,"publicationDate":"2024-08-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"44413489","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Development of a novel Eu3+-doped tantalate red-emitting phosphor for w-LEDs application 一种用于w-LED应用的新型Eu3+掺杂钽酸盐红色荧光粉的研制
IF 5.2 1区 化学
Journal of Rare Earths Pub Date : 2024-08-01 DOI: 10.1016/j.jre.2023.07.014
{"title":"Development of a novel Eu3+-doped tantalate red-emitting phosphor for w-LEDs application","authors":"","doi":"10.1016/j.jre.2023.07.014","DOIUrl":"10.1016/j.jre.2023.07.014","url":null,"abstract":"<div><p>Two novel phosphors LiBa<sub>4(1‒<em>x</em>)</sub>Eu<sub>4<em>x</em></sub>Ta<sub>3</sub>O<sub>12</sub> (H-LBTO:<em>x</em>Eu<sup>3+</sup>) and Li<sub>0.25</sub>Ba<sub>1‒<em>x</em></sub>Eu<sub><em>x</em></sub>Ta<sub>0.75</sub>O<sub>3</sub> (C-LBTO:<em>x</em>Eu<sup>3+</sup>) were prepared successfully by a molten salt method. The transformation between these two structures was realized by changing the sintering temperature or changing the Eu<sup>3+</sup> ions concentration, which was also demonstrated by the X-ray diffraction (XRD), scanning electron microscopy (SEM), diffuse reflectance spectra (DRS), and photoluminescence excitation (PLE) analyses. Both the sintering temperature and the Eu<sup>3+</sup> ions doping concentration have significant impact on the formation of the crystal phase. All these phosphors sintered at 1023 K exhibit two major luminescence lines at 594 and 614 nm under near-UV light of 395 nm excitation, corresponding to Eu<sup>3+</sup> ions typical transitions of <sup>5</sup>D<sub>0</sub>→<sup>7</sup>F<sub>1</sub> and <sup>5</sup>D<sub>0</sub>→<sup>7</sup>F<sub>2</sub>. The optimum concentration of Eu<sup>3+</sup> ions is 9 mol% for C-LBTO:<em>x</em>Eu<sup>3+</sup> samples and the quenching interaction type is the nearest-neighbor ion interaction. The thermal stability of the C-LBTO:0.09Eu<sup>3+</sup> sample was investigated in detail and the device application further suggests that C-LBTO:0.09Eu<sup>3+</sup> can be used as a red phosphor for near-UV excited w-LEDs in lighting.</p></div>","PeriodicalId":16940,"journal":{"name":"Journal of Rare Earths","volume":"42 8","pages":"Pages 1479-1488"},"PeriodicalIF":5.2,"publicationDate":"2024-08-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"47699241","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
(Sm/Eu/Tm)3+ doped tantalum semiconductor system for photovoltaic and electrochemical functionality amplification 用于光伏和电化学功能放大的(Sm/Eu/Tm)3+掺杂钽半导体系统
IF 5.2 1区 化学
Journal of Rare Earths Pub Date : 2024-08-01 DOI: 10.1016/j.jre.2023.07.011
{"title":"(Sm/Eu/Tm)3+ doped tantalum semiconductor system for photovoltaic and electrochemical functionality amplification","authors":"","doi":"10.1016/j.jre.2023.07.011","DOIUrl":"10.1016/j.jre.2023.07.011","url":null,"abstract":"<div><p>This work reports the synthesis, characterization, and energy focused applications of the novel lanthanides co-doped tantalum pentoxide hetero-system (Sm<sup>3+</sup>-Eu<sup>3+</sup>-Tm<sup>3+</sup>:Ta<sub>2</sub>O<sub>5</sub>). Ln<sup>3+</sup>-doped Ta<sub>2</sub>O<sub>5</sub> express excellent opto-electronic features reflected by the narrow band gap energy of 3.87 eV. Different vibrations confirm the presence of Ta–O–Ta and Ta–O bonds. The synthesized system possesses orthorhombic geometry with 59.46 nm particle size. With the smoother and compact morphology, the synthesized material succeeds in augmenting the performance of different systems aimed at energy applications. Fully ambient perovskite solar cell device fabricated with the Ln<sup>3+</sup>-doped Ta<sub>2</sub>O<sub>5</sub> as an electron transport layer excels in achieving an efficiency and fill factor of 14.17% and 76% under artificial sun. This device was marked by the negligible hysteresis behavior showing profound photovoltaic performance. The electrochemical activity of the Ln<sup>3+</sup>-doped Ta<sub>2</sub>O<sub>5</sub> decorated electrode was evaluated for electrical charge storage potential with pseudocapacitive behavior. With the highest specific capacitance of 355.39 F/g and quicker ionic diffusion rate, the designed electrode excels conventionally used materials. Electro-catalysis of water with Ln<sup>3+</sup>-doped Ta<sub>2</sub>O<sub>5</sub> material indicates its capacity for H<sub>2</sub> production with the lowest overpotential and Tafel slope values of 148 and 121.2 mV/dec, while the O<sub>2</sub> generation is comparatively lower. With the stable electrochemical output, this rare earth modified material has the potential to replace conventionally used environmentally perilous and costly materials.