{"title":"A new example of 5T2−1A1 spin crossover complex, dithiocyanato-tris(n-phenyl-2-pyridinalimine)iron(II)","authors":"Ho-Hsiang Wei, Ching-Sung Hsiao","doi":"10.1016/0022-1902(81)80253-9","DOIUrl":null,"url":null,"abstract":"<div><p>The preparation of the complex Fe(ppi)<sub>3</sub>(NCS)<sub>2</sub> (where ppi = N-phenyl-2-pyridinaldimine) is described. Mössbauer and magnetic susceptibility of this compound was studied in the temperature range between 298 and 78 K and clearly indicate a temperature induced <span><math><mtext>high-spin</mtext><mtext>(</mtext><msup><mi></mi><mn>5</mn></msup><mtext>T</mtext><msub><mi></mi><mn>2</mn></msub><mtext>)-</mtext><mtext>low-spin</mtext><mtext>(</mtext><msup><mi></mi><mn>1</mn></msup><mtext>A</mtext><msub><mi></mi><mn>1</mn></msub><mtext>)</mtext></math></span> transition.</p></div>","PeriodicalId":16275,"journal":{"name":"Journal of Inorganic and Nuclear Chemistry","volume":"43 10","pages":"Pages 2299-2300"},"PeriodicalIF":0.0000,"publicationDate":"1981-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/0022-1902(81)80253-9","citationCount":"8","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Inorganic and Nuclear Chemistry","FirstCategoryId":"1085","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/0022190281802539","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
引用次数: 8
Abstract
The preparation of the complex Fe(ppi)3(NCS)2 (where ppi = N-phenyl-2-pyridinaldimine) is described. Mössbauer and magnetic susceptibility of this compound was studied in the temperature range between 298 and 78 K and clearly indicate a temperature induced transition.
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