Journal of Energy Chemistry最新文献

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Polymer molecule as nucleating agent to modulate crystallization kinetics for efficient and stable organic solar cells 聚合物分子作为成核剂调控高效稳定有机太阳能电池结晶动力学
IF 14.9 1区 化学
Journal of Energy Chemistry Pub Date : 2025-09-16 DOI: 10.1016/j.jechem.2025.08.094
Xiaoyang Du , Luye Cao , Jia Zhu , Xinrui Li , Hui Lin , Gang Yang , Caijun Zheng , Silu Tao
{"title":"Polymer molecule as nucleating agent to modulate crystallization kinetics for efficient and stable organic solar cells","authors":"Xiaoyang Du ,&nbsp;Luye Cao ,&nbsp;Jia Zhu ,&nbsp;Xinrui Li ,&nbsp;Hui Lin ,&nbsp;Gang Yang ,&nbsp;Caijun Zheng ,&nbsp;Silu Tao","doi":"10.1016/j.jechem.2025.08.094","DOIUrl":"10.1016/j.jechem.2025.08.094","url":null,"abstract":"<div><div>The crystallization and aggregation characteristics of the active layer components in organic solar cells (OSCs) are one of the core factors determining photovoltaic performance, influencing the entire process from light absorption to charge separation, transport, and ultimately charge collection. Dynamic changes in crystallization and aggregation states can also disrupt the microstructure of the active layer, thus shortening the lifetime of the cell. In this study, a morphology modulation strategy is proposed to regulate the crystallization kinetics of non-fullerene acceptors by employing the polymer molecule PYIT as a nucleating agent. An appropriate amount of PYIT was first completely dissolved with the non-fullerene acceptor Y6 and left to stand for 24 h, followed by the fabrication of layer-by-layer processed OSCs. Experiments demonstrated that high crystallinity of PYIT allows it to act as a crystallization nucleus, promoting the crystallization, orientation consistency, and ordered stacking of the acceptor. These nanoscale structural optimizations facilitate efficient charge transport, enhance exciton dissociation efficiency, and suppress unfavorable energetic disorder. Consequently, not only was the power conversion efficiency (PCE) of D18-Cl/Y6-based layer-by-layer processed OSC increased from 18.08 % to 19.13 %, but the atmospheric stability and long-term lifetime of the OSCs were also significantly improved. Notably, this strategy is also applicable to indoor OSCs, and the PYIT-optimized device can achieve a PCE of 27.0 % under 1000 lux light-emitting diode (LED, 3200K) irradiation, which is superior to that of the control device (24.2 %). This work develops a crystal engineering strategy that is able to simultaneously optimize the microscopic morphology and charge dynamics properties in OSCs, thereby achieving simultaneous improvement in efficiency and stability.</div></div>","PeriodicalId":15728,"journal":{"name":"Journal of Energy Chemistry","volume":"112 ","pages":"Pages 770-777"},"PeriodicalIF":14.9,"publicationDate":"2025-09-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145156423","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Dynamic control of crystallization rate enables efficient sodium storage in coal-based hard carbon: synergistic effects of short-range ordered structure and closed pores 动态控制结晶速率可使煤基硬碳高效储钠:近程有序结构和封闭孔隙的协同作用
IF 14.9 1区 化学
Journal of Energy Chemistry Pub Date : 2025-09-16 DOI: 10.1016/j.jechem.2025.08.091
Rui Li , Anjun Hu , Zhen Wang , Wei Yang , Qin He , Weiyue Li , Liangzhi Li , Wei Jiao , Beilei Yuan , Jian Chen , Fei Li , Jianping Long
