ChemPlusChemPub Date : 2025-08-23DOI: 10.1002/cplu.202500299
Juan Manuel Sieben, Andrea E. Alvarez, Myriam Torres García, Diana M. Arciniegas Jaimes, Noelia Bajales Luna, Elizabeth Laura Moyano
{"title":"Mandarin Peel-Derived Carbon-Supported PtPd Catalysts for the Electro-Oxidation of Glycerol in Alkaline Medium","authors":"Juan Manuel Sieben, Andrea E. Alvarez, Myriam Torres García, Diana M. Arciniegas Jaimes, Noelia Bajales Luna, Elizabeth Laura Moyano","doi":"10.1002/cplu.202500299","DOIUrl":"10.1002/cplu.202500299","url":null,"abstract":"<p>In this work, mandarin peel-derived biocarbons synthesized by fast pyrolysis are tested as support materials for PtPd nanoparticles for the electrochemical oxidation of glycerol in an alkaline electrolyte. The biocarbons, synthesized at 300 °C (mandarin peel-derived biocarbons (BCM)-300) and 500 °C (BCM-500), present good electronic conductivities and adequate surface properties. Bimetallic PtPd nanoparticles with average sizes between 3.5 and 3.9 nm and a Pt:Pd ratio of 3:1 are deposited over the biocarbons by a pulse microwave-assisted polyol method. The electrochemical experiments show that the mass-specific activity for the glycerol oxidation reaction of the PtPd particles supported over the biocarbons is higher than that reported for the bimetallic catalyst deposited over Vulcan carbon black. In addition, the catalyst deposited over the biocarbons presents lower potential onsets, lower apparent activation energies, and lower charge transfer resistances compared to the bimetallic particles supported over the commercial carbon material. The superior electrocatalytic performance of PtPd/BCM-300 and PtPd/BCM-500 catalysts is attributed to the synergistic effect between the bimetallic particles and the biocarbons, which promotes glycerol oxidation through both the electronic effects and the bifunctional mechanism.</p>","PeriodicalId":148,"journal":{"name":"ChemPlusChem","volume":"90 10","pages":""},"PeriodicalIF":2.8,"publicationDate":"2025-08-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144937222","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
ChemPlusChemPub Date : 2025-08-21DOI: 10.1002/cplu.202500380
Frank Müh, Julia Gätcke, Athina Zouni
{"title":"Quantifying the Influence of Poly(Ethylene glycol) on the Micelle Formation of Nonionic Detergents","authors":"Frank Müh, Julia Gätcke, Athina Zouni","doi":"10.1002/cplu.202500380","DOIUrl":"10.1002/cplu.202500380","url":null,"abstract":"<p>The influence of poly(ethylene glycol) (PEG with molecular weights between 400 and 4000) on the critical micelle concentration (CMC) of nonionic detergents with maltose as well as oligo(ethylene glycol) head groups is determined by using 8-anilinonaphthalene-1-sulfonate (ANS) as fluorescence probe. The CMC is found to increase with the concentration of PEG (0%–30% (w/v)) in a way that is determined by the molar concentration of oxyethylene (OE) units and independent of the molecular weight of the added polymer. The effect is explained with the extended conformation of PEG in aqueous solution allowing for an interaction of detergent monomers with individual OE units via their alkyl tails. The fluorescence spectra of ANS are found to exhibit two major emission peaks that are affected in position and intensity by binding to micelles as well as PEG. A model with two conformations of ANS combined with two binding sites in the micelles is used to explain the spectra and their correlation with detergent properties. The shapes of the titration curves are shown to depend on the aggregation number and the equilibrium constant describing binding of ANS to micelles and are analyzed to find that PEG competes with micelles for binding of ANS.