International Journal of Polymer Analysis and Characterization最新文献_第9页

High-performance biodegradable triboelectric nanogenerators using CoFe2O4 filled poly (butylene adipate-co-terephthalate) 使用 CoFe2O4 填充聚（己二酸丁二醇酯-对苯二甲酸乙二醇酯）的高性能可生物降解三电纳米发电机

IF 1.7 4区工程技术

International Journal of Polymer Analysis and Characterization Pub Date : 2024-11-16 Epub Date: 2024-10-14 DOI: 10.1080/1023666X.2024.2410762

Vishnu Kadabahalli Thammannagowda , Kariyappa Gowda Guddenahalli Shivanna , Smitha Ankanahalli Shankaregowda , Prashantha Kalappa

{"title":"High-performance biodegradable triboelectric nanogenerators using CoFe2O4 filled poly (butylene adipate-co-terephthalate)","authors":"Vishnu Kadabahalli Thammannagowda , Kariyappa Gowda Guddenahalli Shivanna , Smitha Ankanahalli Shankaregowda , Prashantha Kalappa","doi":"10.1080/1023666X.2024.2410762","DOIUrl":"10.1080/1023666X.2024.2410762","url":null,"abstract":"<div><div>The hunt for sustainable and efficient energy harvesting and storage devices has driven significant interest in triboelectric nanogenerators (TENGs) as potential alternatives to traditional batteries for powering electronic devices. However, the development of biodegradable TENGs remains a formidable challenge. This study presents the preparation of a tribopositive material entirely composed of biodegradable poly(butylene adipate-co-terephthalate) (PBAT) polymer enhanced with CoFe<sub>2</sub>O<sub>4</sub> (CF) nanoparticles. The CF nanoparticles, synthesized via the combustion method, were incorporated into the PBAT matrix through solvent casting to form films with varied filler content (0.2, 0.4, 0.6, 0.8, and 1 g). The CF nanoparticles structural, surface, and electrical properties were characterized using XRD and FTIR spectroscopy. At the same time, the morphology of the nanomaterials and their composites was analyzed by scanning electron microscopy. Specifically, the 0.8 g PBAT-CF TENG demonstrated superior performance, achieving an output voltage of 45.45 V and a current of 4.5 µA. Subsequent electrical studies, including charging commercial capacitors (1.0 to 47 μF) and powering LEDs and calculators, underscored the device’s efficiency. The PBAT-CF TENG also effectively generated voltage and current signals from physical activities like walking and jumping. This innovative approach highlights the potential for biodegradable, high-performing, self-powered flexible electronics, and wearable devices, paving the way for sustainable technological advancements.</div></div>","PeriodicalId":14236,"journal":{"name":"International Journal of Polymer Analysis and Characterization","volume":"29 8","pages":"Pages 685-698"},"PeriodicalIF":1.7,"publicationDate":"2024-11-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142592610","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Dynamic mechanical analysis of additively manufactured cenosphere-filled PETG syntactic foam composite 增材制造仙人球填充 PETG 合成泡沫复合材料的动态力学分析

IF 1.7 4区工程技术

International Journal of Polymer Analysis and Characterization Pub Date : 2024-11-16 Epub Date: 2024-09-26 DOI: 10.1080/1023666X.2024.2404906

Jitendra Kumar , Sushant Negi

{"title":"Dynamic mechanical analysis of additively manufactured cenosphere-filled PETG syntactic foam composite","authors":"Jitendra Kumar , Sushant Negi","doi":"10.1080/1023666X.2024.2404906","DOIUrl":"10.1080/1023666X.2024.2404906","url":null,"abstract":"<div><div>Syntactic foam composite (SFC) has the potential to substitute the conventional material used in damage-tolerance, thermal insulation, and weight-sensitive applications such as automotive parts, submarine structures, etc. Here, SFCs were developed by varying the weight fraction of cenosphere (CS) content from 0-40 wt. % in a polyethylene terephthalate glycol (PETG) matrix. This investigation provides the terse behavior of the viscoelastic properties of 3D-printed PETG/CS foam composites. The thermogravimetric analysis (TGA) results showed that the initial degradation temperature (T<sub>i</sub>) and the temperature at 50% mass loss (T<sub>50</sub>) of the composite filament increased with the addition of CS particles, indicating improved thermal stability. The dynamic mechanical analysis (DMA) results revealed that the storage modulus of SFC increased with increasing cenosphere content. The foam composite’s glass transition temperature (78.9 ± 0.35 °C) is lower by 4 °C than pure PETG. This underscores the potential of the developed syntactic foam composite to effectively utilize industrial waste fly ash through 3D printing routine, thereby promoting sustainable manufacturing practices.</div></div>","PeriodicalId":14236,"journal":{"name":"International Journal of Polymer Analysis and Characterization","volume":"29 8","pages":"Pages 647-657"},"PeriodicalIF":1.7,"publicationDate":"2024-11-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142592612","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Preparation and characterization of fumed silica added PMMA denture base materials 制备添加了气相二氧化硅的 PMMA 义齿基托材料并确定其特性

