Journal of energy storage最新文献

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Numerical investigation of enhanced battery thermal management system performance using radial fin-intensified phase change material: Focus on latent heat contribution 采用径向翅片强化相变材料增强电池热管理系统性能的数值研究:关注潜热贡献
IF 8.9 2区 工程技术
Journal of energy storage Pub Date : 2025-10-14 DOI: 10.1016/j.est.2025.118799
Beyzanur Yavuz Abanoz , Müslüm Arıcı
{"title":"Numerical investigation of enhanced battery thermal management system performance using radial fin-intensified phase change material: Focus on latent heat contribution","authors":"Beyzanur Yavuz Abanoz ,&nbsp;Müslüm Arıcı","doi":"10.1016/j.est.2025.118799","DOIUrl":"10.1016/j.est.2025.118799","url":null,"abstract":"<div><div>Electric vehicles (EVs), which are critical in controlling carbon emissions and protecting ecological harmony and human well-being, are reinforcing their key role in the transportation sector. However, EV batteries can ensure high performance, prolonged service life, and safe driving only with proper and effective battery thermal management systems (BTMSs). The focus and major contribution of this study to literature is to reveal the role of phase change material's (PCM's) latent heat to the thermal performance of batteries, differentiating the latent heat from the overall thermal energy storage capacity which includes both sensible and latent heat. For that purpose, the phase stable material approach, which is a material with the identical thermophysical properties as PCM but does not undergo phase transformation, was applied. In the study, aluminum radial fin intensified approaches are utilized to enhance the thermal performance of PCM-based BTMS. Additionally to the reference model adding only PCM, 3 different simulation scenarios were analyzed: i) PCM + 1 fin (Design-I), ii) PCM + 3 fins (Design-II), iii) PCM + 5 fins (Design-III). The study was conducted under 5C discharge conditions by integrating 3 different PCMs (RT31, RT38, and RT42) and the impacts of fin distribution, fin dimensions, and housing diameters on thermal behavior of PCM and maximum temperature of battery were numerically studied. The results revealed that the fins enhanced the low thermal conductivity of the PCM by increasing the heat transfer area and can be further improved depending on the intensification of the fins. The refinement of the fin distribution accelerated heat transfer. Compared to the reference case, the temperature decrease was approximately 23.22 %, 12.64 %, and 11.12 % for RT31, RT38, and RT42 in Design-III, respectively. The increase in fin length led to a temperature reduction of up to 2.23 °C, demonstrating greater effectiveness compared to the increase in fin thickness. Reducing the inner diameter of the housing from 34 mm to 26 mm slightly increased the temperature values, but the influence on the liquid fraction was considerable. At the end of the discharge process, the liquid fraction reached from 36 % to 89 %, 28 % to 76 % and 19 % to 65 % for RT31, RT38, and RT42, respectively. Contribution of latent heat in reducing the temperature was 21.94 % in the reference case, 23.51 % in Design-I, 25.4 % in Design-II, and 33.62 % in Design-III.</div></div>","PeriodicalId":15942,"journal":{"name":"Journal of energy storage","volume":"139 ","pages":"Article 118799"},"PeriodicalIF":8.9,"publicationDate":"2025-10-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145290070","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Design of phase change materials with radially assembled 3D boron nitride network for enhanced thermal energy storage 径向组装三维氮化硼网络相变材料的设计
IF 8.9 2区 工程技术
Journal of energy storage Pub Date : 2025-10-14 DOI: 10.1016/j.est.2025.118881
Kerui Huang , Yijun Liu , Qinglong Yu , Wanlin Han , Baoshu Chen , Longfei Yi
