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Far IR spectra of dithiocarbamate complexes correlations with structure parameters 二硫代氨基甲酸酯配合物的远红外光谱与结构参数的相关性
Journal of Inorganic and Nuclear Chemistry Pub Date : 1981-01-01 DOI: 10.1016/0022-1902(81)80014-0
R. Kellner, G. Nikolov
{"title":"Far IR spectra of dithiocarbamate complexes correlations with structure parameters","authors":"R. Kellner, G. Nikolov","doi":"10.1016/0022-1902(81)80014-0","DOIUrl":"https://doi.org/10.1016/0022-1902(81)80014-0","url":null,"abstract":"","PeriodicalId":16275,"journal":{"name":"Journal of Inorganic and Nuclear Chemistry","volume":"7 1","pages":"1183-1188"},"PeriodicalIF":0.0,"publicationDate":"1981-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"86984420","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 25
Electronic spectra of Ni(II) in some potassium haloborate glasses 某些卤代酸钾玻璃中Ni(II)的电子光谱
Journal of Inorganic and Nuclear Chemistry Pub Date : 1981-01-01 DOI: 10.1016/0022-1902(81)80204-7
P. Askalani, S. Sidhom
{"title":"Electronic spectra of Ni(II) in some potassium haloborate glasses","authors":"P. Askalani, S. Sidhom","doi":"10.1016/0022-1902(81)80204-7","DOIUrl":"https://doi.org/10.1016/0022-1902(81)80204-7","url":null,"abstract":"","PeriodicalId":16275,"journal":{"name":"Journal of Inorganic and Nuclear Chemistry","volume":"24 1","pages":"689-694"},"PeriodicalIF":0.0,"publicationDate":"1981-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"90792806","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 7
Study of the complexes of Mo(VI) with malic acid 钼(VI)与苹果酸配合物的研究
Journal of Inorganic and Nuclear Chemistry Pub Date : 1981-01-01 DOI: 10.1016/0022-1902(81)80039-5
A. Beltrán, A. Avalos, J. Beltrán
{"title":"Study of the complexes of Mo(VI) with malic acid","authors":"A. Beltrán, A. Avalos, J. Beltrán","doi":"10.1016/0022-1902(81)80039-5","DOIUrl":"https://doi.org/10.1016/0022-1902(81)80039-5","url":null,"abstract":"","PeriodicalId":16275,"journal":{"name":"Journal of Inorganic and Nuclear Chemistry","volume":"7 1","pages":"1337-1341"},"PeriodicalIF":0.0,"publicationDate":"1981-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"91027710","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 17
Mössbauer measurements on iron phthalocyanines Mössbauer酞菁铁的测量
Journal of Inorganic and Nuclear Chemistry Pub Date : 1981-01-01 Epub Date: 2003-05-20 DOI: 10.1016/0022-1902(81)80251-5
J. Blomquist, L.C. Moberg, L.Y. Johansson, R. Larsson
{"title":"Mössbauer measurements on iron phthalocyanines","authors":"J. Blomquist,&nbsp;L.C. Moberg,&nbsp;L.Y. Johansson,&nbsp;R. Larsson","doi":"10.1016/0022-1902(81)80251-5","DOIUrl":"10.1016/0022-1902(81)80251-5","url":null,"abstract":"<div><p>Monomeric and polymeric iron phthalocyanines (FePc) with and without carbon support and subjected to various heat treatments have been studied by Mössbauer spectroscopy. Dispersing FePc on carbon changes the electronic state of the monomer to low spin (S = 0) while the electronic state of the polymer remains unchanged (S = 1). It is suggested that the bonding between polymeric FePc and carbon takes place through the side groups present on the peripheral parts of the polymer and/or through suitable chemical groups present on the carbon surface. The electron-attracting ability of the side-groups deduced from the Mössbauer spectra is discussed. The results will form a basis for a comparison with data from electrochemical measurements.</p></div>","PeriodicalId":16275,"journal":{"name":"Journal of Inorganic and Nuclear Chemistry","volume":"43 10","pages":"Pages 2287-2292"},"PeriodicalIF":0.0,"publicationDate":"1981-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/0022-1902(81)80251-5","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"81472600","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 19