IF 1.7 4区工程技术

International Journal of Polymer Analysis and Characterization Pub Date : 2024-11-16 Epub Date: 2024-10-17 DOI: 10.1080/1023666X.2024.2410754

Hakki Cenker Kucukesmen , Mehmet Fahri Sarac

{"title":"Preparation and characterization of fumed silica added PMMA denture base materials","authors":"Hakki Cenker Kucukesmen , Mehmet Fahri Sarac","doi":"10.1080/1023666X.2024.2410754","DOIUrl":"10.1080/1023666X.2024.2410754","url":null,"abstract":"<div><div>This study was carried out to investigate the chemical, mechanical, and structural properties of increasing amounts of fumed silica added to PMMA denture base material. The effect of adding fumed silica at three different concentrations (0.5%, 1%, and 2% by weight) to PMMA was studied using Fourier transform infrared spectroscopy (FTIR), dynamic mechanical analysis (DMA), density, flexural strength, hardness, atomic force microscopy (AFM), and scanning electron microscopy (SEM). The results showed that the highest flexural strength values (105.64 MPa) and hardness (20.07 microvickers) were obtained with 1% wt. of fumed silica material. According to DMA results, fumed silica samples containing 1% wt. had the highest energy storage (3.24 GPa at 30 °C) and glass transition temperature. As a result, fumed silica in PMMA denture base material reached its maximum saturation limit at 1% wt. A more brittle behavior was observed in samples containing 2% fumed silica, which accumulated on the surface, as confirmed by AFM. The molecular bonds at the resin-fumed silica interface weaken due to the agglomeration of fumed silica. Consequently, the flexural strength and hardness decrease, along with the glass transition temperature and storage modulus. The potential applications of this research are vast, inspiring further exploration and innovation in denture-based materials.</div></div>","PeriodicalId":14236,"journal":{"name":"International Journal of Polymer Analysis and Characterization","volume":"29 8","pages":"Pages 675-684"},"PeriodicalIF":1.7,"publicationDate":"2024-11-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142592676","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Fabrication and performance of short glass fiber reinforced polyamide composites 短玻璃纤维增强聚酰胺复合材料的制造和性能

IF 1.7 4区工程技术

International Journal of Polymer Analysis and Characterization Pub Date : 2024-11-16 Epub Date: 2024-09-13 DOI: 10.1080/1023666X.2024.2394222

Bedriye Ucpinar Durmaz , Elnura Artykbaeva , Ayse Aytac

引用次数: 0

Combined kinetic analysis of thermal degradation characteristics and reaction mechanism of thin intumescent fire-retardant coating of steel structure 钢结构薄型膨胀型防火涂料热降解特性与反应机理的组合动力学分析

IF 1.7 4区工程技术

International Journal of Polymer Analysis and Characterization Pub Date : 2024-11-16 Epub Date: 2024-09-11 DOI: 10.1080/1023666X.2024.2399791

Fengju Shang , Jiaqing Zhang , Taiyun Zhu , Yi Guo , Yabin Fan , Shouwang Tao , Rui Liu , Yanming Ding

