International Journal of Polymer Analysis and Characterization最新文献

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A study on surfactant modified polypyrrole nanostructures and its applications in supercapacitors 表面活性剂修饰聚吡咯纳米结构及其在超级电容器中的应用研究
IF 1.7 4区 工程技术
International Journal of Polymer Analysis and Characterization Pub Date : 2023-08-18 DOI: 10.1080/1023666X.2023.2267257
Neelima Dubey
{"title":"A study on surfactant modified polypyrrole nanostructures and its applications in supercapacitors","authors":"Neelima Dubey","doi":"10.1080/1023666X.2023.2267257","DOIUrl":"10.1080/1023666X.2023.2267257","url":null,"abstract":"<div><div>Nanocomposites of Polypyrrole (Ppy), were synthesized by chemical oxidative polymerization of pyrrole, in the presence of mono and mixed‐surfactant solutions using ammonium persulfate as an oxidant and were investigated for its applications in super capacitors. The surfactants used in the experiments included anionic surfactants, sodium dodecyl sulfate (SDS) and sodium dodecylbenzenesulfonate (SDBS) and cationic surfactants, tetradecyltrimethylammonium bromide (TTAB) as well as cetyltrimethylammonium bromide (CTAB). The morphology and structure of the resulting Ppy were investigated in detail with FESEM and FTIR, respectively. The addition of anionic surfactants produced globular morphology. The results showed that the interaction between the different surfactants and the interaction between the surfactants and the polymer influenced the morphology, structure and conductivity of the resulting polymer to different degrees. Apart from these, XRD, UV-Vis spectroscopy and cyclic voltammetry (CV) were also performed to characterize the prepared composites. In comparison with the results for mono surfactant solutions, the polymerization of pyrrole in mixed‐surfactant solutions shows significant changes in morphologies and electrochemical properties of Ppy. The results of CV show that the specific capacitance values of Ppy samples with anionic surfactants are greater than cationic surfactants. In case of mixed surfactants, sample with SDBS + TTAB posses highest specific capacitance of 204 Fg<sup>−1</sup> at scan rate 100 mVs<sup>−1</sup>. The good electrochemical properties can be attributed to the highly porous structural advantage of the Ppy sample prepared using SDBS + TTAB. It indicates the energy holding capacity or capacitance of the prepared samples and can be utilized in sensing applications like supercapacitors.</div></div>","PeriodicalId":14236,"journal":{"name":"International Journal of Polymer Analysis and Characterization","volume":"28 6","pages":"Pages 625-646"},"PeriodicalIF":1.7,"publicationDate":"2023-08-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"135570898","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Development and characterization of DGEBA-APTES-ZrO2 nanocomposite coatings for anti-corrosion and anti-fouling DGEBA-APTES-ZrO2纳米复合防腐蚀防污涂层的研制与表征
IF 1.7 4区 工程技术
International Journal of Polymer Analysis and Characterization Pub Date : 2023-08-18 DOI: 10.1080/1023666X.2023.2254034
Saravanan P , Anandkumar S , Sharmila J , Chamundeeswari M , Suresh S , Nisha P
{"title":"Development and characterization of DGEBA-APTES-ZrO2 nanocomposite coatings for anti-corrosion and anti-fouling","authors":"Saravanan P ,&nbsp;Anandkumar S ,&nbsp;Sharmila J ,&nbsp;Chamundeeswari M ,&nbsp;Suresh S ,&nbsp;Nisha P","doi":"10.1080/1023666X.2023.2254034","DOIUrl":"10.1080/1023666X.2023.2254034","url":null,"abstract":"<div><div>Tetraethylenetetramine (TETA), 3-aminopropylethoxysilane-treated ZrO<sub>2</sub> nanoparticles, and diglycidyl ethers of bisphenol-A (DGEBA) were used to create an epoxy nanocomposite (DGEBA-APTES-ZrO<sub>2</sub>). The newly synthesized APTES-ZrO<sub>2</sub> was evaluated using FTIR, XRD, SEM, AFM, TEM and elemental analysis for