{"title":"Dynamic control of crystallization rate enables efficient sodium storage in coal-based hard carbon: synergistic effects of short-range ordered structure and closed pores","authors":"Rui Li ,&nbsp;Anjun Hu ,&nbsp;Zhen Wang ,&nbsp;Wei Yang ,&nbsp;Qin He ,&nbsp;Weiyue Li ,&nbsp;Liangzhi Li ,&nbsp;Wei Jiao ,&nbsp;Beilei Yuan ,&nbsp;Jian Chen ,&nbsp;Fei Li ,&nbsp;Jianping Long","doi":"10.1016/j.jechem.2025.08.091","DOIUrl":"10.1016/j.jechem.2025.08.091","url":null,"abstract":"<div><div>Coal-derived hard carbon (HC) represents a promising anode material for sodium-ion batteries owing to its cost-effectiveness and high carbon yield. However, conventional carbonization induces excessive graphitization, yielding insufficient interlayer spacing (<em>d</em><sub>002</sub> &lt; 0.37 nm) and underdeveloped closed pores. Herein, we propose a dynamic crystallization control strategy through carbothermal shock treatment (1300 °C, 30 s) that decouples thermodynamic and kinetic constraints. This method precisely modulates graphite domain ordering kinetics, producing short-range ordered structures with expanded interlayer spacing (<em>d</em><sub>002</sub> = 0.385 nm) and homogeneously distributed closed nanopores. Through combined in situ characterization and first-principles calculations, we elucidate a three-stage crystallization mechanism: (i) amorphous carbon transformation, (ii) open-pore collapse, and (iii) pseudo-graphitic ordering. The optimized HC achieves record performance with 88.6 % initial Coulombic efficiency and 204 mA h g<sup>−1</sup> plateau capacity, while its optimal interlayer spacing lowers Na<sup>+</sup> diffusion barriers to enable exceptional rate capability (221 mA h g<sup>−1</sup> at 0.5C after 300 cycles). Practical pouch cells maintain 85 % capacity retention after 100 cycles at −20 °C and deliver 284 Wh kg<sup>−1</sup> energy density. This work establishes a kinetic regulation paradigm for graphitization-prone precursors, advancing the rational design of high-performance HC anodes.</div></div>","PeriodicalId":15728,"journal":{"name":"Journal of Energy Chemistry","volume":"112 ","pages":"Pages 832-841"},"PeriodicalIF":14.9,"publicationDate":"2025-09-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145269018","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Geometric-electronic shielding effect: Steering the glycerol electrooxidation on PdBi catalysts toward selective value-added organic products 几何-电子屏蔽效应:引导甘油在PdBi催化剂上的电氧化向着选择性高附加值有机产品发展
IF 14.9 1区 化学
Journal of Energy Chemistry Pub Date : 2025-09-14 DOI: 10.1016/j.jechem.2025.09.004
Yipeng Nie , Zipei Cui , Longquan Deng , Zhuo Li , Shuo Chen , Wenchao Sheng
{"title":"Geometric-electronic shielding effect: Steering the glycerol electrooxidation on PdBi catalysts toward selective value-added organic products","authors":"Yipeng Nie ,&nbsp;Zipei Cui ,&nbsp;Longquan Deng ,&nbsp;Zhuo Li ,&nbsp;Shuo Chen ,&nbsp;Wenchao Sheng","doi":"10.1016/j.jechem.2025.09.004","DOIUrl":"10.1016/j.jechem.2025.09.004","url":null,"abstract":"<div><div>Electrocatalytic oxidation of glycerol for value-added chemicals is a superior strategy to utilize the excess glycerol produced in the biodiesel industry. Pd is one of the few active catalysts for alkaline glycerol oxidation reaction (GOR); however, glycerol inevitably dissociates and converts to carbon dioxide on the Pd surface, which results in its low total Faradaic efficiency (FE) for high-value-added products. Herein, a series of Pd/C and Pd<sub>10</sub>Bi<em><sub>x</sub></em>/C catalysts were synthesized to investigate the GOR pathway. The Pd<sub>10</sub>Bi<sub>3</sub>/C catalyst with optimal Bi content achieved an excellent GOR mass activity of 7.5±0.2 A mg<sub>Pd</sub><sup>−1</sup> and an outstanding total FE of 90 %±3 %, which are much higher than those values on Pd/C (1.2±0.2 A mg<sub>Pd</sub><sup>−1</sup> for mass activity and 63 %±4 % for total FE). Combined results of in-situ attenuated total reflection surface enhanced infrared absorption spectroscopy and density functional theory calculations show that Bi suppresses the dissociation of glycerol through the “shielding effect” of Bi to the adjacent Pd sites, which weakens the adsorption strength of GOR intermediates on those sites. This work provides a new insight into the GOR mechanism and puts forward a valid strategy for the rational design of catalysts to enable the transformation of glycerol into high-value-added products.</div></div>","PeriodicalId":15728,"journal":{"name":"Journal of Energy Chemistry","volume":"112 ","pages":"Pages 814-825"},"PeriodicalIF":14.9,"publicationDate":"2025-09-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145156488","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
