{"title":"通过电离辐射固化三元乙丙橡胶/水泥窑灰复合材料的机械和热性能比较研究","authors":"Ehab E. Khozemy , Shaimaa M. Nasef , H. Radi","doi":"10.1080/1023666X.2024.2360855","DOIUrl":null,"url":null,"abstract":"<div><p>In this work, cement kiln dust (CKD) will be studied as an unconventional filler for ethylene-propylene-diene terpolymer (EPDM) rubber as an alternative to silica, which is widely used as filler for many types of rubber. (EPDM)/CKD rubber composites were fabricated using ionizing radiation. EPDM rubber was blended with different portions of cement-kiln dust 5, 10, 15, 20, 25, and 30 phr (phr = parts per hundred rubber). The prepared composites were cured by exposing to different doses of gamma rays up to 150 kGy to enhance the crosslinking of the EPDM rubber. The thermo-mechanical properties of the EPDM/CKD and EPDM/Si composites were investigated as a function of irradiation dose. The results showed a significant improvement in elongation and tensile strength by incorporating cement dust into EPDM rubber up to 20 phr, which is not significantly different from composites incorporated with silica. Gamma irradiation significantly improved the properties of all formulations.</p></div>","PeriodicalId":14236,"journal":{"name":"International Journal of Polymer Analysis and Characterization","volume":"29 5","pages":"Pages 282-299"},"PeriodicalIF":1.7000,"publicationDate":"2024-07-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"A comparative study of the mechanical and thermal properties of EPDM rubber/cement kiln dust composite cured by ionizing radiation\",\"authors\":\"Ehab E. Khozemy , Shaimaa M. Nasef , H. Radi\",\"doi\":\"10.1080/1023666X.2024.2360855\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>In this work, cement kiln dust (CKD) will be studied as an unconventional filler for ethylene-propylene-diene terpolymer (EPDM) rubber as an alternative to silica, which is widely used as filler for many types of rubber. (EPDM)/CKD rubber composites were fabricated using ionizing radiation. EPDM rubber was blended with different portions of cement-kiln dust 5, 10, 15, 20, 25, and 30 phr (phr = parts per hundred rubber). The prepared composites were cured by exposing to different doses of gamma rays up to 150 kGy to enhance the crosslinking of the EPDM rubber. The thermo-mechanical properties of the EPDM/CKD and EPDM/Si composites were investigated as a function of irradiation dose. The results showed a significant improvement in elongation and tensile strength by incorporating cement dust into EPDM rubber up to 20 phr, which is not significantly different from composites incorporated with silica. Gamma irradiation significantly improved the properties of all formulations.</p></div>\",\"PeriodicalId\":14236,\"journal\":{\"name\":\"International Journal of Polymer Analysis and Characterization\",\"volume\":\"29 5\",\"pages\":\"Pages 282-299\"},\"PeriodicalIF\":1.7000,\"publicationDate\":\"2024-07-03\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"International Journal of Polymer Analysis and Characterization\",\"FirstCategoryId\":\"5\",\"ListUrlMain\":\"https://www.sciencedirect.com/org/science/article/pii/S1023666X24000192\",\"RegionNum\":4,\"RegionCategory\":\"工程技术\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q4\",\"JCRName\":\"POLYMER SCIENCE\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"International Journal of Polymer Analysis and Characterization","FirstCategoryId":"5","ListUrlMain":"https://www.sciencedirect.com/org/science/article/pii/S1023666X24000192","RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"POLYMER SCIENCE","Score":null,"Total":0}
A comparative study of the mechanical and thermal properties of EPDM rubber/cement kiln dust composite cured by ionizing radiation
In this work, cement kiln dust (CKD) will be studied as an unconventional filler for ethylene-propylene-diene terpolymer (EPDM) rubber as an alternative to silica, which is widely used as filler for many types of rubber. (EPDM)/CKD rubber composites were fabricated using ionizing radiation. EPDM rubber was blended with different portions of cement-kiln dust 5, 10, 15, 20, 25, and 30 phr (phr = parts per hundred rubber). The prepared composites were cured by exposing to different doses of gamma rays up to 150 kGy to enhance the crosslinking of the EPDM rubber. The thermo-mechanical properties of the EPDM/CKD and EPDM/Si composites were investigated as a function of irradiation dose. The results showed a significant improvement in elongation and tensile strength by incorporating cement dust into EPDM rubber up to 20 phr, which is not significantly different from composites incorporated with silica. Gamma irradiation significantly improved the properties of all formulations.
期刊介绍：
The scope of the journal is to publish original contributions and reviews on studies, methodologies, instrumentation, and applications involving the analysis and characterization of polymers and polymeric-based materials, including synthetic polymers, blends, composites, fibers, coatings, supramolecular structures, polysaccharides, and biopolymers. The Journal will accept papers and review articles on the following topics and research areas involving fundamental and applied studies of polymer analysis and characterization:
Characterization and analysis of new and existing polymers and polymeric-based materials.
Design and evaluation of analytical instrumentation and physical testing equipment.
Determination of molecular weight, size, conformation, branching, cross-linking, chemical structure, and sequence distribution.
Using separation, spectroscopic, and scattering techniques.
Surface characterization of polymeric materials.
Measurement of solution and bulk properties and behavior of polymers.
Studies involving structure-property-processing relationships, and polymer aging.
Analysis of oligomeric materials.
Analysis of polymer additives and decomposition products.
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