Journal of energy storage最新文献

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Enhanced pseudocapacitor performance using polyaniline‑zirconium dioxide nanocomposite all-in-one hydrogel 利用聚苯胺-二氧化锆纳米复合一体水凝胶增强假电容器性能
IF 8.9 2区 工程技术
Journal of energy storage Pub Date : 2025-07-29 DOI: 10.1016/j.est.2025.117827
Fathiah Kamarulazam , N.K. Farhana , Shahid Bashir , M. Pershaanaa , Zhi Ling Goh , Loh Kah Hoe , S. Ramesh , K. Ramesh
{"title":"Enhanced pseudocapacitor performance using polyaniline‑zirconium dioxide nanocomposite all-in-one hydrogel","authors":"Fathiah Kamarulazam ,&nbsp;N.K. Farhana ,&nbsp;Shahid Bashir ,&nbsp;M. Pershaanaa ,&nbsp;Zhi Ling Goh ,&nbsp;Loh Kah Hoe ,&nbsp;S. Ramesh ,&nbsp;K. Ramesh","doi":"10.1016/j.est.2025.117827","DOIUrl":"10.1016/j.est.2025.117827","url":null,"abstract":"<div><div>Hydrogel electrolytes play a distinct and vital role in the development of flexible supercapacitors, as they facilitate excellent interfacial contact with the electrodes. Nevertheless, there remains a substantial opportunity for further development in supercapacitor design, particularly when employing binder-type electrode materials. This is due to the presence of interfacial contact resistance, which can compromise the supercapacitor's performance. Additionally, there are instances where the electrode materials fail to adhere completely to the electrode substrate, leading to a decline in the electrochemical performance of the supercapacitor. To address these challenges, a self-healing, all-in-one hydrogel supercapacitor was fabricated via in-situ polymerization of aniline and Zirconium dioxide (ZrO<sub>2</sub>) nanocomposites on the surface of self-healing natural rubber-based hydrogel electrolyte. This study introduces ZrO<sub>2</sub> nanoparticles along with polyaniline to enhance the all-in-one supercapacitor's performance, leveraging their exceptional structural, thermal, and electrochemical properties. When subjected to galvanostatic charge-discharge tests, the flexible all-in-one hydrogel supercapacitor displayed impressive areal capacitances, reaching 36.59 mF/cm<sup>2</sup>, 42.59 mF/cm<sup>2</sup>, and 47.62 mF/cm<sup>2</sup> for PZ0, PZ1, and PZ3 respectively, at a current density of 0.5 mA/cm<sup>2</sup>. Notably, the highest energy density and power density were achieved by PZ3 (containing 0.3 wt% ZrO<sub>2</sub>), yielding 144.67 μWh/cm<sup>2</sup> (at 0.5 mA/cm<sup>2</sup>) and 1345.10 μW/cm<sup>2</sup> (at 1 mA/cm<sup>2</sup>), respectively. Even at higher current densities (1 mA/cm<sup>2</sup>), the all-in-one hydrogel supercapacitor retained 61.84 % of its initial capacitance. These remarkable electrochemical properties of PZ3 are attributed to the ZrO<sub>2</sub> incorporation, by promoting Faradaic reactions at the electrode.</div></div>","PeriodicalId":15942,"journal":{"name":"Journal of energy storage","volume":"132 ","pages":"Article 117827"},"PeriodicalIF":8.9,"publicationDate":"2025-07-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144721194","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Overcharging beha1vior and multi-signal early warning of the LiNi0.6Co0.2Mn0.2O2 lithium-ion pouch cells LiNi0.6Co0.2Mn0.2O2袋状锂离子电池过充行为及多信号预警
IF 8.9 2区 工程技术
Journal of energy storage Pub Date : 2025-07-29 DOI: 10.1016/j.est.2025.117825
Xueya Zhang , Wei Chen , Meng Li , Hang Yu , Yongfei Ma , Hao Fan , Yibo Zhang , Shidong Li , Binbin Mao , Liang Zhou
{"title":"Overcharging beha1vior and multi-signal early warning of the LiNi0.6Co0.2Mn0.2O2 lithium-ion pouch cells","authors":"Xueya Zhang ,&nbsp;Wei Chen ,&nbsp;Meng Li ,&nbsp;Hang Yu ,&nbsp;Yongfei Ma ,&nbsp;Hao Fan ,&nbsp;Yibo Zhang ,&nbsp;Shidong Li ,&nbsp;Binbin Mao ,&nbsp;Liang Zhou","doi":"10.1016/j.est.2025.117825","DOIUrl":"10.1016/j.est.2025.117825","url":null,"abstract":"<div><div>Overcharging of lithium-ion batteries (LIBs) leads to irreversible degradation, failure, and severe thermal runaway (TR). This study systematically investigates the TR behavior of commercial Li (Ni<sub>0.6</sub>Co<sub>0.2</sub>Mn<sub>0.2</sub>) O<sub>2</sub>//graphite pouch cells under overcharging conditions at different C-rates (0.5, 0.75, and 1C). Based on the evolution of key parameters, the overcharging process could be divided into