Journal of Energy Chemistry最新文献

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Graph-guided fault detection for multi-type lithium-ion batteries in realistic electric vehicles optimized by ensemble learning
IF 13.1 1区 化学
Journal of Energy Chemistry Pub Date : 2025-03-18 DOI: 10.1016/j.jechem.2025.03.004
Caiping Zhang , Shuowei Li , Jingcai Du , Linjing Zhang , Wei Luo , Yan Jiang
{"title":"Graph-guided fault detection for multi-type lithium-ion batteries in realistic electric vehicles optimized by ensemble learning","authors":"Caiping Zhang ,&nbsp;Shuowei Li ,&nbsp;Jingcai Du ,&nbsp;Linjing Zhang ,&nbsp;Wei Luo ,&nbsp;Yan Jiang","doi":"10.1016/j.jechem.2025.03.004","DOIUrl":"10.1016/j.jechem.2025.03.004","url":null,"abstract":"<div><div>Accurately evaluating the safety status of lithium-ion battery systems in electric vehicles is imperative due to the challenges in effectively predicting potential battery failure risks under stochastic profiles. Complex battery fault mechanisms and limited poor-quality data collection impede fault detection for battery systems under real-world conditions. This paper proposes a novel graph-guided fault detection method designed to recognize concealed anomalies in realistic data. Graphs guided by physical relationships are constructed for learning the dynamic evolution of physical quantities under normal conditions and their potential change characteristics in fault scenarios. An ensemble Graph Sample and Aggregate Network model are developed to tackle sample distribution imbalances and non-uniformity battery system specifications across vehicles. Failure risk probabilities for diverse battery charging and discharging segments are derived. An ablation study verifies the necessity of ensemble learning in addressing imbalanced datasets. Analysis of 102,095 segments across 86 vehicles with different battery material systems, battery capacities, and numbers of cells and temperature sensors confirms the robustness and generalization of the proposed method, yielding a recall of 98.37%. By introducing the graph, spatio-temporal global fault characteristics of battery systems are automatically extracted. The coupling relationship and evolution of physical quantities under both normal and faulty states are established, effectively uncovering fault information hidden in collected battery data without observable anomalies. The safety state of battery systems is reflected in terms of failure risk probability, providing reliable data support for battery system maintenance.</div></div>","PeriodicalId":15728,"journal":{"name":"Journal of Energy Chemistry","volume":"106 ","pages":"Pages 507-522"},"PeriodicalIF":13.1,"publicationDate":"2025-03-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143747800","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Enhanced overall water splitting by CQDs-coupled RuO2-IrO2 heterojunction in acidic media
IF 13.1 1区 化学
Journal of Energy Chemistry Pub Date : 2025-03-17 DOI: 10.1016/j.jechem.2025.02.050
Yuwen Su , Han Wu , Siyang Wang , Zhiang Hu , Jian Li , Jiangwei Chang , Guangchao Yin , Siyu Lu
{"title":"Enhanced overall water splitting by CQDs-coupled RuO2-IrO2 heterojunction in acidic media","authors":"Yuwen Su ,&nbsp;Han Wu ,&nbsp;Siyang Wang ,&nbsp;Zhiang Hu ,&nbsp;Jian Li ,&nbsp;Jiangwei Chang ,&nbsp;Guangchao Yin ,&nbsp;Siyu Lu","doi":"10.1016/j.jechem.2025.02.050","DOIUrl":"10.1016/j.jechem.2025.02.050","url":null,"abstract":"<div><div>The development of highly active and stable bifunctional electrocatalysts in acidic media is crucial to hydrogen production by proton exchange membrane. In this study, we designed a RuO<sub>2</sub>-IrO<sub>2</sub> heterostructure catalyst coupled by carbon quantum dots (CQDs). The catalyst showed excellent electrocatalytic performance for water splitting under acidic conditions. The overpotentials of oxygen evolution reaction (OER) and hydrogen evolution reaction (HER) were as low as 180 and 15 mV at 10 mA/cm<sup>2</sup> in 0.5 M H<sub>2</sub>SO<sub>4</sub>, respectively. The acid electrolytic cell developed with RuO<sub>2</sub>-IrO<sub>2</sub>@CQDs as anode and cathode operated stably at 10 mA/cm<sup>2</sup> for 120 h. In situ measurements and theoretical calculation reveal that the unique lattice oxygen mechanism path of RuO<sub>2</sub>-IrO<sub>2</sub>@CQDs can bypass the OOH* intermediate and breaks the linear relationship of adsorbent evolution mechanism path, resulting in higher OER catalytic activity.