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Boron-Containing Organic Two Dimensional Materials: Synthesis and Application. 含硼有机二维材料：合成与应用》。
IF 3.9 2区 化学
Chemistry - A European Journal Pub Date : 2024-11-22 DOI: 10.1002/chem.202403810
Fenggui Zhao, Mengjie An, Nan Wang, Xiaodong Yin
{"title":"Boron-Containing Organic Two Dimensional Materials: Synthesis and Application.","authors":"Fenggui Zhao, Mengjie An, Nan Wang, Xiaodong Yin","doi":"10.1002/chem.202403810","DOIUrl":"10.1002/chem.202403810","url":null,"abstract":"<p><p>Organic two-dimensional materials have garnered widespread attention due to their well-defined structures, structural diversity, and rich electronic effects, demonstrating significant application potential across various fields. Atomic-level manipulation of the structures of organic two-dimensional materials has been a primary strategy for enriching and optimizing their properties. The introduction of heteroatoms often significantly affects their electronic structure, thereby endowing these materials with novel and unique properties. Boron atoms, due to their electron-deficient nature, have been extensively studied in luminescent materials, semiconductor materials, and chemical sensing materials. Consequently, boron-containing organic two-dimensional materials are also believed to be promising as a new class of materials with excellent optoelectronic and chemical activities. This article collates and summarizes the preparation and property studies of three types of boron-containing organic two-dimensional materials in recent years.</p>","PeriodicalId":144,"journal":{"name":"Chemistry - A European Journal","volume":" ","pages":"e202403810"},"PeriodicalIF":3.9,"publicationDate":"2024-11-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142692261","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Iridium/Acid-Dual Catalyzed Enantioselective Intramolecular Allylic Dearomatization Reaction of Allylic Alcohol Tethered α- and β-Naphthols. 铱/酸双催化α-和β-萘酚系链烯丙基醇的不对称分子内烯丙基脱芳烃反应。
IF 3.9 2区 化学
Chemistry - A European Journal Pub Date : 2024-11-21 DOI: 10.1002/chem.202403664
Amit Shikari, Subhas Chandra Pan
{"title":"Iridium/Acid-Dual Catalyzed Enantioselective Intramolecular Allylic Dearomatization Reaction of Allylic Alcohol Tethered α- and β-Naphthols.","authors":"Amit Shikari, Subhas Chandra Pan","doi":"10.1002/chem.202403664","DOIUrl":"10.1002/chem.202403664","url":null,"abstract":"<p><p>The first catalytic enantioselective intramolecular allylic dearomatization of allylic alcohol tethered α- and β-naphthols has been developed with iridium/acid-dual catalysis. A wide range of polycyclic spiroketones containing vicinal tertiary and quaternary carbon stereocenters were readily prepared in good to high yields with high diastereo- and moderate to excellent enantioselectivities. An unusual anti-Markovnikov Wacker oxidation has also been shown in synthetic transformations.</p>","PeriodicalId":144,"journal":{"name":"Chemistry - A European Journal","volume":" ","pages":"e202403664"},"PeriodicalIF":3.9,"publicationDate":"2024-11-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142685556","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Experimental and Theoretical Insights on Gas Trapping of Noble Gases in MFU-4-Type Metal-Organic Frameworks. 关于 MFU-4 型金属有机框架中惰性气体捕集的实验和理论见解。
IF 3.9 2区 化学
Chemistry - A European Journal Pub Date : 2024-11-21 DOI: 10.1002/chem.202403574
Hana Bunzen, Beliz Sertcan Gökmen, Andreas Kalytta-Mewes, Maciej Grzywa, Jakub Wojciechowski, Jürg Hutter, Anna-Sophia Hehn, Dirk Volkmer