structural and compositional analysis. Due to its resilience in acidic, basic and saline conditions, mild steel is crucial in sectors like shipbuilding and the automobile industry. ZrO<sub>2</sub> nanoparticles have excellent corrosion resistance. As a result, it is intended to prepare DGEBA-APTES-ZrO<sub>2</sub> for a barrier layer that prevents corrosion on mild steel surfaces. FTIR spectroscopy tests provided proof of DGEBA-APTES-ZrO<sub>2</sub>-coated mild steel’s ability to limit corrosion and microbiological growth. Using salt spray and an electrochemical impedance technique, corrosion inhibition was evaluated. On mild steel surfaces, DGEBA-APTES-ZrO<sub>2</sub> nanohybrid coatings demonstrated excellent corrosion prevention and antifouling.</div></div>","PeriodicalId":14236,"journal":{"name":"International Journal of Polymer Analysis and Characterization","volume":"28 6","pages":"Pages 564-580"},"PeriodicalIF":1.7,"publicationDate":"2023-08-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"135980927","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Nanocomposites based on polyurethane and modified montmorillonite: thermodynamic approach to reinforcement 基于聚氨酯和改性蒙脱土的纳米复合材料:热力学增强方法
IF 1.7 4区 工程技术
International Journal of Polymer Analysis and Characterization Pub Date : 2023-08-18 DOI: 10.1080/1023666X.2023.2250137
Lyudmyla Karabanova , Oleksii Gonchar , Stanislav Nesin , Yuri Savelyev
{"title":"Nanocomposites based on polyurethane and modified montmorillonite: thermodynamic approach to reinforcement","authors":"Lyudmyla Karabanova ,&nbsp;Oleksii Gonchar ,&nbsp;Stanislav Nesin ,&nbsp;Yuri Savelyev","doi":"10.1080/1023666X.2023.2250137","DOIUrl":"10.1080/1023666X.2023.2250137","url":null,"abstract":"<div><div>Nanocomposites based on thermoplastic polyurethane and montmorillonite (Mt) modified with oligourethaneammonium chloride were synthesized. The nanocomposites were obtained by the method <em>solution exfoliation</em>. The influence of the filler content on the thermodynamic of interactions, physical and mechanical properties, the structure and morphology of the created nanocomposites was investigated. The investigations have shown that the free energy of mixing the filler and the matrix during the formation of the nanocomposites decisively determines the physical and mechanical properties of the created nanocomposites. In case of thermodynamic compatibility between the matrix and the filler, dense surface layers of the matrix on the filler, high-quality polymer–filler contacts in the system are formed, which leads to the creation of nanocomposites with increased parameters of physical and mechanical properties. Mt modified with urethane-containing compounds can form strong hydrogen bonds with the polar polymer matrix and this allow to exfoliate the Mt up to the plates</div></div>","PeriodicalId":14236,"journal":{"name":"International Journal of Polymer Analysis and Characterization","volume":"28 6","pages":"Pages 537-551"},"PeriodicalIF":1.7,"publicationDate":"2023-08-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"89461223","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Thermal decomposition kinetic study on one-pack formulations of epoxy resin cured with novel phosphorus-containing flame retardant latent curing agents 新型含磷阻燃潜固化剂固化环氧树脂单包配方的热分解动力学研究
IF 1.7 4区 工程技术
International Journal of Polymer Analysis and Characterization Pub Date : 2023-08-18 DOI: 10.1080/1023666X.2023.2264604
J. Kamalipour , M. H. Beheshty , M. J. Zohuriaan-Mehr