</p>","PeriodicalId":148,"journal":{"name":"ChemPlusChem","volume":"90 10","pages":""},"PeriodicalIF":2.8,"publicationDate":"2025-08-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://chemistry-europe.onlinelibrary.wiley.com/doi/epdf/10.1002/cplu.202500380","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144937188","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Methylene Blue Dye Absorption Studies of PHEMA@MOF801 and PHEMA@MOF303 Hybrid Hydrogel Composites","authors":"Yasemin Samav, Sevde Demir, Gökhan Solmaz, Cansel Tuncer, Hakan Erer","doi":"10.1002/cplu.202500336","DOIUrl":"10.1002/cplu.202500336","url":null,"abstract":"<p>In this study, hybrid hydrogel composites combining two distinct metal-organic frameworks (MOFs) (MOF801 and MOF303) into a poly(2-hydroxyethyl methacrylate) (PHEMA) matrix are successfully fabricated and evaluated in terms of their pH-responsive swelling and dye adsorption performance. The MOF801 and MOF303 are dispersed into the hydrogel matrix by simple physical blending, ensuring the formation of hybrid materials without chemical bonding. Structural and morphological characterizations are performed using Fourier transform infrared spectroscopy, powder X-ray diffraction, scanning electron microscopy–energy-dispersive X-ray spectroscopy, and thermogravimetric–differential thermal analysis. Swelling behaviors of hydrogels are investigated in solutions with pH values of 3, 7, and 11. Among the tested conditions, the highest swelling ratios are observed at pH 11, with swelling percentages (S%) of 151%, 173%, and 164% for PHEMA, PHEMA@MOF303, and PHEMA@MOF801, respectively. Furthermore, the hydrogels are employed as adsorbents for the removal of cationic dye methylene blue. The dye removal efficiency (W%) is found to be 61.0% for MOF-free PHEMA, 67.6% for PHEMA@MOF801, and 75.0% for PHEMA@MOF303. The corresponding adsorption capacities (q) are calculated as 2.57, 2.43, and 3.95 mg g<sup>−1</sup>, respectively. UV–vis spectrophotometry is employed to monitor dye adsorption. These findings demonstrate the synergistic effects between coordination polymers and hydrogel matrices, offering promising insights for the development of responsive and efficient adsorbent materials for wastewater treatment.</p>","PeriodicalId":148,"journal":{"name":"ChemPlusChem","volume":"90 10","pages":""},"PeriodicalIF":2.8,"publicationDate":"2025-08-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144881790","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
ChemPlusChemPub Date : 2025-08-20DOI: 10.1002/cplu.202500453
Yihan Shi, Robert Plavan, Miguel A. Soto, Mark J. MacLachlan
{"title":"Acid-Responsive Inks via Shuttling in a Pseudorotaxane Complex","authors":"Yihan Shi, Robert Plavan, Miguel A. Soto, Mark J. MacLachlan","doi":"10.1002/cplu.202500453","DOIUrl":"10.1002/cplu.202500453","url":null,"abstract":"<p>Pseudorotaxanes are host-guest complexes where a guest molecule threads through a ring-shaped host via noncovalent interactions. If the guest has two recognition sites, the host can dynamically shuttle between them. These complexes enable stimulus-responsive molecular shuttles, where a stimulus, such as pH change, can control the position of the host, affecting properties like color and solubility. In this study, a guest molecule (<b>Gc</b>) with two recognition sites—1,4-dialkoxyphenylene and pH-sensitive 1,5-diaminonaphthalene—is synthesized. These sites interact strongly with cyclobis(paraquat-<i>p</i>-phenylene) (<b>CBPQT<sup>4</sup><sup>+</sup></b>), a cationic host. <b>CBPQT<sup>4</sup><sup>+</sup></b> binds to the neutral diaminonaphthalene group to produce a green solution. Upon protonation of the diaminonaphthalene group, the host shifts to the dialkoxyphenylene site, turning the solution light orange. This color-switching behavior remains stable over multiple protonation-deprotonation cycles. The pseudorotaxane complex can also be disassembled via slow solvent diffusion, allowing recovery of the <b>Gc</b> and <b>CBPQT<sup>4</sup><sup>+</sup></b> components. Additionally, cellulose nanocrystal films incorporating the <b>Gc</b>⊂<b>CBPQT<sup>4</sup><sup>+</sup></b> complex show similar green-to-orange color shifts, demonstrating their potential for information encryption applications.</p>","PeriodicalId":148,"journal":{"name":"ChemPlusChem","volume":"90 10","pages":""},"PeriodicalIF":2.8,"publicationDate":"2025-08-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://chemistry-europe.onlinelibrary.wiley.com/doi/epdf/10.1002/cplu.202500453","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144937277","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