</p></div>","PeriodicalId":16940,"journal":{"name":"Journal of Rare Earths","volume":"42 8","pages":"Pages 1586-1594"},"PeriodicalIF":5.2,"publicationDate":"2024-08-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"45257123","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Large reversible magnetocaloric effect in antiferromagnetic Er3Si2C2 compound 反铁磁性Er3Si2C2化合物的大可逆磁热效应
IF 5.2 1区 化学
Journal of Rare Earths Pub Date : 2024-08-01 DOI: 10.1016/j.jre.2023.07.024
{"title":"Large reversible magnetocaloric effect in antiferromagnetic Er3Si2C2 compound","authors":"","doi":"10.1016/j.jre.2023.07.024","DOIUrl":"10.1016/j.jre.2023.07.024","url":null,"abstract":"<div><p>The magnetic properties, magnetic phase transition and magnetocaloric effects (MCE) of Er<sub>3</sub>Si<sub>2</sub>C<sub>2</sub> compound were investigated based on theoretical calculations and experimental analysis. Based on the first principles calculations, the antiferromagnetic (AFM) ground state type in Er<sub>3</sub>Si<sub>2</sub>C<sub>2</sub> compound was predicted and its electronic structure was investigated. The experimental results show that Er<sub>3</sub>Si<sub>2</sub>C<sub>2</sub> compound is an AFM compound with the Néel temperature (<em>T</em><sub>N</sub>) of 7 K and undergoes a field-induced first-order magnetic phase transition from AFM to ferromagnetic (FM) under magnetic fields exceeding 0.6 T at 2 K. The magnetic transition process of Er<sub>3</sub>Si<sub>2</sub>C<sub>2</sub> compound was investigated and discussed. The values of the maximum magnetic entropy change (<span><math><mrow><msubsup><mrow><mo>−</mo><mo>Δ</mo><mi>S</mi></mrow><mi>M</mi><mi>max</mi></msubsup><mo>)</mo></mrow></math></span> and the refrigeration capacity (RC) are 17 J/(kg·K) and 193 J/kg under changing magnetic fields of 0–5 T, respectively. As a potential cryogenic magnetic refrigerant, the Er<sub>3</sub>Si<sub>2</sub>C<sub>2</sub> compound also provides an interesting research medium to study the magnetic phase transition process.</p></div>","PeriodicalId":16940,"journal":{"name":"Journal of Rare Earths","volume":"42 8","pages":"Pages 1555-1559"},"PeriodicalIF":5.2,"publicationDate":"2024-08-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"41718397","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Magnetic properties and magnetocaloric effects in Eu(Ti,Nb,Mn)O3 perovskites Eu(Ti,Nb,Mn)O3 包晶的磁性能和磁致效应
IF 5.2 1区 化学
Journal of Rare Earths Pub Date : 2024-08-01 DOI: 10.1016/j.jre.2023.06.015
{"title":"Magnetic properties and magnetocaloric effects in Eu(Ti,Nb,Mn)O3 perovskites","authors":"","doi":"10.1016/j.jre.2023.06.015","DOIUrl":"10.1016/j.jre.2023.06.015","url":null,"abstract":"<div><p>In perovskite EuTiO<sub>3</sub>, the magnetic characteristics and magnetocaloric effect (MCE) can be flexibly regulated by converting the magnetism from antiferromagnetic to ferromagnetic. In the present work, a series of Eu(Ti,Nb,Mn)O<sub>3</sub> compounds, abbreviated as ETNMO for convenience of description, was fabricated and their crystallography, magnetism together with cryogenic magnetocaloric effects were systematically investigated. The crystallographic results demonstrate the cubic perovskite structure for all the compounds, with the space group of <em>Pm</em>3<em>m</em>. Two magnetic phase transitions are observed in these second-order phase transition (SOPT) materials. The joint substitution of elements Mn and Nb can considerably manipulate the magnetic phase transition process and