{"title":"Experimental and Theoretical Insights on Gas Trapping of Noble Gases in MFU-4-Type Metal-Organic Frameworks.","authors":"Hana Bunzen, Beliz Sertcan Gökmen, Andreas Kalytta-Mewes, Maciej Grzywa, Jakub Wojciechowski, Jürg Hutter, Anna-Sophia Hehn, Dirk Volkmer","doi":"10.1002/chem.202403574","DOIUrl":"https://doi.org/10.1002/chem.202403574","url":null,"abstract":"<p><p>Isostructural metal-organic frameworks (MOFs), namely MFU-4 and MFU-4-Br, in which the pore apertures are defined by anionic side ligands (Cl- and Br-, respectively), were synthesized and loaded with noble gases. By selecting the type of side ligand, one can fine-tune the pore aperture size, allowing for precise regulation of the entry and release of gas guests. In this study, we conducted experiments to examine gas loading and release using krypton and xenon as model gases, and we complemented our findings with computational modeling. Remarkably, the loaded gas guests remained trapped inside the pores even after being exposed to air under ambient conditions for extended periods, in some cases for up to several weeks. Therefore, we focused on determining the energy barrier preventing gas release using both theoretical and experimental methods. The results were compared in relation to the types of hosts and guests, providing valuable insights into the gas trapping process in MOFs, as well as programmed gas release in air under ambient conditions. Furthermore, the crystal structure of MFU-4-Br was elucidated using the three-dimensional electron diffraction (3DED) technique, and the bulk purity of the sample was subsequently verified through Rietveld refinement.</p>","PeriodicalId":144,"journal":{"name":"Chemistry - A European Journal","volume":" ","pages":"e202403574"},"PeriodicalIF":3.9,"publicationDate":"2024-11-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142685554","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Selective Oxidation of Alcohols to Carbonyls under Decatungstate-Mediated Photoelectrochemical Conditions 在十钨酸盐介导的光电化学条件下将醇选择性氧化为羰基化合物
IF 3.9 2区 化学
Chemistry - A European Journal Pub Date : 2024-11-21 DOI: 10.1002/chem.202486504
Andrea Capucciati, Luca Baraglia, Elena Cassera, Daniele Merli, Luca Capaldo, Davide Ravelli
{"title":"Selective Oxidation of Alcohols to Carbonyls under Decatungstate-Mediated Photoelectrochemical Conditions","authors":"Andrea Capucciati,&nbsp;Luca Baraglia,&nbsp;Elena Cassera,&nbsp;Daniele Merli,&nbsp;Luca Capaldo,&nbsp;Davide Ravelli","doi":"10.1002/chem.202486504","DOIUrl":"https://doi.org/10.1002/chem.202486504","url":null,"abstract":"<p><b>The Cover Feature</b> depicts the conversion of benzyl alcohols to the corresponding carbonyl compounds. The protocol, also extended to aliphatic derivatives, leverages the unique properties of the decatungstate anion in the role of photocatalyst. The transformation occurred smoothly under photoelectrochemical conditions, requiring the simultaneous irradiation and electrolysis of the reaction mixture, and delivered the desired products in high chemical yields and faradaic efficiencies. More information can be found in the Research Article by D. Ravelli and co-workers (DOI: 10.1002/chem.202402986). Artwork created by Elena Cassera.\u0000 <figure>\u0000 <div><picture>\u0000 <source></source></picture><p></p>\u0000 </div>\u0000 </figure>\u0000 </p>","PeriodicalId":144,"journal":{"name":"Chemistry - A European Journal","volume":"30 65","pages":""},"PeriodicalIF":3.9,"publicationDate":"2024-11-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/chem.202486504","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142685363","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Quadruple stimuli-responsive behaviour of acylhydrazone crystals: Mechanical, Photomechanical, Thermomechanical, and Optical Waveguide Properties. 酰腙晶体的四重刺激响应行为：机械、光机械、热机械和光波导特性。
IF 3.9 2区 化学
Chemistry - A European Journal Pub Date : 2024-11-21 DOI: 10.1002/chem.202403283
