Journal of energy storage最新文献

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In-depth review of CaCO3/CaO TCES system with the perspective of cyclic stability, reactors and its integration with CSPs
IF 8.9 2区 工程技术
Journal of energy storage Pub Date : 2024-12-01 DOI: 10.1016/j.est.2024.114820
Azhar Abbas Khosa , Hafeez Ur Rehman , Najam-ul-Hassan Shah , Xinyue Han , JianFeng Pan
{"title":"In-depth review of CaCO3/CaO TCES system with the perspective of cyclic stability, reactors and its integration with CSPs","authors":"Azhar Abbas Khosa ,&nbsp;Hafeez Ur Rehman ,&nbsp;Najam-ul-Hassan Shah ,&nbsp;Xinyue Han ,&nbsp;JianFeng Pan","doi":"10.1016/j.est.2024.114820","DOIUrl":"10.1016/j.est.2024.114820","url":null,"abstract":"<div><div>A concentrated solar power (CSP) plant integrated with CaCO<sub>3</sub>/CaO thermochemical energy storage (TCES) system is capable of producing dispatchable renewable electricity. However, the integration process is complex and needs more study to be upgraded to a more sophisticated and advanced level. Besides, the agglomeration of powder particles still challenges the CaCO<sub>3</sub>/CaO reaction pair because of sintering. Therefore, the current study aims to provide a detailed review of the CaCO<sub>3</sub>/CaO TCES system. It addresses the challenges related to material properties, dopants, multi-cycle use of materials, and their effect on the reaction kinetics. In addition, this review also focuses on state-of-the-art CSP technologies, TCES system integration schemes with CSP, reactors for commercial use, and CO<sub>2</sub> capture systems. At the end of the literature review, the CaCO<sub>3</sub>/CaO TCES system has been compared with other TES systems and solar power plants based on capital cost and levelized cost of energy (LCOE), with critical findings corresponding to associated problems within the system and its future.</div></div>","PeriodicalId":15942,"journal":{"name":"Journal of energy storage","volume":"106 ","pages":"Article 114820"},"PeriodicalIF":8.9,"publicationDate":"2024-12-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142757735","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Thermal runaway properties of power cells under tunnel scenarios: Impact of heating patterns and heating powers
IF 8.9 2区 工程技术
Journal of energy storage Pub Date : 2024-11-30 DOI: 10.1016/j.est.2024.114814
Dongxu Ouyang , Xiaojun Liu , Bo Liu , Junling Wang , Zhirong Wang
{"title":"Thermal runaway properties of power cells under tunnel scenarios: Impact of heating patterns and heating powers","authors":"Dongxu Ouyang ,&nbsp;Xiaojun Liu ,&nbsp;Bo Liu ,&nbsp;Junling Wang ,&nbsp;Zhirong Wang","doi":"10.1016/j.est.2024.114814","DOIUrl":"10.1016/j.est.2024.114814","url":null,"abstract":"<div><div>Due to the rapid increase in the number of electric vehicles and tunnels in cities, combining the inherent safety defect of power cells, the thermal runaway risk of power cells in tunnels requires significant attention. Herein, an experimental exploration is carried out to unveil the thermal runaway properties of power cells at tunnel scenarios, whereby the impact of heating patterns (electric oven and plate) and heating powers is involved as well. Under the effect of various heating patterns, cells show quite different thermal runaway properties inside a tunnel. In the oven case, the cell is uniformly heated, leading to two instances of smoke/gas release, followed by ejection fire and stable combustion. Whereas, the cell under the plate pattern illustrates smoke/gas releasing only once, with no combustion occurring due to the relatively low surrounding temperature. In addition, the cell affected by a plate experiences a process of thermal runaway propagation, i.e., the left part of the cell encounters thermal runaway first and then propagates to the right part, with the severity of the thermal runaway increasing over time. The cell heated by an oven illustrates worse thermal hazards with a more dramatic temperature rise and heat release, though the associated smoke hazard is relatively mild. The thermal conductivity of the cells is calculated to be approximately 3800 W/(m·K). The power of electric ovens and plates shows little impact on the heat release, mass loss, and smoke release of cells during thermal runaway. Finally, the dimensionless temperature rise at specific positions along the tunnel ceiling exhibits an exponential reduction as the dimensionless position increases during thermal runaway.</div></div>","PeriodicalId":15942,"journal":{"name":"Journal of energy storage","volume":"106 ","pages":"Article 114814"},"PeriodicalIF":8.9,"publicationDate":"2024-11-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142746323","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Rapid HCFC-141b hydrate formation and high-density cold storage in the presence of acid ester surfactants