In-situ collaborative design of crosslinking and fluorination toward poly(1,3-dioxolane) for high-performance semi-solid lithium metal batteries 高性能半固态锂金属电池中聚(1,3-二恶烷)交联和氟化的原位协同设计
IF 14.9 1区 化学
Journal of Energy Chemistry Pub Date : 2025-09-14 DOI: 10.1016/j.jechem.2025.08.090
Dezhi Yang , Yaqiong Zhu , Yanan Yang , Yiyang Sun , Tao Zhang
{"title":"In-situ collaborative design of crosslinking and fluorination toward poly(1,3-dioxolane) for high-performance semi-solid lithium metal batteries","authors":"Dezhi Yang ,&nbsp;Yaqiong Zhu ,&nbsp;Yanan Yang ,&nbsp;Yiyang Sun ,&nbsp;Tao Zhang","doi":"10.1016/j.jechem.2025.08.090","DOIUrl":"10.1016/j.jechem.2025.08.090","url":null,"abstract":"<div><div>In-situ poly(1,3-dioxolane) (PDOL)-based electrolyte has received extensive attention in the research of lithium metal batteries due to its high stability to lithium anode and simple processing. However, it is still faced with defects such as low intrinsic ionic conductivity, a narrow electrochemical window, and poor thermal stability. A crosslinking and fluorination molecular design strategy toward PDOL is proposed to tackle the issues above. The amorphous crosslinked structure effectively improves ionic conductivity by inhibiting long-chain crystallization. Especially, the antioxidant –CF<sub>3</sub> groups, stable crosslinked structure, and reduced terminal hydroxyl groups significantly enhance the electrochemical oxidation stability with a superb high-voltage window of 4.7 V. In addition, the designed electrolyte also exhibits obviously improved thermal stability with no deformation at 120 °C for 5 min. Furthermore, the semi-solid NCM811||Li batteries exhibit a favourable capacity retention of 88.8 % after 150 cycles at 0.5 C. Even assembled with NCM622 cathode working at 4.5 V, the semi-solid batteries can still show a satisfactory capacity retention of 85.3 % after 100 cycles at 0.5 C. Also, a 0.1 Ah NCM811||Li pouch cell with active materials loading of 9 mg/cm<sup>2</sup> demonstrates satisfactory cycling stability and working ability, which shows promising practical application prospects.</div></div>","PeriodicalId":15728,"journal":{"name":"Journal of Energy Chemistry","volume":"112 ","pages":"Pages 880-890"},"PeriodicalIF":14.9,"publicationDate":"2025-09-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145268387","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Multi-dimensional optimization of polymer-involved Li+ solvation enabling stable polymer plastic crystal electrolyte for long-cycle lithium metal batteries 聚合物参与的Li+溶剂化的多维优化使长循环锂金属电池稳定的聚合物塑料晶体电解质
IF 14.9 1区 化学
Journal of Energy Chemistry Pub Date : 2025-09-13 DOI: 10.1016/j.jechem.2025.08.086
Lianzhan Huang , Yuanlong Wu , Piao Luo , Kexin Su , Xin Song , Mingdong Liu , Minjian Li , Huiyu Song , Zhiming Cui
{"title":"Multi-dimensional optimization of polymer-involved Li+ solvation enabling stable polymer plastic crystal electrolyte for long-cycle lithium metal batteries","authors":"Lianzhan Huang ,&nbsp;Yuanlong Wu ,&nbsp;Piao Luo ,&nbsp;Kexin Su ,&nbsp;Xin Song ,&nbsp;Mingdong Liu ,&nbsp;Minjian Li ,&nbsp;Huiyu Song ,&nbsp;Zhiming Cui","doi":"10.1016/j.jechem.2025.08.086","DOIUrl":"10.1016/j.jechem.2025.08.086","url":null,"abstract":"<div><div>Succinonitrile (SN)-based polymer plastic crystal electrolytes (PPCEs) are regarded as promising candidates for lithium metal batteries but suffer from serious side reactions with Li metal. Herein, we propose a multi-dimensional optimization strategy to alleviate the side reactions between SN and Li metal, and develop a highly stable poly-vinylethylene carbonate-based PPCE (PPCE-VEC). Moreover, we identify the intrinsic factors of multi-dimensional polymer structures on