Journal of contaminant hydrology最新文献

{"title":"From brushite to hydroxylapatite: A study on phosphate mineral transformation and the fate of oxytetracycline","authors":"Jianan Guo,&nbsp;Lina Chen,&nbsp;Xinying Zhang,&nbsp;Changmin Jin,&nbsp;Yue Cui","doi":"10.1016/j.jconhyd.2025.104497","DOIUrl":"10.1016/j.jconhyd.2025.104497","url":null,"abstract":"<div><div>Livestock manure, a common fertilizer in Chinese agriculture, can lead to environmental contamination and potential health risks due to elevated antibiotic and phosphorus levels. Importantly, the high phosphorus levels initiates transformations of phosphate minerals in soils, especially calcareous soils. These variations in phosphate mineralogy can significantly impact the migration and fate of antibiotics within the soil. However, the impact of the transformation process, particularly involving the metastable phase brushite (DCPD), on the fate of antibiotics remains unclear. In this study, we synthesized DCPD and hydroxylapatite (HAP) and examined their transformation process to assess their removal capacity and investigate the migration and fate of oxytetracycline (OTC). The findings reveal that HAP exhibits a maximum immobilization capacity for OTC of 20.10 mg/g, surpassing that of DCPD by 2.56 times (7.86 mg/g). This disparity in immobilization capacity between DCPD and HAP leads to a redistribution of OTC between the solid and liquid phases during the transformation process. Notably, the introduction of OTC also inhibits the transformation process, potentially impacting the fate of other potentially harmful elements. The study highlights that the transformation process of calcium phosphorus minerals has a significant impact on the mobility and fate of antibiotics in soil, which aids in better management and mitigation of the environmental risks associated with fertilizer application.</div></div>","PeriodicalId":15530,"journal":{"name":"Journal of contaminant hydrology","volume":"269 ","pages":"Article 104497"},"PeriodicalIF":3.5,"publicationDate":"2025-02-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142983791","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Influence of wettability on water retention curves in unconsolidated porous media","authors":"Gerhard Schäfer ,&nbsp;Kevin Hernandez Perez ,&nbsp;Panav Hulsurkar ,&nbsp;Magda Ibrahim Youssif ,&nbsp;François Lehmann ,&nbsp;Mohammad Piri","doi":"10.1016/j.jconhyd.2025.104502","DOIUrl":"10.1016/j.jconhyd.2025.104502","url":null,"abstract":"<div><div>Controlled laboratory experiments were carried out using the hanging column method. Prior to the experiments, three uniform silica sands, which were originally water-wet, were aged in contact with crude oil until they were moderately oil-wet. Five fractionally wet sands were obtained by mixing the water-wet sands with oil-wet sands containing 25, 50 and 75 vol% oil-wet sands. A total of 11 tests formed the basis for the present study. The measured water retention curves showed that the capillary pressure heads were greatly reduced in sands that were oil-wet or fractionally wet. Changes in the wettability of the sands also affected their irreducible water saturation: The higher the proportion of oil-wet sand in the sand mixtures, the lower the irreducible water saturation. To quantify the characteristics of the measured water retention curves, the Van Genuchten model was used. The two optimized parameters seem to indicate a general trend: The higher the volume fraction of oil-wet sand, the higher is <em>α</em> and the lower is <em>n</em>. For the three unaged sands and the aged medium-sized sand, it was found that each of the two branches of the measured retention curves can be suitably scaled to a unique curve if, in addition to the petrophysical parameters (intrinsic permeability, porosity, surface tension, gas-water contact angle), the irreducible residual water saturation and the residual air saturation are taken into account. To quantify the observed deviations of the other two aged sands from the unified Leverett J-function, a theoretical fit function was used to match the experimental data of the three unaged sands. The experimental data sets for P2040ag and P100ag were found to be overestimated overall by the fit function. However, when the petrophysical parameters of the unaged sands were used instead of the actual measured parameters, the individual experimental Leverett J-functions came closer to the uniform J-curve. Based on this, it could be concluded that the apparent differences in pore structure between aged and unaged sands in addition to wettability, expressed by the cosine of the contact angle, may have contributed to a further reduction in the capillary pressure plateaus of the aged sands, which was particularly visible and significant in the P2040 and P100 sand. Using the measured static contact angles for two-phase gas-oil and oil-water systems and the measured interfacial tensions when the porous medium is either water-wet or moderately oil-wet, it was shown that the Bartell-Osterhof equation overestimates the measured gas-water contact angles. Reasonable agreement was achieved when a calibrated roughness factor of the solid surface was considered in the Young's contact angle.