{"title":"Thermal decomposition kinetic study on one-pack formulations of epoxy resin cured with novel phosphorus-containing flame retardant latent curing agents","authors":"J. Kamalipour ,&nbsp;M. H. Beheshty ,&nbsp;M. J. Zohuriaan-Mehr","doi":"10.1080/1023666X.2023.2264604","DOIUrl":"10.1080/1023666X.2023.2264604","url":null,"abstract":"<div><div>Several phosphorous-containing flame retardant latent curing agents newly derived from 4,4-diamino diphenyl sulfone (DDS) and 4,4-diamino diphenyl methane (DDM) were designed to cure epoxy resin alongside dicyandiamide (Dicy). The thermal decomposition and kinetics of cured one-packed systems were investigated in detail. The epoxy systems were studied under a nitrogen atmosphere by using thermal gravimetric analysis at different heating rates. The kinetics of thermal decomposition was evaluated by Flynn-Wall-Ozawa, Kissinger-Akahira-Sunose, and Starink methods. The correlation coefficient for all systems obtained by the three above methods was almost equal to one, indicating that these three methods were correctly chosen. The results demonstrated that the activation energy of epoxy/Dicy blended with different phosphorous-containing DDS- and DDM-derived curing agents at a lower degree of conversion decreased by incorporation of the agents while increasing at a higher degree of conversion. The thermodynamic parameters (ΔH*, ΔG*, and ΔS*) of the studied systems were calculated by the obtained activation energy via three kinetics methods. It was found that as the conversion degree and the enthalpy increased, the Gibbs free energy decreased, while entropy changed from negative to positive values.</div></div>","PeriodicalId":14236,"journal":{"name":"International Journal of Polymer Analysis and Characterization","volume":"28 6","pages":"Pages 596-624"},"PeriodicalIF":1.7,"publicationDate":"2023-08-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"135883687","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Synthesis and characterization of glyceryl starch and determination of molar substitution 甘油淀粉的合成、表征及摩尔取代的测定
IF 1.9 4区 工程技术
International Journal of Polymer Analysis and Characterization Pub Date : 2023-08-15 DOI: 10.1080/1023666X.2023.2221873
Xue-Li Liu , Shi-Ye Xu , Jin Yang , Si-Jin Li , Yi-Wen Chen
{"title":"Synthesis and characterization of glyceryl starch and determination of molar substitution","authors":"Xue-Li Liu ,&nbsp;Shi-Ye Xu ,&nbsp;Jin Yang ,&nbsp;Si-Jin Li ,&nbsp;Yi-Wen Chen","doi":"10.1080/1023666X.2023.2221873","DOIUrl":"https://doi.org/10.1080/1023666X.2023.2221873","url":null,"abstract":"<div><p>In this work, glyceryl starch was prepared by changing the reactant ratio (v/w) of etherifying agent/starch using chlorinated glycerol as etherifying agent. The molar substitution of glyceryl starch was determined. The modified colorimetric method for the determination of molar substitution was described. The glyceryl starch was characterized by using FT-IR and <sup>1</sup>H NMR spectroscopy. Experimental analyses were performed to investigate the effect of dihydroxypropylation on a range of starch properties, including degree of crystallinity, granule morphology, paste clarity, and retrogradation stability and compare them with those of the native corn starch.</p></div>","PeriodicalId":14236,"journal":{"name":"International Journal of Polymer Analysis and Characterization","volume":"28 4","pages":"Pages 396-406"},"PeriodicalIF":1.9,"publicationDate":"2023-08-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"49866707","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Development and assessment on hemp–carbon–basalt fibre base hybrid composite with organic fillers for structural applications 结构用有机填料大麻-碳-玄武岩纤维基复合材料的开发与评价
IF 1.9 4区 工程技术
International Journal of Polymer Analysis and Characterization Pub Date : 2023-08-15 DOI: 10.1080/1023666X.2023.2221483
Sudhakar Uppalapati , J. Bensam Raj , N. Natarajan , M. Adam Khan