ChemPlusChemPub Date : 2025-08-20DOI: 10.1002/cplu.202500312
Sohan Lal, Prashanth Goud Banda, Gangavara L. Tejashree, Dilshad Javed, Neeraj Kumbhakarna, Arindrajit Chowdhury, Irishi N. N. Namboothiri
{"title":"Development of Polynitrogen and Halogen-Containing Bishomocubane-Based High Energy Density Materials: Synthetic, Theoretical, and Thermogravimetric Studies","authors":"Sohan Lal, Prashanth Goud Banda, Gangavara L. Tejashree, Dilshad Javed, Neeraj Kumbhakarna, Arindrajit Chowdhury, Irishi N. N. Namboothiri","doi":"10.1002/cplu.202500312","DOIUrl":"10.1002/cplu.202500312","url":null,"abstract":"<p>Novel nitro, tetrazole, and halo-substituted 1,3-bishomocubanes have been successfully synthesized and characterized by various spectroscopic and analytical techniques, including single-crystal X-ray analysis. According to Density Functional Theory (DFT) calculations, performed at B3LYP/6-311++G(d, p) level of theory, the densities and heats of formation of the newly synthesized compounds are in the range of 1.52–2.26 g cm<sup>−3</sup> and −70.8–111.4 kcal mol<sup>−1</sup>, respectively. These compounds are predicted to exhibit enhanced propulsive properties in terms of density-specific impulse (ρIsp), compared to that of conventional liquid propellant RP1 and solid propellant binder hydroxy-terminated polybutadiene (HTPB), which makes them potential candidates for volume-limited propulsion systems. However, two derivatives have exceptional calculated figures of merit for volume-limited propulsion systems, a dibromoester (ρIsp 415.8 s), and a dibromonitroalcohol (ρIsp 421.3 s). Though its detonation properties indicate low explosive potential, the dibromonitroalcohol possesses the highest detonation pressure (20.1 GPa) and velocity (6.3 Km s<sup>−1</sup>), which are closer to the detonation performance of trinitrotoluene (TNT). Stability parameters, including Highest Occupied Molecular Orbital (HOMO) and Lowest Unoccupied Molecular Orbital (LUMO) energy gaps, thermogravimetric analysis, and differential thermal analysis, confirm the robust kinetic and thermal stability of our compounds.</p>","PeriodicalId":148,"journal":{"name":"ChemPlusChem","volume":"90 10","pages":""},"PeriodicalIF":2.8,"publicationDate":"2025-08-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144881789","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
ChemPlusChemPub Date : 2025-08-19DOI: 10.1002/cplu.202400601
Jose M González-Domínguez
{"title":"Rethinking Dispersion in Nanotechnology: Biopolymer Nanostructures as Green Enablers of Functional Integration.","authors":"Jose M González-Domínguez","doi":"10.1002/cplu.202400601","DOIUrl":"10.1002/cplu.202400601","url":null,"abstract":"<p><p>The integration of carbon-based and inorganic nanoparticles into practical technologies requires their dispersion in liquid media, a step that remains a major bottleneck due to structural degradation and unsustainable processing methods. Biopolymer ?>nanostructures, particularly nanocellulose, offer a dual advantage: they are high-performance, renewable materials and can facilitate the aqueous dispersion of otherwise insoluble or hydrophobic nanoparticles. This function extends beyond passive stabilization, potentially enabling more sustainable and structurally preserving processing routes. However, current literature often underrepresents this active role of nanocellulose. Here, initial findings that demonstrate nanocellulose's capacity to mediate nanoparticle dispersion while preserving their integrity and enhancing process sustainability are presented. These results suggest a broader utility for nanocellulose in nanotechnology, not merely as a support material but as a transformative processing agent. This perspective proposes a shift in how nanocellulose is viewed and utilized, potentially marking the beginning of a more sustainable paradigm in nanomaterials engineering.</p>","PeriodicalId":148,"journal":{"name":"ChemPlusChem","volume":" ","pages":"e202400601"},"PeriodicalIF":2.8,"publicationDate":"2025-08-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144870581","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
ChemPlusChemPub Date : 2025-08-19DOI: 10.1002/cplu.202500390