IF 8.9 2区 工程技术
Journal of energy storage Pub Date : 2024-11-30 DOI: 10.1016/j.est.2024.114819
Jie Luo, Zhigao Sun
{"title":"Rapid HCFC-141b hydrate formation and high-density cold storage in the presence of acid ester surfactants","authors":"Jie Luo,&nbsp;Zhigao Sun","doi":"10.1016/j.est.2024.114819","DOIUrl":"10.1016/j.est.2024.114819","url":null,"abstract":"<div><div>To improve HCFC-141b hydrate production, eco-friendly nonionic surfactants were used as promoters to enhance hydrate formation. Stearic acid polyoxyethylene ester (SG) effectively improve HCFC-141b hydrate formation, and the promotion effect is influenced by the hydrophilicity and mass fraction of surfactant. Ethylene oxide (EO) numbers of SG series surfactants affect on hydrate nucleation induction time and cold storage density. Surfactants with appropriate HLB values have better promotion effects. Hydrate has shorter induction times and higher cold storage density with SG-20. When the concentration of SG-20 is 1 %, the induction time reduces to 36 min, and the cold storage density is up to 245.1 kJ/kg, which is the optimal addition amount for HCFC-141b hydrate production. Comparing the three systems, the HCFC-141b hydrate system with 1 wt% SG-20 has the best cycling stability.</div></div>","PeriodicalId":15942,"journal":{"name":"Journal of energy storage","volume":"106 ","pages":"Article 114819"},"PeriodicalIF":8.9,"publicationDate":"2024-11-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142746412","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Mechanical performance of polyurethane polymer mortar—A novel sealing material for CAES man-made caverns
IF 8.9 2区 工程技术
Journal of energy storage Pub Date : 2024-11-30 DOI: 10.1016/j.est.2024.114845
Xue Yang , Zhongming Jiang , Zhaofeng Shi , Qiang Mao , Junhui Liao , Xiang Tian
{"title":"Mechanical performance of polyurethane polymer mortar—A novel sealing material for CAES man-made caverns","authors":"Xue Yang ,&nbsp;Zhongming Jiang ,&nbsp;Zhaofeng Shi ,&nbsp;Qiang Mao ,&nbsp;Junhui Liao ,&nbsp;Xiang Tian","doi":"10.1016/j.est.2024.114845","DOIUrl":"10.1016/j.est.2024.114845","url":null,"abstract":"<div><div>This work aims to investigate the feasibility of polyurethane polymer mortar (PPM) as a sealing material for compressed air energy storage (CAES) caverns. The effect of polymer content, aggregates ratio (fine sand to medium sand) and filler types (bentonite, clay, and fly ash) on gas permeability, tensile strength, and resistance to high and low temperature of PPM were conducted. The scanning electron microscopy (SEM) and Fourier transform infrared spectroscopy (FTIR) were performed to characterize the microstructure of PPM. Additionally, numerical simulations were performed to analyze the stress distribution characteristics of PPM when used as a sealing structure. The results demonstrate that PPM exhibits low gas permeability (10<sup>−21</sup> m<sup>2</sup>), high tensile strength (up to 2.96 MPa), and significant tensile strain (up to 27.02 %), with a relatively low elastic modulus (11.87–35.05 MPa). Meanwhile, PPM containing fly ash showed the highest strength, followed by those with clay, while PPM with bentonite exhibited the lowest strength. However, only the PPM with bentonite as a filler remained stable and did not collapse under high temperatures. The hoop stresses in the PPM are only compressive and not tensile, and the maximum hoop tensile strain remains well below the ultimate tensile strain of the material, thus preventing the tensile damage and ensuring the gas-tightness. These findings provide a theoretical basis for using PPM in CAES sealing applications, and advance the understanding and application of sealing materials in CAES man-made caverns.</div></div>","PeriodicalId":15942,"journal":{"name":"Journal of energy storage","volume":"106 ","pages":"Article 114845"},"PeriodicalIF":8.9,"publicationDate":"2024-11-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142757736","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
The mechanism of the impact of Li2MnO3 with dual-edged sword functionality on the cyclic performance of lithium-rich manganese-based cathode materials
IF 8.9 2区 工程技术
Journal of energy storage Pub Date : 2024-11-30 DOI: 10.1016/j.est.2024.114808
Zihao Su , Zhihao Guo , Haoyu Xie , Meizhen Qu , Hao Wang , Gongchang Peng