{"title":"Development and assessment on hemp–carbon–basalt fibre base hybrid composite with organic fillers for structural applications","authors":"Sudhakar Uppalapati ,&nbsp;J. Bensam Raj ,&nbsp;N. Natarajan ,&nbsp;M. Adam Khan","doi":"10.1080/1023666X.2023.2221483","DOIUrl":"https://doi.org/10.1080/1023666X.2023.2221483","url":null,"abstract":"<div><p>Hybrid composites are in increasing demand for structural applications. The created composite material is anticipated to possess fundamental qualities and a typical load-bearing capacity. The development of a hybrid composite hemp-epoxy polymer material with carbon and/or basalt fiber reinforcement is proposed in this study. With carbon fiber at 6%, basalt fiber at 6%, and carbon-basalt at 2 + 4% in the reinforcement, the weight percentage of the fiber reinforcement was altered for 15, 20, and 25% of hemp fiber in the composite. Additionally, natural fillers like coconut shell powder and calcium carbonate were incorporated into the matrix material. To create the composite with various combinations of fiber reinforcement, industrial standards processes were followed. In comparison to other compositions, the hemp-carbon fiber sample (A3) has a maximum strength of 104 MPa. The same composition also has a maximum stiffness of 197 N/mm, which may be attributed to the matrix material’s high bonding strength (67 weight percent). The shore hardness of the hemp-carbon fiber composite is likewise at its highest, falling between 90 and 98 on the hardness scale. The results revealed that composites composed of carbon and hemp fibers have superior mechanical characteristics to basalt fiber reinforcement. To investigate the material behavior, an electron microscope will be used to examine the cracked surfaces. The material will be suggested for use in structural applications based on the findings.</p></div>","PeriodicalId":14236,"journal":{"name":"International Journal of Polymer Analysis and Characterization","volume":"28 4","pages":"Pages 383-395"},"PeriodicalIF":1.9,"publicationDate":"2023-08-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"49867066","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Characterization of natural cellulosic fibers from the bark of the Edgeworthia chrysantha plant 菊花树皮天然纤维素纤维的特性
IF 1.9 4区 工程技术
International Journal of Polymer Analysis and Characterization Pub Date : 2023-08-12 DOI: 10.1080/1023666X.2023.2217559
Yuying Xiao , Hailong Li , Menglan Yu , Lisheng Shi , Jingshan Zeng , Mengru Liu
{"title":"Characterization of natural cellulosic fibers from the bark of the Edgeworthia chrysantha plant","authors":"Yuying Xiao ,&nbsp;Hailong Li ,&nbsp;Menglan Yu ,&nbsp;Lisheng Shi ,&nbsp;Jingshan Zeng ,&nbsp;Mengru Liu","doi":"10.1080/1023666X.2023.2217559","DOIUrl":"https://doi.org/10.1080/1023666X.2023.2217559","url":null,"abstract":"<div><p>In this paper, the structural, morphological, and mechanical properties of <em>Edgeworthia chrysantha</em> phloem fibers are characterized. The chemical composition of <em>Edgeworthia chrysantha</em> mainly includes cellulose (47.13%), hemicelluloses (15.20%), and lignin (7.30%). X-ray diffraction analysis shows that <em>Edgeworthia chrysantha</em> phloem fiber has high crystallinity (76.38%) and small grain size (3.13 nm). Thermogravimetric analysis shows that the maximum degradation temperature of <em>Edgeworthia chrysantha</em> phloem fiber is 351 °C. The results of scanning electron microscopy and atomic force microscopy show that <em>Edgeworthia chrysantha</em> phloem fiber has an obvious hierarchical structure and a relatively rough surface. Additionally, the elastic modulus (6.04–15.21 GPa) and hardness (0.17–0.88 GPa) of <em>Edgeworthia chrysantha</em> phloem fiber were measured by nanoindentation. The result provided a theoretical basis for the high-value application of <em>Edgeworthia chrysantha</em> phloem fibers, especially in papermaking, textiles, fiber-reinforced material and other applications.</p></div>","PeriodicalId":14236,"journal":{"name":"International Journal of Polymer Analysis and Characterization","volume":"28 4","pages":"Pages 341-350"},"PeriodicalIF":1.9,"publicationDate":"2023-08-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"49866715","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Mutual influence of the morphology and growth kinetics in binary crystalline blends of poly(butylene terephthalate) and polyarylate 聚对苯二甲酸丁二酯和聚芳酯二元结晶共混物的形态和生长动力学的相互影响