</div></div>","PeriodicalId":15728,"journal":{"name":"Journal of Energy Chemistry","volume":"106 ","pages":"Pages 331-339"},"PeriodicalIF":13.1,"publicationDate":"2025-03-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143706237","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Bimetallic tellurides electrodes: From synthesis to applications in energy storage and conversion
IF 13.1 1区 化学
Journal of Energy Chemistry Pub Date : 2025-03-15 DOI: 10.1016/j.jechem.2025.02.047
Ziyi Cheng , Xi Pan , Panjun Dou , Kening Liu , Peng Wan , Yutong Li , Na Tao , Lixin Qian , Wei Wang , Jianhua Chu
{"title":"Bimetallic tellurides electrodes: From synthesis to applications in energy storage and conversion","authors":"Ziyi Cheng ,&nbsp;Xi Pan ,&nbsp;Panjun Dou ,&nbsp;Kening Liu ,&nbsp;Peng Wan ,&nbsp;Yutong Li ,&nbsp;Na Tao ,&nbsp;Lixin Qian ,&nbsp;Wei Wang ,&nbsp;Jianhua Chu","doi":"10.1016/j.jechem.2025.02.047","DOIUrl":"10.1016/j.jechem.2025.02.047","url":null,"abstract":"<div><div>The rapid growth in global energy demand has necessitated the development of efficient energy storage and conversion devices, with the aim of enhancing grid stability, promoting the adoption of electric vehicles, and powering portable electronics. However, the performance of these devices is constrained by the limitations of traditional electrode materials and catalysts. Bimetallic tellurides have emerged as a promising solution due to their exceptional synergistic effects, high electronic conductivity, abundant redox-active sites, and outstanding electrochemical stability. Nevertheless, achieving cost-effective synthesis and stable applications remains a significant challenge. Hence, the most recent advances of bimetallic tellurides electrodes from synthesis to application are systematically reviewed. Several synthetic strategies for exquisite bimetallic tellurides nanostructures, including tellurization, ball-milling, solvo/hydrothermal, electrodeposition, wet chemical, and template method, are discussed. Moreover, the applications of bimetallic tellurides are extensively summarized in energy storage and conversion devices, which include alkali metal-ion batteries (Li-ion, Na-ion, and K-ion), supercapacitor, hydrogen evolution reaction (HER), and oxygen evolution reaction (OER). Besides, the challenges and potential solutions of bimetallic telluride for energy applications are also suggested. This work provides fundamental insight and guidelines for the future design of bimetallic tellurides in energy storage and conversion technologies.</div></div>","PeriodicalId":15728,"journal":{"name":"Journal of Energy Chemistry","volume":"106 ","pages":"Pages 360-386"},"PeriodicalIF":13.1,"publicationDate":"2025-03-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143714687","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Lignin-derived carbon quantum dots: advancing renewable nanomaterials for energy and photocatalysis
IF 13.1 1区 化学
Journal of Energy Chemistry Pub Date : 2025-03-13 DOI: 10.1016/j.jechem.2025.02.045
Tianyue Chen , Lina Jia , Shiqi Xu , Yang Shi , Jinxuan Jiang , Shengbo Ge , Mashallah Rezakazemi , Runzhou Huang