Yaru Zhang, Yang Ye, Ying Sun, Yuanhang Wang, Haowen Du, Hongxun Hao, Chuang Xie
{"title":"Quadruple stimuli-responsive behaviour of acylhydrazone crystals: Mechanical, Photomechanical, Thermomechanical, and Optical Waveguide Properties.","authors":"Yaru Zhang, Yang Ye, Ying Sun, Yuanhang Wang, Haowen Du, Hongxun Hao, Chuang Xie","doi":"10.1002/chem.202403283","DOIUrl":"https://doi.org/10.1002/chem.202403283","url":null,"abstract":"<p><p>As society advances, the demand for high-performance crystal materials with versatile stimuli-responsive capabilities has increased. However, there remains a notable shortage of simple molecular crystals that exhibit stable and swift responses to various stimuli. In this study, we synthesized a novel acylhydrazone crystal by integrating benzene-fused heterocycles and halogens, achieving a crystal material with multiple stimuli-responsive behaviours. The crystal demonstrates good mechanical flexibility, capable of with standing a strain of 2.3% under applying mechanical force and recovering its original shape after force removal. Crystal structure analysis reveals this property is due to the strong and flexible intermolecular interactions. It also exhibits rapid photomechanical bending away from light source under UV irradiation, which could be attributed to the facile photoisomerization. Moreover, the crystal undergoes significant thermomechanical transitions, including cracking and jumping, upon heating. Additionally, the prepared crystal exhibits passive optical waveguide of red light at 850 nm, which, combining the photomechanical bending, can achieve controllable light output direction. These multi-stimuli-responsive behaviors make the acylhydrazone crystal a promising candidate for applications in multifunctional sensors, optoelectronic devices, and thermal switches. This work provides a helpful reference for the study of potential crystal material design and functionality of advanced responsive systems.</p>","PeriodicalId":144,"journal":{"name":"Chemistry - A European Journal","volume":" ","pages":"e202403283"},"PeriodicalIF":3.9,"publicationDate":"2024-11-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142685558","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Synthesis of Polysubstituted Vinyl Sulfones by Direct C-S Cross-Coupling. 通过直接 C-S 交叉偶联合成多取代乙烯基砜。
IF 3.9 2区 化学
Chemistry - A European Journal Pub Date : 2024-11-21 DOI: 10.1002/chem.202403947
Tian-Sih Huang, Chun-Lin Chen, Ming-Hsuan Tsai, Yu-Chi Chen, Che-Sheng Hsu
{"title":"Synthesis of Polysubstituted Vinyl Sulfones by Direct C-S Cross-Coupling.","authors":"Tian-Sih Huang, Chun-Lin Chen, Ming-Hsuan Tsai, Yu-Chi Chen, Che-Sheng Hsu","doi":"10.1002/chem.202403947","DOIUrl":"10.1002/chem.202403947","url":null,"abstract":"<p><p>Vinyl sulfones are valued for their unique chemical properties and bioactivity, but creating a wide range of different analogs remains a challenge. To address this limitation, we have developed a novel approach that facilitates the synthesis of polysubstituted vinyl sulfones. This method utilizes the dual functionality of NIS as a promoter that enables sulfonation and elimination in the synthesis of vinyl sulfones. We used the broad applicability, efficiency, selectivity, and functional group tolerance of this approach to synthesize more than 70 examples. Additionally, competition experiments have provided insights into the reactivity and selectivity of the transient sulfonyl radical towards various C-C multiple bonds. Herein, we describe using this mild protocol in the late-stage vinyl sulfonation of complex molecules to simplify the synthesis of specific targets and enable the modification of complex natural products and advanced materials.</p>","PeriodicalId":144,"journal":{"name":"Chemistry - A European Journal","volume":" ","pages":"e202403947"},"PeriodicalIF":3.9,"publicationDate":"2024-11-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142685561","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