{"title":"Design of phase change materials with radially assembled 3D boron nitride network for enhanced thermal energy storage","authors":"Kerui Huang ,&nbsp;Yijun Liu ,&nbsp;Qinglong Yu ,&nbsp;Wanlin Han ,&nbsp;Baoshu Chen ,&nbsp;Longfei Yi","doi":"10.1016/j.est.2025.118881","DOIUrl":"10.1016/j.est.2025.118881","url":null,"abstract":"<div><div>Phase Change Materials (PCMs) have attracted significant attention due to their high latent heat and isothermal phase transition properties. However, their large-scale application in daily life has been limited by challenges such as low thermal conductivity and insufficient shape stability during phase transitions. In this study, boron nitride (BN) and chitosan (CS) aerogels were employed as 3D skeleton materials using an ice-templating method, where the controlled growth of ice crystals in radial pattern enabled the ordered alignment of thermally conductive fillers. A paraffin-based composite material was successfully fabricated. Compared with pure paraffin, the incorporation of only 15.11 vol% BN resulted in a 1944.5 % increase in thermal conductivity (4.089 W/mK). Furthermore, this value was 59.54 % higher than that of composites with randomly dispersed BN at the same concentration. Consequently, the composite exhibited excellent thermal cycling stability, a latent heat storage capacity exceeding 175.8 J/g, and effective leakage prevention at high temperatures, while maintaining an ultrahigh electrical resistivity (2.3 × 10<sup>11</sup> Ω·cm) and low dielectric loss. This work presents an innovative approach for developing thermally conductive and shape-stable composite PCMs for energy storage applications.</div></div>","PeriodicalId":15942,"journal":{"name":"Journal of energy storage","volume":"139 ","pages":"Article 118881"},"PeriodicalIF":8.9,"publicationDate":"2025-10-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145290048","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Nitrogen-modified Ti3C2 MXene with enhanced catalytic activity for efficient hydrogen storage in MgH2 氮修饰ti3c2mxene在MgH2中高效储氢的催化活性增强
IF 8.9 2区 工程技术
Journal of energy storage Pub Date : 2025-10-14 DOI: 10.1016/j.est.2025.118880
Ruyi Guo , Zhenluo Yuan , Yitian Wu , Hanxi He , Yaojie Zhang , Haiwen Li , Qiuming Peng , Shumin Han , Yanping Fan , Baozhong Liu
{"title":"Nitrogen-modified Ti3C2 MXene with enhanced catalytic activity for efficient hydrogen storage in MgH2","authors":"Ruyi Guo ,&nbsp;Zhenluo Yuan ,&nbsp;Yitian Wu ,&nbsp;Hanxi He ,&nbsp;Yaojie Zhang ,&nbsp;Haiwen Li ,&nbsp;Qiuming Peng ,&nbsp;Shumin Han ,&nbsp;Yanping Fan ,&nbsp;Baozhong Liu","doi":"10.1016/j.est.2025.118880","DOIUrl":"10.1016/j.est.2025.118880","url":null,"abstract":"<div><div>The practical implementation of MgH<sub>2</sub> is impeded by its slow kinetics. Herein, surface engineering of Ti<sub>3</sub>C<sub>2</sub> via nitrogen doping was employed to synthesize nitrogen-doped Ti<sub>3</sub>C<sub>2</sub> (N-Ti<sub>3</sub>C<sub>2</sub>) and improve the hydrogen storage properties of MgH<sub>2</sub>. The results reveal that N-Ti<sub>3</sub>C<sub>2</sub> prepared at 600 °C (denoted as N-Ti<sub>3</sub>C<sub>2</sub>-600) possesses superior catalytic performance compared to pristine Ti<sub>3</sub>C<sub>2</sub>. The initial hydrogen liberation temperature is reduced from 287 °C (for pure MgH<sub>2</sub>) to 169 °C for MgH<sub>2</sub> with N-Ti<sub>3</sub>C<sub>2</sub>-600. In addition, MgH<sub>2</sub> + 5 wt% N-Ti<sub>3</sub>C<sub>2</sub>-600 can rapidly desorb 7.0 wt% H<sub>2</sub> in 10 min at 240 °C, and absorb 5.4 wt% H<sub>2</sub> in 100 min at 50 °C. Moreover, the dehydrogenation activation energy of MgH<sub>2</sub> doped with N-Ti<sub>3</sub>C<sub>2</sub>-600 is 78.90 kJ/mol, demonstrating superior kinetics. Microscopic analysis demonstrates that the uniformly distributed and stable titanium species (Ti<sup>0</sup> and Ti<sup>2+</sup>) and nitrogen species (C=N), along with their interaction, contribute to the enhanced kinetics and cyclic stability of MgH<sub>2</sub>. This research presents a viable approach to developing MXene-based catalysts for solid-state hydrogen storage.</div></div>","PeriodicalId":15942,"journal":{"name":"Journal of energy storage","volume":"139 ","pages":"Article 118880"},"PeriodicalIF":8.9,"publicationDate":"2025-10-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145290062","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
