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Ligand exchange reactions between copper(II)- and nickel(II)-chelates of different sulfur- and selenium-containing ligands 不同含硫和含硒配体的铜(II)-和镍(II)-螯合物之间的配体交换反应
Journal of Inorganic and Nuclear Chemistry Pub Date : 1984-01-01 DOI: 10.1016/0022-1902(77)80302-3
W. Dietzsch, J. Reinhold, R. Kirmse, E. Hoyer, I. Marov, V. K. Belyaeva
{"title":"Ligand exchange reactions between copper(II)- and nickel(II)-chelates of different sulfur- and selenium-containing ligands","authors":"W. Dietzsch, J. Reinhold, R. Kirmse, E. Hoyer, I. Marov, V. K. Belyaeva","doi":"10.1016/0022-1902(77)80302-3","DOIUrl":"https://doi.org/10.1016/0022-1902(77)80302-3","url":null,"abstract":"","PeriodicalId":16275,"journal":{"name":"Journal of Inorganic and Nuclear Chemistry","volume":"21 1","pages":"1377-1384"},"PeriodicalIF":0.0,"publicationDate":"1984-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"77623684","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 40
Polarographic studies on mixed ligand systems involving amino acids—I. Ternary system cadmium-oxalate glycinate 氨基酸- i混合配体体系的极谱研究。三元体系草酸镉甘氨酸
Journal of Inorganic and Nuclear Chemistry Pub Date : 1981-01-01 DOI: 10.1016/0022-1902(81)80511-8
A. Aggarwal, H. Arora, K. Pandeya, R. Singh
{"title":"Polarographic studies on mixed ligand systems involving amino acids—I. Ternary system cadmium-oxalate glycinate","authors":"A. Aggarwal, H. Arora, K. Pandeya, R. Singh","doi":"10.1016/0022-1902(81)80511-8","DOIUrl":"https://doi.org/10.1016/0022-1902(81)80511-8","url":null,"abstract":"","PeriodicalId":16275,"journal":{"name":"Journal of Inorganic and Nuclear Chemistry","volume":"22 1","pages":"601-603"},"PeriodicalIF":0.0,"publicationDate":"1981-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"73433391","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 8
Electron impact ionisation energies of some halo-cyclotriphosphazenes 某些环三磷杂烯的电子冲击电离能
Journal of Inorganic and Nuclear Chemistry Pub Date : 1981-01-01 Epub Date: 2003-05-20 DOI: 10.1016/0022-1902(81)80486-1
Philip Clare, D. Bryan Sowerby
{"title":"Electron impact ionisation energies of some halo-cyclotriphosphazenes","authors":"Philip Clare,&nbsp;D. Bryan Sowerby","doi":"10.1016/0022-1902(81)80486-1","DOIUrl":"10.1016/0022-1902(81)80486-1","url":null,"abstract":"<div><p>Ionisation energies have been determined for N<sub>3</sub>P<sub>3</sub>F<sub><em>n</em></sub>X<sub>6−<em>n</em></sub> where <em>n</em> = 2, 3 and 4 and X = Br, Cl or NMe<sub>2</sub>, using an electron impact ion source and the semi-logarithmic plot method. Results are compared with values for N<sub>3</sub>P<sub>3</sub>X<sub>6</sub> where X = Br, Cl, F or NMe<sub>2</sub>. The substitution of dimethylamino groups for fluorines in N<sub>3</sub>P<sub>3</sub>F<sub>6</sub> causes a marked decrease in ionisation energy. A similar though less pronounced decrease occurs on substitution of fluorine by bromine or chlorine. The appearance energies were determined for several fragment ions.</p></div>","PeriodicalId":16275,"journal":{"name":"Journal of Inorganic and Nuclear Chemistry","volume":"43 3","pages":"Pages 477-480"},"PeriodicalIF":0.0,"publicationDate":"1981-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/0022-1902(81)80486-1","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"72905232","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 4