the electrolyte stability by three typical classes of polyesters. The PPCE-VEC constructed by in situ polymerization exhibits much better stability than poly-vinylene carbonate-based PPCE (PPCE-VCA) and poly-trifluoroethyl acrylate-based PPCE (PPCE-TFA), which is verified by its fewer SN-decomposition species in X-ray photoelectron spectroscopy (XPS) and outstanding full cell performance. The PPCE-VEC-enabled LiNi<sub>0.6</sub>Co<sub>0.2</sub>Mn<sub>0.2</sub>O<sub>2</sub> full cell achieve 73.7 % capacity retention after 1400 cycles, which outperforms PPCE-VCA- and PPCE-TFA-enabled full cells (61.9 % and 46.9 %). Spectral analysis and theoretical calculation reveal that the high solvation ability of the carbonyl site, flexible polymer chain, and homogeneous electrolyte phase of PPCE-VEC are favorable to maximizing competition coordination with Li<sup>+</sup> to weaken the Li<sup>+</sup>–SN binding and shape an anion-rich solvation structure. This optimized polymer-involved Li<sup>+</sup> solvation enhances SN stability and facilitates the formation of B/F enriched solid-electrolyte interphase (SEI), thus significantly improving PPCE stability.</div></div>","PeriodicalId":15728,"journal":{"name":"Journal of Energy Chemistry","volume":"112 ","pages":"Pages 656-665"},"PeriodicalIF":14.9,"publicationDate":"2025-09-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145156490","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Efficient and stable inverted perovskite solar cells employing self-assembled hole-transporting monolayers with enhanced interface interaction 采用具有增强界面相互作用的自组装空穴传输单层的高效稳定的倒钙钛矿太阳能电池
IF 14.9 1区 化学
Journal of Energy Chemistry Pub Date : 2025-09-11 DOI: 10.1016/j.jechem.2025.08.081
Botong Li , Jie Liu , Boyang Lu , Xuepeng Liu , Mingyuan Han , Weilun Du , Ziqiang Su , Zedong Lin , Wenyong Feng , Lei Xiao , Zhipeng Shao , Yong Ding , Songyuan Dai , Mohammad Khaja Nazeeruddin
{"title":"Efficient and stable inverted perovskite solar cells employing self-assembled hole-transporting monolayers with enhanced interface interaction","authors":"Botong Li ,&nbsp;Jie Liu ,&nbsp;Boyang Lu ,&nbsp;Xuepeng Liu ,&nbsp;Mingyuan Han ,&nbsp;Weilun Du ,&nbsp;Ziqiang Su ,&nbsp;Zedong Lin ,&nbsp;Wenyong Feng ,&nbsp;Lei Xiao ,&nbsp;Zhipeng Shao ,&nbsp;Yong Ding ,&nbsp;Songyuan Dai ,&nbsp;Mohammad Khaja Nazeeruddin","doi":"10.1016/j.jechem.2025.08.081","DOIUrl":"10.1016/j.jechem.2025.08.081","url":null,"abstract":"<div><div>Molecular tailoring of self-assembled hole-transporting monolayers (SAMs) has been proven as an efficient approach for improving the device performance of inverted perovskite solar cells. Herein, a novel SAM with extended conjugation is designed and synthesized, named NaPh-4PACz. Compared to Ph-4PACz, NaPh-4PACz exhibits a larger adsorption energy with the ITO substrate, enabling the formation of a more uniform and dense film, thereby preventing direct contact between the perovskite and ITO. Additionally, NaPh-4PACz also has a stronger interaction with the perovskite, which can reduce buried interface defects and suppress non-radiative recombination. Consequently, NaPh-4PACz-based devices achieved a power conversion efficiency of 25.48 % due to their interfacial “adhesive” ability. Importantly, the stability of the NaPh-4PACz-based devices was significantly improved.</div></div>","PeriodicalId":15728,"journal":{"name":"Journal of Energy Chemistry","volume":"112 ","pages":"Pages 712-719"},"PeriodicalIF":14.9,"publicationDate":"2025-09-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145156431","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Seamlessly integrated flexible Janus membranes enabling water-heat-salt synergy for solar desalination and wastewater treatment 无缝集成的柔性Janus膜使水-热-盐协同作用用于太阳能脱盐和废水处理
IF 14.9 1区 化学
Journal of Energy Chemistry Pub Date : 2025-09-11 DOI: 10.1016/j.jechem.2025.08.083
Lu Wang , Chengbing Wang , Wenhe Zhang , Hang Zhu , Jingjing Jin , Dingwen Yin , Wanda Liao , Jinbu Su