four stages, and the electrical and thermal behaviors of each stage are studied. Incremental capacity and differential voltage analysis reveals that overcharging disrupts the lithium-ion transport channels, leading to electrode material degradation and side reactions, which in turn increases the risk of TR. This deduction is confirmed through microscopic and spectroscopic characterizations. Post-mortem analysis reveals that overcharging causes the collapse of the layered cathode structure, the formation of large amounts of lithium deposits on the anode surface, and a reduction in the graphitization degree. To enhance the safety of LIBs, a multi-level early warning strategy is proposed according to the changes in multiple signals, such as maximum temperature difference, crest voltage, and the detection of gas. This study through comprehensive analyses, links electrode degradation to TR risk and innovatively proposes a multi-level early warning strategy with clear thresholds based on the evolution of multiple signals during the overcharging process, alleviating the limitations of existing single signal studies. It provides a theoretical foundation for the life management and safety surveillance of lithium-ion batteries under overcharge conditions.</div></div>","PeriodicalId":15942,"journal":{"name":"Journal of energy storage","volume":"132 ","pages":"Article 117825"},"PeriodicalIF":8.9,"publicationDate":"2025-07-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144721195","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Lithium plating in commercial lithium-ion cells: An extensive study combining electrical methods with post-mortem analysis 商用锂离子电池中的锂电镀:一项结合电学方法和尸检分析的广泛研究
IF 8.9 2区 工程技术
Journal of energy storage Pub Date : 2025-07-29 DOI: 10.1016/j.est.2025.117706
Heinrich Ditler , Thorsten Tegetmeyer-Kleine , Gereon Stahl , Christiane Rahe , Dirk Uwe Sauer
{"title":"Lithium plating in commercial lithium-ion cells: An extensive study combining electrical methods with post-mortem analysis","authors":"Heinrich Ditler ,&nbsp;Thorsten Tegetmeyer-Kleine ,&nbsp;Gereon Stahl ,&nbsp;Christiane Rahe ,&nbsp;Dirk Uwe Sauer","doi":"10.1016/j.est.2025.117706","DOIUrl":"10.1016/j.est.2025.117706","url":null,"abstract":"<div><div>The identification of lithium plating represents a fundamental aspect in the development of fast charging algorithms. This extensive study correlates established electrical detection methods with results of a post-mortem investigation. Commercial cells were therefore charged under a variety of operating conditions, including variations in temperature, current, cooling, clamping pressure and state-of-charge. Indicators of Li plating were analyzed using electrical stripping and voltage relaxation measurements. The post-mortem analysis included the digital image processing of over 5000 flatbed scans of anode electrode surfaces. To analyze the Li plating morphology and validate that the observed macroscopic structures are lithium plating, laser-scanning and scanning electron microscopy measurements combined with energy dispersive X-ray (EDX) analysis were performed. The use of a windowless EDX detector enabled the measurement of Li K<span><math><mi>α</mi></math></span> X-rays at 54<!--> <!-->eV, thereby confirming the presence of lithium metal in the grown structures. The structural analysis of the surface deposits revealed, for the first time in a commercial cell, a novel polyhedral Li plating morphology. These results contribute to the field of Li plating detection, as it is essential to understand the plating process and detect metallic lithium at an early stage in order to optimize battery lifetime and increase safety for the target application.</div></div>","PeriodicalId":15942,"journal":{"name":"Journal of energy storage","volume":"132 ","pages":"Article 117706"},"PeriodicalIF":8.9,"publicationDate":"2025-07-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144721196","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Movable SiO2 reinforced polymethyl methacrylate dual network coating for highly stable zinc anodes 用于高稳定性锌阳极的可移动SiO2增强聚甲基丙烯酸甲酯双网涂层
IF 8.9 2区 工程技术
Journal of energy storage Pub Date : 2025-07-29 DOI: 10.1016/j.est.2025.117752
