Journal of Inorganic and Nuclear Chemistry最新文献

{"title":"Formation and thermodynamic properties of mixed complexes of Cd(II) with SCN2H4 and C−, Br−, I− as ligands","authors":"Domenico De Marco,&nbsp;Athos Bellomo,&nbsp;Alessandro De Robertis","doi":"10.1016/0022-1902(81)80450-2","DOIUrl":"10.1016/0022-1902(81)80450-2","url":null,"abstract":"<div><p>Thermodynamic parameters for in-water-formation of mononuclear complexes of cadmium-halide-thiourea systems, calculated by means of potentiometric measurements at different temperatures and at μ = 1 for KNO₃, are reported.</p></div>","PeriodicalId":16275,"journal":{"name":"Journal of Inorganic and Nuclear Chemistry","volume":"43 1","pages":"Pages 137-141"},"PeriodicalIF":0.0,"publicationDate":"1981-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/0022-1902(81)80450-2","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"87584656","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Hydrothermal stability of β-Cs2U2O7 and SrZrO3 in fluids","authors":"Sridhar Komarneni","doi":"10.1016/0022-1902(81)80626-4","DOIUrl":"10.1016/0022-1902(81)80626-4","url":null,"abstract":"<div><p>The stability of β-Cs₂U₂O₇ and SrZrO₃, two possible phases of spent fuel elements, in hydrothermal fluids was investigated. β-Cs₂U₂O₇ was unstable under hydrothermal conditions of 100, 200 and 300°C/300 bars releasing substantial amounts of its Cs in deionized water and all of its Cs in a bittern (high-Mg and-Ca) brine. SrZrO₃ was found to be quite stable in deionized water but not in a bittern brine. For example, Sr released into solution decreased from 3.9 to 2.8% with an increase in temperature from 100 to 300°C probably because of better crystallization of SrZrO₃ at higher temperatures. In bittern brine, 23.3, 94.9 and 100% of Sr was released into solution at 100, 200 and 300°C respectively as a result of acidic conditions generated by the hydrolysis of MgCl₂ and formation of brucite. These results suggest that bittern brine which may be encountered in a salt repository is highly corrosive and may release all the Cs and Sr into solution under hydrothermal conditions if the containment were breached. The use of tailor-made overpacks or backfill barriers of highly stable and sorptive materials is essential especially in a salt repository in order to minimize the threat of highly hazardous Cs and Sr radionuclides finding their way into ground waters.</p></div>","PeriodicalId":16275,"journal":{"name":"Journal of Inorganic and Nuclear Chemistry","volume":"43 11","pages":"Pages 2833-2837"},"PeriodicalIF":0.0,"publicationDate":"1981-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/0022-1902(81)80626-4","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"87961947","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"On the nature of the products of the reaction between Cr(III) and alanine","authors":"Ron Trujillo,&nbsp;Albert Baca,&nbsp;Carolyn Castillo,&nbsp;William F. Coleman","doi":"10.1016/0022-1902(81)80527-1","DOIUrl":"10.1016/0022-1902(81)80527-1","url":null,"abstract":"","PeriodicalId":16275,"journal":{"name":"Journal of Inorganic and Nuclear Chemistry","volume":"43 3","pages":"Pages 631-633"},"PeriodicalIF":0.0,"publicationDate":"1981-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/0022-1902(81)80527-1","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"88103178","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Schiff base complexes of organotin(iv): Synthesis, IR and Mössbauer spectral studies of addition complexes of diorganotin dichlorides with N-(hydroxyalkyl) salicylideneimines","authors":"B.S. Saraswat ,&nbsp;G. Srivastava,&nbsp;R.C. Mehrotra","doi":"10.1016/0022-1902(81)80664-1","DOIUrl":"10.1016/0022-1902(81)80664-1","url":null,"abstract":"","PeriodicalId":16275,"journal":{"name":"Journal of Inorganic and Nuclear Chemistry","volume":"43 11","pages":"Pages 3003-3007"},"PeriodicalIF":0.0,"publicationDate":"1981-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/0022-1902(81)80664-1","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"88202751","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Chloro complexes of cobalt(II) in acetone","authors":"Kiyoshi Sawada,&nbsp;Tsukio Onoda,&nbsp;Toshio Suzuki","doi":"10.1016/0022-1902(81)80099-1","DOIUrl":"10.1016/0022-1902(81)80099-1","url":null,"abstract":"<div><p>Equilibria of cobalt(II) perchlorate with lithium chloride in 0.1 M LiClO₄ acetone solution have been investigated by means of potentiometry and spectrophotometry at 25.0°C. By the addition of a large excess of medium salt (LiClO₄), the ionic dissociation of electrolytes are surpressed and the ion-pairs predominate in this medium. It was confirmed that AgAgCl electrode gives rise to the Nernstian response in this medium. The potentiometry reveals the formation of following chloro complexes of cobalt (II): <span><span><span><math><mtext>Co(ClO</mtext><msub><mi></mi><mn>4</mn></msub><mtext>)</mtext><msub><mi></mi><mn>2</mn></msub><mtext>+LiCl</mtext><mtext>⇌</mtext><mtext>K</mtext><msub><mi></mi><mn>1</mn></msub><mtext>CoCl(ClO</mtext><msub><mi></mi><mn>4</mn></msub><mtext>)+LiClO</mtext><msub><mi></mi><mn>4</mn></msub></math></span></span></span><span><span><span><math><mtext>Co(ClO</mtext><msub><mi></mi><mn>4</mn></msub><mtext>)+LiCl</mtext><mtext>⇌</mtext><mtext>K</mtext><msub><mi></mi><mn>2</mn></msub><mtext>CoCl</mtext><msub><mi></mi><mn>2</mn></msub><mtext>+LiClO</mtext><msub><mi></mi><mn>4</mn></msub></math></span></span></span><span><span><span><math><mtext>CoCl</mtext><msub><mi></mi><mn>2</mn></msub><mtext>+LiCl</mtext><mtext>⇌</mtext><mtext>K</mtext><msub><mi></mi><mn>3</mn></msub><mtext>LiCoCl</mtext><msub><mi></mi><mn>3</mn></msub></math></span></span></span></p><p>Successive