Preparation of new ligands o-(4,5-dimethyl-2-thiazolylazo)phenols and their metal complexes 新型配体o-(4,5-二甲基-2-噻唑偶氮)酚及其金属配合物的制备
Journal of Inorganic and Nuclear Chemistry Pub Date : 1981-01-01 Epub Date: 2003-05-20 DOI: 10.1016/0022-1902(81)80668-9
Fumiaki Kai, Hidenori Takeshita, Seiya Sukimoto, Katsumi Tamaoku
{"title":"Preparation of new ligands o-(4,5-dimethyl-2-thiazolylazo)phenols and their metal complexes","authors":"Fumiaki Kai,&nbsp;Hidenori Takeshita,&nbsp;Seiya Sukimoto,&nbsp;Katsumi Tamaoku","doi":"10.1016/0022-1902(81)80668-9","DOIUrl":"10.1016/0022-1902(81)80668-9","url":null,"abstract":"","PeriodicalId":16275,"journal":{"name":"Journal of Inorganic and Nuclear Chemistry","volume":"43 11","pages":"Pages 3013-3015"},"PeriodicalIF":0.0,"publicationDate":"1981-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/0022-1902(81)80668-9","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"82174130","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 2
Indium and thalium fluorosulphates
Journal of Inorganic and Nuclear Chemistry Pub Date : 1981-01-01 Epub Date: 2003-05-20 DOI: 10.1016/0022-1902(81)80409-5
R.C. Paul, R.D. Sharma, Sukhjinder Singh, R.D. Verma
{"title":"Indium and thalium fluorosulphates","authors":"R.C. Paul,&nbsp;R.D. Sharma,&nbsp;Sukhjinder Singh,&nbsp;R.D. Verma","doi":"10.1016/0022-1902(81)80409-5","DOIUrl":"10.1016/0022-1902(81)80409-5","url":null,"abstract":"","PeriodicalId":16275,"journal":{"name":"Journal of Inorganic and Nuclear Chemistry","volume":"43 8","pages":"Pages 1919-1920"},"PeriodicalIF":0.0,"publicationDate":"1981-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/0022-1902(81)80409-5","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"86197577","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 3
Stability and C.D. spectra of Co2+ and Cu2+ complexes with epimeric threonines and isoleucines 外链苏氨酸和异亮氨酸的Co2+和Cu2+配合物的稳定性和cd光谱
Journal of Inorganic and Nuclear Chemistry Pub Date : 1981-01-01 Epub Date: 2003-05-20 DOI: 10.1016/0022-1902(81)80311-9
N. Ivičić, Vl. Simeon
{"title":"Stability and C.D. spectra of Co2+ and Cu2+ complexes with epimeric threonines and isoleucines","authors":"N. Ivičić,&nbsp;Vl. Simeon","doi":"10.1016/0022-1902(81)80311-9","DOIUrl":"10.1016/0022-1902(81)80311-9","url":null,"abstract":"<div><p>Acid dissociation constants of epimeric threonines (Thr, <em>allo</em>-Thr) and isoleucines (Ile, <em>allo</em>-Ile) and the stability constants of their complexes with Co<sup>2+</sup> and Cu<sup>2+</sup> were determined by potentiometry. The natural epimers form more stable complexes than the <em>allo</em> forms. C.d. spectra of the complexes investigated were recorded, resolved into component bands and assigned.</p></div>","PeriodicalId":16275,"journal":{"name":"Journal of Inorganic and Nuclear Chemistry","volume":"43 10","pages":"Pages 2581-2584"},"PeriodicalIF":0.0,"publicationDate":"1981-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/0022-1902(81)80311-9","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"86199134","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 9
The chemical state of 82Br, 81mSe and 76As recoil atoms in KBrO3 crystals KBrO3晶体中82Br、81mSe和76As反冲原子的化学状态
Journal of Inorganic and Nuclear Chemistry Pub Date : 1981-01-01 Epub Date: 2003-05-20 DOI: 10.1016/0022-1902(81)80059-0
M.T.A. Teeling , A.H.W. Aten Jr. , J. Boersma, P.W.F. Louwrier, D.J. Apers
