Aliya Zh. Omarova, Talgatbek Ayazbaev, Zhanar S. Yesdauletova, Sholpan A. Aldabergen, Artem L. Kozlovskiy, Gulnaz Zh. Moldabayeva
{"title":"Evaluation of the Applicability of Modifying CdSe Thin Films by the Addition of Cobalt and Nickel to Enhance the Efficiency of Photocatalytic Decomposition of Organic Dyes","authors":"Aliya Zh. Omarova, Talgatbek Ayazbaev, Zhanar S. Yesdauletova, Sholpan A. Aldabergen, Artem L. Kozlovskiy, Gulnaz Zh. Moldabayeva","doi":"10.3390/jcs7110460","DOIUrl":"https://doi.org/10.3390/jcs7110460","url":null,"abstract":"This article presents the results of an assessment of the use of CdSe, NiCdSe, and CoCdSe thin films as a basis for photocatalysts used for the decomposition of the organic dyes rhodamine B, cargo red, and indigo carmine. Interest in this area was determined by the need to solve a number of issues related to increasing the efficiency purifying aqueous media from the negative effects of organic dyes, which cannot be disposed of using traditional methods associated with adsorption or filtration. The use of the electrochemical synthesis method to obtain thin films of a given thickness showed that the addition of nickel or cobalt sulfates to the standard electrolyte solution used to obtain CdSe films results in the formation of CdSe films with a higher degree of structural ordering (the crystallinity degree was more than 50%), as well as a decline in the band gap. When analyzing data on the photocatalytic decomposition of organic dyes, it was found that a change in the structure of the films due to the introduction of nickel and cobalt leads, in the case of the decomposition of the rhodamine B dye, to a more efficient decomposition, and in the case of the cargo red and indigo carmine dyes, not only to their complete decomposition and mineralization, but also to a reduction in the time of photocatalytic reactions (decomposition growth rate). Moreover, an analysis of cyclic tests demonstrated that NiCdSe and CoCdSe films maintain 90% of their photocatalytic decomposition efficiency compared to that achieved during the first decomposition cycle, while CdSe degrades after three consecutive cycles and its efficiency reduces by more than 2.5–3 times.","PeriodicalId":15435,"journal":{"name":"Journal of Composites Science","volume":"13 S4","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2023-11-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"135872950","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Xiaowen Han, Xinru Zuo, Ying Liu, Zixing Wang, Kefeng Cai
{"title":"Preparation and Properties of Flexible CuI/Polyvinylpyrrolidone Nanocomposite Thermoelectric Film","authors":"Xiaowen Han, Xinru Zuo, Ying Liu, Zixing Wang, Kefeng Cai","doi":"10.3390/jcs7110461","DOIUrl":"https://doi.org/10.3390/jcs7110461","url":null,"abstract":"A facile preparation method for flexible p-type CuI/polyvinylpyrrolidone (PVP) nanocomposite thermoelectric (TE) film is developed. First, CuI powder was synthesized by a one-pot method; second, PVP was coated in situ with the CuI powder; third, the CuI/PVP nanocomposite film was prepared on a nylon membrane by vacuum filtration and then hot-pressing. Transmission electron microscopy (TEM) observation indicates that the film consists of CuI nanograins with an average size of ~15 nm and PVP distributed at the inner wall of nanopores and the surface of the CuI nanograins. The composite film shows a large Seebeck coefficient of ~605 µVK−1 and a power factor of ~8.05 µWm−1K−2 at 300 K. The nanocomposite film also exhibits excellent flexibility (~96% of initial electrical conductivity retention after being bent 1000 times along a 4 mm radius rod). A single-leg TE module outputs a voltage of ~3.6 mV when the temperature difference is 6 K. This work provides a fast, simple, and environmentally friendly method by which to prepare flexible CuI/PVP nanocomposite TE film with a large Seebeck coefficient, which could be used as a wearable sensor.","PeriodicalId":15435,"journal":{"name":"Journal of Composites Science","volume":"8 2","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2023-11-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"135818946","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Marco Dederichs, Oliver Lackner, Harald Kuepper, Mike Decker, Stephanie Viebranz, Christoph-Ludwig Hennig, Arndt Guentsch, Christine Kuepper