{"title":"Combined kinetic analysis of thermal degradation characteristics and reaction mechanism of thin intumescent fire-retardant coating of steel structure","authors":"Fengju Shang , Jiaqing Zhang , Taiyun Zhu , Yi Guo , Yabin Fan , Shouwang Tao , Rui Liu , Yanming Ding","doi":"10.1080/1023666X.2024.2399791","DOIUrl":"10.1080/1023666X.2024.2399791","url":null,"abstract":"<div><div>To determine the thermal kinetic triplets and elucidate the reaction mechanism of thin intumescent fire-retardant coatings (IFR) of steel structures, one efficient combined kinetic approach was implemented in this study. Thermogravimetric experiments were conducted in air atmosphere at four heating rates, and the whole IFR thermal degradation process was divided into two stages. The average activation energy values derived by model-free methods were 78.9 kJ/mol and 175.16 kJ/mol for Stage I (0<<em>α</em> < 0.2) and Stage II (0.2<<em>α</em> < 0.9), respectively. Furthermore, the linear Coats-Redfern (CR) and non-linear Masterplots models were applied to identify the possible reaction mechanism. It was found that the F3/2 mechanistic model was better suited to the main thermal degradation process. Then model reconstruction based on the F3/2 mechanism model was performed. The results showed that the reconstructed model had a strict linear relationship in the independence analysis and KCE analysis, along with a good agreement between the theoretical and experimental results. The current study provided new insights into the systematic thermal degradation mechanism of IFR, and the proposed kinetic model would be helpful for the thermal protection prediction for steel structure during fire.</div></div>","PeriodicalId":14236,"journal":{"name":"International Journal of Polymer Analysis and Characterization","volume":"29 8","pages":"Pages 635-646"},"PeriodicalIF":1.7,"publicationDate":"2024-11-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142592613","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Mechanical, Thermal, and Water Absorption Behavior of Ash Gourd (Benincasa Hispida) Peel Particles Filled Epoxy Composites 灰葫芦（Benincasa Hispida）果皮颗粒填充环氧树脂复合材料的力学、热学和吸水性能

IF 1.7 4区工程技术

International Journal of Polymer Analysis and Characterization Pub Date : 2024-10-02 Epub Date: 2024-07-24 DOI: 10.1080/1023666X.2024.2378890

Amit Agarwal , Vikas Upadhyay

{"title":"Mechanical, Thermal, and Water Absorption Behavior of Ash Gourd (Benincasa Hispida) Peel Particles Filled Epoxy Composites","authors":"Amit Agarwal , Vikas Upadhyay","doi":"10.1080/1023666X.2024.2378890","DOIUrl":"10.1080/1023666X.2024.2378890","url":null,"abstract":"<div><div>Recently, bio-composites have attracted much attention due to their potential applications in various industries. The most notable benefits are the product’s low cost, biodegradability, lightweight, availability, and ability to solve environmental issues. The present research utilizes ash gourd (<em>Benincasa hispida</em>) peel, a food waste, as a filler material to produce epoxy (EP) composites. The effect of ash gourd peel particle percentage (ranging from 0 to 25 wt.%) was studied on the developed composites’ mechanical and thermal properties and water absorption behavior. The maximum tensile strength, flexural strength, and shore D hardness were 47.52 MPa, 2409.17 MPa, and 79.6respectively, when the ash gourd peel was 5% by weight in the composite. It was observed that the mechanical characteristics of manufactured bio-composites are negatively affected by the high concentration of ash gourd peel particles in the epoxy matrix. Also, increasing ash gourd peel particle fraction increases the water absorption of composites when immersed in distilled, sea, and tap water. The composite with 5% filler by weight absorbs water at a minimal rate when immersed in seawater. Thermogravimetric analysis was conducted to investigate the newly developed composite’s thermal behavior. In addition, a morphological examination of the fractured surfaces was carried out with assistance from a scanning electron microscope. The work presents ash gourd peel particles as the potential alternative to be used as filler in composites.</div></div>","PeriodicalId":14236,"journal":{"name":"International Journal of Polymer Analysis and Characterization","volume":"29 7","pages":"Pages 465-477"},"PeriodicalIF":1.7,"publicationDate":"2024-10-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141807387","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Micromechanical modeling, thermal, and dielectric studies of poly (methyl methacrylate)-barium titanate composites 聚（甲基丙烯酸甲酯）-钛酸钡复合材料的微机械建模、热和介电研究

IF 1.7 4区工程技术

International Journal of Polymer Analysis and Characterization Pub Date : 2024-10-02 Epub Date: 2024-08-17 DOI: 10.1080/1023666X.2024.2391802