</div></div>","PeriodicalId":15530,"journal":{"name":"Journal of contaminant hydrology","volume":"269 ","pages":"Article 104502"},"PeriodicalIF":3.5,"publicationDate":"2025-02-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143006379","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Use of process-based coupled ecological-hydrodynamic models to support lake water ecosystem service protection planning at the regional scale","authors":"Andrea Fenocchi ,&nbsp;Nicolò Pella ,&nbsp;Diego Copetti ,&nbsp;Fabio Buzzi ,&nbsp;Daniele Magni ,&nbsp;Nico Salmaso ,&nbsp;Claudia Dresti","doi":"10.1016/j.jconhyd.2024.104469","DOIUrl":"10.1016/j.jconhyd.2024.104469","url":null,"abstract":"<div><div>Protection plans of lake waters are based on ecological and/or chemical targets, often simplified in terms of total phosphorus (<em>TP</em>) concentrations, customarily the depth-averaged ones at spring mixing for temperate environments. These target lake <em>TP</em> concentrations are then commonly employed to determine target external loading through reverse use of Vollenweider-OECD-type steady-state empirical models. Such models are also adopted in their direct form to estimate lake <em>TP</em> concentrations following hypothetical external load reductions. However, such approaches suffer from extreme parameterisation and often give inaccurate results. Process-based coupled ecological-hydrodynamic models offer a much wider flexibility and produce an extensive set of information, solving many of the issues of Vollenweider-OECD-type models. However, their application has been up to now restricted to single lakes due to calibration effort and data availability burdens. To overcome these obstacles, in this study we developed a simplified application of the process-based coupled model QWET over 9 lakes in Northern Italy, making use of the ParSAC automatic calibration tool and feeding the models only with general data available from public monitoring. QWET models were calibrated over past observations, simulating nutrient reduction scenarios for the near-future decades. The advantages over traditionally employed models for lake water protection planning at the regional scale were hence identified through a practical application, determining the strengths and limits of the herein-adopted simplified process-based approach over lakes with different features. Obtained results were also analysed considering the specific case study.</div></div>","PeriodicalId":15530,"journal":{"name":"Journal of contaminant hydrology","volume":"268 ","pages":"Article 104469"},"PeriodicalIF":3.5,"publicationDate":"2024-11-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142746711","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Potential health, environmental implication of microplastics: A review on its detection","authors":"Bhawana Yadav ,&nbsp;Payal Gupta ,&nbsp;Vinay Kumar ,&nbsp;Mridul Umesh ,&nbsp;Deepak Sharma ,&nbsp;Jithin Thomas ,&nbsp;Suraj Kumar Bhagat","doi":"10.1016/j.jconhyd.2024.104467","DOIUrl":"10.1016/j.jconhyd.2024.104467","url":null,"abstract":"<div><div>Microplastic contamination of terrestrial and aquatic environment has gained immense research attention due to their potential ecotoxicity and biomagnification property when enterer into food chain. Heterogenous nature of microplastics coupled with their ability to combine with other emerging pollutants have increased the severity of this crisis. Existing detection methods often fails to accurately quantify the amount of microplastic components present in environmental and biological samples. Thus, a great deal of research gap always exists in our current understanding about microplastics including the limitations in screening, detection and mitigation. This review work presents a comprehensive out look on the impact of microplastics on both terrestrial and aquatic environment. Furthermore, an in-depth discussion on various microplastic detection techniques recently used for microplastic quantification along with their significance and limitations is summarised in this review. The review also elaborates various physical, chemical and biological methods used for the mitigation of microplastics from environmental samples.