Yuting Zhang , Yuwei Tang , Baoming Jin , Ruiping Yan , Li Zhang , Yilong Li , Jinchunzi Li , Shuang Liang
{"title":"Urea-modified hazelnut shell biochar (N-HSB) for efficient Cr(VI) removal: Performance and mechanism insights","authors":"Yuting Zhang , Yuwei Tang , Baoming Jin , Ruiping Yan , Li Zhang , Yilong Li , Jinchunzi Li , Shuang Liang","doi":"10.1016/j.jconhyd.2024.104414","DOIUrl":"10.1016/j.jconhyd.2024.104414","url":null,"abstract":"<div><p>Composite with a high specific surface area of 224.62 m<sup>2</sup> g<sup>−1</sup> was prepared by adding urea as a nitrogen source to hazelnut shell biochar (HSB). Nitrogen doping significantly enhanced the ability of biochar for Cr(VI) elimination, achieving twice the removal efficiency of unmodified biochar. The impacts of varying the pH and initial concentrations on Cr(VI) removal by urea-modified biochar (N-HSB) were investigated. The Cr(VI) removal by N-HSB was better described by intra particle diffusion model and pseudo-second order kinetic model under optimal conditions. Furthermore, XPS, FTIR, SEM, and BET analyses were used to verify the pivotal roles of oxygen- and nitrogen-containing functional groups. Electrostatic attraction, redox reaction, and complexation constituted the principal mechanisms facilitating Cr(VI) elimination by N-HSB. This study demonstrated that the modification of biochar with urea as a nitrogen source represented a promising strategy for enhancing the removal capacity of biochar for Cr(VI) in aqueous environments.</p></div>","PeriodicalId":15530,"journal":{"name":"Journal of contaminant hydrology","volume":"266 ","pages":"Article 104414"},"PeriodicalIF":3.5,"publicationDate":"2024-08-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142000066","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Jishi Geng , Hao Huang , Qiang Sun , Jianjun Hu , Qingmin Shi , Chao Lyu
{"title":"Study on the influence of different water and black shale content on the resistivity of loess","authors":"Jishi Geng , Hao Huang , Qiang Sun , Jianjun Hu , Qingmin Shi , Chao Lyu","doi":"10.1016/j.jconhyd.2024.104413","DOIUrl":"10.1016/j.jconhyd.2024.104413","url":null,"abstract":"<div><p>Soil degradation, characterized by the deterioration of soil physical and chemical properties, nutrient loss, and an increase in toxic substances, is a key ecological concern in mining activities. This study explores the use of waste black shale from mining development as an additive to loess to enhance soil properties for reclamation in mining areas. The research includes resistivity and organic carbon content tests on modified reclaimed loess with varying black shale and water contents. Additionally, the electrical properties of these modified soils are investigated across different AC frequencies. The results highlight the significance of soil plasticity and a 1.5% black shale content in influencing reclaimed loess's electrical properties. Moisture content and black shale influence changes in soil conductive paths and resistivity. The abundance of clay minerals in black shale plays a crucial role in altering soil electrical resistivity due to the adsorption of cations in water and the directional transport under an electric field. Considering soil's three-phase composition and diffuse bilayer structure, the study elucidates the mechanism behind changes in the electrical properties of improved reclaimed loess, accounting for water and black shale content. This research demonstrates the feasibility of using black shale as a soil additive and emphasizes the non-destructive assessment potential of electrical resistivity test (ERT) measurements for modified reclaimed soils.</p></div>","PeriodicalId":15530,"journal":{"name":"Journal of contaminant hydrology","volume":"266 ","pages":"Article 104413"},"PeriodicalIF":3.5,"publicationDate":"2024-08-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141964249","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Jéssica Rafaelly Almeida Lopes , Zabele Laís Lyra Mendonça , João Paulo Siqueira da Silva , Ademir Amaral , André Maciel Netto