The reaction wave analysis in an open adsorption thermal energy storage reactor 开放式吸附式储热反应器反应波分析
IF 8.9 2区 工程技术
Journal of energy storage Pub Date : 2025-10-14 DOI: 10.1016/j.est.2025.118886
Shichao Gao , Shugang Wang , Peiyu Hu , Wenzhuo Zhang , Jihong Wang
{"title":"The reaction wave analysis in an open adsorption thermal energy storage reactor","authors":"Shichao Gao ,&nbsp;Shugang Wang ,&nbsp;Peiyu Hu ,&nbsp;Wenzhuo Zhang ,&nbsp;Jihong Wang","doi":"10.1016/j.est.2025.118886","DOIUrl":"10.1016/j.est.2025.118886","url":null,"abstract":"<div><div>Adsorption thermal energy storage (ATES) is one of the most promising approaches to achieve efficient utilization of solar energy. The available sorption reaction wave model reveals the mechanism of heat transfer in the reactor during the adsorption process. However, the model can only be used to identify whether a reactor can provide stable output. In this paper, the expressions used to quantify the general performance of the ATES reactor were derived with the wave parameters of adsorption reaction waves. To analyze the distributions of air temperature and moisture concentration in the ATES reactor, an experimental bench was built and a numerical model was developed. It was found that the temperature gradient, the negative of the concentration gradient and the adsorption rate in the reactor all presented the characteristics of a reaction wave. The predictions by the proposed expressions were in agreement with the experimental data with the maximum relative error less than 6.5 %. The proposed method achieves a fast estimation of the thermal performance of reactor from a new perspective.</div></div>","PeriodicalId":15942,"journal":{"name":"Journal of energy storage","volume":"139 ","pages":"Article 118886"},"PeriodicalIF":8.9,"publicationDate":"2025-10-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145290045","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Multi-objective identification of a metal hydride tank lumped parameter model 金属氢化物储罐集总参数模型的多目标辨识
IF 8.9 2区 工程技术
Journal of energy storage Pub Date : 2025-10-10 DOI: 10.1016/j.est.2025.118759
Mingrui Chen , Carles Batlle , Bryan Escachx , Ramon Costa-Castelló , Jing Na
{"title":"Multi-objective identification of a metal hydride tank lumped parameter model","authors":"Mingrui Chen ,&nbsp;Carles Batlle ,&nbsp;Bryan Escachx ,&nbsp;Ramon Costa-Castelló ,&nbsp;Jing Na","doi":"10.1016/j.est.2025.118759","DOIUrl":"10.1016/j.est.2025.118759","url":null,"abstract":"<div><div>In this paper, a third-order state–space model of the metal hydride tank is formulated and analysed. Before the identification of the unknown parameters of the model, we first analysed their identifiability, i.e., whether we can obtain a unique unknown parameter vector from the available information. Secondly, due to the large number of unknown parameters in the proposed model, the identification of all the unknown parameters requires huge computational costs. In order to reduce the number of unknown parameters that need to be identified, we performed a sensitivity analysis of unknown parameters for the developed model. Finally, since the model has two outputs, we performed single-objective and multi-objective identification on the same experimental data, and the results show that multi-objective identification is more effective.</div></div>","PeriodicalId":15942,"journal":{"name":"Journal of energy storage","volume":"139 ","pages":"Article 118759"},"PeriodicalIF":8.9,"publicationDate":"2025-10-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145270798","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