{"title":"Lignin-derived carbon quantum dots: advancing renewable nanomaterials for energy and photocatalysis","authors":"Tianyue Chen ,&nbsp;Lina Jia ,&nbsp;Shiqi Xu ,&nbsp;Yang Shi ,&nbsp;Jinxuan Jiang ,&nbsp;Shengbo Ge ,&nbsp;Mashallah Rezakazemi ,&nbsp;Runzhou Huang","doi":"10.1016/j.jechem.2025.02.045","DOIUrl":"10.1016/j.jechem.2025.02.045","url":null,"abstract":"<div><div>Carbon quantum dots are a new type of fluorescent nanomaterials with broad applications in drug delivery, bioimaging, solar cells, and photocatalysis due to their unique biocompatibility, optical properties and easy functionalization. In the meantime, because of its high carbon content, renewable nature, and environmental friendliness, lignin has drawn the attention of researchers as a desirable raw material for creating carbon quantum dots. Here we review the synthesis of carbon quantum dots from lignin, focusing on synthetic methods, properties, and applications in energy, and photocatalysis. Later, we propose some new development prospects from preparation methods, luminescence mechanism research, application, and commercial cost of lignin carbon quantum dots. Finally, based on this, the development prospects of this field are prospected and summarized.</div></div>","PeriodicalId":15728,"journal":{"name":"Journal of Energy Chemistry","volume":"106 ","pages":"Pages 271-290"},"PeriodicalIF":13.1,"publicationDate":"2025-03-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143680003","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
A low-cost and high-energy aqueous potassium-ion battery
IF 13.1 1区 化学
Journal of Energy Chemistry Pub Date : 2025-03-13 DOI: 10.1016/j.jechem.2025.02.039
Raphael L. Streng , Tim Steeger , Anatoliy Senyshyn , Steffen Abel , Peter Schneider , Christine Benning , Bernardo Miller Naranjo , David Gryc , Mian Zahid Hussain , Oliver Lieleg , Martin Elsner , Aliaksandr S. Bandarenka , Katarina Cicvarić
{"title":"A low-cost and high-energy aqueous potassium-ion battery","authors":"Raphael L. Streng ,&nbsp;Tim Steeger ,&nbsp;Anatoliy Senyshyn ,&nbsp;Steffen Abel ,&nbsp;Peter Schneider ,&nbsp;Christine Benning ,&nbsp;Bernardo Miller Naranjo ,&nbsp;David Gryc ,&nbsp;Mian Zahid Hussain ,&nbsp;Oliver Lieleg ,&nbsp;Martin Elsner ,&nbsp;Aliaksandr S. Bandarenka ,&nbsp;Katarina Cicvarić","doi":"10.1016/j.jechem.2025.02.039","DOIUrl":"10.1016/j.jechem.2025.02.039","url":null,"abstract":"<div><div>To address challenges related to the intermittency of renewable energy sources, aqueous potassium-ion batteries (AKIBs) are a promising and sustainable alternative to conventional systems for large-scale energy storage. To enable their practical application, maximizing energy density and longevity while minimizing production and material costs is a key goal. In this work, we propose an AKIB consisting only of abundant and cost-efficient materials, which delivers a high energy density of more than 70 Wh kg<sup>−1</sup>. We combine simple strategies to stabilize the Mn-rich Prussian blue analog cathode by Fe-doping, improving the crystallinity, and tuning the electrolyte composition without employing expensive water-in-salt electrolytes. Using a mixed 2.5 M Ca(NO<sub>3</sub>)<sub>2</sub> + 1.5 M KNO<sub>3</sub> electrolyte, we assemble a novel AKIB with a Fe-doped manganese hexacyanoferrate cathode and an organic poly(naphthalene-4-formyl-ethylenediamine) anode. Besides a high energy density, the full cell delivers a specific capacity of approximately 60 mA h g<sup>−1</sup>, a power density of 5000 W kg<sup>−1</sup>, and 80% capacity retention after 600 cycles.</div></div>","PeriodicalId":15728,"journal":{"name":"Journal of Energy Chemistry","volume":"106 ","pages":"Pages 523-531"},"PeriodicalIF":13.1,"publicationDate":"2025-03-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143760004","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Importance of passivation efficiency of the passivator for efficient printable mesoscopic perovskite solar cells
IF 13.1 1区 化学
Journal of Energy Chemistry Pub Date : 2025-03-12 DOI: 10.1016/j.jechem.2025.02.041
Kangming Ou , Jiale Liu , Junwei Xiang, Chaoyang Wang, Jiayu Xie, Xiaoyu Li, Yanjie Cheng, Qiaojiao Gao, Lingya Gao, Anyi Mei, Yang Zhou, Hongwei Han