Liang Wu , Yuxuan Hu , Xian Du , Jie Lu , Zhuo Li , Na Cao , Shengrong Zhang , Huiling Du
{"title":"Movable SiO2 reinforced polymethyl methacrylate dual network coating for highly stable zinc anodes","authors":"Liang Wu ,&nbsp;Yuxuan Hu ,&nbsp;Xian Du ,&nbsp;Jie Lu ,&nbsp;Zhuo Li ,&nbsp;Na Cao ,&nbsp;Shengrong Zhang ,&nbsp;Huiling Du","doi":"10.1016/j.est.2025.117752","DOIUrl":"10.1016/j.est.2025.117752","url":null,"abstract":"<div><div>Aqueous zinc-ion batteries (ZIBs) have attracted significant attention due to their high volumetric energy density, low redox potential, and remarkable safety features. However, zinc anodes in ZIBs suffer from issues such as uncontrolled dendrite growth, hydrogen evolution reaction (HER), corrosion, and passivation, which severely limit their performance and lifespan. Herein, an interfacial composite coating was constructed on the zinc anode. SiO<sub>2</sub> is uniformly dispersed as a secondary network within the polymethyl methacrylate (PMMA) matrix. It enhances the mechanical strength and ionic conductivity of the PMMA framework, promotes the homogeneous deposition of zinc ions (Zn<sup>2+</sup>), and serves as an effective barrier between the anode and the electrolyte, thereby inhibiting the hydrogen evolution reaction (HER) and reducing metal corrosion. The symmetric cell with the modified anode achieves an ultralong cycling lifespan of 2200 h at 3 mA cm<sup>−2</sup>, while the full cell demonstrates exceptional rate capability and cycling stability. Furthermore, theoretical calculations elucidate that SiO₂ acts as a “restrictor” by reducing the crystallinity of PMMA and enhancing the movement of chain segments, ultimately facilitating the transfer of Zn<sup>2+</sup>. This research provides a technological foundation for expanding the applications of ZIBs.</div></div>","PeriodicalId":15942,"journal":{"name":"Journal of energy storage","volume":"132 ","pages":"Article 117752"},"PeriodicalIF":8.9,"publicationDate":"2025-07-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144721826","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Centralized strategy learning with multi-feature scale health factors for lithium-ion battery RUL prediction 基于多特征尺度健康因子的锂离子电池RUL预测集中策略学习
IF 8.9 2区 工程技术
Journal of energy storage Pub Date : 2025-07-29 DOI: 10.1016/j.est.2025.117875
Jun Zhou , Peng Wang , Xing Wu , Tao Liu
{"title":"Centralized strategy learning with multi-feature scale health factors for lithium-ion battery RUL prediction","authors":"Jun Zhou ,&nbsp;Peng Wang ,&nbsp;Xing Wu ,&nbsp;Tao Liu","doi":"10.1016/j.est.2025.117875","DOIUrl":"10.1016/j.est.2025.117875","url":null,"abstract":"<div><div>The prediction accuracy of the remaining useful life (RUL) of lithium-ion batteries is an important condition to ensure the safe and effective driving of electric vehicles. In the feature factor selection stage, the existing methods mostly use a single health factor, or introduce the method of sample entropy to fuse the features of multiple health factors. This paper proposes a lithium-ion battery RUL prediction based on multi-feature scale health factors and a centralized strategy learning method. It aims to reduce the time complexity of data preprocessing and consider the interaction between data. Firstly, to ensure the richness of the data sequences and its interaction effects, multi-feature scale health factors are extracted from the battery dataset. Secondly, the proposed multi-feature scale star aggregation and redistribution model is adopted. Multiple correlation coefficients were used to analyze the correlation of the extracted data sequences, and then self-adaptive selection was performed. A centralized strategy learning approach was employed to capture inter-sequence dependencies, followed by feature aggregation and redistribution for prediction. Finally, the proposed method was rigorously evaluated on three distinct datasets: the NASA benchmark dataset, the Oxford battery degradation dataset, and our proprietary experimental dataset. Experimental validation demonstrates that the proposed prediction method achieves superior performance, maintaining consistently high coefficients of determination for RUL estimation across all datasets. Compared with other prediction methods, the proposed approach maintains errors below 1.7 %, demonstrating superior accuracy and enhanced generalization capability.</div></div>","PeriodicalId":15942,"journal":{"name":"Journal of energy storage","volume":"132 ","pages":"Article 117875"},"PeriodicalIF":8.9,"publicationDate":"2025-07-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144721837","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Characterizing the diffusion of hydrogen and methane in rock salt formations: A comparative study of molecular dynamic simulation 表征氢和甲烷在岩盐地层中的扩散:分子动力学模拟的比较研究