formation constants were determined as log K₁ = 5.0 ± 0.3, log K₂ = 6.2 ± 0.3 (log <em>β</em>₂ = log K₁K₂ = 11.15 ± 0.03) and log K₃ = 5.97 ± 0.03. By the spectrophotometric titration at higher concentration of lithium chloride, we have the following equilibrium: <span><span><span><math><mtext>LiCoCl</mtext><msub><mi></mi><mn>3</mn></msub><mtext>+LiCl</mtext><mtext>⇌</mtext><mtext>K</mtext><msub><mi></mi><mn>4</mn></msub><mtext>LiCoCl</mtext><msub><mi></mi><mn>3</mn></msub></math></span></span></span> with formation constant of log K₄ = 2.64 ± 0.05. Absorption spectra of these complexes are presented.</p></div>","PeriodicalId":16275,"journal":{"name":"Journal of Inorganic and Nuclear Chemistry","volume":"43 12","pages":"Pages 3263-3268"},"PeriodicalIF":0.0,"publicationDate":"1981-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/0022-1902(81)80099-1","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"88204953","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Indium and thalium fluorosulphates","authors":"R.C. Paul,&nbsp;R.D. Sharma,&nbsp;Sukhjinder Singh,&nbsp;R.D. Verma","doi":"10.1016/0022-1902(81)80409-5","DOIUrl":"10.1016/0022-1902(81)80409-5","url":null,"abstract":"","PeriodicalId":16275,"journal":{"name":"Journal of Inorganic and Nuclear Chemistry","volume":"43 8","pages":"Pages 1919-1920"},"PeriodicalIF":0.0,"publicationDate":"1981-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/0022-1902(81)80409-5","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"86197577","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Stability and C.D. spectra of Co2+ and Cu2+ complexes with epimeric threonines and isoleucines","authors":"N. Ivičić,&nbsp;Vl. Simeon","doi":"10.1016/0022-1902(81)80311-9","DOIUrl":"10.1016/0022-1902(81)80311-9","url":null,"abstract":"<div><p>Acid dissociation constants of epimeric threonines (Thr, <em>allo</em>-Thr) and isoleucines (Ile, <em>allo</em>-Ile) and the stability constants of their complexes with Co²⁺ and Cu²⁺ were determined by potentiometry. The natural epimers form more stable complexes than the <em>allo</em> forms. C.d. spectra of the complexes investigated were recorded, resolved into component bands and assigned.</p></div>","PeriodicalId":16275,"journal":{"name":"Journal of Inorganic and Nuclear Chemistry","volume":"43 10","pages":"Pages 2581-2584"},"PeriodicalIF":0.0,"publicationDate":"1981-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/0022-1902(81)80311-9","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"86199134","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Differential scanning calorimetric and Raman spectroscopic study of polymorphism in Na2SO4","authors":"C.A. Cody,&nbsp;L. Dicarlo,&nbsp;R.K. Darlington","doi":"10.1016/0022-1902(81)90031-2","DOIUrl":"10.1016/0022-1902(81)90031-2","url":null,"abstract":"","PeriodicalId":16275,"journal":{"name":"Journal of Inorganic and Nuclear Chemistry","volume":"43 2","pages":"Pages 398-400"},"PeriodicalIF":0.0,"publicationDate":"1981-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/0022-1902(81)90031-2","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"83659847","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Simple organomercurial amine complex formation","authors":"C.R. Bennett","doi":"10.1016/0022-1902(81)80301-6","DOIUrl":"10.1016/0022-1902(81)80301-6","url":null,"abstract":"","PeriodicalId":16275,"journal":{"name":"Journal of Inorganic and Nuclear Chemistry","volume":"43 10","pages":"Pages 2555-2556"},"PeriodicalIF":0.0,"publicationDate":"1981-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/0022-1902(81)80301-6","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"82713297","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Electronic absorption spectra of Fe(III) in some phosphate glasses","authors":"Anwar A. Kinawi","doi":"10.1016/0022-1902(81)80535-0","DOIUrl":"10.1016/0022-1902(81)80535-0","url":null,"abstract":"<div><p>Electronic absorption spectra of Fe(III) in some phosphate glasses have been measured at room and near liquid-nitrogen temperatures, in the energy range 11,500–30,000 cm⁻¹. Assuming cubic-field microsymmetry, and taking no account of spin-orbit coupling, it was found that the energies of the five observed bands are accounted for satisfactorily in terms of single values of B, C and Δ using the free-atom representation of the crystal-field theory, provided that a Trees' correction is included. It was found that the simple strong-field representation gives less satisfactory results. The Racah parameters, B and C, were evaluated for Fe(III) in two different phosphate media without a pre-assigned value of the fraction C/B and an empirical value of C/B = 3.60 was determined and applied to other data in the literature.</p></div>","PeriodicalId":16275,"journal":{"name":"Journal of Inorganic and Nuclear Chemistry","volume":"43 9","pages":"Pages 1989-1995"},"PeriodicalIF":0.0,"publicationDate":"1981-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/0022-1902(81)80535-0","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"86737144","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}