Seven-coordinate mixed-ligand tungsten(II) chelates containing carbonyls, triphenylphosphine, and 8-quinolinolato, picolinato or a quadridentate schiff-base 七配位混合配体钨(II)螯合物，含有羰基，三苯基膦，和8-喹啉啉，吡啶啉或四齿席夫碱
Journal of Inorganic and Nuclear Chemistry Pub Date : 1981-01-01 Epub Date: 2003-05-20 DOI: 10.1016/0022-1902(81)80263-1
William H. Batschelet, Ronald D. Archer
{"title":"Seven-coordinate mixed-ligand tungsten(II) chelates containing carbonyls, triphenylphosphine, and 8-quinolinolato, picolinato or a quadridentate schiff-base","authors":"William H. Batschelet,&nbsp;Ronald D. Archer","doi":"10.1016/0022-1902(81)80263-1","DOIUrl":"10.1016/0022-1902(81)80263-1","url":null,"abstract":"<div><p>The complexes W(CO)<sub>2</sub>(PPh<sub>3</sub>)(q)<sub>2</sub>, W(CO)<sub>2</sub>(PPh<sub>3</sub>)(pic)<sub>2</sub> and W(CO)<sub>2</sub>(PPh<sub>3</sub>)(dsp) (where Ph = C<sub>6</sub>H<sub>5</sub>, q<sup>−</sup> = 8-quinolinolato, pic<sup>−</sup> = picolinato, and dsp<sup>2−</sup> = the anion of the Schiff-base N,N′-disalicylidene-1,2-phenylene-diamine) have been synthesized. The physical properties of these complexes are indicative of seven-coordinate mixed-ligand tungsten(II) chelates. W(CO)<sub>2</sub>(PPh<sub>3</sub>)(pic)<sub>2</sub> is the most photochemically reactive and W(CO)<sub>2</sub>(PPh<sub>3</sub>)(q)<sub>2</sub> is the most thermally reactive. Evidence that the steric effects of the quadriadentate dsp<sup>2−</sup> ligand cause a change in the overall seven-coordinate sterochemistry is presented.</p></div>","PeriodicalId":16275,"journal":{"name":"Journal of Inorganic and Nuclear Chemistry","volume":"43 10","pages":"Pages 2349-2353"},"PeriodicalIF":0.0,"publicationDate":"1981-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/0022-1902(81)80263-1","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"75255694","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 48
2-isopropylaminopyridine N-oxide complexes formed from copper(II) salts 由铜(II)盐形成的2-异丙氨基吡啶n -氧化物配合物
Journal of Inorganic and Nuclear Chemistry Pub Date : 1981-01-01 Epub Date: 2003-05-20 DOI: 10.1016/0022-1902(81)80255-2
Douglas X. West, James B. Sedgwick
{"title":"2-isopropylaminopyridine N-oxide complexes formed from copper(II) salts","authors":"Douglas X. West,&nbsp;James B. Sedgwick","doi":"10.1016/0022-1902(81)80255-2","DOIUrl":"10.1016/0022-1902(81)80255-2","url":null,"abstract":"<div><p>Copper(II) complexes have been prepared with 2-isopropylaminopyridine N-oxide (IP) employing the perchlorate, tetrafluoroborate, nitrate, chloride and bromide salts. Preparative molar ratios of 4:1 and 2:1 ligand to copper(II) salt yielded the following unique salts: Cu(IP)<sub>4</sub>X<sub>2</sub>(X=ClO<sub>4</sub><sup>−</sup>, BF<sub>4</sub><sup>−</sup>), Cu(IP)<sub>3</sub>(NO<sub>3</sub>)<sub>2</sub> and Cu(IP)<sub>2</sub>X<sub>2</sub>(X=NO<sub>3</sub><sup>−</sup>, Cl<sup>−</sup> and Br<sup>−</sup>). Characterization and has been accomplished by infrared, electronic and electron spin resonance measurements primarily of the solid state. IP bonds as a monodentate ligand via its N-oxide oxygen in the first three complexes, but apparently as a bidentate ligand in the latter three. Cu(IP)<sub>2</sub>(NO<sub>3</sub>)<sub>2</sub> is binuclear and anion coordination occurs in both of the nitrate complexes as well as both halogen solids.