{"title":"Seamlessly integrated flexible Janus membranes enabling water-heat-salt synergy for solar desalination and wastewater treatment","authors":"Lu Wang ,&nbsp;Chengbing Wang ,&nbsp;Wenhe Zhang ,&nbsp;Hang Zhu ,&nbsp;Jingjing Jin ,&nbsp;Dingwen Yin ,&nbsp;Wanda Liao ,&nbsp;Jinbu Su","doi":"10.1016/j.jechem.2025.08.083","DOIUrl":"10.1016/j.jechem.2025.08.083","url":null,"abstract":"<div><div>Solar-driven interfacial evaporation presents a promising approach to address global freshwater scarcity. Current challenges in photothermal membrane design lie in achieving concurrent optimization of high solar absorption, low thermal conductivity, and water transport, where existing materials fail to establish effective “water-heat-salt” synergistic regulation at the evaporation interface. This study develops a seamlessly integrated Janus membrane through growing hydrophilic Cu<sub>2−</sub><em><sub>x</sub></em>S nanostructure on a hydrophobic carbon cloth substrate with carbon black coating (CB/CC). By precisely engineering the submicron pore architecture within the Cu<sub>2−</sub><em><sub>x</sub></em>S layer, we established a synergistic optimization mechanism for interfacial water transport, heat management, and salt rejection. The resulting Janus membrane demonstrates a high evaporation rate of 2.22 kg m<sup>−2</sup> h<sup>−1</sup> under 1 sun with an energy efficiency of about 88.4 %. Notably, the system maintains stable operation in hypersaline environments (20 wt% NaCl) and achieves continuous 5-h salt-resistant evaporation. Moreover, the Janus membranes can effectively purify various industrial wastewater, including acidic, alkaline, and organic pollutants. This study provides a new strategy for developing high-efficiency portable desalination systems through interfacial engineering of pore architecture.</div></div>","PeriodicalId":15728,"journal":{"name":"Journal of Energy Chemistry","volume":"112 ","pages":"Pages 701-711"},"PeriodicalIF":14.9,"publicationDate":"2025-09-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145156426","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
In situ directly grown carboxylated UiO-66-infused separator as a comprehensive regulator of Zn solvation structure enabling dendrite- and corrosion-free Zn metal anode 原位直接生长的羧化uio -66注入分离器作为锌溶剂化结构的综合调节剂,实现了无枝晶和无腐蚀的锌金属阳极
IF 14.9 1区 化学
Journal of Energy Chemistry Pub Date : 2025-09-11 DOI: 10.1016/j.jechem.2025.08.082
Jung Bin Park , Bo Keun Park , Ji Woo Han , Sung Joon Park , Seungyeop Kang , Dong-Joo Yoo , Ki Jae Kim
{"title":"In situ directly grown carboxylated UiO-66-infused separator as a comprehensive regulator of Zn solvation structure enabling dendrite- and corrosion-free Zn metal anode","authors":"Jung Bin Park ,&nbsp;Bo Keun Park ,&nbsp;Ji Woo Han ,&nbsp;Sung Joon Park ,&nbsp;Seungyeop Kang ,&nbsp;Dong-Joo Yoo ,&nbsp;Ki Jae Kim","doi":"10.1016/j.jechem.2025.08.082","DOIUrl":"10.1016/j.jechem.2025.08.082","url":null,"abstract":"<div><div>Aqueous zinc ion batteries (AZIBs) are considered promising candidates owing to their inherent safety and low cost. However, the conventional glass fiber (GF) separator used in AZIBs suffers from poor physicochemical properties, leading to uncontrolled zinc (Zn) dendrite formation and undesirable side reactions. To address these limitations and enhance the electrochemical performance of AZIBs, a precisely designed functional separator is developed by incorporating UiO-66-(COOH)<sub>2</sub> into a poly(vinylidene fluoride) (PVDF) framework (U-PVDF) via a direct in situ growth method. This approach enables uniform distribution of UiO-66-(COOH)<sub>2</sub> both on the surface and within the PVDF backbone, without increasing separator thickness. Owing to the strong interaction between Zn<sup>2+</sup> and the abundant carboxyl groups in UiO-66-(COOH)<sub>2</sub>, the U-PVDF separator regulates the Zn<sup>2+</sup> solvation structure toward a contact ion pair-dominated structure