IF 8.9 2区 工程技术
Journal of energy storage Pub Date : 2025-07-29 DOI: 10.1016/j.est.2025.117804
Zhuyan Zheng , Guibin Wang , Hongling Ma , Chengcheng Niu , Huandui Liu , Zhen Zeng , Hang Li , Xuan Wang , Chunhe Yang
{"title":"Characterizing the diffusion of hydrogen and methane in rock salt formations: A comparative study of molecular dynamic simulation","authors":"Zhuyan Zheng ,&nbsp;Guibin Wang ,&nbsp;Hongling Ma ,&nbsp;Chengcheng Niu ,&nbsp;Huandui Liu ,&nbsp;Zhen Zeng ,&nbsp;Hang Li ,&nbsp;Xuan Wang ,&nbsp;Chunhe Yang","doi":"10.1016/j.est.2025.117804","DOIUrl":"10.1016/j.est.2025.117804","url":null,"abstract":"<div><div>Underground hydrogen storage in salt caverns is a promising solution for large-scale storage, yet hydrogen's high diffusivity raises safety concerns compared to conventional methane storage. This study employs molecular dynamics simulations to quantitatively compare the diffusion behaviors of hydrogen and methane in nanoscale halite slit pores under typical storage conditions. Results reveal that hydrogen exhibits 6.42–12.35 times higher diffusion coefficients than methane. Attributed to hydrogen's weaker van der Waals interactions with halite surfaces, methane adsorption energy is 0.730–1.029 kcal/mol lower and accumulates 1.72–2.23 times more densely near slit pore walls, while hydrogen distributes homogeneously with secondary mid-pore density peaks. Activation energy analysis indicates methane requires 0.424–0.724 kcal/mol higher energy for diffusion. Furthermore, three components of diffusion activation energy are identified: gas-mineral interaction, spatial confinement, and gas-gas interaction. As pore size increases, gas-gas interaction dominates, with hydrogen converging to 0.915 kcal/mol and methane to 1.642 kcal/mol. Notably, hydrogen requires more energy to overcome spatial confinement in slit pores compared to methane, likely due to its smaller molecular diameter. These findings provide atomic-scale insights into gas transport mechanisms, offering critical guidance for optimizing salt cavern hydrogen storage design and leakage mitigation strategies.</div></div>","PeriodicalId":15942,"journal":{"name":"Journal of energy storage","volume":"132 ","pages":"Article 117804"},"PeriodicalIF":8.9,"publicationDate":"2025-07-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144721823","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Augmented real-time lumped-parameter model for enhanced reliability in battery management systems 提高电池管理系统可靠性的增强实时集总参数模型
IF 8.9 2区 工程技术
Journal of energy storage Pub Date : 2025-07-29 DOI: 10.1016/j.est.2025.117717
Mehrdad Babazadeh, James Marco, Mona Faraji Niri
{"title":"Augmented real-time lumped-parameter model for enhanced reliability in battery management systems","authors":"Mehrdad Babazadeh,&nbsp;James Marco,&nbsp;Mona Faraji Niri","doi":"10.1016/j.est.2025.117717","DOIUrl":"10.1016/j.est.2025.117717","url":null,"abstract":"<div><div>Accurate and computationally efficient battery management systems (BMSs) rely heavily on lumped-parameter models for real-time monitoring and control. However, these models often fail to maintain precision under rapidly fluctuating operating conditions due to limitations in conventional parameter identification methods. This paper presents a new framework that augments a modified equivalent circuit model (ECM) with a lumped-parameter thermal representation of a cell (LPTM) and a reliable real-time parameter estimation algorithm. The core novelty of the framework is the new representation of the cell and the Modified Recursive Least Squares (ModRLS) algorithm, which addresses challenges of data saturation, parameter sensitivity, and initial condition uncertainty. Simulations demonstrate a significant improvement in parameter tracking accuracy, with root mean square errors as low as 3% not only for key electrical parameters but also thermal ones. The proposed framework minimises the reliance on extensive sensor networks, offering a cost-effective and scalable solution for dynamic applications such as electric vehicles. This work lays the foundation for more reliable and longer-lasting energy storage systems through advanced monitoring.