{"title":"Enhancing herbicide adsorption in low-fertility soil using sugarcane biochar: Insights from Imazapic dynamics","authors":"Jéssica Rafaelly Almeida Lopes , Zabele Laís Lyra Mendonça , João Paulo Siqueira da Silva , Ademir Amaral , André Maciel Netto","doi":"10.1016/j.jconhyd.2024.104412","DOIUrl":"10.1016/j.jconhyd.2024.104412","url":null,"abstract":"<div><p>Biochar amendment has emerged as a potential solution for preventing, remediating, and mitigating agricultural compound pollution. This groundbreaking technique not only improves crucial soil properties like porosity, water retention capacity, cation exchange capacity, and pH, but also intricately impacts the interaction and retention mechanisms of polluting molecules. In this study, we investigate the dynamic of the herbicide Imazapic when subjected to applying pyrolyzed biochars, specifically at temperatures of 300 and 500 °C, within the context of a low-fertility soil characterized as dystrophic Yellow Ultisol (YUd) in a sugarcane cultivation area in Igarassu-PE, Brazil. The biochars were produced from sugarcane bagasse by pyrolysis process in a muffle furnace. In laboratory conditions, with saturated soil columns under steady-state, analyses of the mechanisms involved in interaction and transport and determining hydrodispersive parameters for Imazapic were performed by the two-site nonequilibrium transport model using the CXTFIT 2.0 program. Samples of YUd soil amended with biochar pyrolyzed at 300 °C presented a negligible interaction with Imazapic. However, adding biochar pyrolyzed at 500 °C (BC500) to the soil samples enhanced the adsorption coefficient and improved the interaction with Imazapic. This research points out that biochar produced from agricultural waste biomass, such as sugarcane bagasse specifically pyrolyzed at 500 °C, offers a potential means to adsorb herbicides, reducing their leaching to deeper layers of the amended soils and the risk of groundwater contamination and potential environmental negative impacts.</p></div>","PeriodicalId":15530,"journal":{"name":"Journal of contaminant hydrology","volume":"266 ","pages":"Article 104412"},"PeriodicalIF":3.5,"publicationDate":"2024-08-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141912860","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Microplastics and heavy metal contamination along a land-use gradient in a Himalayan foothill river: Prevalence and controlling factors","authors":"Sunil Kumar , Diptimayee Behera , Kumar Ajay , Balasubramanian Karthick , Chetan Dharia , Ambili Anoop","doi":"10.1016/j.jconhyd.2024.104411","DOIUrl":"10.1016/j.jconhyd.2024.104411","url":null,"abstract":"<div><p>The co-occurrence of microplastics (MPs) and heavy metals in aquatic systems has raised significant concerns, yet their relationship in freshwater ecosystems remains poorly understood. This study aims to evaluate the prevalence of MPs and factors controlling their distribution in both water and sediment in the Markanda River, Northwest India. MPs were extracted from sediment and water samples using density separation and classified through fluorescence microscopy and Raman spectroscopy. Metal concentrations in river water samples were analyzed using ICP-MS, and their correlation with MP abundance was explored. The results indicated the widespread occurrence of MP pollution across the Markanda River basin, with particle concentrations ranging from 10 to 530 particles L<sup>−1</sup> in surface water and 1330–4330 particles kg<sup>−1</sup> dry weight (dw) in sediment samples. The variability in MP abundance at sampling sites along the Markanda River courses results from factors such as the proximity of industrial establishments and human habitation, while the influence of grain size on MP distribution appears to be limited. Pellets (88.5 %) and fragments (8.5 %) were the most abundant types of MPs, with polyethylene (45.45 %) and polystyrene (30.9 %) being the dominant forms in water samples. The ICP-MS analysis of heavy metals in water samples indicated elevated levels of As (1.67 to 32.31 ppb) in downstream areas of the river system, influenced by human activities. While metals exhibited correlation with each other, there was a weak association, except for As, with the levels of MPs in the Markanda River. The SEM-EDX analyses to characterize chemical elements absorbed onto the surface of MP showed distinct variations in upstream and downstream sites, with the presence of elements such as Mn, Ni, Cr, Zn, As, Se, and Cu found in downstream areas. We conclude that MPs contaminated with heavy metals potentially threaten the ecological security of freshwater aquatic systems and highlight the importance of management action to reduce plastic pollution worldwide.