magnetocaloric performance of the ETNMO compounds. As the Mn content increases, gradually widened –Δ<em>S</em><sub>M</sub>-<em>T</em> curves are obtained, and two peaks with a broad shoulder are observed in the –Δ<em>S</em><sub>M</sub>-<em>T</em> curves for Δ<em>μ</em><sub>0</sub><em>H</em>≤0–1 T. Under a field change of 0–5 T, the values of maximum magnetic entropy change (−Δ<span><math><mrow><msubsup><mi>S</mi><mrow><mi>M</mi></mrow><mrow><mtext>max</mtext></mrow></msubsup></mrow></math></span>) and refrigeration capacity (RC) are evaluated to be 34.7 J/(kg·K) and 364.9 J/kg for EuTi<sub>0.8625</sub>Nb<sub>0.0625</sub>Mn<sub>0.075</sub>O<sub>3</sub>, 27.8 J/(kg·K) and 367.6 J/kg for EuTi<sub>0.8375</sub>Nb<sub>0.0625</sub>Mn<sub>0.1</sub>O<sub>3</sub>, 23.2 J/(kg·K) and 369.2 J/kg for EuTi<sub>0.8125</sub>Nb<sub>0.0625</sub>Mn<sub>0.125</sub>O<sub>3</sub>, 17.1 J/(kg·K) and 357.6 J/kg for EuTi<sub>0.7875</sub>Nb<sub>0.0625</sub>Mn<sub>0.15</sub>O<sub>3</sub>, respectively. The considerable MCE parameters make the ETNMO compounds potential candidates for cryogenic magnetic refrigeration.</p></div>","PeriodicalId":16940,"journal":{"name":"Journal of Rare Earths","volume":"42 8","pages":"Pages 1560-1567"},"PeriodicalIF":5.2,"publicationDate":"2024-08-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"135220150","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Cr3+ activated Na3RESi3O9 (RE = Y, Lu, Sc) silicate broadband near-infrared phosphors for luminescence towards NIR-II region via a multi-site occupancy strategy 通过多位点占据策略激活 Cr3+ 的 Na3RESi3O9(RE = Y、Lu、Sc)硅酸盐宽带近红外荧光粉,使其向近红外-II 区发光
IF 5.2 1区 化学
Journal of Rare Earths Pub Date : 2024-08-01 DOI: 10.1016/j.jre.2024.05.006
{"title":"Cr3+ activated Na3RESi3O9 (RE = Y, Lu, Sc) silicate broadband near-infrared phosphors for luminescence towards NIR-II region via a multi-site occupancy strategy","authors":"","doi":"10.1016/j.jre.2024.05.006","DOIUrl":"10.1016/j.jre.2024.05.006","url":null,"abstract":"<div><p>Phosphor-converted near-infrared light-emitting diodes (NIR pc-LEDs) are finding applications in various fields including food quality analysis, biomedical imaging, night vision, and biomedicine. The crucial factor in the development of NIR pc-LEDs devices lies in the advancement of high-performance broadband NIR phosphors. In this work, novel Cr<sup>3+</sup>-activated silicate phosphors NaRESi<sub>3</sub>O<sub>9</sub> (RE = Y, Lu, Sc) are reported. This silicate has a special 3D network structure in which RE has four different sites, forming four octahedrons and providing suitable occupation sites for Cr<sup>3+</sup>. The phosphors demonstrate a wide emission spectrum ranging from 750 to 1450 nm when excited by light at 468 nm. The full width at half maximum (FWHM), which benefits from the presence of Cr<sup>3+</sup> ions occupying multiple sites, is measured to be 203 nm. Notably, the strongest emission peak is observed at a longer wavelength of 984 nm compared to most other systems activated by Cr<sup>3+</sup>. The Na<sub>3</sub>ScSi<sub>3</sub>O<sub>9</sub> lattice provides a weak crystal field (<em>Dq</em>/<em>B</em> = 1.97) and weak phonon-photon coupling for Cr<sup>3+</sup>, and the integrated emission intensity of Na<sub>3</sub>ScSi<sub>3</sub>O<sub>9</sub>:0.03Cr<sup>3+</sup> is 4.66 times stronger than that of Na<sub>3</sub>YSi<sub>3</sub>O<sub>9</sub>:0.03Cr<sup>3+</sup>.</p></div>","PeriodicalId":16940,"journal":{"name":"Journal of Rare Earths","volume":"42 8","pages":"Pages 1447-1457"},"PeriodicalIF":5.2,"publicationDate":"2024-08-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141144035","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Advanced rare earth tantalate RETaO4 (RE=Dy, Gd and Sm) with excellent oxygen/thermal barrier performance 先进的稀土钽酸盐 RETaO4(RE=镝、钆和钐)具有优异的氧气/热障性能
IF 5.2 1区 化学
Journal of Rare Earths Pub Date : 2024-08-01 DOI: 10.1016/j.jre.2024.05.012
