{"title":"由铜(II)盐形成的2-异丙氨基吡啶n -氧化物配合物","authors":"Douglas X. West, James B. Sedgwick","doi":"10.1016/0022-1902(81)80255-2","DOIUrl":null,"url":null,"abstract":"<div><p>Copper(II) complexes have been prepared with 2-isopropylaminopyridine N-oxide (IP) employing the perchlorate, tetrafluoroborate, nitrate, chloride and bromide salts. Preparative molar ratios of 4:1 and 2:1 ligand to copper(II) salt yielded the following unique salts: Cu(IP)<sub>4</sub>X<sub>2</sub>(X=ClO<sub>4</sub><sup>−</sup>, BF<sub>4</sub><sup>−</sup>), Cu(IP)<sub>3</sub>(NO<sub>3</sub>)<sub>2</sub> and Cu(IP)<sub>2</sub>X<sub>2</sub>(X=NO<sub>3</sub><sup>−</sup>, Cl<sup>−</sup> and Br<sup>−</sup>). Characterization and has been accomplished by infrared, electronic and electron spin resonance measurements primarily of the solid state. IP bonds as a monodentate ligand via its N-oxide oxygen in the first three complexes, but apparently as a bidentate ligand in the latter three. Cu(IP)<sub>2</sub>(NO<sub>3</sub>)<sub>2</sub> is binuclear and anion coordination occurs in both of the nitrate complexes as well as both halogen solids.</p></div>","PeriodicalId":16275,"journal":{"name":"Journal of Inorganic and Nuclear Chemistry","volume":"43 10","pages":"Pages 2307-2311"},"PeriodicalIF":0.0000,"publicationDate":"1981-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/0022-1902(81)80255-2","citationCount":"17","resultStr":"{\"title\":\"2-isopropylaminopyridine N-oxide complexes formed from copper(II) salts\",\"authors\":\"Douglas X. West, James B. Sedgwick\",\"doi\":\"10.1016/0022-1902(81)80255-2\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>Copper(II) complexes have been prepared with 2-isopropylaminopyridine N-oxide (IP) employing the perchlorate, tetrafluoroborate, nitrate, chloride and bromide salts. Preparative molar ratios of 4:1 and 2:1 ligand to copper(II) salt yielded the following unique salts: Cu(IP)<sub>4</sub>X<sub>2</sub>(X=ClO<sub>4</sub><sup>−</sup>, BF<sub>4</sub><sup>−</sup>), Cu(IP)<sub>3</sub>(NO<sub>3</sub>)<sub>2</sub> and Cu(IP)<sub>2</sub>X<sub>2</sub>(X=NO<sub>3</sub><sup>−</sup>, Cl<sup>−</sup> and Br<sup>−</sup>). Characterization and has been accomplished by infrared, electronic and electron spin resonance measurements primarily of the solid state. IP bonds as a monodentate ligand via its N-oxide oxygen in the first three complexes, but apparently as a bidentate ligand in the latter three. Cu(IP)<sub>2</sub>(NO<sub>3</sub>)<sub>2</sub> is binuclear and anion coordination occurs in both of the nitrate complexes as well as both halogen solids.</p></div>\",\"PeriodicalId\":16275,\"journal\":{\"name\":\"Journal of Inorganic and Nuclear Chemistry\",\"volume\":\"43 10\",\"pages\":\"Pages 2307-2311\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"1981-01-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"https://sci-hub-pdf.com/10.1016/0022-1902(81)80255-2\",\"citationCount\":\"17\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of Inorganic and Nuclear Chemistry\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/0022190281802552\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Inorganic and Nuclear Chemistry","FirstCategoryId":"1085","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/0022190281802552","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
2-isopropylaminopyridine N-oxide complexes formed from copper(II) salts
Copper(II) complexes have been prepared with 2-isopropylaminopyridine N-oxide (IP) employing the perchlorate, tetrafluoroborate, nitrate, chloride and bromide salts. Preparative molar ratios of 4:1 and 2:1 ligand to copper(II) salt yielded the following unique salts: Cu(IP)4X2(X=ClO4−, BF4−), Cu(IP)3(NO3)2 and Cu(IP)2X2(X=NO3−, Cl− and Br−). Characterization and has been accomplished by infrared, electronic and electron spin resonance measurements primarily of the solid state. IP bonds as a monodentate ligand via its N-oxide oxygen in the first three complexes, but apparently as a bidentate ligand in the latter three. Cu(IP)2(NO3)2 is binuclear and anion coordination occurs in both of the nitrate complexes as well as both halogen solids.
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