by reducing coordinated water molecules, which effectively mitigates water-induced parasitic reactions and promotes compact Zn deposition. Consequently, a Zn/Zn symmetric cell employing the U-PVDF separator demonstrates superior cycling stability over 1500 cycles without internal short-circuiting at a current density of 6 mA cm<sup>−2</sup> and an areal capacity of 2 mAh cm<sup>−2</sup>. Moreover, Zn/NaV<sub>3</sub>O<sub>8</sub>·<em>x</em>H<sub>2</sub>O (NVO) cell with the U-PVDF separator exhibits markedly improved cyclability and rate performance compared with those using conventional GF separator.</div></div>","PeriodicalId":15728,"journal":{"name":"Journal of Energy Chemistry","volume":"112 ","pages":"Pages 634-644"},"PeriodicalIF":14.9,"publicationDate":"2025-09-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145156494","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Eliminating Schottky Barrier via interface state manipulation on phase-tailored 2D/3D perovskite solar cells 二维/三维钙钛矿太阳能电池界面态控制消除肖特基势垒
IF 14.9 1区 化学
Journal of Energy Chemistry Pub Date : 2025-09-11 DOI: 10.1016/j.jechem.2025.08.084
Junmin Xia , Hao Gu , Ziyi Wang , Mengting Chen , Hui Hong , Zhifeng Li , Bo Cai , Kun Cao , Jia Guo , Guangbao Wu , Ke Guo , Shengwen Li , Annan Zhu , Shi Chen , Yongqing Cai , Chao Liang , Shufen Chen , Guichuan Xing
{"title":"Eliminating Schottky Barrier via interface state manipulation on phase-tailored 2D/3D perovskite solar cells","authors":"Junmin Xia ,&nbsp;Hao Gu ,&nbsp;Ziyi Wang ,&nbsp;Mengting Chen ,&nbsp;Hui Hong ,&nbsp;Zhifeng Li ,&nbsp;Bo Cai ,&nbsp;Kun Cao ,&nbsp;Jia Guo ,&nbsp;Guangbao Wu ,&nbsp;Ke Guo ,&nbsp;Shengwen Li ,&nbsp;Annan Zhu ,&nbsp;Shi Chen ,&nbsp;Yongqing Cai ,&nbsp;Chao Liang ,&nbsp;Shufen Chen ,&nbsp;Guichuan Xing","doi":"10.1016/j.jechem.2025.08.084","DOIUrl":"10.1016/j.jechem.2025.08.084","url":null,"abstract":"<div><div>Surface passivation via two-dimensional (2D) perovskite has emerged as a promising strategy to enhance the performance of perovskite solar cells (PSCs) due to the effective compensation of interfacial states. However, the in situ grown 2D perovskite passivation layers typically comprise a mixture of multiple dimensionalities at the interface, where band alignment has only been portrayed qualitatively and empirically. Herein, the interface states for precisely phase-tailored 2D perovskite passivated PSCs are quantitatively investigated. In comparison to traditional passivation molecules, 2D perovskite layers based on 4-trifluoromethyl-phenylethylammonium iodide (CF<sub>3</sub>PEAI) exhibit an increased work function, introducing desirable downward band bending to eliminate the Schottky Barrier. Furthermore, precisely phase-tailored 2D layers could modulate the interface trap density and energetics. The <em>n =</em> 1 film delivers optimal performance with a hole extraction efficiency of 95.1 %. The optimized n-i-p PSCs in the two-step method significantly improve PCE to 25.40 %, along with enhanced photostability and negligible hysteresis. It highlights that tailoring in the composition and phase distribution of the 2D perovskite layer could modulate the interface states at the 2D/3D interface.</div></div>","PeriodicalId":15728,"journal":{"name":"Journal of Energy Chemistry","volume":"112 ","pages":"Pages 760-769"},"PeriodicalIF":14.9,"publicationDate":"2025-09-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145156489","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Effects of molecular conformation on buried interface passivation and efficient perovskite solar cell realization employing fluorine substituted benzoic acid 氟取代苯甲酸对埋藏界面钝化及高效钙钛矿太阳能电池实现的分子构象影响
IF 14.9 1区 化学
Journal of Energy Chemistry Pub Date : 2025-09-11 DOI: 10.1016/j.jechem.2025.09.003
Boyan Li , Rongbo Wang , Ya Wang , Wentao Wu , Weitao Yan , Handong Zhang , Xingyuan Zhong , Juntao Zhao , Liyi Yao , Wei-Hua Wang , Yi Ding
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