{"title":"The mechanism of the impact of Li2MnO3 with dual-edged sword functionality on the cyclic performance of lithium-rich manganese-based cathode materials","authors":"Zihao Su ,&nbsp;Zhihao Guo ,&nbsp;Haoyu Xie ,&nbsp;Meizhen Qu ,&nbsp;Hao Wang ,&nbsp;Gongchang Peng","doi":"10.1016/j.est.2024.114808","DOIUrl":"10.1016/j.est.2024.114808","url":null,"abstract":"<div><div>The Li<sub>2</sub>MnO<sub>3</sub> phase is a double-edged sword hanging over lithium-rich manganese-based cathode materials (LLOs). It provides a theoretical specific capacity of over 300mAh/g for LLOs, but it is also the main source of issues such as low Initial Coulombic efficiency (ICE), poor rate performance, and voltage decay. In recent years, related research has primarily focused on the lattice oxygen. From the perspective related to the Li<sub>2</sub>MnO<sub>3</sub> phase, this study achieves different activation degrees of Li<sub>2</sub>MnO<sub>3</sub> phase through ingenious electrochemical methods. It conducts a detailed analysis of the phase transition and polarization of Li<sub>2</sub>MnO<sub>3</sub> phase under high and low rates, and delves into the different mechanisms that cause the electrochemical performance degradation of LLOs under high and low rates. The results show that during low-rate cycling, the more Li<sub>2</sub>MnO<sub>3</sub> phase in LLOs, the more transformation of crystal structure from layered to spinel phase occurs during cycling, and the structural transformation of the material will ultimately lead to the degradation of cycle performance and voltage decay. During high-rate cycling, due to the intrinsic conductivity difference of Li<sub>2</sub>MnO<sub>3</sub> phase, the large polarization effect of LLOs can lead to severe decomposition of the electrolyte at high voltages, resulting in the degradation of cycle performance. Therefore, conducting research on LLOs focused on the Li<sub>2</sub>MnO<sub>3</sub> phase may be an effective approach, providing a new modification idea for achieving more excellent cycling performance of LLOs.</div></div>","PeriodicalId":15942,"journal":{"name":"Journal of energy storage","volume":"106 ","pages":"Article 114808"},"PeriodicalIF":8.9,"publicationDate":"2024-11-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142757741","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
The knowledge contributions from science to technology on lithium-ion batteries from the industry chain view
IF 8.9 2区 工程技术
Journal of energy storage Pub Date : 2024-11-30 DOI: 10.1016/j.est.2024.114694
Sida Feng , Huajiao Li , Yabin Qi , Ze Wang , Feng An
{"title":"The knowledge contributions from science to technology on lithium-ion batteries from the industry chain view","authors":"Sida Feng ,&nbsp;Huajiao Li ,&nbsp;Yabin Qi ,&nbsp;Ze Wang ,&nbsp;Feng An","doi":"10.1016/j.est.2024.114694","DOIUrl":"10.1016/j.est.2024.114694","url":null,"abstract":"<div><div>The lithium-ion industry chain comprises multiple links such as battery components, battery (pack) and management, and recycling. Each link has its features, and they are interlinked. Industry chain development cannot be separated from the mutual promotion of all links in the industry chain. The scientific and technological innovation of the lithium-ion battery chain is widely studied because it is considered one of the most promising energy storage systems. Moreover, scientific development is widely considered to promote technological innovation, and the contribution of knowledge from science to technology is studied by analyzing citations from patents to papers. However, there are two research gaps. First, there is little research on the contributions of science and technology in the lithium-ion battery field. The second gap is the lack of an industrial chain view in the study of science–technology linkages. Therefore, this study proposed a framework to reveal the knowledge contributions from science to technology from the industry chain view and applied it to the lithium-ion battery industry. The findings are summarized as follows: (1) A total of 130 topics were mined, summarized, and classified from the industry view. The electrode, battery management and electrolyte are relatively complex and are more discussed, especially regarding the electrode. (2) Knowledge contributions from science to technology have concentrated on the electrolyte, electrode and battery management. The knowledge contributions from paper topics on the electrode to patent topics on the electrode are the strongest. Patent inventors who focus on these three elements should refer to science on this element and science on the other two elements. Besides, policy- makers could promulgate promotion policies to stimulate the scientific development of these three elements, especially for the electrode. (3) Garnet-type ceramic sintering was the topic that had the greatest contributions in 2017 and 2018, and the patent topic to which it contributed as the most was “garnet-type ceramic sintering. Silicon has a consistently high degree of knowledge interaction between science and technology. These findings could serve as a reference for policy-makers when making incentive policies and scholars when selecting research content.