</div></div>","PeriodicalId":15942,"journal":{"name":"Journal of energy storage","volume":"132 ","pages":"Article 117717"},"PeriodicalIF":8.9,"publicationDate":"2025-07-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144721824","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Bi-level optimization of small pumped hydro systems for enhanced integration of renewable energy in hydro-electric coupling networks 小型抽水蓄能系统的二级优化,以增强水电耦合网络中可再生能源的整合
IF 8.9 2区 工程技术
Journal of energy storage Pub Date : 2025-07-29 DOI: 10.1016/j.est.2025.117709
Huibo Men, Jiajia Chen, Yanxin Wang
{"title":"Bi-level optimization of small pumped hydro systems for enhanced integration of renewable energy in hydro-electric coupling networks","authors":"Huibo Men,&nbsp;Jiajia Chen,&nbsp;Yanxin Wang","doi":"10.1016/j.est.2025.117709","DOIUrl":"10.1016/j.est.2025.117709","url":null,"abstract":"<div><div>The integration of renewable energy into rural power grids poses significant challenges, such as line overloads and voltage violations, due to the mismatch between energy supply and increasing irrigation power demands. Small pumped hydro systems (PHS) provide a viable solution by dynamically addressing this mismatch through hydro-electric coupling. We introduce a bi-level iterative optimization approach to determine the optimal capacity and coupling point of PHS, while considering the uncertainties inherent in renewable energy sources. The upper level focuses on multi-objective voltage and loss sensitivity (MoVLS) to identify potential hydro-electric coupling points, which are subsequently evaluated at the lower level. The lower level utilizes robust information gap decision theory (IGDT) to optimize PHS capacity, aiming to minimize annual costs, with feedback provided to the upper level. Our results indicate a 3.285% reduction in annual costs compared to scenarios without a PHS system. Furthermore, our method achieves a 12.08% decrease in power loss and a 45.14% reduction in voltage fluctuation, surpassing single-objective siting strategies based solely on voltage and loss sensitivity.</div></div>","PeriodicalId":15942,"journal":{"name":"Journal of energy storage","volume":"132 ","pages":"Article 117709"},"PeriodicalIF":8.9,"publicationDate":"2025-07-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144721193","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Oxygen vacancy-engineered Nb2O5-x quantum dots confined in mesoporous CMK-3 host-guest architecture for synergistic dual-regulation of polysulfide redox kinetics in lithium‑sulfur batteries 介孔CMK-3主客体结构中氧空位工程Nb2O5-x量子点对锂硫电池中多硫氧化还原动力学的协同双调控
IF 8.9 2区 工程技术
Journal of energy storage Pub Date : 2025-07-29 DOI: 10.1016/j.est.2025.117897
Qianqian Liu , Zhongyu Wang , Rui Qiu , Ruirui Wang , Miao Cheng , Tao Wei , Yuanyuan Cui , Yun Ling , Jing Hu , Wanfei Li , Bo Liu
{"title":"Oxygen vacancy-engineered Nb2O5-x quantum dots confined in mesoporous CMK-3 host-guest architecture for synergistic dual-regulation of polysulfide redox kinetics in lithium‑sulfur batteries","authors":"Qianqian Liu ,&nbsp;Zhongyu Wang ,&nbsp;Rui Qiu ,&nbsp;Ruirui Wang ,&nbsp;Miao Cheng ,&nbsp;Tao Wei ,&nbsp;Yuanyuan Cui ,&nbsp;Yun Ling ,&nbsp;Jing Hu ,&nbsp;Wanfei Li ,&nbsp;Bo Liu","doi":"10.1016/j.est.2025.117897","DOIUrl":"10.1016/j.est.2025.117897","url":null,"abstract":"<div><div>Defect engineering has emerged as a scalable strategy to address the lithium polysulfides (LiPSs) shuttling and sluggish reaction kinetics in lithium‑sulfur (Li<img>S) batteries. However, the relationship among defect structure, material architecture, and polysulfide redox kinetics remains insufficiently explored. Herein, Oxygen vacancy-engineered Nb<sub>2</sub>O<sub>5-x</sub> quantum dots confined within an ordered mesoporous tubular carbon (CMK-3) host-guest