A comprehensive framework for harnessing energy arbitrage benefits through an electric vehicle aggregator 通过电动汽车聚合器利用能源套利利益的综合框架
IF 8.9 2区 工程技术
Journal of energy storage Pub Date : 2025-10-10 DOI: 10.1016/j.est.2025.118617
Adlan Pradana, M.M. Haque, Mithulananthan Nadarajah
{"title":"A comprehensive framework for harnessing energy arbitrage benefits through an electric vehicle aggregator","authors":"Adlan Pradana,&nbsp;M.M. Haque,&nbsp;Mithulananthan Nadarajah","doi":"10.1016/j.est.2025.118617","DOIUrl":"10.1016/j.est.2025.118617","url":null,"abstract":"<div><div>This paper proposes a comprehensive framework for an EV aggregator to operate as an energy arbitrage entity, aiming to provide a steady income stream to EV owners while reducing grid stress by maximising the system's Load Factor (LF). The framework integrates spatial EV behaviour analysis, machine learning-based forecasting of electricity demand and prices, and a two-stage optimisation process. The first stage utilises Mixed-Integer Linear Programming (MILP) to optimise charging and discharging schedules, thereby maximising EV owner revenue. The second stage employs Gradient-Based Sequential Quadratic Programming (GD-SQP) to optimise the number of participating EVs for grid benefits. The model is built on real-world data from Queensland, Australia, including EV mobility derived from travel surveys and historical 5-minute resolution data from the National Electricity Market. Forecasting performance indicates that the Fine Tree Algorithm (FTA) is most effective for electricity demand prediction, while the Ensemble Bagged Tree Algorithm (EBTA) performs best for price forecasting. Simulation results on the IEEE 9-bus and 39-bus systems validate the framework's performance. In the 9-bus system, LF improves by up to 6.08 % in the H-EV Over-optimum scenario. In contrast, HW-EV scenarios yield reduced LF due to misalignment between revenue-optimised dispatch and system objectives. In contrast, the 39-bus results show that HW-EV Optimum can achieve up to 6.2 % LF improvement, highlighting the influence of grid topology and spatial flexibility. The framework also achieves up to 6.08 % reduction in transmission loss, with additional benefits including peak load shifting, deferred infrastructure investment, and increased revenue for aggregators. An important finding is that longer EV connection durations, as in HW-EV cases, do not guarantee better grid performance due to a trade-off inherent in the two-stage optimisation. These results confirm that EV participation must be carefully managed to strike a balance between economic and technical objectives. Overall, this study demonstrates that data-driven EV coordination, supported by forecasting and dual optimisation, can unlock substantial benefits for both EV owners and the power grid in future smart energy systems.</div></div>","PeriodicalId":15942,"journal":{"name":"Journal of energy storage","volume":"139 ","pages":"Article 118617"},"PeriodicalIF":8.9,"publicationDate":"2025-10-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145270845","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Experimental insights into surface wettability alterations and solvent adsorption effects on porous sandstone and carbonate rocks in H₂-brine systems: Implications for underground hydrogen storage 氢-盐水体系中多孔砂岩和碳酸盐岩表面润湿性变化和溶剂吸附效应的实验研究:对地下储氢的影响
IF 8.9 2区 工程技术
Journal of energy storage Pub Date : 2025-10-10 DOI: 10.1016/j.est.2025.118808
Aneeq Nasir Janjua , Muhammad Ali , Muhammad Shahzad Kamal , Shirish Patil , Hussein Hoteit , Arshad Raza , Mohamed Mahmoud , Muhammad Younas