{"title":"The chemical state of 82Br, 81mSe and 76As recoil atoms in KBrO3 crystals","authors":"M.T.A. Teeling ,&nbsp;A.H.W. Aten Jr. ,&nbsp;J. Boersma,&nbsp;P.W.F. Louwrier,&nbsp;D.J. Apers","doi":"10.1016/0022-1902(81)80059-0","DOIUrl":"10.1016/0022-1902(81)80059-0","url":null,"abstract":"<div><p>The retention of <sup>82</sup>BrO<sub>3</sub><sup>−</sup> in KBrO<sub>3</sub> activated with fast nuetrons is about 18% at ambient temperature. Annealing at 523 K gives an increase to 50%. Simultaneously produced <sup>81m</sup>Se appears in about 90% as SeO<sub>4</sub><sup>2−</sup> at room temperature, which percentage increases to near 100% after annealing. The <sup>76</sup>As recoil atoms appear 100% as AsO<sub>4</sub><sup>3−</sup>. A description is proposed, based on processes with different spectra of energies of activation. A model is given for these processes, based on the hypothesis that the recoil atom stabilizes in the host lattice in a form which is compatible with, and may be imposed by the crystal structure of the host lattice.</p></div>","PeriodicalId":16275,"journal":{"name":"Journal of Inorganic and Nuclear Chemistry","volume":"43 12","pages":"Pages 3043-3046"},"PeriodicalIF":0.0,"publicationDate":"1981-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/0022-1902(81)80059-0","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"77867969","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 2
Chemistry of substituted sulphuric acids—XIII. Acidity function (H0) measurements in methanesulphuric acid 取代硫酸的化学- xiii。甲烷硫酸酸度函数(H0)的测定
Journal of Inorganic and Nuclear Chemistry Pub Date : 1981-01-01 Epub Date: 2003-05-20 DOI: 10.1016/0022-1902(81)80455-1
R.C. Paul, V.P. Kapila, Raj Kumar, S.K. Sharma
{"title":"Chemistry of substituted sulphuric acids—XIII. Acidity function (H0) measurements in methanesulphuric acid","authors":"R.C. Paul,&nbsp;V.P. Kapila,&nbsp;Raj Kumar,&nbsp;S.K. Sharma","doi":"10.1016/0022-1902(81)80455-1","DOIUrl":"10.1016/0022-1902(81)80455-1","url":null,"abstract":"","PeriodicalId":16275,"journal":{"name":"Journal of Inorganic and Nuclear Chemistry","volume":"43 1","pages":"Page 171"},"PeriodicalIF":0.0,"publicationDate":"1981-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/0022-1902(81)80455-1","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"81933791","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 4
A NMR spectroscopic study of some monothio-β-diketonate chelates and the corresponding β-diketones with a perfluoroethyl substituent 一些含全氟乙基取代基的单硫代β-二酮酸螯合物及相应的β-二酮的核磁共振光谱研究
Journal of Inorganic and Nuclear Chemistry Pub Date : 1981-01-01 Epub Date: 2003-05-20 DOI: 10.1016/0022-1902(81)80257-6
Manoranjan Das, Daniel T. Haworth
{"title":"A NMR spectroscopic study of some monothio-β-diketonate chelates and the corresponding β-diketones with a perfluoroethyl substituent","authors":"Manoranjan Das,&nbsp;Daniel T. Haworth","doi":"10.1016/0022-1902(81)80257-6","DOIUrl":"10.1016/0022-1902(81)80257-6","url":null,"abstract":"<div><p>The <sup>13</sup>C and <sup>19</sup>F NMR of nine metal complexes contained perfluoroethylmonothio-β-diketonate ligands are recorded in chloroform-<em>d</em>. The complexes are of the type M[RC(S)CHC(O)C<sub>2</sub>F<sub>5</sub>]<sub>n</sub> where M is of nickel, palladium or cobalt; <em>n</em> is 2 or 3 and R is 2′-thienyl, phenyl or 2′-naphthyl. The <sup>13</sup>C-NMR data support a <em>fac</em>-octahedral geometry for the cobalt complex (<em>n</em>=3). The <sup>19</sup>F NMR show the chemical shift of the difluoromethylene group to be metal dependent. Correlations between the chemical shifts of the respective carbon resonances are also presented and NMR data for the three corresponding β-diketones, RC(OH) = CHC(O)C<sub>2</sub>F<sub>5</sub>, are described.</p></div>","PeriodicalId":16275,"journal":{"name":"Journal of Inorganic and Nuclear Chemistry","volume":"43 10","pages":"Pages 2317-2319"},"PeriodicalIF":0.0,"publicationDate":"1981-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/0022-1902(81)80257-6","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"73624668","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 8
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