IF 1.9 4区 工程技术
International Journal of Polymer Analysis and Characterization Pub Date : 2023-08-08 DOI: 10.1080/1023666X.2023.2217560
Wei-Chi Lai , Shih-Huang Tung , Wen-Bin Liau
{"title":"Mutual influence of the morphology and growth kinetics in binary crystalline blends of poly(butylene terephthalate) and polyarylate","authors":"Wei-Chi Lai ,&nbsp;Shih-Huang Tung ,&nbsp;Wen-Bin Liau","doi":"10.1080/1023666X.2023.2217560","DOIUrl":"https://doi.org/10.1080/1023666X.2023.2217560","url":null,"abstract":"<div><p>The spherulitic morphology and crystallization behaviors of binary crystalline blends of poly(butylene terephthalate) (PBT) and polyarylate (PAr), based on bisphenol A, (27:73 isophthalic:terephthalic acids), are investigated herein. PBT and PAr crystallize simultaneously or sequentially; various crystallization behaviors and morphologies are observed. In the PBT-rich blends, PAr does not crystallize; the PBT spherulites coarsen as the PAr concentration increases. Non-crystallizable PAr is trapped inside the spherulites. The PBT spherulitic growth rate decreases when PAr is added and remains constant thereafter. For the 50/50 blends, PBT and PAr crystallize simultaneously, and their spherulites co-exist separately. The spherulitic growth rate of PBT increases with time while PAr is crystallizing, but it remains constant if PAr crystallizes prior. At a crystallization temperature of 250 °C, only PAr crystallizes; the non-crystallizable PBT is expelled from the PAr spherulites because the crystallization rate of PAr is low. The spherulites of PAr do not fill the space in the final crystallization stage. The crystallization rate of the binary crystalline PBT/PAr blends was notably influenced by the prior crystallization of the other component, and was due to the change of the amorphous composition in addition to the constraints of the crystals on the chain mobility.</p></div>","PeriodicalId":14236,"journal":{"name":"International Journal of Polymer Analysis and Characterization","volume":"28 4","pages":"Pages 351-365"},"PeriodicalIF":1.9,"publicationDate":"2023-08-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"49866708","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 1
Performance improvement of a modified copolymer as an antiscalant and microbial growth inhibitor 改性共聚物抗垢剂和微生物生长抑制剂的性能改进
IF 1.9 4区 工程技术
International Journal of Polymer Analysis and Characterization Pub Date : 2023-08-08 DOI: 10.1080/1023666X.2023.2212565
Fatemeh Karchoubi , Mahsa Baghban Salehi , Reza Panahi , Shahriar Salemi Parizi
{"title":"Performance improvement of a modified copolymer as an antiscalant and microbial growth inhibitor","authors":"Fatemeh Karchoubi ,&nbsp;Mahsa Baghban Salehi ,&nbsp;Reza Panahi ,&nbsp;Shahriar Salemi Parizi","doi":"10.1080/1023666X.2023.2212565","DOIUrl":"https://doi.org/10.1080/1023666X.2023.2212565","url":null,"abstract":"<div><p>Prevention and control of calcium sulfate scale formation and microbial growth accumulation in water handling systems is one of the challenging operations to avoid corrosion and flow restriction through equipment. This paper examines modified low-molecular-weight Maleic Anhydride (MAn) copolymerized by Acrylamide (AAm), which was successfully synthesized, developed, and analyzed as a multifunctional non-phosphorous antiscalant to overcome these problems. The structure, morphology, and thermal property of poly(MAn-co-AAm) were characterized. The intended structure and copolymerization were confirmed through GPC, FT-IR, SEM, and EDX analyses. The high thermal resistivity up to 400<!