</div></div>","PeriodicalId":15530,"journal":{"name":"Journal of contaminant hydrology","volume":"268 ","pages":"Article 104467"},"PeriodicalIF":3.5,"publicationDate":"2024-11-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142746710","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Experimental investigation on heat and moisture transfer of propylene glycol-mixed steam in porous media","authors":"Zhixin Chen,&nbsp;Yan Tian,&nbsp;Liming Hu","doi":"10.1016/j.jconhyd.2024.104468","DOIUrl":"10.1016/j.jconhyd.2024.104468","url":null,"abstract":"<div><div>Propylene glycol (PG)-mixed steam enhanced extraction is a promising remediation technique for removing semi-volatile organic compounds (SVOCs) from the unsaturated zone. However, the mechanisms of heat and moisture transfer during PG-mixed steam injection remain unclear. In this study, a 2D experimental system was developed to enable non-invasive monitoring of the spatio-temporal distribution of temperature and degree of saturation during steam injection into porous media. Experiments were conducted to observe the migration of PG-mixed steam in horizontal and vertical planes across three varying particle sizes, while pure superheated steam injection experiments serving as a comparison. Temperature field results show that the addition of PG decreases the zone of influence during steam migration, while significantly enhancing the emergence of the superheated steam zone. The influence of particle size on the area variance of the saturated steam zone is greater than that of the superheated steam zone. The downward migration of the superheated steam front due to density different between PG vapor and air is impeded with decreasing permeability. Furthermore, saturation field results reveal that the condensed liquid within the superheated zone is a PG solution. The downward migration of condensates with high PG concentration might increase the potential risk of beneath groundwater pollution, highlighting the significance of understanding PG migration during PG-mixed steam injection.</div></div>","PeriodicalId":15530,"journal":{"name":"Journal of contaminant hydrology","volume":"268 ","pages":"Article 104468"},"PeriodicalIF":3.5,"publicationDate":"2024-11-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142706291","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Experimental application of micro/nano bubbles to control P release and separate P particles from benthic lake sediment","authors":"Yong-Ho Choi ,&nbsp;Yong-Hoon Jeong ,&nbsp;Hong-Hue Thi Nguyen ,&nbsp;Dong-Heui Kwak","doi":"10.1016/j.jconhyd.2024.104466","DOIUrl":"10.1016/j.jconhyd.2024.104466","url":null,"abstract":"<div><div>Under persistent hypoxic conditions in the bottom layer of a lake, phosphorus (P) can be released from benthic sediments, significantly impacting the lake ecosystem. Hypoxia reduces iron ions, leading to P release through biogeochemical reactions associated with organic matter degradation, which in turn depletes dissolved oxygen (DO) in the sediment. The application of bubble technology is beneficial, as microbubbles (MBs) effectively remove P and enhance DO levels in both the overlying water and sediment surface. To identify the optimal bubble size for application, we conducted a series of flotation experiments and P fractionation studies using MBs and nanobubbles (NBs). Results indicate that NBs achieved a flotation efficiency of 12 %, MBs reached 44 %, and the combined use of NBs and MBs attained the highest flotation efficiency at 62 %, confirming that a combination of bubble sizes can enhance flotation efficiency. Furthermore, the introduction of air bubbles to mitigate hypoxia in the overlying water increased DO concentrations from 1 to 5 mg/L, followed by a gradual decline. P release in the bubble-injected groups was up to three times lower than in the control group. Water quality profiling of P distribution in sediments revealed a significant increase of approximately 10 % in iron-bound P under aerobic conditions, highlighting its critical role in regulating P release. Our findings suggest that utilizing a combination of bubble sizes, including NBs, enhances P removal efficiency and improves the anaerobic conditions of the lake's bottom layer, thereby further reducing P release from sediments.</div></div>","PeriodicalId":15530,"journal":{"name":"Journal of contaminant hydrology","volume":"268 ","pages":"Article 104466"},"PeriodicalIF":3.5,"publicationDate":"2024-11-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142693027","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Rainfall-induced microplastic fate and transport in unsaturated Dutch soils","authors":"Rozita Soltani Tehrani,&nbsp;Xiaomei Yang,&nbsp;Jos van Dam","doi":"10.1016/j.jconhyd.2024.104456","DOIUrl":"10.1016/j.jconhyd.2024.104456","url":null,"abstract":"<div><div>Microplastic pollution has become a growing concern in terrestrial ecosystems, with significant implications for environmental and human health. Understanding the fate and transport of microplastics in soil environment is crucial for effective mitigation strategies. This study investigates the dynamics of microplastic (Low-density polyethylene (LDPE), polybutylene adipate terephthalate (PBAT), and starch-based biodegradable plastic) transport in unsaturated soils under varying rainfall intensities and soil types, aiming to elucidate the factors influencing their behavior. Effluent samples were analyzed to measure microplastic transport, with microplastic balance analysis ensuring experimental accuracy. The setup replicated real-world flow conditions, providing insights into microplastic transport in unsaturated porous media. Microplastic balance analysis revealed high recovery factors (between 64 % and 104 %), indicating the reliability of the experimental approach. Microplastic transport varied significantly between sandy loam and loamy sand soils, with loamy sand soils exhibiting higher wash-off rates due to their unique properties. LDPE microplastics showed a higher tendency to detach from soil columns compared to PBAT and starch-based particles. Higher rainfall intensity in loamy sand soil columns resulted in an increased washout of LDPE, PBAT, and starch-based particles by 92 %, 144 %, and 85 %, respectively, compared to low rainfall intensity. In sandy loam soil, increased rainfall intensity resulted in a significantly higher washout of LDPE, PBAT, and starch-based particles with percentages of 93 %, 69 %, and 45 %, respectively. This underscores the important role of water flow in mobilizing microplastics within the soil matrix.</div></div>","PeriodicalId":15530,"journal":{"name":"Journal of contaminant hydrology","volume":"268 ","pages":"Article 104456"},"PeriodicalIF":3.5,"publicationDate":"2024-11-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142643982","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Micro-nano bubbles enhanced immobilized Chlorella vulgaris to remove ofloxacin from groundwater","authors":"Mengyao Jing ,&nbsp;Jianping Zhang ,&nbsp;Guijuan Li ,&nbsp;Dan Zhang ,&nbsp;Fengjia Liu ,&nbsp;Shengke Yang","doi":"10.1016/j.jconhyd.2024.104458","DOIUrl":"10.1016/j.jconhyd.2024.104458","url":null,"abstract":"<div><div>The phenomenon of antibiotic pollution has emerged as a significant global environmental concern. However, there is a lack of technical research on the effective removal of antibiotics based on the characteristics of the groundwater environment. This paper used micro-nano bubbles (MNBs) enhanced immobilized Chlorella technology to remove ofloxacin (OFLX) from groundwater. The study discussed the impact of initial antibiotic concentration (5–30 mg/mL), algae concentration (0.25–4 bead/mL), aeration time (5–30 min), and coexisting ions on the antibiotic removal rate and analyzed the removal mechanism by scanning electron microscopy (SEM) and Fourier transform infrared spectroscopy (FT-IR). The results showed that MNBs increased <em>Chlorella vulgaris</em> biomass by 2.48 times and significantly improved OFLX removal efficiency. The removal rate of OFLX exhibited a significant positive correlation with the algal concentration and coexisting ions and a significant negative correlation with the aeration time and the initial concentration of antibiotics. Enhanced immobilization of <em>Chlorella vulgaris</em> by MNBs for OFLX removal may involve -NH, -OH, -C=O, -CH₂, and -C-O-C groups. Degradation (including biodegradation and non-biodegradation) is the primary mechanism of antibiotic removal. Overall, intensive immobilization of Chlorella by MNBs promises to be a technically feasible method for removing antibiotics from groundwater.</div></div>","PeriodicalId":15530,"journal":{"name":"Journal of contaminant hydrology","volume":"268 ","pages":"Article 104458"},"PeriodicalIF":3.5,"publicationDate":"2024-11-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142662825","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Quantifying aquifer heterogeneity using superparamagnetic DNA particles","authors":"Swagatam Chakraborty ,&nbsp;Fuad Alqrinawi ,&nbsp;Jan Willem Foppen ,&nbsp;Jack Schijven","doi":"10.1016/j.jconhyd.2024.104454","DOIUrl":"10.1016/j.jconhyd.2024.104454","url":null,"abstract":"<div><div>Identifying and determining hydraulic parameters of physically heterogeneous aquifers is pivotal for flow field analysis, contaminant migration and risk assessment. In this research, we applied a novel uniquely sequenced DNA tagged superparamagnetic silica microparticles (SiDNAmag) to quantify hydraulic parameters and associated uncertainties of a heterogeneous sand tank. In the sand tank with lens shaped heterogeneity, we conducted three sets of multi – point injection experiments in unconsolidated (1) homogeneous (zone 0), (2) heterogeneous with a no-conductivity-zone (zone 1), and (3) heterogeneous with a high-conductive-zone (zone 2). From the breakthrough curves (BTC), we estimated the parameters distributions of hydraulic conductivity (k), effective porosity (n_e), longitudinal dispersivity (α_L), transverse