{"title":"An Explorative Evaluation on the Influence of Filler Content of Polyetheretherketone (PEEK) on Adhesive Bond to Different Luting Resin Cements","authors":"Marco Dederichs, Oliver Lackner, Harald Kuepper, Mike Decker, Stephanie Viebranz, Christoph-Ludwig Hennig, Arndt Guentsch, Christine Kuepper","doi":"10.3390/jcs7110456","DOIUrl":"https://doi.org/10.3390/jcs7110456","url":null,"abstract":"Polyetheretherketone (PEEK) is considered one of the most innovative prosthetic materials of the last few decades. Its chemically inert behavior and high biocompatibility make it a promising material in many areas of dentistry. The aim of this study was to test whether PEEK with different TiO2 filler contents achieves comparable bond strength values when using different resin cements. N = 70 PEEK samples each with different TiO2 filler content (20 wt.% TiO2 vs. 5 wt.% TiO2 vs. no filler as a control group) were divided into seven groups and cemented with various conventional (ResiCem, RelyX Ultimate, Variolink Esthetic DC) and self-adhesive resin cements (RelyXUnicem 2, Bifix SE, Panavia SA Cement Plus, SpeedCem). The shear strength of the bond was assessed after 24 h and after 25,000 thermal loading cycles. Mann-Whitney U and Wilcoxon tests were used for statistical analysis (significance level: α = 0.05). PEEK without filler showed the highest mean shear strength (24.26 MPa using RelyX Ultimate), then high-filled PEEK (22.90 MPa using ResiCem) and low-filled PEEK (21.76 MPa using RelyX Ultimate). Conventional resin cements generally achieved slightly higher adhesive strengths than self-adhesive resin cements. It appears that the filler content does not affects the adhesive bond strengths.","PeriodicalId":15435,"journal":{"name":"Journal of Composites Science","volume":"20 3","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2023-11-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"135935299","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Kon-Bae Lee, Kanhu C. Nayak, Cheol-Hwee Shim, Hye-In Lee, Se-Hoon Kim, Hyun-Joo Choi, Jae-Pyoung Ahn
{"title":"Tensile Properties of Aluminum Matrix Composites Produced via a Nitrogen-Induced Self-Forming Process","authors":"Kon-Bae Lee, Kanhu C. Nayak, Cheol-Hwee Shim, Hye-In Lee, Se-Hoon Kim, Hyun-Joo Choi, Jae-Pyoung Ahn","doi":"10.3390/jcs7110457","DOIUrl":"https://doi.org/10.3390/jcs7110457","url":null,"abstract":"This study compares the tensile properties of commercial aluminum matrix composites (AMCs) with those of AMCs produced via a nitrogen-induced self-forming process. This process is a newly developed AMCs manufacturing process that takes advantage of the price competitiveness and productivity of large-scale products produced via the liquid process. Additionally, this process has the freedom of choice of the reinforcement phase and the homogeneous dispersibility of the powder process. Compared to commercial monolithic 6061 alloys, 6061 aluminum alloy matrix composites exhibit increased Young’s modulus, yield strength, and ultimate tensile strength by 59%, 66%, and 81%, respectively. This study also compares the tensile properties of AMCs with different matrix compositions, including 2009 and 7050 aluminum alloys. The study shows that AMCs produced using the nitride-induced self-forming aluminum composite (NISFAC) process exhibit comparable or superior tensile properties to those obtained using existing commercial powder metallurgy (P/M) processes.","PeriodicalId":15435,"journal":{"name":"Journal of Composites Science","volume":"5 3","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2023-11-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"135973603","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Green Synthesised Silver Nanoparticles Using Anoectochilus elatus Leaf Extract: Characterisation and Evaluation of Antioxidant, Anti-Inflammatory, Antidiabetic, and Antimicrobial Activities","authors":"Bhuvaneshwari Venkataesan Kumari, Renuka Mani, Balakrishnan Ramajayam Asokan, Karthikeyan Balakrishnan, Arulmani Ramasamy, Rengasamy Parthasarathi, Chitra Kandasamy, Rubalakshmi Govindaraj, Natesan Vijayakumar, Sekar Vijayakumar","doi":"10.3390/jcs7110453","DOIUrl":"https://doi.org/10.3390/jcs7110453","url":null,"abstract":"The present study investigates