S/Se-Annulated Star-Shaped Perylene Diimides (PDIs) with Large Two-Photon Absorption (TPA) Cross-Section in NIR-I Region. S/Se-Annulated Star-Shaped Perylene Diimides (PDIs)，在近红外 I 区具有较大的双光子吸收 (TPA) 截面。
IF 3.9 2区 化学
Chemistry - A European Journal Pub Date : 2024-11-21 DOI: 10.1002/chem.202403510
Dandan Li, Wenrong Zhao, Gang Li, Yan Xu, Liang Xu, Bo Tang
{"title":"S/Se-Annulated Star-Shaped Perylene Diimides (PDIs) with Large Two-Photon Absorption (TPA) Cross-Section in NIR-I Region.","authors":"Dandan Li, Wenrong Zhao, Gang Li, Yan Xu, Liang Xu, Bo Tang","doi":"10.1002/chem.202403510","DOIUrl":"10.1002/chem.202403510","url":null,"abstract":"<p><p>Two-photon absorption (TPA) has attracted growing attention over recent years owing to the wide range of applications in organic nonlinear optical (NLO) materials. The quantitative sensitivity of a two-photon molecular entity is determined by its TPA cross-section (δ<sub>TPA</sub>). Perylene diimides (PDIs) are excellent n-type organic semiconductor materials demonstrating distinguished thermal, optical, and chemical stability. Nonetheless, PDIs-based scaffolds exhibit poor δ<sub>TPA</sub> in the NIR-I region (700-900 nm) due to the lack of suitable molecular design. Here, two novel star-shaped PDIs fluorophores, namely PDI-S and PDI-Se, were constructed by four periphery S/Se-fused PDIs connected with bicarbazole core. PDI-S manifested excellent δ<sub>TPA</sub> of 3775 GM, which are among the highest values reported for PDIs excited in the NIR-I region.</p>","PeriodicalId":144,"journal":{"name":"Chemistry - A European Journal","volume":" ","pages":"e202403510"},"PeriodicalIF":3.9,"publicationDate":"2024-11-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142685559","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Manipulating the Substituent Sphere of a Bicyclic Silicon(I) Ring Compound Results in Anionic Cubane-Type Clusters and a Tetrahedral Silanide 操纵双环硅(I)环化合物的取代基球面可产生阴离子古巴比伦型团簇和四面体硅化物
IF 3.9 2区 化学
Chemistry - A European Journal Pub Date : 2024-11-21 DOI: 10.1002/chem.202486503
Michael Quest, Alexander Hepp, Marian Hebenbrock, Constantin G. Daniliuc, Jonas Bresien, Felicitas Lips
{"title":"Manipulating the Substituent Sphere of a Bicyclic Silicon(I) Ring Compound Results in Anionic Cubane-Type Clusters and a Tetrahedral Silanide","authors":"Michael Quest,&nbsp;Alexander Hepp,&nbsp;Marian Hebenbrock,&nbsp;Constantin G. Daniliuc,&nbsp;Jonas Bresien,&nbsp;Felicitas Lips","doi":"10.1002/chem.202486503","DOIUrl":"https://doi.org/10.1002/chem.202486503","url":null,"abstract":"<p><b>The silicon(I) ring compound Si<sub>4</sub>{N(SiMe<sub>3</sub>)Mes}<sub>4</sub></b> can be reduced by using KC<sub>8</sub> in the presence of [18]crown-6 under abstraction of four amido substituents. This results after dimerization in the first dianionic octasilacubane-type compound with four unsubstituted silicon atoms. DFT calculations revealed that it exhibits a four-center–six-electron bond with electron density inside the cube. Further derivatizations of the silicon(I) ring compound with KC<sub>8</sub> in the absence of [18]crown-6 but using trapping reagents results in more and different anionic silicon based clusters. More information can be found in the Research Article by F. Lips and co-workers (DOI: 10.1002/chem.202400368).\u0000 <figure>\u0000 <div><picture>\u0000 <source></source></picture><p></p>\u0000 </div>\u0000 </figure>\u0000 </p>","PeriodicalId":144,"journal":{"name":"Chemistry - A European Journal","volume":"30 65","pages":""},"PeriodicalIF":3.9,"publicationDate":"2024-11-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/chem.202486503","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142685362","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Cover Feature: One-Pot Divergent Synthesis of a 13-Ring Triquinone and its Facile Conversion to a [4.4.4]Tridecastarphene (Chem. Eur. J. 65/2024) 封面特写：13 环三醌的一锅发散合成及其向 [4.4.4]Tridecastarphene 的简便转化（《欧洲化学杂志》第 65/2024 期）