</p></div>","PeriodicalId":16275,"journal":{"name":"Journal of Inorganic and Nuclear Chemistry","volume":"43 10","pages":"Pages 2307-2311"},"PeriodicalIF":0.0,"publicationDate":"1981-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/0022-1902(81)80255-2","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"78838206","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 17
Crystal structure of a new insertion compound formed by PdCl2 and tri-methylamine [(CH3)3NH]2PdCl4.(CH3)3NHCl 由PdCl2和三甲胺[(CH3) 3nhh]2PdCl4.(CH3)3NHCl组成的新插入化合物的晶体结构
Journal of Inorganic and Nuclear Chemistry Pub Date : 1981-01-01 Epub Date: 2003-05-20 DOI: 10.1016/0022-1902(81)80086-3
Dominique Zveguintzoff, Claudette Bois, Nguyen Quy Dao
{"title":"Crystal structure of a new insertion compound formed by PdCl2 and tri-methylamine [(CH3)3NH]2PdCl4.(CH3)3NHCl","authors":"Dominique Zveguintzoff,&nbsp;Claudette Bois,&nbsp;Nguyen Quy Dao","doi":"10.1016/0022-1902(81)80086-3","DOIUrl":"10.1016/0022-1902(81)80086-3","url":null,"abstract":"<div><p>The complex 3[(CH<sub>3</sub>)<sub>3</sub>NHCl].pdCl<sub>2</sub> crystallises in the orthorhombic system, space group <em>Pnma</em>: <em>a</em> = 990(1) pm; <em>b</em> = 1209(1) pm; <em>c</em> = 1721(2) pm; <em>Z</em> = 4; <em>d</em><sub>th</sub> = 1.49; <em>d</em><sub>exp</sub> = 1.45. The structure is composed of square planar PdCl<sub>4</sub><sup>2−</sup> ions (average length PdCl = 230 pm), of two ammonium groups, each one equidistant of two chlorine atoms and in <em>cis</em> position to the plane of PdCl<sub>4</sub><sup>2−</sup>. A third (CH<sub>3</sub>)<sub>3</sub>NHCl molecule is in insertion in the structure. This is a new type of solvate in which the insertion molecule is an ion pair.</p></div>","PeriodicalId":16275,"journal":{"name":"Journal of Inorganic and Nuclear Chemistry","volume":"43 12","pages":"Pages 3183-3185"},"PeriodicalIF":0.0,"publicationDate":"1981-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/0022-1902(81)80086-3","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"87192427","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 1
Preparation and characterization of dicarboniltriphenylphosphinedi(xanthate) molybdenum(II) and- tungsten(II) complexes 二碳基三苯膦(黄药)钼(II)和钨(II)配合物的制备和表征
Journal of Inorganic and Nuclear Chemistry Pub Date : 1981-01-01 Epub Date: 2003-05-20 DOI: 10.1016/0022-1902(81)80461-7
M.F. Perpiñán, A. Santos
{"title":"Preparation and characterization of dicarboniltriphenylphosphinedi(xanthate) molybdenum(II) and- tungsten(II) complexes","authors":"M.F. Perpiñán,&nbsp;A. Santos","doi":"10.1016/0022-1902(81)80461-7","DOIUrl":"10.1016/0022-1902(81)80461-7","url":null,"abstract":"","PeriodicalId":16275,"journal":{"name":"Journal of Inorganic and Nuclear Chemistry","volume":"43 1","pages":"Pages 181-184"},"PeriodicalIF":0.0,"publicationDate":"1981-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/0022-1902(81)80461-7","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"88610058","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 5