{"title":"Experimental insights into surface wettability alterations and solvent adsorption effects on porous sandstone and carbonate rocks in H₂-brine systems: Implications for underground hydrogen storage","authors":"Aneeq Nasir Janjua ,&nbsp;Muhammad Ali ,&nbsp;Muhammad Shahzad Kamal ,&nbsp;Shirish Patil ,&nbsp;Hussein Hoteit ,&nbsp;Arshad Raza ,&nbsp;Mohamed Mahmoud ,&nbsp;Muhammad Younas","doi":"10.1016/j.est.2025.118808","DOIUrl":"10.1016/j.est.2025.118808","url":null,"abstract":"<div><div>The hydrogen (H₂) economy promises a transformative shift toward clean energy and environmental sustainability. However, its large-scale implementation relies on efficient, safe, and economical storage systems. While underground hydrogen storage (UHS) in porous media presents a viable solution, the H₂ wettability behavior of rocks under various geological conditions remains poorly understood, particularly regarding surface roughness and solvent-induced wettability alterations upon adsorption. Therefore, the present study investigates the wettability and adsorption effects of various solvents on porous sandstone and carbonate rocks in H₂/brine systems under various pressure (0.1–20 MPa) and temperature (293–343 K) conditions. Experiments are conducted using the tilted plate method to measure the advancing (θ<sub>a</sub>) and receding (θ<sub>r</sub>) contact angles both before and after exposing the substrates to organic solvents mixed with stearic acid. The results reveal that the wettability of sandstone increases with rising pressure and temperature, thereby enhancing the H₂ wettability under reservoir conditions. By contrast, the wettability of carbonate increases with pressure but decreases with the increase in temperature. Hence, these results highlight the importance of mineralogical composition along with the influence of temperature, pressure, surface roughness, and organic acids on solvent adsorption. Moreover, these findings highlight the critical role of H₂ wettability and rock-fluid interactions for optimizing the fluid flow, capillary trapping, and efficiency of the UHS system. This study presents significant implications for H<sub>2</sub> storage potential and containment strategies, and supports the industrial-scale deployment of UHS in sandstone and carbonate formations.</div></div>","PeriodicalId":15942,"journal":{"name":"Journal of energy storage","volume":"139 ","pages":"Article 118808"},"PeriodicalIF":8.9,"publicationDate":"2025-10-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145270981","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Nanocellulose/N, P dual-doped graphene composites coupled with aqueous and a sodium alginate-based electrolyte for supercapacitors application 纳米纤维素/N, P双掺杂石墨烯复合材料与水电解质和海藻酸钠电解质耦合用于超级电容器
IF 8.9 2区 工程技术
Journal of energy storage Pub Date : 2025-10-10 DOI: 10.1016/j.est.2025.118824
Tiantian Yu , Yong Zhang , Wenhui Ma , Xuefeng Wang , Chaohui Wang , Shan Fan
{"title":"Nanocellulose/N, P dual-doped graphene composites coupled with aqueous and a sodium alginate-based electrolyte for supercapacitors application","authors":"Tiantian Yu ,&nbsp;Yong Zhang ,&nbsp;Wenhui Ma ,&nbsp;Xuefeng Wang ,&nbsp;Chaohui Wang ,&nbsp;Shan Fan","doi":"10.1016/j.est.2025.118824","DOIUrl":"10.1016/j.est.2025.118824","url":null,"abstract":"<div><div>In this paper, innovative solutions are proposed to solve the problem of gravimetric/volumetric performance imbalance in graphene-based electrodes, as well as the technical challenges faced by existing gel electrolytes, such as poor water retention, low ion transport efficiency, and limited temperature adaptability. Herein, Nanocellulose/N, P dual-doped graphene composites (NNPGs) were successfully prepared by the hydrothermal process with graphene oxide (GO), nanocellulose (NC), and triammonium phosphate as precursors. In addition, using sodium alginate (SA), GO, NC, and KOH as starting materials, a new gel electrolyte material (SGNK) with renewable capacity, broad operating temperature range, and excellent water retaining ability was successfully synthesized. Benefiting from the good porous structure, excellent pseudocapacitive properties, and high bulk density of NNPGs, the aqueous symmetric supercapacitor based on NNPG20 exhibits high gravimetric and volumetric specific capacitance (288.2 F g<sup>−1</sup>, 409.2 F cm<sup>−3</sup>), good rate capability, and favorable cycle stability. More importantly, the flexible solid-state supercapacitors (FSSCs) fabricated with SGNK and NNPGs deliver high specific capacitance (216.8 F g<sup>−1</sup>), benign renewable performance, excellent bending resistance, and a wide operating temperature range. In summary, the SGNK and NNPGs developed in this work have important reference value for the design of advanced energy storage devices.