the green synthesis of silver nanoparticles was carried out using a leaf extract of Anoectochilus elatus (Ae-AgNPs). The synthesised Ae-AgNPs were characterised using different analytical techniques like UV-visible spectroscopy, X-ray diffraction (XRD), Fourier transform infrared (FTIR), and scanning electron microscopy (SEM) with energy-dispersive X-ray analysis (EDX). Additionally, in vitro activities were investigated, and they possess antioxidant, anti-inflammatory, antidiabetic, and antimicrobial properties. The UV-Vis spectra exhibited characteristic absorption peaks at approximately 480 nm. FTIR identified functional groups of the Ae-AgNPs. The crystalline structure of the Ae-AgNPs was verified via XRD analysis. SEM studies revealed that the nanoparticles exhibited a spherical morphology. The fabrication of Ae-AgNPs was established by the EDX spectrum, which exhibited prominent signals of silver atoms. The Ae-AgNPs show potent antioxidant, anti-inflammatory, and antidiabetic activity compared to standard drugs. In addition, Ae-AgNPs demonstrated the most significant zone of Inhibition. This study affirms the superior biological capability of Ae-AgNPs for target drug delivery and their potential for usage in biomedical research and therapeutics.","PeriodicalId":15435,"journal":{"name":"Journal of Composites Science","volume":"54 3","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2023-11-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"135221358","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Jesús Daniel Aragón-Vallejo, Beatriz Adriana Salazar-Cruz, María Yolanda Chávez-Cinco, José Luis Rivera-Armenta, Ana Cecilia Espindola-Flores
{"title":"Novel PolyPropylene–Sargassum Particles Composites: Evaluation of Thermal and Thermomechanical Properties","authors":"Jesús Daniel Aragón-Vallejo, Beatriz Adriana Salazar-Cruz, María Yolanda Chávez-Cinco, José Luis Rivera-Armenta, Ana Cecilia Espindola-Flores","doi":"10.3390/jcs7110455","DOIUrl":"https://doi.org/10.3390/jcs7110455","url":null,"abstract":"Sargassum is a type of marine algae that has caused environmental problems in Mexico because it arrives in high quantities along the Mexican coast, especially in the Mexican Caribbean. This situation has become an environmental and economic problem, impacting tourism and other activities. As a result, it is reasonable to try to find an application for these algae. Recently, some applications in civil construction, cosmetics, and the food industry, among others, have been reported. The present work evaluates the thermal and structural properties of new polypropylene (PP)–Sargassum-based composites. Also, the effect of adding calcium stearate (CS) to increase the interaction between PP and Sargassum particles was investigated. PP–Sargassum particle composites were prepared by a melt mixing process, and the properties of these composites were evaluated using thermal techniques such as dynamic mechanical analysis (DMA), thermogravimetric analysis (TGA), differential scanning calorimetry (DSC), X-ray diffraction (XRD), and infrared spectroscopy (FTIR). The DMA results showed that composites with low concentrations of Sargassum particles perform better than those with higher concentrations. When CS was added to composites, there was a significant improvement in storage modulus compared with composites without CS. This was attributed to the good adhesion of the particles to the matrix because the mobility of macromolecules increased in the presence of CS. The thermal stability of PP–Sargassum particle composites decreases when the amount of particles increases, and the addition of CS does not positively affect the thermal behavior of composites. The findings open the possibility of using Sargassum particles in new applications of these algae as a polymer additive to generate sustainable materials.","PeriodicalId":15435,"journal":{"name":"Journal of Composites Science","volume":"14 6","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2023-11-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"135326128","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Andrey A. Belmesov, Alexander A. Glukhov, Maxim V. Tsvetkov, Lyubov V. Shmygleva, Timofey A. Shikhov, Aleksey O. Lembikov, Anton A. Belov, Nikita P. Ivanov, Oleg O. Shichalin