Lorenzo Veronico, Luigi Gentile
{"title":"Salt-Induced Modulation of Self-Assembly in C8-10 AlkylPolyGlucoside/Fatty Alcohol Formulations","authors":"Lorenzo Veronico, Luigi Gentile","doi":"10.1002/cplu.202500390","DOIUrl":"10.1002/cplu.202500390","url":null,"abstract":"<p>A formulation strategy based on the alkyl polyglucoside (APG) surfactant Triton CG-110, in combination with 1-Dodecanol as a co-surfactant and brine as an additive, is developed. The results highlight the pivotal role of brine in modulating the rheological properties of the system, inducing a shift from viscous to viscoelastic and yield-pseudoplastic behavior at elevated surfactant and salt concentrations. Small-angle X-ray scattering analysis reveals that increased salinity enhances interparticle correlations within bicellar nanostructures, which are closely associated with improved viscoelasticity and formulation stability. The salting-out effect, combined with the ability to incorporate 1-Dodecanol, leads to nanoscale structural transitions that provide a rational basis for tuning the performance of surfactant systems. The resulting high oil-uptake efficiency of 82% in the final formulation demonstrates a viable pathway toward high-efficiency, environmentally benign surfactants, supporting the broader transition to greener chemistries in industrial applications.</p>","PeriodicalId":148,"journal":{"name":"ChemPlusChem","volume":"90 10","pages":""},"PeriodicalIF":2.8,"publicationDate":"2025-08-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://chemistry-europe.onlinelibrary.wiley.com/doi/epdf/10.1002/cplu.202500390","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144881791","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
ChemPlusChemPub Date : 2025-08-19DOI: 10.1002/cplu.202500398
Domenico Santandrea, Cécile Sillard, Valentina Beghetto, Julien Bras
{"title":"Aqueous-Phase Surface Amidation of TEMPO-CNF Films for Improved Adsorption of Organic Pollutants in Water","authors":"Domenico Santandrea, Cécile Sillard, Valentina Beghetto, Julien Bras","doi":"10.1002/cplu.202500398","DOIUrl":"10.1002/cplu.202500398","url":null,"abstract":"<p>Wastewater treatment remains a critical global issue due to the release of hazardous chemicals that pose environmental and health risks. This study presents the first preparation of highly efficient and recyclable TEMPO-oxidized cellulose nanofiber (TEMPO-CNF) films, surface-grafted through a novel and straightforward method for water decontamination. The films are modified via immersion in an aqueous solution of benzylamine and DMTMM, yielding TEMPO-CNF-<i>g</i>-BnNH<sub>2</sub> materials. Characterization by atomic force microscopy, attenuated total reflectance Fourier trasnsform infrared spectroscopy, X-ray photoelectron spectroscopy, elemental analysis, and water-resistance testing confirmed successful grafting. This functionalization enhanced material properties, improving water stability by 81% and reducing water uptake by 88%. Contact angle measurements, surface plasmon resonance analysis, and kinetic and thermodynamic studies indicate that the introduction of benzylamine modifies surface hydrophobicity and increases chemical affinity with organic pollutants. While π–π interactions may play a role, especially with aromatic contaminants, the sorption behavior is overall influenced by a combination of hydrophobic effects and increased molecular similarity with the target molecules. The grafted films demonstrated high adsorption capacities for methylene blue and chlorhexidine (163.9 and 217.4 mg g<sup>−1</sup>, respectively), along with excellent reusability and washability. Biodegradability tests confirmed complete degradation within 90 days. This work offers a sustainable strategy for producing advanced cellulose-based adsorbents for efficient and ecofriendly wastewater treatment.</p>","PeriodicalId":148,"journal":{"name":"ChemPlusChem","volume":"90 10","pages":""},"PeriodicalIF":2.8,"publicationDate":"2025-08-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144870579","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
ChemPlusChemPub Date : 2025-08-19DOI: 10.1002/cplu.202500344
Néstor Gutiérrez-Sánchez, Fernando Mendizábal, Sebastián Miranda-Rojas