</div></div>","PeriodicalId":15942,"journal":{"name":"Journal of energy storage","volume":"106 ","pages":"Article 114694"},"PeriodicalIF":8.9,"publicationDate":"2024-11-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142746405","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Formation of a robust SEI through covalent binding nitrile to silicon toward stabilized micron-sized silicon anodes
IF 8.9 2区 工程技术
Journal of energy storage Pub Date : 2024-11-30 DOI: 10.1016/j.est.2024.114833
Dan Zhao , Dengfeng Yu , Bing Bai , Yao Lu , Yingqi Li , Wei Xu , Jinyu Wu , Qiongying Huang , Xiaofeng Zhang , Kui-Qing Peng
{"title":"Formation of a robust SEI through covalent binding nitrile to silicon toward stabilized micron-sized silicon anodes","authors":"Dan Zhao ,&nbsp;Dengfeng Yu ,&nbsp;Bing Bai ,&nbsp;Yao Lu ,&nbsp;Yingqi Li ,&nbsp;Wei Xu ,&nbsp;Jinyu Wu ,&nbsp;Qiongying Huang ,&nbsp;Xiaofeng Zhang ,&nbsp;Kui-Qing Peng","doi":"10.1016/j.est.2024.114833","DOIUrl":"10.1016/j.est.2024.114833","url":null,"abstract":"<div><div>Constructing robust solid electrolyte interface (SEI) has long been regarded as an effective strategy for stabilizing silicon anodes and still remains a great challenge. In this work, we experimentally demonstrate that the covalent binding of polyacrylonitrile (PAN) binder to silicon results in the formation of robust bilayer SEI containing a Li<sub>3</sub>N-rich inner layer and an organic-components-rich outer layer. The in situ generated N-rich SEI is mechanically stable and ion-conductive. As a result, the stability and adhesion of silicon electrodes are greatly enhanced. Specifically, silicon electrodes utilizing PAN binder exhibit remarkable improvements in terms of Coulombic efficiency (CE), rate performance, and cycling stability (1290 mAh g<sup>−1</sup> after over 800 cycles at 0.5 C) compared to the electrodes utilizing other binders. The silicon surface functionalization strategy offers a potential approach paving the way toward the development of stable and high-energy silicon-based lithium-ion batteries.</div></div>","PeriodicalId":15942,"journal":{"name":"Journal of energy storage","volume":"106 ","pages":"Article 114833"},"PeriodicalIF":8.9,"publicationDate":"2024-11-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142746473","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
One-step preparation of waste epoxy resin-derived nanosized carbon aerogel and its high supercapacitor performance
IF 8.9 2区 工程技术
Journal of energy storage Pub Date : 2024-11-30 DOI: 10.1016/j.est.2024.114742
Chongjun Zhao, Haimin Ou, Chunhua Zhao
{"title":"One-step preparation of waste epoxy resin-derived nanosized carbon aerogel and its high supercapacitor performance","authors":"Chongjun Zhao,&nbsp;Haimin Ou,&nbsp;Chunhua Zhao","doi":"10.1016/j.est.2024.114742","DOIUrl":"10.1016/j.est.2024.114742","url":null,"abstract":"<div><div>Energy storage devices serve critical roles in both harvesting energy from new energy sources and supplying energy to consumers, and the performance of supercapacitors is heavily reliant on the performance of activated material, which is determined by the qualities achieved during the specified preparation process. Herein, due to the merit of isotropy of 0D carbon nanoparticles in structure and current transfer, spherical carbon aerogels (CA) with the size of <em>ϕ</em> ~ 100 nm are carbonized within 3 min in air in an open tube furnace, in which those waste epoxy resin blocks are chosen and reused as the carbon source. After the activation, the surface of activated CA (ACA) becomes rough, and its specific surface area reaches 1222.40 m<sup>2</sup>·g<sup>−1</sup>. The above ACA owns high electrochemical supercapacitor performance: Referring to the ACA-based electrode, a specific capacitance of 298.8 F·g<sup>−1</sup> at 1 A·g<sup>−1</sup> and 92.81 % retention after 20,000 cycles of repeated charge/discharge. As for its symmetric supercapacitor (SSC), it has good CV behavior even at 1000 mV·s<sup>−1</sup>, accompanied by an energy density of 20.92 W h·kg<sup>−1</sup> at the power density of 300 W·kg<sup>−1</sup>, and 12.34 W h·kg<sup>−1</sup> even at 12000 W·kg<sup>−1</sup>.</div></div>","PeriodicalId":15942,"journal":{"name":"Journal of energy storage","volume":"106 ","pages":"Article 114742"},"PeriodicalIF":8.9,"publicationDate":"2024-11-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142747283","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Effect of microstructure on performance and working mechanism of MnO2-PEDOT supercapacitors based on nonaqueous electrolytes