</div></div>","PeriodicalId":15942,"journal":{"name":"Journal of energy storage","volume":"139 ","pages":"Article 118824"},"PeriodicalIF":8.9,"publicationDate":"2025-10-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145271363","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Unlocking the potential of highly stable pseudocapacitive performance in asymmetric SnS/Graphite||AC hybrid supercapacitors via hydrothermal method 通过水热法解锁非对称SnS/石墨||交流混合超级电容器高稳定赝电容性能的潜力
IF 8.9 2区 工程技术
Journal of energy storage Pub Date : 2025-10-10 DOI: 10.1016/j.est.2025.118809
Nivin Thulasibai Sasidharan , Varun Karthik Murugesan , Aashna Sharin Manoharan , Kamala Bharathi Karuppanan , Karthigeyan Annamalai
{"title":"Unlocking the potential of highly stable pseudocapacitive performance in asymmetric SnS/Graphite||AC hybrid supercapacitors via hydrothermal method","authors":"Nivin Thulasibai Sasidharan ,&nbsp;Varun Karthik Murugesan ,&nbsp;Aashna Sharin Manoharan ,&nbsp;Kamala Bharathi Karuppanan ,&nbsp;Karthigeyan Annamalai","doi":"10.1016/j.est.2025.118809","DOIUrl":"10.1016/j.est.2025.118809","url":null,"abstract":"<div><div>Tin-based chalcogenides are promising materials for energy storage but are hindered by intrinsic low conductivity and structural instability. Here, we report a high-performance tin sulfide/graphite (SnS/G) composite that addresses these challenges by strategically incorporating graphite into the SnS matrix. Graphite enhances electrical conductivity, alters the interlayer spacings and provides a stress-buffering network, significantly improving the composite's electrochemical stability. The SnS/G composite, fabricated via a cost-effective hydrothermal method, exhibits a micro-rod morphology with high surface area and excellent ionic transport properties. Electrochemical characterisation of the SnS/G electrode in half-cell configuration reveals a remarkable specific capacitance of 411.6 F/g at 1 A/g and exceptional cycling stability, retaining 96 % of its initial capacitance after 1200 cycles. When assembled into an asymmetric supercapacitor (ASC) with activated carbon (AC) (SnS/G||AC (1.0 V)), the device achieves a specific capacitance of 187 F/g. Along with an energy density of 26.03 Wh/kg, a power density of 5000 W/kg and outstanding long-term stability with 86 % retention after 25,000 cycles for the full cell is achieved. For SnS/G 10 %|| AC (1.5 V) device delivers an energy density of 39.50 Wh/kg and a power density of 7500 W/kg, with 92 % retention after 6000 cycles. These findings underscore the promise of SnS/G composites as scalable, low-cost, high-performance electrodes for next-generation energy storage systems.</div></div>","PeriodicalId":15942,"journal":{"name":"Journal of energy storage","volume":"139 ","pages":"Article 118809"},"PeriodicalIF":8.9,"publicationDate":"2025-10-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145270979","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Harnessing off-peak renewable electricity via resistive heating in solar salt based latent heat storage: Performance enhancement through fins and shell configurations 通过太阳能盐基潜热储存中的电阻加热利用非峰值可再生电力:通过翅片和外壳配置增强性能
IF 8.9 2区 工程技术
Journal of energy storage Pub Date : 2025-10-10 DOI: 10.1016/j.est.2025.118573
Mallayya Swami , K. Ravi Kumar , Dibakar Rakshit
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