{"title":"Importance of passivation efficiency of the passivator for efficient printable mesoscopic perovskite solar cells","authors":"Kangming Ou ,&nbsp;Jiale Liu ,&nbsp;Junwei Xiang,&nbsp;Chaoyang Wang,&nbsp;Jiayu Xie,&nbsp;Xiaoyu Li,&nbsp;Yanjie Cheng,&nbsp;Qiaojiao Gao,&nbsp;Lingya Gao,&nbsp;Anyi Mei,&nbsp;Yang Zhou,&nbsp;Hongwei Han","doi":"10.1016/j.jechem.2025.02.041","DOIUrl":"10.1016/j.jechem.2025.02.041","url":null,"abstract":"<div><div>The stacking of multiple defect-rich grain boundaries (GBs) along the long transportation path (∼3 μm) of charge carriers in printable mesoscopic perovskite solar cells (p-MPSCs) impedes their power conversion efficiency (PCE). Organic Lewis bases are widely utilized for defect passivation at GBs, but how their passivation efficiency affects energy loss remains unclear. Here we employed triphenylphosphine (TPP) and triphenylphosphine oxide (TPPO) as the model passivators in p-MPSCs. TPPO has a more negatively charged center than TPP, which enables its stronger coordination with one of the most common and detrimental defects at the GBs—undercoordinated lead. When added into the perovskite with the same ratio, TPPO passivates defects more significantly and thus less TPPO remaining inactive compared with TPP. Inactive organic passivators accumulated at the GBs could impose barriers to charge carrier transportation. Indeed, TPPO improves the device performance more significantly with a champion PCE of 20.54% achieved. Besides, the TPPO devices demonstrate excellent stability with 95% of initial PCE remaining after 600 h of maximum power point tracking at (55 ± 5)°C.</div></div>","PeriodicalId":15728,"journal":{"name":"Journal of Energy Chemistry","volume":"106 ","pages":"Pages 438-445"},"PeriodicalIF":13.1,"publicationDate":"2025-03-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143734884","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Leveraging machine learning for accelerated materials innovation in lithium-ion battery: a review
IF 13.1 1区 化学
Journal of Energy Chemistry Pub Date : 2025-03-12 DOI: 10.1016/j.jechem.2025.02.038
Rushuai Li , Wanyu Zhao , Ruimin Li , Chaolun Gan , Li Chen , Zhitao Wang , Xiaowei Yang
{"title":"Leveraging machine learning for accelerated materials innovation in lithium-ion battery: a review","authors":"Rushuai Li ,&nbsp;Wanyu Zhao ,&nbsp;Ruimin Li ,&nbsp;Chaolun Gan ,&nbsp;Li Chen ,&nbsp;Zhitao Wang ,&nbsp;Xiaowei Yang","doi":"10.1016/j.jechem.2025.02.038","DOIUrl":"10.1016/j.jechem.2025.02.038","url":null,"abstract":"<div><div>As energy demands continue to rise in modern society, the development of high-performance lithium-ion batteries (LIBs) has become crucial. However, traditional research methods of material science face challenges such as lengthy timelines and complex processes. In recent years, the integration of machine learning (ML) in LIB materials, including electrolytes, solid-state electrolytes, and electrodes, has yielded remarkable achievements. This comprehensive review explores the latest applications of ML in predicting LIB material performance, covering the core principles and recent advancements in three key inverse material design strategies: high-throughput virtual screening, global optimization, and generative models. These strategies have played a pivotal role in fostering LIB material innovations. Meanwhile, the paper briefly discusses the challenges associated with applying ML to materials research and offers insights and directions for future research.</div></div>","PeriodicalId":15728,"journal":{"name":"Journal of Energy Chemistry","volume":"106 ","pages":"Pages 44-62"},"PeriodicalIF":13.1,"publicationDate":"2025-03-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143680007","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Exploring damping effect of oxygen vacancies for lithium-rich layered cathode cycling at high rate
IF 13.1 1区 化学