IF 8.9 2区 工程技术
Journal of energy storage Pub Date : 2024-11-30 DOI: 10.1016/j.est.2024.114824
Ł. Łańcucki, P. Pasierb
{"title":"Effect of microstructure on performance and working mechanism of MnO2-PEDOT supercapacitors based on nonaqueous electrolytes","authors":"Ł. Łańcucki,&nbsp;P. Pasierb","doi":"10.1016/j.est.2024.114824","DOIUrl":"10.1016/j.est.2024.114824","url":null,"abstract":"<div><div>In this work we demonstrate the impact of synthesis conditions on the properties of stable nanostructured MnO<sub>2</sub> and their application as electrode material in supercapacitors. Samples synthesized by hydrothermal method were characterized by XRD, XPS, SEM, BET surface area and the correlation with the electrochemical performance of constructed prototype supercapacitors was discussed. The morphological study of the as-synthesized MnO<sub>2</sub> samples shown the morphology consisting of nanorods for pH value of 2.5 and cauliflower shape for pH of 3 and 6.5. The XRD study revealed that at low pH a α-MnO<sub>2</sub> is formed whereas an increase of pH during synthesis leads to birnessite phase formation. The electrochemical studies, for 5 % KNO<sub>3</sub> dissolved in dimethyl sulfoxide (DMSO) used as an electrolyte, shown that the birnessite MnO<sub>2</sub> structure exhibits much better electrochemical behavior of constructed supercapacitors comparing to α-MnO2. The observed electrochemical behavior can be explained by the microstructure differences of prepared materials.</div></div>","PeriodicalId":15942,"journal":{"name":"Journal of energy storage","volume":"106 ","pages":"Article 114824"},"PeriodicalIF":8.9,"publicationDate":"2024-11-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142757737","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Expanded graphite/reduced graphene oxide hybrid architecture functionalized with RuO2 nanoclusters for high performance energy storage
IF 8.9 2区 工程技术
Journal of energy storage Pub Date : 2024-11-30 DOI: 10.1016/j.est.2024.114776
Chi-Kai Hung , Antony R. Thiruppathi , Cameron McGuire , De-Tong Jiang , Aicheng Chen
{"title":"Expanded graphite/reduced graphene oxide hybrid architecture functionalized with RuO2 nanoclusters for high performance energy storage","authors":"Chi-Kai Hung ,&nbsp;Antony R. Thiruppathi ,&nbsp;Cameron McGuire ,&nbsp;De-Tong Jiang ,&nbsp;Aicheng Chen","doi":"10.1016/j.est.2024.114776","DOIUrl":"10.1016/j.est.2024.114776","url":null,"abstract":"<div><div>In this study, a one-step thermal process was employed to functionalize a graphene-based composite consisting of expanded graphite (EG) and reduced graphene oxide (rGO) with ruthenium nanoclusters of 2–3 nm in diameter. The Ru/EG-rGO nanocomposites were optimized by varying the EG content and annealing temperature, revealing their effects on substrate interconnectivity, nanoparticle binding affinity, and the degree of reduction of graphene oxide (GO) and ruthenium chloride. The optimized Ru/EG-rGO nanocomposite, with a 1:1 ratio of EG:GO and annealing temperature of 350 °C, exhibited the highest specific capacitance at 382 F g<sup>−1</sup> in 0.5 M H<sub>2</sub>SO<sub>4</sub>. In a symmetric capacitor configuration, the material demonstrated superior performance compared to other Ru-based supercapacitors, achieving a high energy density of 22.1 Wh kg<sup>−1</sup> at a power density of 0.5 kW kg<sup>−1</sup>, and retained 13.6 Wh kg<sup>−1</sup> at a power density of 10 kW kg<sup>−1</sup>. Furthermore, the material showcased remarkable durability, retaining 97 % of the initial capacitance after 10,000 cycles at 5 kW kg<sup>−1</sup>. The high performance and stability, combined with the ease of fabrication, makes this novel Ru/EG-rGO nanocomposite promising for supercapacitor applications, and the design strategies demonstrated in this work can be further applied to the development and large-scale fabrication of energy storage materials.</div></div>","PeriodicalId":15942,"journal":{"name":"Journal of energy storage","volume":"106 ","pages":"Article 114776"},"PeriodicalIF":8.9,"publicationDate":"2024-11-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142747285","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
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