</p></div>","PeriodicalId":15530,"journal":{"name":"Journal of contaminant hydrology","volume":"266 ","pages":"Article 104411"},"PeriodicalIF":3.5,"publicationDate":"2024-07-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141993623","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Unveiling the ecotoxicological impact of microplastics on organisms - the persistent organic pollutant (POP): A comprehensive review","authors":"Sneha Siwach , Meghali Bharti , Sheetal Yadav , Padma Dolkar , Sonakshi Modeel , Pankaj Yadav , Tarana Negi , Ram Krishan Negi","doi":"10.1016/j.jconhyd.2024.104397","DOIUrl":"10.1016/j.jconhyd.2024.104397","url":null,"abstract":"<div><p>Microplastics have been ubiquitous in our environment for decades, and numerous studies have revealed their extensive dispersion, reaching far beyond the surface of the land, soil, aquatic ecosystems. They have infiltrated the food-chain, the food web, even the air we breathe, as well as the water we drink. Microplastics have been detected in the food we consume, acting as vectors for hazardous chemicals that adhere to their hydrophobic surfaces. This can result in the transfer of these chemicals to the aquatic life, posing a threat to their well-being. The release of microplastics into different environmental settings can give rise to various eco-toxicological implications. The substantial body of literature has led scientists to the consensus that microplastic pollution is a global problem with the potential to impact virtually any type of ecosystem. This paper aims to discuss crucial information regarding the occurrence, accumulation, and ecological effects of microplastics on organisms. It also highlights the new and emerging disease named “Plasticosis” that is directly linked to microplastics and its toxicological effects like permanent scarring and long-term inflammation in the digestive system of the seabirds. By comprehending the behaviour of these microplastic pollutants in diverse habitats and evaluating their ecological consequences, it becomes possible to facilitate a better understanding of this toxicological issue.</p></div>","PeriodicalId":15530,"journal":{"name":"Journal of contaminant hydrology","volume":"266 ","pages":"Article 104397"},"PeriodicalIF":3.5,"publicationDate":"2024-07-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141766191","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Swagatam Chakraborty , Rayan Elhaj , Jan Willem Foppen , Jack F. Schijven
{"title":"Dispersion of silica-encapsulated DNA magnetic particles in a homogeneous sand tank","authors":"Swagatam Chakraborty , Rayan Elhaj , Jan Willem Foppen , Jack F. Schijven","doi":"10.1016/j.jconhyd.2024.104410","DOIUrl":"10.1016/j.jconhyd.2024.104410","url":null,"abstract":"<div><p>In this study, we focused on the 3D dispersion of colloids. To our knowledge, we were the first to do so. Thereto, we injected silica encapsulated DNA tagged superparamagnetic particles (SiDNAmag) in a homogeneous coarse grain sand tank. At four downstream locations, SiDNAmag concentrations were determined as a function of time. Longitudinal and transverse dispersivity values and associated uncertainties of SiDNAmag were determined using Monte Carlo modelling approach. The parameter associated uncertainties of hydraulic conductivity as well as of the effective porosity estimated from SiDNAmag breakthrough curves were statistically similar to those estimated from salt tracer breakthrough curves. Further, the SiDNAmag dispersivity uncertainty ranges were then statistically compared with the salt tracer (NaCl, and fluorescein) dispersivities. Our results indicated that time to rise, time of peak concentration and shape of the breakthrough curves of SiDNAmag were similar to those of the salt tracer breakthrough curves. Despite the size difference between the salt tracer molecules and SiDNAmag, size exclusion did not occur, probably due to the large pore throat diameter to SiDNAmag diameter ratio. The median longitudinal dispersivity (α<sub>L</sub>) of salt tracer and SiDNAmag were 4.9 and 5.8 × 10<sup>−4</sup> m, respectively. The median ratio of horizontal and vertical transverse dispersivities to α<sub>L</sub>, (α<sub>TH</sub> /α<sub>L</sub> and α<sub>TV</sub> /α<sub>L</sub>, respectively), for salt tracer and SiDNAmag ranged between 0.52 and 0.56. Through the statistical tests, we concluded that the longitudinal and traverse dispersivities of SiDNAmag were not statistically significantly different from salt tracer in 3 dimensions and could be used to characterize the dispersive properties of the medium we used. Our work contributes to a better understanding of 3D dispersion of SiDNAmag in saturated porous media.</p></div>","PeriodicalId":15530,"journal":{"name":"Journal of contaminant hydrology","volume":"266 ","pages":"Article 104410"},"PeriodicalIF":3.5,"publicationDate":"2024-07-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S0169772224001141/pdfft?md5=af360fe3f88ce834833b87efe47b6e66&pid=1-s2.0-S0169772224001141-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141788235","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Rajesh Debnath , Gora Shiva Prasad , Adnan Amin , Monisa M. Malik , Ishtiyaq Ahmad , Adnan Abubakr , Simanku Borah , Mohd Ashraf Rather , Federica Impellitteri , Ifra Tabassum , Giuseppe Piccione , Caterina Faggio