--> <!-->°C was observed via TGA analysis. The standard NACE TM0374 methodologies were applied to evaluate the scale controlling capacity of poly(MAn-co-AAm) at various dosages (1–20 ppm), temperatures (50–90 °C), and regular intervals of 24–72 h. Interestingly, for low values of poly(MAn-co-AAm), efficiency was found 100% at the third level within the standard state. Further SEM and XRD analyses emphasized the validity of successful inhibition of calcium sulfate scale formation in comparison with other antiscalant agents, even at very low concentrations. In addition, antibacterial properties of poly(MAn-co-AAm) were investigated against <em>Staphylococcus aureus (S. aureus)</em> and <em>Escherichia coli (E. coli)</em>. The results revealed that the developed copolymer possesses a wide antibacterial activity against both Gram-negative and Gram-positive bacteria. With this in mind, poly(MAn-co-AAm) is believed to be an effective and economical multifunctional antiscalant in cooling water treatment systems.</p></div>","PeriodicalId":14236,"journal":{"name":"International Journal of Polymer Analysis and Characterization","volume":"28 4","pages":"Pages 325-340"},"PeriodicalIF":1.9,"publicationDate":"2023-08-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"49866716","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Structure and properties of aromatic naphthalene thermotropic liquid crystal copolyester/MWCNT composites 芳烃萘热致液晶共聚酯/MWCNT复合材料的结构与性能
IF 1.9 4区 工程技术
International Journal of Polymer Analysis and Characterization Pub Date : 2023-08-04 DOI: 10.1080/1023666X.2023.2211727
Peng Wei , Zhiqiang Li , Yanan Zhang , Yumin Xia , Yanping Wang , Yimin Wang
{"title":"Structure and properties of aromatic naphthalene thermotropic liquid crystal copolyester/MWCNT composites","authors":"Peng Wei ,&nbsp;Zhiqiang Li ,&nbsp;Yanan Zhang ,&nbsp;Yumin Xia ,&nbsp;Yanping Wang ,&nbsp;Yimin Wang","doi":"10.1080/1023666X.2023.2211727","DOIUrl":"https://doi.org/10.1080/1023666X.2023.2211727","url":null,"abstract":"<div><p>Aromatic naphthalene thermotropic liquid crystal copolyesters (N-TLCP) have strong intermolecular forces and possess excellent comprehensive properties. In this study, the N-TLCP/MWCNT nanocomposites derived from 6-hydroxy-2-naphthoic acid (HNA), 2,6-naphthalene dicarboxylic acid (NDA), terephthalic acid (TA), 4,4′-dihydroxy biphenyl (BP) and carboxyl MWCNT were prepared via in situ “one-pot” melt polymerization method. The structure and properties of N-TLCP/MWCNT composites were fully analyzed. The interaction between MWCNT and TLCP matrix was confirmed by FTIR, XPS, Raman spectrum and rheometric measurements; and the strong interaction was observed for addition of a small amount of MWCNT (&lt;0.5 wt%), which was attributed to the fact that the functional group COOH on the surface of MWCNTs enhances the dispersion state of the CNTs and molecular interaction through hydrogen bond/chemical covalent bonds. As a result, the glass transition temperature, melting temperature, thermal stability and mechanical properties of the N-TLCP/MWCNT composite was improved. However, more addition of MWCNT would tend to aggregate and impact the molecular weight and structure of the N-TLCP by the chemical reaction between its COOH group and OH group of the N-TLCP, which is not favor for improving the mechanical properties.</p></div>","PeriodicalId":14236,"journal":{"name":"International Journal of Polymer Analysis and Characterization","volume":"28 4","pages":"Pages 293-306"},"PeriodicalIF":1.9,"publicationDate":"2023-08-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"49866717","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
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