{"title":"Synthesis and Properties of Rubidium Salts of Phosphotungstic Acid","authors":"Andrey A. Belmesov, Alexander A. Glukhov, Maxim V. Tsvetkov, Lyubov V. Shmygleva, Timofey A. Shikhov, Aleksey O. Lembikov, Anton A. Belov, Nikita P. Ivanov, Oleg O. Shichalin","doi":"10.3390/jcs7110454","DOIUrl":"https://doi.org/10.3390/jcs7110454","url":null,"abstract":"The work is devoted to the study of the influence of synthesis conditions on the properties of water-insoluble rubidium salts of phosphotungstic acid (PTA). Such heteropoly compounds have a wide range of applications, including in the field of electrocatalysts and solid electrolytes for various electrochemical devices. The acid salts of PTA with high activity of acid sites on the particle surface are of particular interest. It is known that the properties of water-insoluble PTA salts strongly depend on synthesis conditions, such as the ratio of reagents, temperature, concentrations, and other parameters. The work examines the influence of the ratio and concentration of reagents on the sizes of crystallites and agglomerates, specific surface area (SSA), porosity, water content, and ionic conductivity of the synthesized PTA salts. The SSA value of the obtained samples varied in the range of 84–123 m2 g−1, and the ionic conductivity was 13–90 mS cm−1 at room temperature and 75% RH. An increase in the acid concentration and the degree of proton substitution led to an increase in SSA, accompanied by an increase in particle sizes without changing the size of crystallites. The results of the work may be useful for the development of new materials based on the obtained salts in many fields, including hydrogen energy.","PeriodicalId":15435,"journal":{"name":"Journal of Composites Science","volume":"27 1-2","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2023-11-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"135325544","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Azamat Taurbekov, Alisher Abdisattar, Meiram Atamanov, Bayan Kaidar, Mukhtar Yeleuov, Reza Joia, Rachid Amrousse, Tolganay Atamanova
{"title":"Investigations of Activated Carbon from Different Natural Sources for Preparation of Binder-Free Few-Walled CNTs/Activated Carbon Electrodes","authors":"Azamat Taurbekov, Alisher Abdisattar, Meiram Atamanov, Bayan Kaidar, Mukhtar Yeleuov, Reza Joia, Rachid Amrousse, Tolganay Atamanova","doi":"10.3390/jcs7110452","DOIUrl":"https://doi.org/10.3390/jcs7110452","url":null,"abstract":"In this study, we present another approach to fabricating high-performance supercapacitor electrodes by combining activated carbon particles with carbon nanotubes (AC/CNT). We synthesized activated carbon from diverse biomass sources using a carbonization process and chemical activation with KOH. By incorporating carbon nanotubes, we significantly augmented the electrode’s surface area, resulting in exceptional ion transport and a substantial increase in specific capacitance. Our investigation reveals that the optimized composition, 85:10:5 of AC, CNT, and conductive additive, achieved outstanding specific capacitance values, notably 125.6 F g−1 at 1 mV s−1 and 118 F g−1 at 1 A g−1, along with a maximum energy density of 4 Wh kg−1. Electrochemical impedance spectroscopy (EIS) further demonstrated the superior charge transfer capabilities of these electrodes, notably at a frequency range from 100 kHz to 10 mHz. Additionally, our research highlights the influence of different biomass precursors, such as apricot kernels, walnut shells, and rice husks, on the electrochemical behavior of these electrodes. Overall, this study provides valuable insights into the development of high-performance supercapacitors, emphasizing the potential of diverse biomass sources in optimizing electrode materials.","PeriodicalId":15435,"journal":{"name":"Journal of Composites Science","volume":"34 2","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2023-10-31","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"135808702","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Clara González-Chomón, Vasil M. Garamus, Judith Hoyland, Silvia S. Halacheva