architecture, designed as Nb<sub>2</sub>O<sub>5-x</sub>@CMK-3, was successfully developed as a functional separator for Li<img>S batteries. The developed confinement strategy effectively suppresses the aggregation of Nb<sub>2</sub>O<sub>5-x</sub> quantum dots through spatial restriction within CMK-3 channels, and constructs a matrix integrating physical confinement with defect-mediated chemical interactions. This effectively regulates the deposition and conversion processes of sulfur, inhibits the shuttling of LiPSs, and promotes the kinetics of the sulfur electrode conversion reactions. Through the synergism of physical confinement, chemical adsorption, and catalytic conversion, the Li<img>S batteries assembled with the Nb<sub>2</sub>O<sub>5-x</sub>@CMK-3 modified separators not only exhibit remarkable electrochemical performance but also achieve favorable stability under a high sulfur loading of 4.1 mg cm<sup>−2</sup>. This work has great potential in the development of multi-functional intermediate layers for high-performance Li<img>S batteries.</div></div>","PeriodicalId":15942,"journal":{"name":"Journal of energy storage","volume":"132 ","pages":"Article 117897"},"PeriodicalIF":8.9,"publicationDate":"2025-07-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144721822","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Advancing thermal runaway modeling in lithium-ion batteries: A review of heat source models, thermodynamic frameworks, and microkinetic approaches 锂离子电池热失控模型的发展:热源模型、热力学框架和微动力学方法综述
IF 8.9 2区 工程技术
Journal of energy storage Pub Date : 2025-07-29 DOI: 10.1016/j.est.2025.117762
Mostafa M.E.H. Ali , Maryam Ghodrat , Wei Wang
{"title":"Advancing thermal runaway modeling in lithium-ion batteries: A review of heat source models, thermodynamic frameworks, and microkinetic approaches","authors":"Mostafa M.E.H. Ali ,&nbsp;Maryam Ghodrat ,&nbsp;Wei Wang","doi":"10.1016/j.est.2025.117762","DOIUrl":"10.1016/j.est.2025.117762","url":null,"abstract":"<div><div>Heat sources models for modeling exothermic chemical reactions during thermal abuse in lithium-ion batteries (LIBs) have become widely used to assess the safety of LIBs by predicting rises in temperature and heat transfer, as well as pressure accumulation and ignition behavior. These Conventional models have progressed significantly in terms of forecasting the initial stages, limitations, and spread of the thermal runaway (TR). However, these models have some drawbacks. Originally, these models were material-specific, assumed breakdown products a priori and failed to forecast rapid heat release above ~450 K. Additionally, the accuracy of sub-models of thermal abuse, such as venting and combustion models, is dependent on decomposition models' ability to predict temperature and gas evolution. This review provides valuable guidance for researchers involved in the development of TR models for LIBs. By highlighting the limitations of existing models and presenting innovative approaches, it offers a roadmap for advancing the state-of-the-art in this field. This review discusses upgraded traditional models and novel approaches that refine and extend prior models for exothermic reactions during TR. In general, there are two primary approaches: legacy modeling employing empirical equations and innovative approaches including thermodynamic and microkinetic approaches, for modeling thermal abuse often known as exothermic reactions. Micro-kinetic modeling enhances modeling skills by predicting flammable gas generation while Thermodynamic models can be employed to quantitatively quantify heat production under a variety of failure conditions, including Li-ion batteries, and solid-state batteries. Emphasizing the integration of micro-kinetic and thermodynamic modeling techniques is vital to enhance predictive accuracy and achieve a more comprehensive understanding of failure mechanisms particularly at large scale applications.</div></div>","PeriodicalId":15942,"journal":{"name":"Journal of energy storage","volume":"132 ","pages":"Article 117762"},"PeriodicalIF":8.9,"publicationDate":"2025-07-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144721840","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
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