{"title":"Advanced rare earth tantalate RETaO4 (RE=Dy, Gd and Sm) with excellent oxygen/thermal barrier performance","authors":"","doi":"10.1016/j.jre.2024.05.012","DOIUrl":"10.1016/j.jre.2024.05.012","url":null,"abstract":"<div><p>Thermal barrier coatings (TBCs) materials with lowered thermal and oxygen ion conductivity can provide thermal and oxidative protection for high temperature hot-end components in aeronautical engines and gas turbines. The rare-earth tantalate RETaO<sub>4</sub> (RE = Dy, Gd and Sm) ceramics with monoclinic (m) phase were successfully synthesized via spark plasma sintering. Oxygen vacancies responsible for the thermal and oxygen ion conductivities of RETaO<sub>4</sub> were demonstrated by atomic-resolution energy dispersive X-ray and X-ray photoelectron spectroscopy. Among the three samples, DyTaO<sub>4</sub> has excellent oxygen/thermal barrier performance. Compared to the current service thermal barrier coating material ZrO<sub>2</sub>-8 wt% Y<sub>2</sub>O<sub>3</sub> (8 YSZ), DyTaO<sub>4</sub> has an ultra-low oxygen ion conductivity benefiting from low oxygen vacancy concentration and strong stretching force constants. The intrinsic thermal conductivity of DyTaO<sub>4</sub> is 68.2% less than that of 8 YSZ. Additionally, the thermal expansion rate curves indicate that the phase transformation does not happen from room temperature to 1200 °C. The above results demonstrate that high-growth rate thermally grown oxide can be retarded by creating dense DyTaO<sub>4</sub> coating with lowered thermal and oxygen ion conductivity.</p></div>","PeriodicalId":16940,"journal":{"name":"Journal of Rare Earths","volume":"42 8","pages":"Pages 1595-1603"},"PeriodicalIF":5.2,"publicationDate":"2024-08-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141406772","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Enhanced saturation magnetization in La3+ doped NiCo ferrites prepared by sol–gel auto-combustion method 溶胶-凝胶自燃烧法制备的La3+掺杂NiCo铁氧体的饱和磁化强度增强
IF 5.2 1区 化学
Journal of Rare Earths Pub Date : 2024-08-01 DOI: 10.1016/j.jre.2023.08.011
{"title":"Enhanced saturation magnetization in La3+ doped NiCo ferrites prepared by sol–gel auto-combustion method","authors":"","doi":"10.1016/j.jre.2023.08.011","DOIUrl":"10.1016/j.jre.2023.08.011","url":null,"abstract":"<div><p>Lanthanum doped nickel–cobalt nano ferrites with chemical formula Ni<sub>0.5</sub>Co<sub>0.5</sub>La<sub><em>x</em></sub>Fe<sub>2–<em>x</em></sub>O<sub>4</sub> (<em>x</em> = 0.05, 0.10, 0.15 and 0.20) were prepared using a simple sol–gel auto combustion method. The basic structural properties were determined by X-ray diffraction method and the formation of single phased spinel ferrite was confirmed. The crystalline size decreased from 25 to 11 nm and lattice parameter <em>a</em> increases with increase of La doping. The surface morphology of these ferrites was observed by field-emission scanning electron microscopy (FESEM) and agglomerated irregular grains are observed with increase of the rare earth element La doping. Energy-dispersive X-ray spectroscopy (EDX) result confirms the presence of the required elements. The Fourier transform infrared spectroscopy (FTIR) spectrum indicates the formation of the spinel ferrite structure with M−O bonds. Optical direct band measurements from ultraviolet–visible spectroscopy (UV-Vis) spectroscopy indicate that the direct band gap decreases from 1.39 to 1.19 eV for <em>x</em> = 0.05 to <em>x</em> = 0.15, then increases to 1.28 eV for <em>x</em> = 0.20. The room temperature magnetic properties of these ferrites were studied by a vibrating sample magnetometer (VSM). The enhanced saturation magnetization of 49.73 emu/g is observed for <em>x</em> = 0.10 and then saturation magnetizations are gradually decreased for <em>x</em> = 0.15 and <em>x</em> = 0.20. Interestingly the remanent magnetization and coercivity also follow the same trend.</p></div>","PeriodicalId":16940,"journal":{"name":"Journal of Rare Earths","volume":"42 8","pages":"Pages 1546-1554"},"PeriodicalIF":5.2,"publicationDate":"2024-08-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"47187716","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
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