K. Umashankar , G. Kamala Vasanth , R. Krishna Prasad

{"title":"Micromechanical modeling, thermal, and dielectric studies of poly (methyl methacrylate)-barium titanate composites","authors":"K. Umashankar , G. Kamala Vasanth , R. Krishna Prasad","doi":"10.1080/1023666X.2024.2391802","DOIUrl":"10.1080/1023666X.2024.2391802","url":null,"abstract":"<div><div>Polymer composites containing poly (methyl methacrylate) (PMMA) and barium titanate (BaTiO<sub>3</sub>) were synthesized using the solution mixing method. The electrical conductivity of PMMA is 6 × 10<sup>−9</sup> S/cm, and adding 2% fillers reduces to 5 × 10<sup>−9</sup> S/cm. The melting point of PMMA is 373 °C, and adding 2% and 4% fillers increased it to 376 °C and 379 °C, respectively. The polymer chains become less mobile and block macromolecules on the filler surface. The modulus of elasticity and mechanical tensile stress of the polymer composites with a 5-wt% of BaTiO<sub>3</sub> are 759.3 MPa and 75.6 MPa, respectively. The breakdown strength of PMMA is 203 KV and reduces with the addition of 5% filler to 144 KV. The values of <em>E c</em>/<em>E m</em> evaluated using the Tsai-Pagano, Christensen-Waals, ROM, Mori-Tanaka, and Halpin-Tsai models underpredict the modulus compared to experimental <em>E c</em>/<em>E m</em> values. Fourier spectroscopy confirmed the presence of Ti-O and BaTiO<sub>3</sub> bonds in the polymer composite. Scanning electron microscope images reveal spherical aggregates of BaTiO<sub>3</sub> coated with PMMA and an interparticle network. The dielectric constant of PMMA is 3 and increased with the addition of 2% and 4% fillers to 4 and 4.3, respectively.</div></div>","PeriodicalId":14236,"journal":{"name":"International Journal of Polymer Analysis and Characterization","volume":"29 7","pages":"Pages 521-532"},"PeriodicalIF":1.7,"publicationDate":"2024-10-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142359454","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Enhanced performance in a NASICON-incorporated solid polymer electrolyte 性能增强的 NASICON 掺杂固体聚合物电解质

IF 1.7 4区工程技术

International Journal of Polymer Analysis and Characterization Pub Date : 2024-10-02 Epub Date: 2024-08-07 DOI: 10.1080/1023666X.2024.2383460

Dharmendra Kumar , Shweta Mukherjee , Avirup Das

{"title":"Enhanced performance in a NASICON-incorporated solid polymer electrolyte","authors":"Dharmendra Kumar , Shweta Mukherjee , Avirup Das","doi":"10.1080/1023666X.2024.2383460","DOIUrl":"10.1080/1023666X.2024.2383460","url":null,"abstract":"<div><div>In the present work, a novel ‘doped ceramic-polymer composite’-based solid polymer electrolytes (SPEs) has been synthesized using Zr (LAZTP) and Nb (LANbTP)-doped LATP as a ceramic filler and polyacrylonitrile (PAN) as a host polymer via the solution cast method. A series of SPEs with different ceramic loadings ranging from 10, 20, 30, 40, and 80 wt. % have been investigated using XRD, SEM, and impedance analysis. XRD spectra show the presence of crystalline ceramic peaks in composite solid polymer electrolyte. Further, the homogeneous distribution of the filler has been confirmed by SEM images. For SPEs, the highest conductivity of 5.31 × 10<sup>−5</sup> S cm<sup>−1</sup> has been obtained for PAN + LANbTP30 at room temperature. Whereas, the optimized conductivity for LATP-incorporated PAN shows 1.79 × 10<sup>−5</sup> S cm<sup>−1</sup>, and the LAZTP-incorporated sample shows a conductivity of 3.03 × 10<sup>−5</sup> S cm<sup>−1</sup> at room temperature. Also, LANbTP-contained SPE shows excellent voltage stability of 4.90 V w.r.t. pure PAN.</div></div>","PeriodicalId":14236,"journal":{"name":"International Journal of Polymer Analysis and Characterization","volume":"29 7","pages":"Pages 573-587"},"PeriodicalIF":1.7,"publicationDate":"2024-10-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141926439","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Fabrication, structure and optical characteristics of CuO/polymer nanocomposites materials for optical devices 用于光学设备的氧化铜/聚合物纳米复合材料的制备、结构和光学特性

IF 1.7 4区工程技术

International Journal of Polymer Analysis and Characterization Pub Date : 2024-10-02 Epub Date: 2024-09-06 DOI: 10.1080/1023666X.2024.2397392