Journal of Energy Chemistry Pub Date : 2025-03-12 DOI: 10.1016/j.jechem.2025.02.044
Yuanyuan Du , Qingyuan Li , Lingyu Zeng , Zeya Hu , Wenguang Zhao , Xingxing Yin , Ruohong Ke , Jin Xu , Jiachun Wu , Yonghong Deng , Jun Wang , Rui Si , Dong Zhou
{"title":"Exploring damping effect of oxygen vacancies for lithium-rich layered cathode cycling at high rate","authors":"Yuanyuan Du ,&nbsp;Qingyuan Li ,&nbsp;Lingyu Zeng ,&nbsp;Zeya Hu ,&nbsp;Wenguang Zhao ,&nbsp;Xingxing Yin ,&nbsp;Ruohong Ke ,&nbsp;Jin Xu ,&nbsp;Jiachun Wu ,&nbsp;Yonghong Deng ,&nbsp;Jun Wang ,&nbsp;Rui Si ,&nbsp;Dong Zhou","doi":"10.1016/j.jechem.2025.02.044","DOIUrl":"10.1016/j.jechem.2025.02.044","url":null,"abstract":"<div><div>Lithium-rich manganese-based oxide (LRMO) cathode has emerged as a particularly promising candidate for achieving high energy densities in lithium-ion batteries due to its capability to access anion redox reactions at high voltage. The successful implementation of LRMO in energy storage systems is contingent upon the enhancement of their rate capabilities. However, the underlying relationship between high-rate cycling and electrode degradation for LRMO, particularly concerning structural evolution, still remains unclear. Benefiting from the high time resolution abilities of liquid-metal-jet operando two-dimensional X-ray diffraction, it is observed that the Li<sub>2</sub>MnO<sub>3</sub> phase in LRMO is gradually activated accompanied by the emergence of oxygen vacancies during cycling at 1 C (1 C = 250 mA/g). Consequently, the crystal lattice flexibility of LRMO is systematically enhanced, thereby preventing the collapse of the bulk structure. While, continuous release of oxygen during extended cycling results in deteriorations of the self-adjusting damping effect of the structure, ultimately leading to a decline in capacity. The findings of this study not only contribute to a more profound understanding of the structural changes of LRMOs at high rates, but also provide novel perspectives for the rational design of LRMOs with superior rate performances.</div></div>","PeriodicalId":15728,"journal":{"name":"Journal of Energy Chemistry","volume":"106 ","pages":"Pages 185-193"},"PeriodicalIF":13.1,"publicationDate":"2025-03-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143696712","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Revealing the low-temperature aging mechanisms of the whole life cycle for lithium-ion batteries (nickel-cobalt-aluminum vs. graphite)
IF 13.1 1区 化学
Journal of Energy Chemistry Pub Date : 2025-03-12 DOI: 10.1016/j.jechem.2025.02.043
Ranjun Huang , Gang Wei , Xueyuan Wang , Bo Jiang , Jiangong Zhu , Jingan Chen , Xuezhe Wei , Haifeng Dai
{"title":"Revealing the low-temperature aging mechanisms of the whole life cycle for lithium-ion batteries (nickel-cobalt-aluminum vs. graphite)","authors":"Ranjun Huang ,&nbsp;Gang Wei ,&nbsp;Xueyuan Wang ,&nbsp;Bo Jiang ,&nbsp;Jiangong Zhu ,&nbsp;Jingan Chen ,&nbsp;Xuezhe Wei ,&nbsp;Haifeng Dai","doi":"10.1016/j.jechem.2025.02.043","DOIUrl":"10.1016/j.jechem.2025.02.043","url":null,"abstract":"<div><div>The degradation of Lithium-ion batteries (LIBs) during cycling is particularly exacerbated at low temperatures, which has a significant impact on the longevity of electric vehicles, energy storage systems, and consumer electronics. A comprehensive understanding of the low-temperature aging mechanisms throughout the whole life cycle of LIBs is crucial. However, existing research is limited, which typically focuses on capacity degradation to 80%. To fill this gap, this paper conducts low-temperature cyclic aging tests at three different charging rates. The investigation employs differential voltage analysis, the distribution of relaxation times technique, and disassembly characterization to explore both thermodynamic degradation and kinetic degradation, alongside a correlation analysis of the factors influencing these degradation