{"title":"Understanding and addressing microplastic pollution: Impacts, mitigation, and future perspectives","authors":"Rajesh Debnath , Gora Shiva Prasad , Adnan Amin , Monisa M. Malik , Ishtiyaq Ahmad , Adnan Abubakr , Simanku Borah , Mohd Ashraf Rather , Federica Impellitteri , Ifra Tabassum , Giuseppe Piccione , Caterina Faggio","doi":"10.1016/j.jconhyd.2024.104399","DOIUrl":"10.1016/j.jconhyd.2024.104399","url":null,"abstract":"<div><p>Improper disposal of household and industrial waste into water bodies has transformed them into de facto dumping grounds. Plastic debris, weathered on beaches degrades into micro-particles and releases chemical additives that enter the water. Microplastic contamination is documented globally in both marine and freshwater environments, posing a significant threat to aquatic ecosystems. The small size of these particles makes them susceptible to ingestion by low trophic fauna, a trend expected to escalate. Ingestion leads to adverse effects like intestinal blockages, alterations in lipid metabolism, histopathological changes in the intestine, contributing to the extinction of vulnerable species and disrupting ecosystem balance. Notably, microplastics (MPs) can act as carriers for pathogens, potentially causing impaired reproductive activity, decreased immunity, and cancer in various organisms. Studies have identified seven principal sources of MPs, including synthetic textiles (35%) and tire abrasion (28%), highlighting the significant human contribution to this pollution. This review covers various aspects of microplastic pollution, including sources, extraction methods, and its profound impact on ecosystems. Additionally, it explores preventive measures, aiming to guide researchers in selecting techniques and inspiring further investigation into the far-reaching impacts of microplastic pollution, fostering effective solutions for this environmental challenge.</p></div>","PeriodicalId":15530,"journal":{"name":"Journal of contaminant hydrology","volume":"266 ","pages":"Article 104399"},"PeriodicalIF":3.5,"publicationDate":"2024-07-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S0169772224001037/pdfft?md5=9d867d626dbd230cc14e62c059a23296&pid=1-s2.0-S0169772224001037-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141732301","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Anna Yu. Romanchuk , Alexander L. Trigub , Stepan N. Kalmykov
{"title":"Going deeper into plutonium sorption affected by redox","authors":"Anna Yu. Romanchuk , Alexander L. Trigub , Stepan N. Kalmykov","doi":"10.1016/j.jconhyd.2024.104400","DOIUrl":"10.1016/j.jconhyd.2024.104400","url":null,"abstract":"<div><p>Sorption of Pu(VI) onto synthesized goethite under oxidizing and normal conditions was investigated, which revealed its pH dependence on different solid/liquid ratios. Pu speciation upon sorption on the solid phase was characterized via extended X-ray absorption fine structure (EXAFS) spectroscopy, while that in solution was assessed using ultraviolet–visible (UV–Vis) spectroscopy and liquid–liquid extraction. The obtained results demonstrate differences in plutonium behavior in the studied systems. Pu(VI) remains hexavalent on the goethite surface and in solution under oxidizing conditions. While Pu(IV) is stabilized on the mineral and Pu(V) is found in solution under normal conditions. This study provides the thermodynamic descriptions of these reactions.</p></div>","PeriodicalId":15530,"journal":{"name":"Journal of contaminant hydrology","volume":"266 ","pages":"Article 104400"},"PeriodicalIF":3.5,"publicationDate":"2024-07-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141636723","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Traversing the prevalence of microplastics in soil-agro ecosystems: Origin, occurrence, and pollutants synergies","authors":"Kanika Dogra , Manish Kumar , Kanchan Deoli Bahukhandi , Jian Zang","doi":"10.1016/j.jconhyd.2024.104398","DOIUrl":"10.1016/j.jconhyd.2024.104398","url":null,"abstract":"<div><p>The ubiquity of plastics in modern life has made them a significant environmental concern and a marker of the Anthropocene era. The degradation of plastics results in the formation of microplastics (MPs), which measure 5 mm or less. The coexistence of MPs with other pollutants found in sludge, water treatment plant effluents, surface water, and groundwater, shapes the environmental landscape together. Despite extensive investigation, the long-term implications of MPs in soils remain uncertain, underscoring