IF 3.9 2区 化学
Chemistry - A European Journal Pub Date : 2024-11-21 DOI: 10.1002/chem.202486502
Hao Geng, Ryan P. Kopreski, Qian Liu, Jonathan B. Briggs, Glen P. Miller
{"title":"Cover Feature: One-Pot Divergent Synthesis of a 13-Ring Triquinone and its Facile Conversion to a [4.4.4]Tridecastarphene (Chem. Eur. J. 65/2024)","authors":"Hao Geng,&nbsp;Ryan P. Kopreski,&nbsp;Qian Liu,&nbsp;Jonathan B. Briggs,&nbsp;Glen P. Miller","doi":"10.1002/chem.202486502","DOIUrl":"https://doi.org/10.1002/chem.202486502","url":null,"abstract":"<p><b>Our one-pot synthesis</b> of a 13-ring triquinone followed by aromatization to give a novel Starphene was accomplished in a manner consistent with making cookies: mix, bake, beautify. More information can be found in the Research Article by G. P. Miller and co-workers (DOI: 10.1002/chem.202402745).\u0000 <figure>\u0000 <div><picture>\u0000 <source></source></picture><p></p>\u0000 </div>\u0000 </figure>\u0000 </p>","PeriodicalId":144,"journal":{"name":"Chemistry - A European Journal","volume":"30 65","pages":""},"PeriodicalIF":3.9,"publicationDate":"2024-11-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/chem.202486502","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142685361","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Front Cover: Photoinduced Enantioselective Triplet Radical Reaction on Metal: Copper-Catalyzed Conjugate Addition of Acylsilanes to α,β-Unsaturated Ketones and Aldehydes (Chem. Eur. J. 65/2024) 封面：金属上的光诱导对映选择性三重自由基反应：铜催化的酰基硅烷与α,β-不饱和酮和醛的共轭加成（欧洲化学杂志 65/2024）
IF 3.9 2区 化学
Chemistry - A European Journal Pub Date : 2024-11-21 DOI: 10.1002/chem.202486501
Yusuke Masuda, Yusuke Ueda, Aiko Sueki, Junpei Shimosato, Kousei Nishimura, Min Gao, Jun-ya Hasegawa, Masaya Sawamura
{"title":"Front Cover: Photoinduced Enantioselective Triplet Radical Reaction on Metal: Copper-Catalyzed Conjugate Addition of Acylsilanes to α,β-Unsaturated Ketones and Aldehydes (Chem. Eur. J. 65/2024)","authors":"Yusuke Masuda,&nbsp;Yusuke Ueda,&nbsp;Aiko Sueki,&nbsp;Junpei Shimosato,&nbsp;Kousei Nishimura,&nbsp;Min Gao,&nbsp;Jun-ya Hasegawa,&nbsp;Masaya Sawamura","doi":"10.1002/chem.202486501","DOIUrl":"https://doi.org/10.1002/chem.202486501","url":null,"abstract":"<p><b>A photoinduced</b> copper-catalyzed enantioselective conjugate addition of acylsilanes to α,β-unsaturated ketones and aldehydes has been developed. Metal-to-ligand charge-transfer excitation of an alkene-bound acylcopper intermediate generates a triplet β-radical-C-enolate-Cu<sup>II</sup>-acyl complex with an acyl radical character, which undergoes facile C−C bond formation in the copper coordination sphere. The picture represents the triplet excited state C−C bond formation as a powerful synthetic strategy. More information can be found in the Research Article by M. Gao, M. Sawamura and co-workers (DOI: 10.1002/chem.202402564).\u0000 <figure>\u0000 <div><picture>\u0000 <source></source></picture><p></p>\u0000 </div>\u0000 </figure>\u0000 </p>","PeriodicalId":144,"journal":{"name":"Chemistry - A European Journal","volume":"30 65","pages":""},"PeriodicalIF":3.9,"publicationDate":"2024-11-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/chem.202486501","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142692112","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
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