processes. The results reveal two distinct knee points in the capacity decline of LIBs during the whole life cycle, in contrast to prior studies identifying only one. Before the first knee point, the thickening of the SEI film dominates capacity loss, with higher charging rates accelerating the process. After the first knee point, the main degradation mechanisms shift to lithium plating and the fracture of the positive electrode active particles. These two aging factors become more pronounced with ongoing cycling, culminating in a second knee point in capacity decline. Notably, a novel finding demonstrates that after the second knee point, capacity degradation progresses faster at lower charging rates compared to medium rates. The reason is the fracture of graphite particles also becomes a critical contributor to the severe capacity degradation at lower charging rates. These insights will guide the designs of next-generation low-temperature LIBs and low-temperature battery management systems.</div></div>","PeriodicalId":15728,"journal":{"name":"Journal of Energy Chemistry","volume":"106 ","pages":"Pages 31-43"},"PeriodicalIF":13.1,"publicationDate":"2025-03-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143680006","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Aqueous dual ionic/electronic conducting binder enabling water-scarce, Zn2+-enriched interface for aqueous zinc metal batteries
IF 13.1 1区 化学
Journal of Energy Chemistry Pub Date : 2025-03-12 DOI: 10.1016/j.jechem.2025.02.036
Zhiying Meng , Rongfu Xu , Yinglin Yan , Ningxin Chen , Sida Xie , Jie Deng , Ying Zhang , Yiming Zou , Rong Yang , Zhaohui Wang
{"title":"Aqueous dual ionic/electronic conducting binder enabling water-scarce, Zn2+-enriched interface for aqueous zinc metal batteries","authors":"Zhiying Meng ,&nbsp;Rongfu Xu ,&nbsp;Yinglin Yan ,&nbsp;Ningxin Chen ,&nbsp;Sida Xie ,&nbsp;Jie Deng ,&nbsp;Ying Zhang ,&nbsp;Yiming Zou ,&nbsp;Rong Yang ,&nbsp;Zhaohui Wang","doi":"10.1016/j.jechem.2025.02.036","DOIUrl":"10.1016/j.jechem.2025.02.036","url":null,"abstract":"<div><div>The development of aqueous zinc-ion batteries is crucial for advancing sustainable energy storage technologies. However, their widespread application is hindered by Zn corrosion and uncontrolled Zn dendrite growth. One promising approach involves creating a functional organic-inorganic interface on the Zn surface. Traditional binders, such as polyvinylidene fluoride (PVDF), fail to regulate water activity and ion migration, limiting the effectiveness of the interface. Herein, we introduce an aqueous dual ionic/electronic conducting binder, poly(3,4-ethylenedioxythiophene): polystyrene sulfonate (PEDOT:PSS), to build a water-scarce, Zn<sup>2+</sup>-enriched interface. Our findings demonstrate that PEDOT:PSS not only facilitates uniform distribution of inorganic fillers, forming a cohesive and compact interface, but also significantly enhances mechanical integrity. Additionally, the sulfonate groups within the binder matrix disrupt the hydrogen bond network of water molecules, reducing water activity and lowering the desolvation energy barrier of Zn(H<sub>2</sub>O)<sub>6</sub><sup>2+</sup> clusters. Therefore, the transference number of Zn<sup>2+</sup> is elevated to 0.81 (compared to 0.61 with PVDF), mitigating undesirable side reactions and enabling dendrite-less Zn deposition. Consequently, symmetrical Zn||Zn cells with PEDOT:PSS binder demonstrate a lifetime with 4.2 times longer than those with PVDF. This work underscores the critical role of binder chemistry in stabilizing metal anodes for aqueous batteries.</div></div>","PeriodicalId":15728,"journal":{"name":"Journal of Energy Chemistry","volume":"106 ","pages":"Pages 194-204"},"PeriodicalIF":13.1,"publicationDate":"2025-03-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143696713","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
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