{"title":"Trimethoxy Silyl End-Capped Hyperbranched Polyglycidol/Polycaprolactone Particle Gels for Cell Delivery and Tissue Repair: Mechanical Properties, Biocompatibility, and Biodegradability Studies","authors":"Clara González-Chomón, Vasil M. Garamus, Judith Hoyland, Silvia S. Halacheva","doi":"10.3390/jcs7110451","DOIUrl":"https://doi.org/10.3390/jcs7110451","url":null,"abstract":"This study focuses on the development of new biocompatible and biodegradable particle gel scaffolds based on PCL-HBPG/1SiHBPG triblock copolymers composed of a polycaprolactone (PCL) core and two outer blocks of trimethoxysilyl end-capped hyperbranched polyglycidol (HBPG/1SiHBPG) that have the potential to be used in soft tissue regeneration. The relationship between the gel’s composition, structure, mechanical properties, and performance has been investigated for the first time and the copolymer design parameters have been optimized. The particle gel scaffolds were formed from the concentrated dispersions of the most hydrophobic PCL-45HBPG/1SiHBPG at low temperatures, and were the result of the numerous hydrogen bonds formed from the HBPG/1SiHBPG moieties as well as the formation of siloxane crosslinks (i.e., Si–O–Si bonds). These gels were formed in the physiological temperature range. Gels with a mechanical strength that gradually increases were formed from the physically crosslinked PCL-45HBPG/1SiHBPG particles effectively and safely, in the absence of UV radiation. They feature high elasticity and undergo enzyme-triggered disassembly. The gels are biocompatible and have the potential to invoke cell attachment and differentiation in the absence of exogenous biological stimuli. A successful outcome of this study will be the prospect of a new approach for tissue regeneration that is currently not available.","PeriodicalId":15435,"journal":{"name":"Journal of Composites Science","volume":"34 3","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2023-10-31","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"135808701","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Soodad A. Muhammed, Aseel Mohammed Al-Khafaji, Haydar H. J. Jamal Al-Deen
{"title":"The Influence of Strontium Oxide on the Physio-Mechanical Properties of Biomedical-Grade Titanium in Ti-SrO Composites","authors":"Soodad A. Muhammed, Aseel Mohammed Al-Khafaji, Haydar H. J. Jamal Al-Deen","doi":"10.3390/jcs7110449","DOIUrl":"https://doi.org/10.3390/jcs7110449","url":null,"abstract":"Dental implants can be made of various materials, and amongst them, titanium and titanium alloy were the materials of choice for dental implants for many years because of their biocompatibility. The two alloys have a high level of biocompatibility, a lower modulus of elasticity, and better corrosion resistance than other alloys. Thus, they are frequently utilized in biomedical applications and mostly replace stiff fabrics. The latest advances in a new strontium oxide–cp titanium composite alloy are the main topic of this research. With regard to biomedical applications, additions of strontium oxide were synthesized at three distinct weight percentages (2%, 4%, and 6% by wt%). Powder metallurgy was used to create the alloys, which were then sintered by heating the samples. The effects of adding strontium oxide were analyzed by utilizing measurements of the Brinell hardness, X-ray diffraction, porosity, diametral tensile strength, roughness, and wettability of the finished surfaces. The results show that adding more strontium oxide (gradually increasing the ratio from 2% SrO to a 6% addition) raised the roughness and porosity. However, the microhardness and diametral tensile strength were enhanced with an increase in the volume fraction of strontium oxide particles. In conclusion, the alloy that contained 6 wt% strontium oxide microparticles had reasonably high mechanical properties and might be regarded as suitable for use in dental and medical applications due to its high wettability or, in other words, its low contact angle. The Brinell testing results for the diametral tensile strength, microhardness, and porosity of the generated strontium oxide–cp titanium composite alloy demonstrate its high potential for usage as a biomaterial, particularly in dental applications.","PeriodicalId":15435,"journal":{"name":"Journal of Composites Science","volume":"19 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2023-10-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"136023146","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}