B. M. Alotaibi , Reem Altuijri , A. Atta , E. Abdeltwab , M. M. Abdelhamied

{"title":"Fabrication, structure and optical characteristics of CuO/polymer nanocomposites materials for optical devices","authors":"B. M. Alotaibi , Reem Altuijri , A. Atta , E. Abdeltwab , M. M. Abdelhamied","doi":"10.1080/1023666X.2024.2397392","DOIUrl":"10.1080/1023666X.2024.2397392","url":null,"abstract":"<div><div>The films of P(4ClAni)/CuO, which formed of mixing poly 4-chloroaniline P(4ClAni) by CuO, were fabricated by the casting solution method. The XRD confirmed the successful prepration of the P(4ClAni)/CuO films. Additionally, the effect of CuO on the optical characteristics was determined. The CuO increased the refractive index from 1.09 for P(4ClAni) to 1.11 for P(4ClAni)/CuO-1, and 1.19 for P(4ClAni)/CuO-3, respectively, while the oscillation energy E<sub>0</sub> dropped from 4.29 eV for P(4ClAni) to 3.57 eV for P(4ClAni)/CuO-1, 3.12 eV for P(4ClAni)/CuO-2, and 3.06 eV for P(4ClAni)/CuO-3. The charge transfer between P(4ClAni) and CuO increased optical conductivity as the CuO ratios increased. This suggests that modifications in the electronic structure of the composite due to the interactions between P(4ClAni) and CuO. Also, the plasma frequency increased from 0.87 x 10<sup>12</sup> s<sup>−1</sup> to 2.32 x 10<sup>12</sup> s<sup>−1</sup>. These changes in optical parameters occurred when the polarization of the P(4ClAni)/CuO was altered. The study elucidated the advantages of incorporating CuO nanoparticles as fillers in improving the properties of P(4ClAni) structures. The obtained results indicate the P(4ClAni)/CuO composites were sucessfuly fabricated with novel characteristics that can be applied in flexible optical devices.</div></div>","PeriodicalId":14236,"journal":{"name":"International Journal of Polymer Analysis and Characterization","volume":"29 7","pages":"Pages 562-572"},"PeriodicalIF":1.7,"publicationDate":"2024-10-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142359456","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Effect of heat treatment on charge states, thermophysical and mechanical properties of polypropylene doped with ZrO2 nanoparticles 热处理对掺杂 ZrO2 纳米粒子的聚丙烯的电荷状态、热物理性能和机械性能的影响

IF 1.7 4区工程技术

International Journal of Polymer Analysis and Characterization Pub Date : 2024-10-02 Epub Date: 2024-08-10 DOI: 10.1080/1023666X.2024.2387605

Hijran S. Ibrahimova , Tahir D. Ibragimov

{"title":"Effect of heat treatment on charge states, thermophysical and mechanical properties of polypropylene doped with ZrO2 nanoparticles","authors":"Hijran S. Ibrahimova , Tahir D. Ibragimov","doi":"10.1080/1023666X.2024.2387605","DOIUrl":"10.1080/1023666X.2024.2387605","url":null,"abstract":"<div><div>Charge states, thermophysical and mechanical properties of polypropylene doped with zirconium oxide nanoparticles, and their changes during heat treatment at temperatures 60 °C, 100 °C, and 140 °C are studied. The methods used are thermal stimulated depolarization (TSD), scanning differential calorimetry (SDC), and mechanical life assessment. It is shown that with an increase in the concentration of the filler, the intensity of the TSD peaks increases up to 3 vol.%. A further increase in concentration leads to a decrease in the intensity of the peaks. The activation energy of charge release from traps, temperature of maximum of the peaks, and the magnitude of the accumulated charge in the traps have also maximal value at nanoparticle concentration of 3 vol.%. The study of charge characteristics of the nanocomposite with concentration of 3 vol.% after heat treatment shows that the intensity of TSD peaks, the temperature of peak maxima, and the activation energy of charge release increase with increasing pretreatment temperature. The magnitude of the charge accumulated in traps has a maximal value at treatment temperature of 140 °C owing to the increase in the number of traps. The melting point of the composite is 149.38 °C and shifts to 146.88 °C after heat treatment at 140 °C. It indicates that the high temperature of heat treatment leads to partial destruction of polymer chains, leading to a decrease in the critical melting temperature. The mechanical durability of PP + 3%ZrO<sub>2</sub> nanocomposite decreases with increase in pretreatment temperature.</div></div>","PeriodicalId":14236,"journal":{"name":"International Journal of Polymer Analysis and Characterization","volume":"29 7","pages":"Pages 508-520"},"PeriodicalIF":1.7,"publicationDate":"2024-10-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141943869","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0