{"title":"Unveiling SalL Chlorinase Reaction Mechanism and Selectivity through Quantum Mechanical/Molecular Mechanics and Activation-Strain Model","authors":"Néstor Gutiérrez-Sánchez, Fernando Mendizábal, Sebastián Miranda-Rojas","doi":"10.1002/cplu.202500344","DOIUrl":"10.1002/cplu.202500344","url":null,"abstract":"<p>Here, an exhaustive exploration of the reaction mechanism toward the chlorination process carried out by SalL, a chlorinase enzyme that catalyzes the conversion of SAM into 5′-chloro-5′-deoxyadenosine through an <i>S</i><sub><i>N</i></sub>2 reaction, is presented. To this end, molecular dynamics simulations and quantum mechanical/molecular mechanics calculations are performed, and 14 density functionals are benchmarked. Among the tested functionals, TPSSh(BJ) provides the closest energy barrier to experimental value. Three configurations of interaction between chloride and the halogen pocket are found, where the best model exhibits a barrier height of 20.1 kcal mol<sup>−1</sup>, close to the 19.9 kcal mol<sup>−1</sup> experimentally obtained. This model is characterized by the chloride interacting with the backbone-amide of Gly131 and Tyr130. The reaction pathway is calculated through the intrinsic reaction coordinate approach, and it is characterized using reaction force analysis and the activation-strain model with energy decomposition analysis to obtain chemical insights into the inner working of this enzyme. According to the main findings, the overstabilization of the halogen binding on the active site increases the barrier height, explaining the lack of activity against fluoride, while the interaction energy between nucleophile−electrophile is responsible of reducing the barrier height, with the orbital interaction energy as the main stabilizing factor during the chlorination process.</p>","PeriodicalId":148,"journal":{"name":"ChemPlusChem","volume":"90 10","pages":""},"PeriodicalIF":2.8,"publicationDate":"2025-08-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144870582","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Harnessing Multiple Adsorption Sites in a Phosphonate Metal–Organic Framework for Efficient C2H2/CO2 Separation","authors":"Xiangsen Yuan, Wenpeng Xie, Qiuju Fu, Huimin Jiang, Shilong Wen, Xiaokun Yang, Liting Yan, Ling-Zhi Yang, Xuebo Zhao","doi":"10.1002/cplu.202500495","DOIUrl":"10.1002/cplu.202500495","url":null,"abstract":"<p>Due to their comparable molecular dimensions and volatility, distinguishing C<sub>2</sub>H<sub>2</sub> from CO<sub>2</sub> during purification remains a significant challenge in industrial applications. Achieving effective isolation of C<sub>2</sub>H<sub>2</sub> from binary mixtures of C<sub>2</sub>H<sub>2</sub>/CO<sub>2</sub> is therefore a critical objective in petrochemical processes. Herein, an adsorption mechanism enabling selective C<sub>2</sub>H<sub>2</sub>/CO<sub>2</sub> separation has been elucidated in the phosphonate metal–organic framework (MOF) Ni-STA-12. The high C<sub>2</sub>H<sub>2</sub> uptake and remarkable CO<sub>2</sub> selectivity of Ni-STA-12 arise from the synergistic effect of diverse adsorption sites distributed throughout its structure, including various oxygen atoms and open metal sites. The adsorbed C<sub>2</sub>H<sub>2</sub> interacts strongly with the exposed adsorption sites in the framework and its binding capacity is much larger than that of CO<sub>2</sub>. Dynamic breakthrough experiments demonstrated the practical potential for the separation of C<sub>2</sub>H<sub>2</sub> in mixtures, and excellent separation potential (Δ<i>q</i>) demonstrating high C<sub>2</sub>H<sub>2</sub> recovery from C<sub>2</sub>H<sub>2</sub>/CO<sub>2</sub> mixtures. Theoretical calculations show the synergistic interaction of various oxygen atoms of the MOF with the open metal site Ni and the dominant role of uncoordinated oxygen atoms in the adsorption of C<sub>2</sub>H<sub>2</sub>.</p>","PeriodicalId":148,"journal":{"name":"ChemPlusChem","volume":"90 10","pages":""},"PeriodicalIF":2.8,"publicationDate":"2025-08-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144870580","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}