vertical (α_TV), and transverse horizontal dispersivities (α_TH) applying Monte Carlo simulation approach for BTC fitting. The estimated parameters and associated uncertainties for each of the heterogeneous sections were further statistically compared (distribution non-specific Mann Whitney <em>U</em> test) these parameter distributions with parameter distributions estimated from the conservative salt tracer. While the time of arrival and time to peak concentration of SiDNAmag and salt in effluent were comparable, peak concentration of SiDNAmag was 1–3 log reduced as compared to the salt tracer due to first order kinetic attachment. Nonetheless, the parameters and associated uncertainty distributions (5 %–95 %) of K, n_e, α_L, α_TV, and α_TH, determined from SiDNAmag BTCs were statistically equivalent to the salt tracer in all three experiment systems. Through our experimental and modelling approach, our work demonstrated that in a coarse to very coarse grain sand medium, with lens shaped heterogeneity, the uniquely sequenced SiDNAmag were a promising tool to identify heterogeneity and determine hydraulic parameters and associated uncertainty distributions.</div></div>","PeriodicalId":15530,"journal":{"name":"Journal of contaminant hydrology","volume":"268 ","pages":"Article 104454"},"PeriodicalIF":3.5,"publicationDate":"2024-11-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142687231","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Quantification of contaminant mass discharge and uncertainties: Method and challenges in application at contaminated sites","authors":"A. Bøllingtoft ,&nbsp;P.L. Bjerg ,&nbsp;V. Rønde ,&nbsp;N. Tuxen ,&nbsp;W. Nowak ,&nbsp;M. Troldborg","doi":"10.1016/j.jconhyd.2024.104453","DOIUrl":"10.1016/j.jconhyd.2024.104453","url":null,"abstract":"<div><div>Contaminant mass discharge (CMD) estimation involves combining multilevel concentration and flow measurements to quantify the contaminant mass passing through a control plane downgradient of a point source. However, geological heterogeneities and limited data introduce uncertainties that complicate CMD estimation and risk assessment. Although CMD is increasingly used in groundwater management, methods for quantifying and handling these uncertainties are still needed. This study develops and tests a CMD estimation method based on Bayesian geostatistics to quantify CMD uncertainties using data from a control plane perpendicular to the contaminant plume.</div><div>By combining geostatistical conditional simulations of the spatial concentration distribution with the flow, an ensemble of CMD realizations is generated, from which a cumulative distribution function is derived. A key element of this approach is the use of a macrodispersive transport model to simulate the spatial concentration trend. This ensures that the estimated concentration reflects the expected physical behavior of the contaminant plume while also allowing the integration of site-specific conceptual information.</div><div>The method is applicable to plumes with dissolved contaminants, such as chlorinated solvents, petroleum hydrocarbons, <em>Per</em>- and polyfluoroalkyl substances (PFAS) and pesticides. Site-specific conceptual understanding is used to inform the prior probability density functions of the structural model parameters and to define acceptable simulated concentration limits. We applied the method at three sites contaminated with chlorinated ethenes, demonstrating its robustness across varying information levels and data availability.</div><div>Our results shows that strong site-specific conceptual knowledge and high sampling density constrain the CMD uncertainty (CV = 21 %) and results in estimated model parameters and a spatial concentration distribution that agrees well with the conceptual model. For a site with less data and limited conceptual knowledge, CMD and concentration distribution estimates are still feasible, though with higher uncertainty (CV = 41 %). Extending the method to account for multiple source zones and complex plume migration improved parameter identification and reduced the 95 % CMD confidence interval by 11 % ([4950–8750] to [5090–8480] g yr⁻¹), while also providing a spatial concentration distribution in better agreement with the plume conceptualization.</div><div>This study highlights the importance of integrating site-specific conceptual knowledge in CMD estimation, particularly for less-sampled sites. The method can furthermore assist in identifying remediation targets, evaluating remedial effectiveness, and optimizing sampling strategies.</div></div>","PeriodicalId":15530,"journal":{"name":"Journal of contaminant hydrology","volume":"268 ","pages":"Article 104453"},"PeriodicalIF":3.5,"publicationDate":"2024-11-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142621372","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}