A new example of 5T2−1A1 spin crossover complex, dithiocyanato-tris(n-phenyl-2-pyridinalimine)iron(II) 5T2−1A1自旋交叉配合物双硫氰酸酯-三(n-苯基-2-吡啶胺)铁(II)的新例子
Journal of Inorganic and Nuclear Chemistry Pub Date : 1981-01-01 Epub Date: 2003-05-20 DOI: 10.1016/0022-1902(81)80253-9
Ho-Hsiang Wei, Ching-Sung Hsiao
{"title":"A new example of 5T2−1A1 spin crossover complex, dithiocyanato-tris(n-phenyl-2-pyridinalimine)iron(II)","authors":"Ho-Hsiang Wei,&nbsp;Ching-Sung Hsiao","doi":"10.1016/0022-1902(81)80253-9","DOIUrl":"10.1016/0022-1902(81)80253-9","url":null,"abstract":"<div><p>The preparation of the complex Fe(ppi)<sub>3</sub>(NCS)<sub>2</sub> (where ppi = N-phenyl-2-pyridinaldimine) is described. Mössbauer and magnetic susceptibility of this compound was studied in the temperature range between 298 and 78 K and clearly indicate a temperature induced <span><math><mtext>high-spin</mtext><mtext>(</mtext><msup><mi></mi><mn>5</mn></msup><mtext>T</mtext><msub><mi></mi><mn>2</mn></msub><mtext>)-</mtext><mtext>low-spin</mtext><mtext>(</mtext><msup><mi></mi><mn>1</mn></msup><mtext>A</mtext><msub><mi></mi><mn>1</mn></msub><mtext>)</mtext></math></span> transition.</p></div>","PeriodicalId":16275,"journal":{"name":"Journal of Inorganic and Nuclear Chemistry","volume":"43 10","pages":"Pages 2299-2300"},"PeriodicalIF":0.0,"publicationDate":"1981-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/0022-1902(81)80253-9","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"78844217","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 8
On the nature of the products of the reaction between Cr(III) and alanine Cr(III)与丙氨酸反应产物的性质
Journal of Inorganic and Nuclear Chemistry Pub Date : 1981-01-01 Epub Date: 2003-05-20 DOI: 10.1016/0022-1902(81)80527-1
Ron Trujillo, Albert Baca, Carolyn Castillo, William F. Coleman
{"title":"On the nature of the products of the reaction between Cr(III) and alanine","authors":"Ron Trujillo,&nbsp;Albert Baca,&nbsp;Carolyn Castillo,&nbsp;William F. Coleman","doi":"10.1016/0022-1902(81)80527-1","DOIUrl":"10.1016/0022-1902(81)80527-1","url":null,"abstract":"","PeriodicalId":16275,"journal":{"name":"Journal of Inorganic and Nuclear Chemistry","volume":"43 3","pages":"Pages 631-633"},"PeriodicalIF":0.0,"publicationDate":"1981-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/0022-1902(81)80527-1","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"88103178","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Studies on some mixed ligand complexes of Ni(II) Ni(II)混合配体配合物的研究
Journal of Inorganic and Nuclear Chemistry Pub Date : 1981-01-01 Epub Date: 2003-05-20 DOI: 10.1016/0022-1902(81)80512-X
C.P. Saxena, P.V. Khadikar
{"title":"Studies on some mixed ligand complexes of Ni(II)","authors":"C.P. Saxena,&nbsp;P.V. Khadikar","doi":"10.1016/0022-1902(81)80512-X","DOIUrl":"https://doi.org/10.1016/0022-1902(81)80512-X","url":null,"abstract":"","PeriodicalId":16275,"journal":{"name":"Journal of Inorganic and Nuclear Chemistry","volume":"43 3","pages":"Pages 603-605"},"PeriodicalIF":0.0,"publicationDate":"1981-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/0022-1902(81)80512-X","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"91739993","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 11
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