the importance of delving into their transportation and interactions with soil biota and other contaminants. The present article provides a comprehensive overview of MPs contamination in soil, encompassing its sources, prevalence, features, and interactions with soil flora and fauna, heavy metals, and organic compounds. The sources of MPs in soil agroecosystems are mulching, composting, littering, sewage sludge, irrigation water, and fertilizer application. The concentration of MPs reported in plastic mulch, littering, and sewage sludge is 503 ± 2760 items per kg<sup>−1</sup>, 4483 ± 2315 MPs/kg, and 11,100 ± 570 per/kg. The transport of MPs in soil agroecosystems is due to their horizontal and vertical migration including biotic and abiotic mobility. The article also highlighted the analytical process, which includes sampling planning, collection, purification, extraction, and identification techniques of MPs in soil agroecosystems. The mechanism in the interaction of MPs and organic pollutants includes surface adsorption or adhesion cation bridging, hydrogen bonding, charge transfer, ligand exchange, van der Waals interactions, and ion exchange.</p></div>","PeriodicalId":15530,"journal":{"name":"Journal of contaminant hydrology","volume":"266 ","pages":"Article 104398"},"PeriodicalIF":3.5,"publicationDate":"2024-07-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141711740","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Changyuan Wang , Xin Liu , Qianqian Ma , Shuyu Xing , Lubin Yuan , Yan Ma
{"title":"Distribution and effects of microplastics as carriers of heavy metals in river surface sediments","authors":"Changyuan Wang , Xin Liu , Qianqian Ma , Shuyu Xing , Lubin Yuan , Yan Ma","doi":"10.1016/j.jconhyd.2024.104396","DOIUrl":"10.1016/j.jconhyd.2024.104396","url":null,"abstract":"<div><p>There are few studies on microplastics (MPs) in urban river sediments compared to oceans, soils, and even rivers. In this study, the seasonal abundance of MPs, as well as their influencing factors on heavy metal adsorption in river sediments of the Ancient Canal of Zhenjiang City, China, were investigated for the first time. Through on-site sampling, microscopic observation, Raman spectroscopy, scanning electron microscopy, and high-temperature digestion, the abundance, shape, color, particle size, type, and surface characteristics of MPs in Ancient Canal sediments in different seasons, as well as the influencing factors of MPs as heavy metal carriers in different seasons, were analyzed. The results showed that the average abundance of MPs is 2049.09 ± 883.78 and 2216.36 ± 826.21 items kg<sup>−1</sup> dry sediments in summer and winter, respectively, and different sites change significantly. In addition, particle sizes, types, colors, and shapes of MPs exhibited seasonal variations. Four MPs shapes were mainly observed: fibers, fragments, particles, and films. Among them, MPs in summer sediments are mainly fiber, and MPs in winter sediments are mainly particles. In the sediment in summer and winter, transparent MPs and small-size (<0.5 mm) MPs are the main ones, where the abundance of MPs decreased with increasing MPs size. The main MPs species are polyvinyl chloride (PVC), polystyrene (PS), polypropylene (PP), polyethylene terephthalate (PET), polycarbonate (PC), and polyethylene (PE), with PP being the predominant MPs in the sediments in different seasons. Scanning electron microscopy-energy dispersive spectrometer (SEM-EDS) revealed that the surfaces of the MPs were characterized by rough, porous, cracked, and torn, with the attachment of various heavy metal elements, and all of the heavy metal elements accumulated to different degrees on the MPs. There was a significant positive correlation (<em>p</em> < 0.05) between the Mn content in the MPs and the Mn content in the sediments in winter, suggesting that the Mn in the MPs in winter may be derived from the sediments. In addition, the type, shape, size, and color of MPs affect the adsorption capacity of heavy metals. Most of the adsorption of MPs on Pb showed a significant negative correlation, and the adsorption of MPs on Cr, Zn, Cu, Cd, and Mn showed a significant positive correlation. MPs can be used as carriers of heavy metals, which will further enhance the hazards of living organisms and pose a potential threat to the safety of the urban river environment.</p></div>","PeriodicalId":15530,"journal":{"name":"Journal of contaminant hydrology","volume":"266 ","pages":"Article 104396"},"PeriodicalIF":3.5,"publicationDate":"2024-07-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141690343","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}