{"title":"5T2−1A1自旋交叉配合物双硫氰酸酯-三(n-苯基-2-吡啶胺)铁(II)的新例子","authors":"Ho-Hsiang Wei, Ching-Sung Hsiao","doi":"10.1016/0022-1902(81)80253-9","DOIUrl":null,"url":null,"abstract":"<div><p>The preparation of the complex Fe(ppi)<sub>3</sub>(NCS)<sub>2</sub> (where ppi = N-phenyl-2-pyridinaldimine) is described. Mössbauer and magnetic susceptibility of this compound was studied in the temperature range between 298 and 78 K and clearly indicate a temperature induced <span><math><mtext>high-spin</mtext><mtext>(</mtext><msup><mi></mi><mn>5</mn></msup><mtext>T</mtext><msub><mi></mi><mn>2</mn></msub><mtext>)-</mtext><mtext>low-spin</mtext><mtext>(</mtext><msup><mi></mi><mn>1</mn></msup><mtext>A</mtext><msub><mi></mi><mn>1</mn></msub><mtext>)</mtext></math></span> transition.</p></div>","PeriodicalId":16275,"journal":{"name":"Journal of Inorganic and Nuclear Chemistry","volume":"43 10","pages":"Pages 2299-2300"},"PeriodicalIF":0.0000,"publicationDate":"1981-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/0022-1902(81)80253-9","citationCount":"8","resultStr":"{\"title\":\"A new example of 5T2−1A1 spin crossover complex, dithiocyanato-tris(n-phenyl-2-pyridinalimine)iron(II)\",\"authors\":\"Ho-Hsiang Wei, Ching-Sung Hsiao\",\"doi\":\"10.1016/0022-1902(81)80253-9\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>The preparation of the complex Fe(ppi)<sub>3</sub>(NCS)<sub>2</sub> (where ppi = N-phenyl-2-pyridinaldimine) is described. Mössbauer and magnetic susceptibility of this compound was studied in the temperature range between 298 and 78 K and clearly indicate a temperature induced <span><math><mtext>high-spin</mtext><mtext>(</mtext><msup><mi></mi><mn>5</mn></msup><mtext>T</mtext><msub><mi></mi><mn>2</mn></msub><mtext>)-</mtext><mtext>low-spin</mtext><mtext>(</mtext><msup><mi></mi><mn>1</mn></msup><mtext>A</mtext><msub><mi></mi><mn>1</mn></msub><mtext>)</mtext></math></span> transition.</p></div>\",\"PeriodicalId\":16275,\"journal\":{\"name\":\"Journal of Inorganic and Nuclear Chemistry\",\"volume\":\"43 10\",\"pages\":\"Pages 2299-2300\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"1981-01-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"https://sci-hub-pdf.com/10.1016/0022-1902(81)80253-9\",\"citationCount\":\"8\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of Inorganic and Nuclear Chemistry\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/0022190281802539\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Inorganic and Nuclear Chemistry","FirstCategoryId":"1085","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/0022190281802539","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
引用次数: 8
摘要
描述了配合物Fe(ppi)3(NCS)2(其中ppi = n -苯基-2-吡啶二胺)的制备。Mössbauer和该化合物的磁化率在298 ~ 78 K的温度范围内进行了研究，清楚地表明温度诱导了高自旋(5T2)-低自旋(1A1)转变。
A new example of 5T2−1A1 spin crossover complex, dithiocyanato-tris(n-phenyl-2-pyridinalimine)iron(II)
The preparation of the complex Fe(ppi)3(NCS)2 (where ppi = N-phenyl-2-pyridinaldimine) is described. Mössbauer and magnetic susceptibility of this compound was studied in the temperature range between 298 and 78 K and clearly indicate a temperature induced transition.
求助内容：
应助结果提醒方式：
京公网安备 11010802042870号
